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81.
82.
Xiaoyu Zhang Jibamitra Ganguly Motoo Ito 《Contributions to Mineralogy and Petrology》2010,159(2):175-186
We have experimentally determined the tracer diffusion coefficients (D*) of 44Ca and 26Mg in a natural diopside (~Di96) as function of crystallographic direction and temperature in the range of 950–1,150 °C at 1 bar and f(O2) corresponding to those of the WI buffer. The experimental data parallel to the a*, b, and c crystallographic directions show significant diffusion anisotropy in the a–c and b–c planes, with the fastest diffusion being parallel to the c axis. With the exception of logD*(26Mg) parallel to the a* axis, the experimental data conform to the empirical diffusion “compensation relation”, converging to logD ~ −19.3 m2/s and T ~ 1,155 °C. Our data do not show any change of diffusion mechanism within the temperature range of the experiments. Assuming
that D* varies roughly linearly as a function of angle with respect to the c axis in the a–c plane, at least within a limited domain of ~20° from the c-axis, our data do not suggest any significant difference between D*(//c) and D*(⊥(001)), the latter being the diffusion data required to model compositional zoning in the (001) augite exsolution lamellae
in natural clinopyroxenes. Since the thermodynamic mixing property of Ca and Mg is highly nonideal, calculation of chemical
diffusion coefficient of Ca and Mg must take into account the effect of thermodynamic factor (TF) on diffusion coefficient.
We calculate the dependence of the TF and the chemical interdiffusion coefficient, D(Ca–Mg), on composition in the diopside–clinoenstatite mixture, using the available data on mixing property in this binary
system. Our D*(Ca) values parallel to the c axis are about 1–1.5 log units larger than those Dimanov et al. (1996). Incorporating the effect of TF, the D(Ca–Mg) values calculated from our data at 1,100–1,200 °C is ~0.6–0.7 log unit greater than the experimental quasibinary D((Ca–Mg + Fe)) data of Fujino et al. (1990) at 1 bar, and ~0.6 log unit smaller than that of Brady and McCallister (1983) at 25 kb, 1,150 °C, if our data are normalized to 25 kb using activation volume (~4 and ~6 cm3/mol for Mg and Ca diffusion, respectively) calculated from theoretical considerations. 相似文献
83.
Haimanti Biswas Mitali Dey Dipnarayan Ganguly Tarun K. De Sandip Ghosh Tapan K. Jana 《Estuaries and Coasts》2010,33(2):384-394
Inter-annual variations of phytoplankton abundance and community organization were observed over a two-decade period along with the ancillary parameters at the land–ocean boundary associated with the Sundarban mangrove forest (21°32′ and 22°40′ N and 88°05′ and 89° E), along the NE Coast of the Bay of Bengal. The number of definable Bacillariophyceae species exceeded Dinophyceae taxa, and the total number of bloom-forming species declined from a maximum of ten in 2000 and a minimum of two in 2007. Blooms of the diatom Coscinodiscus radiatus were common in 2000 and 2007. Tide cycles and the onset of the monsoon season played important roles in diurnal and seasonal variability of phytoplankton. Phytoplankton biovolume showed seasonality, with the highest levels during post-monsoon periods and lowest levels during the monsoon period. Phytoplankton abundance was correlated to rainfall patterns, which may be altered by long-term changes in climate. 相似文献
84.
Ashok K. Chugh 《国际地质力学数值与分析法杂志》2007,31(4):607-648
A forced vibration procedure is presented to estimate fundamental and higher frequencies of vibrations and associated mode shapes of gravity structures. The gravity structures considered are retaining walls and gravity dams. The validity of the proposed procedure is tested on three test problems of varying complexity for which the natural vibration frequencies and mode shapes either have known analytical solutions or have been determined via numerical means/field tests by others. Also included are the results of natural vibration frequencies and associated mode shapes for a spillway control structure located near the abutment end of an embankment dam obtained using the proposed procedure. For all problems considered, fundamental frequency and mode shape results using the proposed procedure are compared with the results obtained using an alternative procedure in which static deflections due to the structure's own weight are used as the starting point for free vibrations by setting the gravity vector to zero. All results compare well. The merits of the proposed procedure are discussed. Published in 2006 by John Wiley & Sons, Ltd. 相似文献
85.
Ashok Kauhsal 《Journal of the Indian Society of Remote Sensing》1999,27(2):xiii-xiii
86.
—?The role of sea-surface temperature (SST) and Coriolis parameter in the evolution and intensification of tropical cyclones has been examined using the ten-level axi-symmetric primitive equation model described in the companion paper (Bhaskar Rao and Ashok, 1999). Two experiments have been conducted using the ten-level model to assess the role of Coriolis parameter “f” in tropical cyclone intensity and the size of the storm generated. Six experiments have been performed to assess the importance of Sea-Surface Temperature (SST) in tropical cyclogenesis and intensification. The initial thermodynamic field and the initial vortex are the same as that used to simulate the Bay of Bengal tropical cyclone discussed in the companion paper. Further sensitivity experiments indicated a strong dependency of the model on SSTs. The model initial vortex could not intensify with an SST of 299?K but could with an SST of 300?K. The increase of SST from 300?K to 300.5?K shows rapid intensification with a minimum central surface pressure of 910?hPa and a maximum tangential wind of 80?m/s. Further increase of SST only shows a marginal increase in intensity and a larger radius of maximum wind. Sensitivity experiments to assess the role of the Coriolis parameter suggest that tropical cyclones develop more intensity and are faster at relatively lower latitudes. 相似文献
87.
A large number of parameters affect the inelastic response of an eccentric system. The centre of resistance no longer remains constant due to continuous loading and unloading of various elements of the system in and out of the inelastic region. The objective of this study is to develop the concept of strength eccentricity for asymmetrical structures excited well into the inelastic region in the event of a severe earthquake. A single mass monosymmetric three-element system is selected. The torsional flexibility parameter is varied so as to obtain nine eccentric configurations covering the entire spectrum of such systems. These models were subjected to S00E component of the El Centro earthquake of 1940 which is considered to be a very severe earthquake. The concept of effective strength eccentricity is introduced which is defined as strength eccentricity at the point of intersection of ductility ratio curves of REE and FEE. It is proposed to provide additional strength in the elements of a torsionally unbalanced system independent of the design eccentricity. Empirical equations are proposed to account for design eccentricity and additional strength as well as distribution of the design strength. The proposed formulation is compared with the torsional provisions of UBC 1991, NBCC 1990 and NZC 1992. It is concluded that additional ductility demand on the REE and FEE designed based on the proposed formulation is almost nil as compared to that given by the three codes. The NZC and UBC require maximum ductility on the REE. The increase in overall strength of the system is least for the proposed formulation as compared to that given by the three codes. NBCC consistently requires the maximum total strength ratio. 相似文献
88.
89.
Jibamitra Ganguly 《Contributions to Mineralogy and Petrology》1976,55(1):81-90
Approximate mixing properties of the dominant calcium silicate end-member components of natural garnets, namely grossularite, andradite and uvarovite, have been derived through theoretical thermodynamic and crystal chemical analysis, and appropriate reduction of the available experimental data. The stability of the solid solution with respect to phase separation in the ternary system has been analyzed. Finally, a general model is presented as to the approximate mixing properties of multicomponent natural garnet solid solution involving substitutions in both eight and six coordinated sites. 相似文献
90.
During the last few years, a remarkable anomaly between 238U and 234U activities has been observed in the top layers of the coastal sediments along the western region of the Indian sub-continent. Sediment samples from Bombay (19°N, 73°E) to Kottilppad (8°N, 77°E) were leached with saturated ammonium carbonate solution to extract uranium isotopes from the surface layers of the sediment particles without attacking the mineral cores. The 234U/238U activity ratios in these leachates are in the range of 1.12–1.14 while 235U/238U activity ratio is 0.046 which is the same as for other natural uranium.
The surface organic matter from the sediment particles was removed by treatment with hydrogen peroxide in presence of 0.05 M hydrochloric acid. 234U/238U and 235u/238U activity ratios in the extract and the residues were determined.
It is observed that disequilibrium between 238U and 234U exists only on the surface of sediment particles. 234U/238U on the surface of the sediment particles is the same as in the ambient water and as the surface organic matter is removed from the particle surface, the cores show equilibrium activities. 相似文献