Isotopic composition of gas hydrates in subsurface sediments from offshore Sakhalin Island, Sea of Okhotsk   总被引：1，自引：1，他引：0  

Akihiro Hachikubo  Alexey Krylov  Hirotoshi Sakagami  Hirotsugu Minami  Yutaka Nunokawa  Hitoshi Shoji  Tatiana Matveeva  Young K. Jin  Anatoly Obzhirov 《Geo-Marine Letters》2010,30(3-4):313-319

Hydrate-bearing sediment cores were retrieved from recently discovered seepage sites located offshore Sakhalin Island in the Sea of Okhotsk. We obtained samples of natural gas hydrates and dissolved gas in pore water using a headspace gas method for determining their molecular and isotopic compositions. Molecular composition ratios C₁/_C2+ from all the seepage sites were in the range of 1,500–50,000, while δ¹³C and δD values of methane ranged from ?66.0 to ?63.2‰ VPDB and ?204.6 to ?196.7‰ VSMOW, respectively. These results indicate that the methane was produced by microbial reduction of CO₂. δ¹³C values of ethane and propane (i.e., ?40.8 to ?27.4‰ VPDB and ?41.3 to ?30.6‰ VPDB, respectively) showed that small amounts of thermogenic gas were mixed with microbial methane. We also analyzed the isotopic difference between hydrate-bound and dissolved gases, and discovered that the magnitude by which the δD hydrate gas was smaller than that of dissolved gas was in the range 4.3–16.6‰, while there were no differences in δ¹³C values. Based on isotopic fractionation of guest gas during the formation of gas hydrate, we conclude that the current gas in the pore water is the source of the gas hydrate at the VNIIOkeangeologia and Giselle Flare sites, but not the source of the gas hydrate at the Hieroglyph and KOPRI sites.  相似文献   

The evolution of eccentricity in the eclipsing binary system AS Camelopardalis     

Valentina Kozyreva  Anatoly Kusakin  Alexey Bogomazov 《天文和天体物理学研究(英文版)》2018,(1)

In 2002,2004 and 2017 we conducted high precision CCD photometry observations of the eclipsing binary system AS Cam.By analysis of the light curves from 1967 to 2017(our data + data from the literature) we obtained photometric elements of the system and found a change in the system's orbital eccentricity of ?e = 0.03 ± 0.01.This change can indicate that there is a third companion in the system in a highly inclined orbit with respect to the orbital plane of the central binary,and its gravitational influence may cause the discrepancy between observed and theoretical apsidal motion rates of AS Cam.  相似文献   

Kobyashevite, Cu5(SO4)2(OH)6·4H2O, a new devilline-group mineral from the Vishnevye Mountains, South Urals, Russia     

Igor V. Pekov  Natalia V. Zubkova  Vasiliy O. Yapaskurt  Dmitriy I. Belakovskiy  Nikita V. Chukanov  Anatoly V. Kasatkin  Aleksey M. Kuznetsov  Dmitry Y. Pushcharovsky 《Mineralogy and Petrology》2013,107(2):201-210

A new mineral kobyashevite, Cu₅(SO₄)₂(OH)₆·4H₂O (IMA 2011–066), was found at the Kapital’naya mine, Vishnevye Mountains, South Urals, Russia. It is a supergene mineral that occurs in cavities of a calcite-quartz vein with pyrite and chalcopyrite. Kobyashevite forms elongated crystals up to 0.2 mm typically curved or split and combined into thin crusts up to 1?×?2 mm. Kobyashevite is bluish-green to turquoise-coloured. Lustre is vitreous. Mohs hardness is 2½. Cleavage is {010} distinct. D(calc.) is 3.16 g/cm³. Kobyashevite is optically biaxial (?), α 1.602(4), β 1.666(5), γ 1.679(5), 2 V(meas.) 50(10)°. The chemical composition (wt%, electron-microprobe data) is: CuO 57.72, ZnO 0.09, FeO 0.28, SO₃ 23.52, H₂O(calc.) 18.39, total 100.00. The empirical formula, calculated based on 18 O, is: Cu_4.96Fe_0.03Zn_0.01S_2.01O_8.04(OH)_5.96·4H₂O. Kobyashevite is triclinic, $ P\overline{\,1 } $ , a 6.0731(6), b 11.0597(13), c 5.5094(6)?Å, α 102.883(9)°, β 92.348(8)°, γ 92.597(9)°, V 359.87(7)?ų, Z?=?1. Strong reflections of the X-ray powder pattern [d,Å-I(hkl)] are: 10.84–100(010); 5.399–40(020); 5.178–12(110); 3.590–16(030); 2.691–16(20–1, 040, 002), 2.653–12(04–1, 02–2), 2.583–12(2–11, 201, 2–1–1), 2.425–12(03–2, 211, 131). The crystal structure (single-crystal X-ray data, R?=?0.0399) сontains [Cu₄(SO₄)₂(OH)₆] corrugated layers linked via isolated [CuO₂(H₂O)₄] octahedra; the structural formula is CuCu₄(SO₄)₂(OH)₆·4H₂O. Kobyashevite is a devilline-group member. It is named in memory of the Russian mineralogist Yuriy Stepanovich Kobyashev (1935–2009), a specialist on mineralogy of the Urals.  相似文献   

Seasonal variability of element fluxes in two Central Siberian rivers draining high latitude permafrost dominated areas     

Marie-Laure Bagard  François Chabaux  Oleg S. Pokrovsky  Anatoly S. Prokushkin  Sophie Rihs  Bernard Dupré 《Geochimica et cosmochimica acta》2011,75(12):3335-3357

In order to constrain the origin and fluxes of elements carried by rivers of high latitude permafrost-dominated areas, major and trace element concentrations as well as Sr and U isotopic ratios were analyzed in the dissolved load of two Siberian rivers (Kochechum and Nizhnyaya Tunguska) regularly sampled over two hydrological cycles (2005-2007). Large water volumes of both rivers were also collected in spring 2008 in order to perform size separation through dialysis experiments. This study was completed by spatial sampling of the Kochechum watershed carried out during summer and by a detailed analysis of the main hydrological compartments of a small watershed. From element concentration variations along the hydrological cycle, different periods can be marked out, matching hydrological periods. During winter baseflow period (October to May) there is a concentration increase for major soluble cations and anions by an order of magnitude. The spring flood period (end of May-beginning of June) is marked by a sharp concentration decrease for soluble elements whereas dissolved organic carbon and insoluble element concentrations strongly increase.When the spring flood discharge occurs, the significant increase of aluminum and iron concentrations is related to the presence of organo-mineral colloids that mobilize insoluble elements. The study of colloidal REE reveals the occurrence of two colloid sources successively involved over time: spring colloids mainly originate from the uppermost organic-rich part of soils whereas summer colloids rather come from the deep mineral horizons. Furthermore, U and Sr isotopic ratios together with soluble cation budgets in the Kochechum river impose for soluble elements the existence of three distinct fluxes over the year: (a) at the spring flood a surface flux coming from the leaching of shallow organic soil levels and containing a significant colloidal component (b) a subsurface flux predominant during summer and fall mainly controlled by water-rock interactions within mineral soils and (c) a deep groundwater flux predominant during winter which enters large rivers through unfrozen permafrost-paths. Detailed study of the Kochechum watershed suggests that the contribution of this deep flux strongly depends on the depth and continuous nature of the permafrost.  相似文献   

A multi-method approach to dating middle and late Quaternary high relative sea-level events on NW Svalbard – A case study     

Helena Alexanderson  Jon Y. Landvik  Anatoly Molodkov  Andrew S. Murray 《Quaternary Geochronology》2011,6(3-4):326-340

Waxing and waning ice sheets and changing sea levels have been interpreted from the Quaternary stratigraphic record at Leinstranda, Brøggerhalvøya in NW Svalbard. We have identified seven high relative sea-level events, related to glacio-isostatic loading, and separated by at least four glacial events. To establish a chronology for the high sea-level events (interstadials and interglacials) and the intervening glaciations, we have used three different absolute dating methods: optically stimulated luminescence (OSL) of shallow marine deposits, and electron spin resonance (ESR) and radiocarbon (AMS-¹⁴C) dating of fossils contained in these sediments. Of the absolute dating methods, OSL has provided the stratigraphically most consistent dataset and which also matches a biostratigraphically inferred interglacial. The ESR ages of mollusc shells suffer from low precision due to unusually large uranium content in most dated shell samples, which in turn is most likely a result of significant recent uranium enrichment of the sediments. Most radiocarbon ages are non-finite. The results show that the high relative sea-level events range in age from the Saalian sensu lato (≥Marine Isotope Stage, MIS, 6) to the early Holocene (MIS 1), and include events OSL-dated to 185 ± 8 ka, 129 ± 10 ka, 99 ± 8 ka and 36 ± 3 ka. The methods used by us and by previous investigators of the same site are compared and assessed, and sources of error, accuracy and precision of ages are discussed.  相似文献   

高压脉冲放电技术成桩法          下载免费PDF全文

李冬霜  王茂森  А.Ю.Юшков 《探矿工程》2011,38(4):78-79

主要介绍了高压脉冲放电技术的发展现状、成桩机理、成桩特点以及成桩的新工艺。该成桩方法具有高的承载能力和经济效益,具有其它桩所不具有的优点。还对其成桩技术的应用前景进行了展望。  相似文献   

Variation Trend and Characteristics of Anthropogenic CO Column Content in the Atmosphere over Beijing and Moscow          下载免费PDF全文

WANG Pu-Cai  Georgy S.GOLITSYN  WANG Geng-Chen  Evgeny I.GRECHKO  Vadim S.RAKITIN  Ekaterina V.FOKEEVA  Anatoly V.DZHOLA 《大气和海洋科学快报》2014,(3):243-247

The anthropogenic CO column content in the atmosphere is derived from measurements with infrared grating spectrometers in Beijing, China, and Moscow, Russia, during 1992-2012. Some specific variation char- acteristics and long-term variation trends of the CO col- umn content in the atmosphere in these regions are dis- cussed. An evident variation trend of anthropogenic CO in the atmosphere for the Beijing region is not observed during 1992-2012, while for the Moscow region, it de- creases yearly by about 1.4% for the same period. High CO concentrations appear quite frequently in Beijing, but much less frequently in Moscow, except during the natu- ral fire events in summer 2010. From back trajectory analysis, the high CO concentration observed in Beijing can be attributed to the intensive CO emission sources in its surrounding areas.  相似文献   

Secular bar formation in galaxies with a significant amount of dark matter     

Octavio Valenzuela  Anatoly Klypin 《Monthly notices of the Royal Astronomical Society》2003,345(2):406-422

  相似文献   

Profiles of dark haloes: evolution, scatter and environment     

J. S. Bullock  T. S. Kolatt  Y. Sigad  R. S. Somerville  A. V. Kravtsov  †  A. A. Klypin  J. R. Primack  A. Dekel 《Monthly notices of the Royal Astronomical Society》2001,321(3):559-575

  相似文献   

Tectonics of Venus: A review     

Nikishin  Anatoly M. 《Earth, Moon, and Planets》1990,(1):101-125

The article presents a new tectonic scheme of Venus and gives the following interpretation of the planet's main structural units: (1) plains — areas of flood volcanism over stretched crust; (2) dome-like uplifts — areas of uplifting and volcanic activity above the mantle hot-spots; (3) coronae —former dome-like uplifts, partially subsided and diffused by gravity; (4) ridge belts — fold zones; (5) tesserae — fragments of ductile compression and shortening of crust; (6) supercoronae — coronae formed in the course of further evolution and relaxation of Beta-type uplifts. Ishtar Terra is considered to be a fragment of an ancient tessera paleocontinent, on the edge of which the Lakshmi supercorona is superimposed. Aphrodite Terra is considered as a belt of mantle hot-spot structures (dome-like uplifts, coronae, supercoronae, volcanoes, rifts).Three types of planetary belts have been distinguished on Venus: uplifted 'weakened' belts with an abundance of mantle hot-spot structures; a northern fan of ridge belts; and belts of low basalt plains. The center of the planetary system of uplifted weakened belts is situated in Atla Regio.The present tectonic structure of Venus is inferred to have formed during two stages of evolution characterized by different tectonic regimes. Stage I is a regime of soft ductile plates (formation of tessera uplifts and volcanic plains). Stage II is a formation of 'weakened' uplifted planetary belts, various tectonic regimes of mantle hot-spots, and plains-forming volcanism.'Geology and Tectonics of Venus', special issue edited by Alexander T. Basilevsky (USSR Acad. of Sci. Moscow), James W. Head (Brown University, Providence), Gordon H. Pettengill (MIT, Cambridge, Massachusetts) and R. S. Saunders (J.P.L., Pasadena).  相似文献