Impact of drying on geo-environmental properties of mature fine tailings pre-dewatered with super absorbent polymer     

A. Roshani  M. Fall  K. Kennedy 《International Journal of Environmental Science and Technology》2017,14(3):453-462

Oil sand operations in Alberta generate a large amount of waste tailings in the form of slurry that is rich with fine particles. The surface disposal of this waste has created several environmental problems. Furthermore, strict governmental regulations on the disposal of such a huge amount of waste called mature fine tailing in tailing ponds have compelled the industry to develop new techniques that are more sustainable and environmentally friendly. Hence, in this study, a new technique that uses a super absorbent polymer to dewater mature fine tailings is investigated by adding 1% by weight polymer to the mature fine tailings. The pre-dewatered mature fine tailings are then exposed to evaporation and the results in terms of changes to the volumetric water content, electrical conductivity, geochemistry, microstructure and permeability are reported. The volumetric water content and electrical conductivity have the same behavior such that as the water content decreases, the electrical conductivity also decreases. In term of changes to the chemistry, the super absorbent polymer reduces the ion concentration of the pore water with uptake of the major cations in its polymer chains. Scanning electron microscopy shows that there is a more compacted clay matrix in the pre-dewatered mature fine tailings as opposed to the raw material. Hence, with further restriction of flow in the pre-dewatering of mature fine tailings with the super absorbent polymer, the hydraulic conductivity is also reduced.  相似文献   

A Pilot Tsunami Inundation Forecast System for Australia     

Stewart C. R. Allen  Diana J. M. Greenslade 《Pure and Applied Geophysics》2016,173(12):3955-3971

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Granitic coastal geomorphology: applying integrated terrestrial and bathymetric LiDAR with multibeam sonar to examine coastal landscape evolution          下载免费PDF全文

David M. Kennedy  Daniel Ierodiaconou  Alexandre Schimel 《地球表面变化过程与地形》2014,39(12):1663-1674

Coasts composed of resistant lithologies such as granite are generally highly resistant to erosion. They tend to evolve over multiple sea level cycles with highstands acting to remove subaerially weathered material. This often results in a landscape dominated by plunging cliffs with shore platforms rarely occurring. The long‐term evolution of these landforms means that throughout the Quaternary these coasts have been variably exposed to different sea level elevations which means erosion may have been concentrated at different elevations from today. Investigations of the submarine landscape of granitic coasts have however been hindered by an inability to accurately image the nearshore morphology. Only with the advent of multibeam sonar and aerial laser surveying can topographic data now be seamlessly collected from above and below sea level. This study tests the utility of these techniques and finds that very accurate measurements can be made of the nearshore thereby allowing researchers to study the submarine profile with the same accuracy as the subaerial profile. From a combination of terrestrial and marine LiDAR data with multibeam sonar data, it is found that the morphology of granite domes is virtually unaffected by erosion at sea level. It appears that evolution of these landscapes on the coast is a very slow process with modern sea level acting only to remove subaerially weathered debris. The size and orientation of the joints determines the erosional potential of the granite. Where joints are densely spaced (<2 m apart) or the bedrock is highly weathered can semi‐horizontal surfaces form. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Ca-Mg inter-diffusion in synthetic polycrystalline dolomite-calcite aggregate at elevated temperatures and pressure     

Wuu-Liang Huang  Teh-Ching Liu  Pouyan Shen  Allen Hsu 《Mineralogy and Petrology》2009,95(3-4):327-340

This study measures the reaction rate of dolomite and aragonite (calcite) into Mg-calcite at 800, 850, and 900°C and 1.6 GPa. The dry synthetic dolomite-aragonite aggregate transformed very rapidly into dolomite-calcite polycrystalline aggregate while Mg-calcites formed at a relatively slow rate, becoming progressively richer in Mg with run time. We modeled the reaction progress semi-empirically by the first-order rate law. The temperature dependence of the overall transport rate of MgCO₃ into calcite can be described by the kinetic parameters (E?=?231.7 kJ/mol and A _o ?=?22.69 h^?1). Extrapolation using the Arrhenius equation to the conditions during exhumation of UHPM rocks indicates that the reaction of dolomite with aragonite into Mg-saturated calcite can be completed as the P-T path enters the Mg-calcite stability field in a geologically short time period (<1 Ky). On the other hand, the extrapolation of the rate to prograde metamorphic conditions reveals that the Mg-calcite formed from dolomitic marble in the absence of metamorphic fluid may not reach Mg-saturation until temperatures corresponding to high-grade metamorphism (e.g., >340°C and >10 My). SEM-EDS analysis of individual calcite grains shows compositional gradients of Mg in the calcite grains. The Mg-Ca inter-diffusion coefficient at 850°C is around 1.68?×?10^?14 m²/sec if diffusion is the major control of the reaction. The calculated closure temperatures for Ca-Mg inter-diffusion as a function of cooling rate and grain size reveal that Ca/Mg resetting in calcite in a dry polycrystalline carbonate aggregate (with grain size around 1 mm) may not occur at temperatures below 480°C at a geological cooling rate around 10°C/My, unless other processes, such as short-circuit interdiffusion along grain boundaries and dislocations, are involved.  相似文献   

Pfiesteria shumwayae (Pfiesteriaceae) in New Zealand     

Lesley L. Rhodes  Joann M. Burkholder  Howard B. Glasgow  Parke A. Rublee  Coy Allen  Janet E. Adamson 《新西兰海洋与淡水研究杂志》2013,47(3):621-630

Pfiesteria shumwayae Steidinger et Burkholder is now known to be present in New Zealand and occurs in estuaries around the country. The presence of Pfiesteria was initially determined by a polymerase chain reaction (PCR)‐based detection assay, using oligonucleotide primers targeted at ribosomal DNA extracted from estuarine water and sediments. Presence was confirmed by isolation from fresh sediments in the presence offish (Oreochromis mossambicus), followed by identification by scanning electron microscopy. The New Zealand isolates of P. shumwayae were ichthyotoxic in bioassays, but there is no historic evidence offish kills in New Zealand associated with the dinoflagellate.  相似文献   

Quantification of Spatial and Thematic Uncertainty in the Application of Underwater Video for Benthic Habitat Mapping     

A. Rattray  J. Monk  L. J. B. Laurenson  P. Kennedy 《Marine Geodesy》2013,36(3):315-336

This study presents an analysis of the application of underwater video data collected for training and validating benthic habitat distribution models. Specifically, we quantify the two major sources of error pertaining to collection of this type of reference data. A theoretical spatial error budget is developed for a positioning system used to co-register video frames to their corresponding locations at the seafloor. Second, we compare interpretation variability among trained operators assessing the same video frames between times over three hierarchical levels of a benthic classification scheme. Propagated error in the positioning system described was found to be highly correlated with depth of operation and varies from 1.5m near the surface to 5.7m in 100m of water. In order of decreasing classification hierarchy, mean overall observer agreement was found to be 98% (range 6%), 82% (range 12%) and 75% (range 17%) for the 2, 4, and 6 class levels of the scheme, respectively. Patterns in between-observer variation are related to the level of detail imposed by each hierarchical level of the classification scheme, the feature of interest, and to the amount of observer experience.  相似文献   

Influence of strong monsoon winds on the water quality around a marine cage-culture zone in a shallow and semi-enclosed bay in Taiwan   总被引：1，自引：0，他引：1  

Huang YC  Huang SC  Meng PJ  Hsieh HJ  Chen CA 《Marine pollution bulletin》2012,64(4):851-860

Influences of marine cage culture and monsoonal disturbances, northeasterly (NE) and southwesterly (SW) monsoons on the proximal marine environment were investigated across a gradient of sites in a semi-enclosed bay, Magong Bay (Penghu Islands, Taiwan). Elevated levels of ammonia produced by the cages were the main pollutant and distinguished the cage-culture and intermediary zones (1000 m away from the cages) from the reference zone in the NE monsoon, indicating currents produced by the strong monsoon may have extended the spread of nutrient-enriched waters without necessarily flushing such effluents outside Magong Bay. Moreover, the levels of chlorophyll-a, dissolved oxygen, and turbidity were distinguishable between two seasons, suggesting that resuspension caused by the NE monsoon winds may also influence the water quality across this bay. It indicated that the impacts of marine cage culture vary as a function of distance, and also in response to seasonal movements of water driven by local climatic occurrences.  相似文献   

Core–mantle boundary topography as a possible constraint on lower mantle chemistry and dynamics     

Teresa Mae Lassak  Allen K. McNamara  Edward J. Garnero  Shijie Zhong 《Earth and Planetary Science Letters》2010,289(1-2):232-241

The origin of large low shear-wave velocity provinces (LLSVPs) in the lowermost mantle beneath the central Pacific and Africa is not well constrained. We explore numerical convection calculations for two proposed hypotheses for these anomalies, namely, thermal upwellings (e.g., plume clusters) and large intrinsically dense piles of mantle material (e.g., thermochemical piles), each of which uniquely affects the topography on Earth's core–mantle boundary (CMB). The thermochemical pile models predict a relatively flat but elevated CMB beneath piles (presumed LLSVPs), with strong upwarping along LLSVP margins. The plume cluster models predict CMB upwarping beneath upwellings that are less geographically organized. Both models display CMB depressions beneath subduction related downwelling. While each of the two models produces a unique, characteristic style of CMB topography, we find that seismic models will require shorter length scales than are currently being employed in order to distinguish between the end-member dynamic models presented here.  相似文献   

Rapidly installed temporary gauging for hurricane waves and surge,and application to Hurricane Gustav     

Andrew B. Kennedy  Uriah Gravois  Brian Zachry  Rick Luettich  Tony Whipple  Robert Weaver  Janelle Reynolds-Fleming  Qin J. Chen  Roni Avissar 《Continental Shelf Research》2010

Hurricanes can produce extreme nearshore waves and surge, but permanent gauging stations are often much sparser than is desired. This paper describes the rationale behind and outline for rapidly installed temporary coastal gauges, and presents results during Hurricane Gustav (2008). Within 48 h prior to landfall, twenty self-recording pressure gauges were deployed in depths of 1.4–23 m over more than 700 km of coastline, using helicopters to cover the large distances. Results showed a complex picture that was strongly dependent on location. East of the Mississippi Delta, open coast waves were large, and surge reached 3.8 m NAVD88 in marshes. West of the delta but near landfall, waves and surge were generally smaller as the river levees blocked flow from East to West. West of landfall, both waves and surge were very small and the most prominent feature was a water level drawdown that reached 1.5 m. Wave spectra varied strongly depending both on location and time from landfall.  相似文献   

Black–White and Hispanic–White Segregation in U.S. Counties     

James P. Allen  Eugene Turner 《The Professional geographer》2013,65(4):503-520

Residential segregation in metropolitan areas has been the subject of much research, but this article analyzes patterns of white–black and white–Hispanic segregation in counties across the United States. Our purpose was to understand county variations in this one dimension of inequality. Conceiving of segregation as relative inequality of access to neighborhood resources, we measured segregation in 2000 by the index of dissimilarity (D) calculated by blocks, mapped the index values, and correlated them with census variables. Three filters enabled us to eliminate counties with characteristics that could have corrupted the analyses, leaving us with more than 1,000 counties in each analysis. Both minority groups were less segregated from whites in the West and South and in metropolitan counties. Lower segregation was strongly associated with higher minority socioeconomic status and higher percentages of minorities living in housing built in the 1990s, and Hispanic–white segregation was lower where more Hispanics were U.S.-born or English proficient. The racial threat hypothesis was supported only weakly and inconsistently. Mapping made it possible to identify regional and local patterns of high and low segregation as well as the lower segregation of suburban counties in some large metropolitan areas.  相似文献