Assessing the potential for CO2 adsorption in a subbituminous coal,Huntly Coalfield,New Zealand,using small angle scattering techniques     

Tennille E. Mares  Andrzej P. Radliński  Tim A. Moore  David Cookson  P. Thiyagarajan  Jan Ilavsky  Jürgen Klepp 《International Journal of Coal Geology》2009,77(1-2):54-68

Small angle scattering techniques (SAXS and SANS) have been used to investigate the microstructural properties of the subbituminous coals (R_max 0.42–0.45%) from the Huntly Coalfield, New Zealand. Samples were collected from the two thick (> 5 m) coal seams in the coalfield and have been analysed for methane and carbon dioxide sorption capacity, petrography, pore size distribution, specific surface area and porosity.Specific surface area (SSA) available for carbon dioxide adsorption, extrapolated to a probe size of 4 Å, ranged from 1.25 × 10⁶ cm^? 1 to 4.26 × 10⁶ cm^? 1 with total porosity varying from 16% to 25%. Porosity was found to be predominantly composed of microporosity, which contributed the majority of the available SSA. Although considerable variation was seen between samples, the results fit well with published rank trends.Gas holding capacity at the reservoir pressure (approximately 4 MPa) ranged from 2.63 to 4.18 m³/t for methane on a dry, ash-free basis (daf) and from 22.00 to 23.72 m³/t daf for carbon dioxide. The resulting ratio of CO₂:CH₄ ranged from 5.7 to 8.6, with an average of 6.7:1.Holding capacities for both methane and carbon dioxide on a dry ash free basis (daf) were found to be correlated with sample microporosity. However, holding capacities for the two gases on an as analysed (aa) basis (that is including mineral matter and moisture), showed no such correlation. Carbon dioxide (aa) does show a negative correlation with both specific surface area and microporosity. As the coals have low inorganic matter content, the reversal is thought to be related to moisture which is likely concentrated in the pore size range 12.5–125 Å. Methane holding capacity, both daf and aa, correlates with macroporosity, thus suggesting that the holding capacity of micropores is diminished by the presence of moisture in the pores.  相似文献   

On the behaviour of liquefied soil   总被引：1，自引：0，他引：1  

Andrzej Sawicki  Jacek Mierczyński 《Computers and Geotechnics》2009

Engineering mechanics of liquefied soil is presented. Firstly, experimental methods and their results are described in order to show that liquefied soil can be approximated as a viscous fluid. The experiments proposed allow for determination of dynamic viscosity of liquefied soil, which is of the order of 10⁶ Ns/m². This value agrees with some theoretical estimates. Then, the model of viscous fluid is applied to practically important problems, in order to predict sinking of structures in liquefied subsoil, and to describe underwater flows of seabed. Enclosed examples show that the model and methods proposed lead to realistic results and, therefore, can be applied in engineering calculations.  相似文献   

Optimization framework for calibration of constitutive models enhanced by neural networks   总被引：1，自引：0，他引：1  

Rafał F. Obrzud  Laurent Vulliet  Andrzej Truty 《国际地质力学数值与分析法杂志》2009,33(1):71-94

A two‐level procedure designed for the estimation of constitutive model parameters is presented in this paper. The neural network (NN) approach at the first level is applied to achieve the first approximation of parameters. This technique is used to avoid potential pitfalls related to the conventional gradient‐based optimization techniques, considered here as a corrector that improves predicted parameters. The feed‐forward NN (FFNN) and the modified Gauss–Newton algorithms are briefly presented. The proposed framework is verified for the elasto‐plastic modified Cam Clay model that can be calibrated based on standard triaxial laboratory tests, i.e. the isotropic consolidation test and the drained compression test. Two different formulations of the input data to the NN, enhanced by a dimensional reduction of experimental data using principal component analysis, are presented. The determination of model characteristics is demonstrated, first on numerical pseudo‐experiments and then on the experimental data. The efficiency of the proposed approach by means of accuracy and computational effort is also discussed. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

LIBS analysis of geomaterials: Geochemical fingerprinting for the rapid analysis and discrimination of minerals     

Russell S. Harmon  Jeremiah Remus  Nancy J. McMillan  Catherine McManus  Leslie Collins  Jennifer L. Gottfried Jr.  Frank C. DeLucia  Andrzej W. Miziolek 《Applied Geochemistry》2009

Laser-induced breakdown spectroscopy (LIBS) is a simple atomic emission spectroscopy technique capable of real-time, essentially non-destructive determination of the elemental composition of any substance (solid, liquid, or gas). LIBS, which is presently undergoing rapid research and development as a technology for geochemical analysis, has attractive potential as a field tool for rapid man-portable and/or stand-off chemical analysis. In LIBS, a pulsed laser beam is focused such that energy absorption produces a high-temperature microplasma at the sample surface resulting in the dissociation and ionization of small amounts of material, with both continuum and atomic/ionic emission generated by the plasma during cooling. A broadband spectrometer-detector is used to spectrally and temporally resolve the light from the plasma and record the intensity of elemental emission lines. Because the technique is simultaneously sensitive to all elements, a single laser shot can be used to track the spectral intensity of specific elements or record the broadband LIBS emission spectra, which are unique chemical ‘fingerprints’ of a material. In this study, a broad spectrum of geological materials was analyzed using a commercial bench-top LIBS system with broadband detection from ∼200 to 965 nm, with multiple single-shot spectra acquired. The subsequent use of statistical signal processing approaches to rapidly identify and classify samples highlights the potential of LIBS for ‘geochemical fingerprinting’ in a variety of geochemical, mineralogical, and environmental applications that would benefit from either real-time or in-field chemical analysis.  相似文献   

Diagenetic and other highly mineralized waters in the Polish Carpathians     

Andrzej Zuber  Józef Chowaniec 《Applied Geochemistry》2009

Highly mineralized waters of different chemical types and origin occur in the flysch formations and their bedrocks in the western part of the Polish Carpathians. The marine sedimentation water of the flysch formations is not preserved, as the most mineralized and the heaviest isotopic values of flysch waters are characterized by δ¹⁸O and δ²H values in the ranges of 5–7‰ and −(20–30)‰, respectively. Their origin is related to the dehydration of clay minerals during burial diagenesis, with molecules of marine water completely removed by molecules of released bound water. They are relatively enriched in Na⁺ in respect to the marine water, supposedly due to the release of Na⁺ during the illitization of smectites and preferable incorporation of other cations from the primary brine into newly formed minerals. In some parts of younger formations, i.e. in the Badenian sediments, brines occur with isotopic composition close to SMOW and Cl⁻ contents greatly exceeding the typical marine value of about 19.6 g/L, supposedly due to ultrafiltration. Most probably, the marine water of the flysch formations was similarly enriched chemically in its initial burial stages. Final Cl⁻ contents in diagenetic waters depend on different Cl⁻ contents in the primary brines and on relationships between diagenetic and further ultrafiltration processes. In some areas, diagenetic waters migrate to the surface along fault zones and mix with young local meteoric waters becoming diluted, with the isotope composition scattering along typical mixing lines. In areas with independent CO₂ flow from great depths, they form chloride CO₂-rich waters. Common CO₂-rich waters are formed in areas without near-surface occurrences of diagenetic waters. They change from the HCO₃–Ca type for modern waters to HCO₃–Mg–Ca, HCO₃–Na–Ca and other types with elevated TDS, Mg²⁺ and/or Na⁻ contents for old waters reaching even those of glacial age. Bedrocks of the flysch are represented by Mesozoic and Paleozoic mudstones, sandstones and carbonates, and in some areas by Badenian sediments. Brines of the Mesozoic and Paleozoic bedrocks are usually significantly enriched in Ca²⁺ and Mg²⁺ in comparison with the Badenian brines. By analogy to the deepest brines in the adjacent Upper Silesian Coal Basin, they are supposed to originate from paleometeoric waters of a hot climate.  相似文献   

Mathematical modeling and practical verification of groundwater and contaminant transport in a chosen natural aquifer     

Andrzej Aniszewski 《Acta Geophysica》2009,57(2):435-453

The paper addresses the 2D mathematical equation of conservative contaminant transport in an aquifer for chosen contaminants. The contaminants (chlorides and sulfates) are subject to instantaneous reversible part of sorption process. The term of instantaneous reversible sorption in the presented equation has been described by the non-linear Freundlich adsorption isotherm, widely applied in practice in relation to static processes (for local equilibrium). The numerical solution (using the finite difference method) has been based on the previously calculated values of longitudinal and transverse dispersion coefficients and the non-linear adsorption parameters for the chosen contaminants. Based on this model, the values of chloride and sulfate concentration isolines have been calculated and compared with the measured maximal concentrations in the chosen natural aquifer (installed piezometers). Additionally, the values of chloride concentrations have been calculated taking into account the influence of radioactive decay term, using the numerical value of the firstorder decay rate constant for an adopted theoretical radionuclide.  相似文献   

Book Review: Seismic Prevention of Damage: A Case Study in a Mediterranean City, ed. M. Maugeri     

Andrzej Kijko  Mayshree Singh 《Pure and Applied Geophysics》2009,166(3):515-516

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Book Review: Transport and Mixing in Geophysical Flows, eds. Jeffrey B. Weiss, Antonello Provenzale     

Andrzej Icha 《Pure and Applied Geophysics》2009,166(3):519-520

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Airborne Fungal Spores of Subalpine Zone of the Karkonosze and Izerskie Mountains （Poland）   总被引：4，自引：1，他引：3  

Wojciech PUSZ  Wlodzimierz KITA  Andrzej DANCEWICZ  Ryszard WEBER 《山地科学学报》2013,10(6):940-952

The incidence of the airborne fungal spores was determined in the air of subalpine zone of the Karkonosze Mountains and of the Izerskie Mountains in the borderland between Poland and the Czech Republic. The experiment was conducted in 2011 and 2012 at three to four week intervals from May to October. Air samples were taken from three locations in the Karkonosze Mts. and one from the Izerskie Mts. To examine the air, the Air Ideal 3P sampler and acidified PDA medium were used. The results show that Cladosporium cladosporioides was the most abundant spore type in all the sampling locations （up to 30%）, followed by Alternaria alternata （16%-20%）, Fusarium （up to 10%） and Sclerotinia sclerotiorium （up to 6%）. The lower spore counts were recorded in May samples, compared to the other months. In this case the snow cover, that was still present in the area at the beginning of May, may be the reason for the lower, compared to June, July and August samplings, CFU （Colony Forming Unit） counts in that month.. The influx of air masses from SE, S and SW sectors in the area under study may affect dissemination of the plant-pathogenic fungi from the Czech Republic and from the South of Europe in general.  相似文献   

X-ray studies of flaring plasma     

B. Sylwester  J. Sylwester  K. J. H. Phillips 《Journal of Astrophysics and Astronomy》2008,29(1-2):147-150

We present some methods of X-ray data analysis employed in our laboratory for deducing the physical parameters of flaring plasma. For example, we have used a flare well observed with Polish instrument RESIK aboard Russian CORONAS-F satellite. Based on a careful instrument calibration, the absolute fluxes in a number of individual spectral lines have been obtained. The analysis of these lines allows us to follow the evolution of important thermodynamic parameters characterizing the emitting plasma throughout this flare evolution.  相似文献