Distribution of aliphatic amines in CO,CV, and CK carbonaceous chondrites and relation to mineralogy and processing history          下载免费PDF全文

José C. Aponte  Neyda M. Abreu  Daniel P. Glavin  Jason P. Dworkin  Jamie E. Elsila 《Meteoritics & planetary science》2017,52(12):2632-2646

The analysis of water‐soluble organic compounds in meteorites provides valuable insights into the prebiotic synthesis of organic matter and the processes that occurred during the formation of the solar system. We investigated the concentration of aliphatic monoamines present in hot acid water extracts of the unaltered Antarctic carbonaceous chondrites, Dominion Range (DOM) 08006 (CO3) and Miller Range (MIL) 05013 (CO3), and the thermally altered meteorites, Allende (CV3), LAP 02206 (CV3), GRA 06101 (CV3), Allan Hills (ALH) 85002 (CK4), and EET 92002 (CK5). We have also reviewed and assessed the petrologic characteristics of the meteorites studied here to evaluate the effects of asteroidal processing on the abundance and molecular distributions of monoamines. The CO3, CV3, CK4, and CK5 meteorites studied here contain total concentrations of amines ranging from 1.2 to 4.0 nmol g^?1 of meteorite; these amounts are 1–3 orders of magnitude below those observed in carbonaceous chondrites from the CI, CM, and CR groups. The low‐amine abundances for CV and CK chondrites may be related to their extensive degree of thermal metamorphism and/or to their low original amine content. Although the CO3 meteorites, DOM 08006 and MIL 05013, do not show signs of thermal and aqueous alteration, their monoamine contents are comparable to those observed in moderately/extensively thermally altered CV3, CK4, and CK5 carbonaceous chondrites. The low content of monoamines in pristine CO carbonaceous chondrites suggests that the initial amounts, and not asteroidal processes, play a dominant role in the content of monoamines in carbonaceous chondrites. The primary monoamines, methylamine, ethylamine, and n‐propylamine constitute the most abundant amines in the CO3, CV3, CK4, and CK5 meteorites studied here. Contrary to the predominance of n‐ω‐amino acid isomers in CO3 and thermally altered meteorites, there appears to be no preference for the larger n‐amines.  相似文献   

Diel and seasonal variability in the fish community structure of a mud‐bottom estuarine habitat in the Gulf of Mexico     

Manuel Castillo‐Rivera  Rocío Zárate‐Hernández  Selene Ortiz‐Burgos  José Zavala‐Hurtado 《Marine Ecology》2010,31(4):633-642

We hypothesized that temporal variation in fish species composition and community structure in a low complexity habitat in the Pueblo Viejo Lagoon, Mexico, is influenced by diel light/dark cycles and tidal stage, and by seasonal changes in salinity and temperature. We collected a total of 17,661 individuals during 2‐h interval sampling over six bi‐monthly 24‐h sampling cycles representing 53 species, of which 11 (～20%) were previously unknown in the system. Diel variation indicated that significantly higher numbers of individuals and species were caught at night, whereas diversity and evenness were higher during the day. Species richness was significantly higher in July and January, whereas diversity and evenness peaked around May; both were correlated with temperature. Diel variation in species composition was influenced primarily by the light/dark cycle. Cluster analyses of each diel cycle separated fish assemblages from midday samples from those of nocturnal samples, separated by an extended wide transition period as fish moved at dawn and during the late afternoon/dusk. Significant shifts (as determined by MANOVA) in assemblage structure occurred between months. Canonical correspondence analysis showed that temperature and day/night effects were the most important environmental variables structuring the fish community. This constrained ordination also defined species with specific habitat preferences as follows: (i) diurnal, warm temperature species (mainly planktivores) (Brevoortia gunteri, Cetengraulis edentulus, Diapterus auratus, and Membras martinica); (ii) nocturnal, warm temperature species (mainly predators) (Citharichthys spilopterus, Cathorops melanopus, and Bairdiella spp.); and (iii) low temperature, diurnal species (Brevoortia patronus and Mugil curema) or those with twilight and nocturnal distributions (Anchoa mitchilli, the most numerically abundant species). Our results indicate that diel and seasonal changes in fish community structure were mainly related to day/night cycles and temperature regimes.  相似文献   

Chemical signature of intermediate water masses along western Portuguese margin     

Graça Cabeçadas  M. José Brogueira  M. Gelena Cavaco  Célia Gonçalves 《Journal of Oceanography》2010,66(2):201-210

Although the circulation of intermediate water masses in the eastern North Atlantic remains poorly defined, the presence of fresher intermediate waters, the Sub-Artic (SAIW) and the Antarctic Intermediate Water (AAIW), as well the saline intermediate Mediterranean Water (MW), has been tracked using biogeochemical properties. Here we assess the hydrographic and chemical structures of intermediate waters along the western Portuguese margin by examining the vertical distributions and property-property plots of chemical tracers (oxygen and nutrients). AAIW was traced by low oxygen and high nutrients, while SAIW was recognized by low nutrients. The Mediterranean Water (MW) undercurrent is shown to spread towards the eastern flank of Gorringe bank. Concurrently, the fresher waters gained salt by direct incorporation of MW, while this water was enriched in nutrients on its way northward and westward owing, to a great extent, to the entrainment of an AAIW branch. The distributions of nutrients and apparent oxygen utilization are discussed in terms of regional ocean circulation. Our analysis suggests a circulation pattern of the various intermediate waters along the western Portuguese margin: MW extends all over the area, but its presence is more pronounced around cape St. Vincent; SAIW apparently moves southward, reaching the Gorringe bank region, and AAIW flows northward along the coast and around the bank.  相似文献   

Joint editorial – Fostering innovation and improving impact assessment for journal publications in hydrology     

Demetris Koutsoyiannis  Günter Blöschl  András Bárdossy  Christophe Cudennec  Denis Hughes  Alberto Montanari 《水文科学杂志》2013,58(7):1170-1173

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Process length variation of the cyst of the dinoflagellate Protoceratium reticulatum in the North Pacific and Baltic‐Skagerrak region: calibration as an annual density proxy and first evidence of pseudo‐cryptic speciation     

Kenneth Neil Mertens  Manuel Bringué  Nicolas Van Nieuwenhove  Yoshihito Takano  Vera Pospelova  Andre Rochon  Anne De Vernal  Taoufik Radi  Barrie Dale  R. Timothy Patterson  Kaarina Weckström  Elinor Andrén  Stephen Louwye  Kazumi Matsuoka 《第四纪科学杂志》2012,27(7):734-744

Process length variation of cysts of the dinoflagellate Protoceratium reticulatum (Claparède et Lachmann) Bütschli in surface sediments from the North Pacific was investigated. The average process length showed a significant inverse relation to annual seawater density: σ_{t annual} = ?0.8674 × average process length + 1029.3 (R² = 0.84), with a standard error of 0.78 kg m^?3. A sediment trap study from Effingham Inlet in British Columbia revealed the same relationship between average process length and local seawater density variations. In the Baltic–Skagerrak region, the average process length variation was related significantly to annual seawater density: σ_{t annual} = 3.5457 × average process length ? 993.28 (R² = 0.86), with a standard error of 3.09 kg m^?3. These calibrations cannot be reconciled, which accentuates the regional character of the calibrations. This can be related to variations in molecular data (small subunit, long subunit and internal transcribed spacer sequences), which show the presence of several genotypes and the occurrence of pseudo‐cryptic speciation within this species. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

The last deglaciation in the Picos de Europa National Park (Cantabrian Mountains,northern Spain)     

Ana Moreno  Blas L. Valero‐Garcés  Montserrat Jiménez‐Sánchez  María José Domínguez‐Cuesta  M. Pilar Mata  Ana Navas  Penélope González‐Sampériz  Heather Stoll  Pedro Farias  Mario Morellón  J. Pablo Corella  Mayte Rico 《第四纪科学杂志》2010,25(7):1076-1091

A sedimentological and geochemical study of the Lago Enol sequence (Cantabrian Mountains, northern Spain), together with detailed geomorphological mapping, provides a first record of glacier evolution and climate change over the last 40 ka in the Picos de Europa National Park. The Enol glacier retreated from its maximum extent prior to 40 ka BP as demonstrated by the onset of proglacial lacustrine sedimentation in two glaciated depressions: the Comella hollow to the north (before 40 ka BP) and the Lago Enol (before 38 ka BP). These results support previous evidence that the maximum extent of southern European glaciers occurred earlier than in northern Europe. Alternation of homogeneous and laminated proglacial sediments during the glacier retreat illustrate a dynamic glacial evolution during the Marine Isotope Stage (MIS) 3 (40–26 ka BP). A slight warming is detected at 26 ka ago with the change from proglacial sediments (in a lake located in contact to the glacier) to glaciolacustrine sedimentation (in a non‐contact or distal lake). Finally, the onset of organic‐rich sediments took place at 18 ka ago. This last transition occurred in two phases, similarly to the North Atlantic Last Termination, suggesting a link between North Atlantic Deep Water formation oscillations and palaeohydrological variability in the Cantabrian Mountains. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Analytic element modelling for strip aquifers     

José Anderson N. Batista  Edson Wendland  Harry E. Schulz 《水文研究》2012,26(8):1254-1262

The Analytic Element Method (AEM) provides a convenient tool for groundwater flow analysis in unbounded continuous domains. The AEM is based on the superposition of analytic functions, known as elements, useful at both regional and local scales. In this study, analytic elements for strip aquifers are presented. Such aquifers occur in riverine or coastal deposits and in outcrop zones of confined aquifers. Local flow field is modelled indirectly, using a reference plane related to the aquifer domain through the Schwarz‐Christoffel transform. The regional flow is obtained as a solution of the one‐dimensional flow equation. The proposed methodology was tested by modelling two hypothetical situations, which were compared to exact solutions. It is shown that regional boundaries can be reproduced exactly while local fields are adequately reproduced with analytic elements. The developed elements are applied to simulate a real flow field in northeastern Brazil showing good agreement with measured water levels. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Estimating impacts of warming temperatures on California's electricity system     

Jayant A. Sathaye  Larry L. Dale  Peter H. Larsen  Gary A. Fitts  Kevin Koy  Sarah M. Lewis  André Frossard Pereira de Lucena 《Global Environmental Change》2013,23(2):499-511

Despite a clear need, little research has been carried out at the regional-level to quantify potential climate-related impacts to electricity production and delivery systems. This paper introduces a bottom-up study of climate change impacts on California's energy infrastructure, including high temperature effects on power plant capacity, transmission lines, substation capacity, and peak electricity demand. End-of-century impacts were projected using the A2 and B1 Intergovernmental Panel on Climate Change emission scenarios. The study quantifies the effect of high ambient temperatures on electricity generation, the capacity of substations and transmission lines, and the demand for peak power for a set of climate scenarios. Based on these scenarios, atmospheric warming and associated peak demand increases would necessitate up to 38% of additional peak generation capacity and up to 31% additional transmission capacity, assuming current infrastructure. These findings, although based on a limited number of scenarios, suggest that additional funding could be put to good use by supporting R&D into next generation cooling equipment technologies, diversifying the power generation mix without compromising the system's operational flexibility, and designing effective demand side management programs.  相似文献   

Study of bond stress–slip relationship and radial dilation in prestressed concrete     

José Mª Benítez  J.C. Gálvez  M.J. Casati 《国际地质力学数值与分析法杂志》2013,37(16):2706-2726

This paper presents two test procedures for evaluating the bond stress–slip and the slip–radial dilation relationships when the prestressing force is transmitted by releasing the steel (wire or strand) in precast prestressed elements. The bond stress–slip relationship is obtained with short length specimens, to guarantee uniform bond stress, for three depths of the wire indentation (shallow, medium and deep). An analytical model for bond stress–slip relationship is proposed and compared with the experimental results. The model is also compared with the experimental results of other researchers. Since numerical models for studying bond‐splitting problems in prestressed concrete require experimental data about dilatancy angle (radial dilation), a test procedure is proposed to evaluate these parameters. The obtained values of the radial dilation are compared with the prior estimated by numerical modelling and good agreement is reached. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Subfossil and modern diatom plankton and the paleolimnology of Rotsee (Switzerland) since 1850     

André F. Lotter 《Aquatic Sciences - Research Across Boundaries》1989,51(4):338-350

The diatom biostratigraphy of the topmost sediment meter of Rotsee, Central Switzerland, is characterized by a major change fromCyclotella comensis-dominated toStephanodiscus hantzschii/S. parvus-dominated assemblages. A comparison between old phytoplankton samples, taken between 1910–1930, and subfossil diatom assemblages is used for dating the upper 35 cm of the core. There is evidence that the change in dominant diatoms occurred in 1919/20, thus before the opening of an artificial inlet in 1922, and is due to increasing eutrophication. Furthermore, the sedimentary carbonate content can be used as a good indicator for past phytoplankton productivity in Rotsee.  相似文献