Mathematical expressions used in amino acid racemisation geochronology—A review     

Simon J. Clarke  Colin V. Murray-Wallace 《Quaternary Geochronology》2006,1(4):261-278

A variety of mathematical expressions that describe changes over time (t) in the extent of amino acid racemisation (AAR, expressed as the ratio of d- to l-amino acid isomers or epimers) have been used in Quaternary geochronology. The integrated rate equation was first used to estimate fossil age from D/L but its geochronological utility is disadvantaged by uncertainties regarding the conformity of AAR in fossil protein to apparent reversible first-order kinetics for the entire reaction history. ‘Non-linear’ models have subsequently been used to relate D/L to t. The logarithmic equation successfully applied to Atlantic Coastal Plain research has not achieved widespread application, perhaps due to the regional calibration required if sensitivity to temperature is to be modelled, or the difficulties encountered when extending the model to include fossils with D/L<0.1. Success producing a linear correlation between D/L transformed with a power function and t has seen this approach emerge as one of the most commonly applied in AAR geochronology in recent years. Like parabola curve fitting, which has been applied to trends in D/L versus t in a variety of fossils and geographic settings, power transformations may not be suitable for geochronological modelling during the latter stages of amino acid diagenesis. Several studies have demonstrated the utility of simple and contingent linear equations for relating D/L to t. Future research should aim to reduce reliance on independent calibration and explore the geochronological benefits of AAR in pools other than the total hydrolysable amino acids.  相似文献   

Feature Extraction in Remote Sensing High-Dimensional Image Data     

Zortea  M. Haertel  V. Clarke  R. 《Geoscience and Remote Sensing Letters, IEEE》2007,4(1):107-111

High-dimensional image data open new possibilities in remote sensing digital image classification, particularly when dealing with classes that are spectrally very similar. The main problem refers to the estimation of a large number of classifier's parameters. One possible solution to this problem consists in reducing the dimensionality of the original data without a significant loss of information. In this letter, a new approach to reduce data dimensionality is proposed. In the proposed methodology, each pixel's curve of spectral response is initially segmented, and the digital numbers (DNs) at each segment are replaced by a smaller number of statistics. In this letter, the proposed statistics are the mean and variance of the segment's DNs, which are supposed to carry information about the segment's position and shape, respectively. Tests were performed by using Airborne Visible/Infrared Imaging Spectrometer hyperspectral image data. The experiments have shown that this methodology is capable of providing very acceptable results, in addition of being computationally efficient  相似文献   

GPS sidereal filtering: coordinate- and carrier-phase-level strategies   总被引：6，自引：1，他引：6  

A. E. Ragheb  P. J. Clarke  S. J. Edwards 《Journal of Geodesy》2007,81(5):325-335

Multipath error is considered one of the major errors affecting GPS observations. One can benefit from the repetition of satellite geometry approximately every sidereal day, and apply filtering to help minimize this error. For GPS data at 1 s interval processed using a double-difference strategy, using the day-to-day coordinate or carrier-phase residual autocorrelation determined with a 10-h window leads to the steadiest estimates of the error-repeat lag, although a window as short as 2 h can produce an acceptable value with > 97% of the optimal lag’s correlation. We conclude that although the lag may vary with time, such variation is marginal and there is little advantage in using a satellite-specific or other time-varying lag in double-difference processing. We filter the GPS data either by stacking a number of days of processed coordinate residuals using the optimum “sidereal” lag (23 h 55 m 54 s), and removing these stacked residuals from the day in question (coordinate space), or by a similar method using double-difference carrier-phase residuals (observational space). Either method results in more consistent and homogeneous set of coordinates throughout the dataset compared with unfiltered processing. Coordinate stacking reduces geometry-related repeating errors (mainly multipath) better than carrier-phase residual stacking, although the latter takes less processing time to achieve final filtered coordinates. Thus, the optimal stacking method will depend on whether coordinate precision or computational time is the over-riding criterion.  相似文献   

Crustal strain in central Greece from repeated GPS measurements in the interval 1989–1997     

P. J. Clarke  R. R. Davies  P. C. England  B. Parsons  H. Billiris  D. Paradissis  G. Veis  P. A. Cross  P. H. Denys  V. Ashkenazi  R. Bingley  H.-G. Kahle  M.-V. Muller  & P. Briole 《Geophysical Journal International》1998,135(1):195-214

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Aliphatic and aromatic hydrocarbons in benthic invertebrates from two sites in Antarctica     

Andrew Clarke  Robin Law 《Marine pollution bulletin》1981,12(1):10-14

Samples of marine benthic invertebrates collected from two sites in the Antarctic have been analysed for both aliphatic and aromatic hydrocarbons in order to establish baseline concentrations for some classes of hydrocarbons.Samples from Signy Island, a pristine site, contained low concentrations of the hydrocarbons determined, whereas those from King Edward Cove, South Georgia, contained significantly higher concentrations. King Edward Cove has a known history of pollution from whaling operations.Platt & Mackie (1979) have suggested that the hydrocarbons in sediments from King Edward Cove are a result of the world-wide dissemination of the pyrolysis products of fossil fuels. Our work suggests, in contrast, that the hydrocarbons in the benthos are derived from local sources.  相似文献   

Nickel,and the existence of high-MgO liquids in nature     

D.B. Clarke  M.J. O&#x;Hara 《Earth and Planetary Science Letters》1979,44(1):153-158

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Magmatic andalusite from the South Mountain batholith,Nova Scotia   总被引：3，自引：0，他引：3  

D. B. Clarke  C. B. McKenzie  G. K. Muecke  S. W. Richardson 《Contributions to Mineralogy and Petrology》1976,56(3):279-287

Accessory andalusite has been found in some late-stage granitic differentiates of the South Mountain batholith. The andalusite is petrographically distinct from the andalusite of the thermal aureole, and it occurs in regions of the batholith which show little evidence of contamination by the country rocks. Analyses of biotites from andalusite-bearing and andalusite-free phases suggest that those coexisting with andalusite actually grew in equilibrium with the andalusite. It is concluded that magmatic andalusite must be confined mainly to water-saturated, peraluminous, epizonal granites, and some possible P-T paths for the crystallization of magmatic andalusite are considered.  相似文献   

Green garnets from the Newlands kimberlite,Cape Province,South Africa     

D.B. Clarke  D.A. Carswell 《Earth and Planetary Science Letters》1977,34(1):30-38

Six crystals of green, uvarovite-rich garnet from the Newlands kimberlite have been analysed. The range of Cr₂O₃ is 10.04–14.04% and CaO is 19.18–25.94% (wt.), and thus they are similar to garnets found in only one other kimberlite province, namely Yakutia. By combining data from both the Russian and South African occurrences, four models are considered for the formation of such garnets. The model which best accounts for the available chemical data, and mode of occurrence, involves formation of the uvarovitic garnets during subsolidus recrystallization of spinel wehrlitic cumulates, which themselves had been produced by a fractionating magma at a depth of about 200–250 km.  相似文献   

Long edge waves over a continental shelf     

Dr. D. J. Clarke 《Ocean Dynamics》1974,27(1):1-8

Summary The existence of long edge waves over a continental shelf is examined for a representative collection of shelf profiles. The frequencies of both trapped and leaky modes are found, when they exist, in terms of the shelf parameters. Certain theoretical trapped waves over a semi-infinite shelf are shown not to exist in the real ocean.A typical shelf profile on the east coast of Australia is modelled in four different ways from the above collection. The amplification of the leaky mode at the shoreline is found in terms of frequency for each model. Comparison of the results illustrates the severe errors introduced by crude approximations to the profile both at the shoreline and at the shelf cut-off region.

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Lange Randwellen über einem Festlandsockel

Zusammenfassung Die Existenz von langen Randwellen über einem Festlandsockel wird untersucht für eine repräsentative Sammlung von Schelfprofilen. Die Frequenzen sowohl der trapped (geführten) als auch der leaky (energieoder impulsabgebenden) Eigenfunktionsformen werden — wenn sie existieren — ermittelt, ausgedrückt in Schelf-Parametern. Es wird gezeigt, daß gewisse, trapped waves (geführte Wellen) über einem semi-unendlichen Schelf im wirklichen Ozean nicht existieren.Mit Hilfe der obigen Sammlung hat man ein typisches Schelfprofil von der Ostküste Australiens in vier verschiedenen Arten modelliert. Die Verstärkung des leaky mode an der Küstenlinie wird für jedes Modell gefunden in Termen der Frequenz. Der Vergleich der Ergebnisse verdeutlicht die schweren Fehler, die durch grobe Näherungen an das Profil entstehen, sowohl an der Küstenlinie als auch in dem Gebiet des Übergangs vom Schelf in die Tiefsee.

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Ondes transversales à longues crêtes au-dessus d'un plateua continental

Résumé On examine l'existence d'ondes transversales à longues crêtes au-dessus d'un plateau continental, afin de constituer une collection représentative des profils du plateau. On a trouvé les fréquences du «trapped mode» (mode captif) et du «leaky mode» (mode de transfert d'énergie et du moment) — quand ils existent — et cela en fonction des paramètres du plateau. On montre qu'il n'y a pas, dans l'océan réel, certaines ondes captées théoriques qui existeraient au-dessus d'un plateau semi-infini.Grâce à la collection dont il est parlé ci-dessus, on a modelé de quatre façons différentes un profil typique de la côte Est de l'Australie. Pour chaque modèle on a trouvé l'amplification du «leaky mode» sur la ligne de côte en fonction de la fréquence. La comparaison des résultats montre les erreurs importantes introduites par des approximations sommaires du profil, à la fois près de la ligne de côte et dans la région de transition du plateau continental en mer abyssale.

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Chandra observations of neutron stars: an overview     

M. C. Weisskopf  M. Karovska  G. G. Pavlov  V. E. Zavlin  T. Clarke 《Astrophysics and Space Science》2007,308(1-4):151-160

We present an overview of Chandra X-ray Observatory observations of neutron stars. The outstanding spatial and spectral resolution of this great observatory have allowed for observations of unprecedented clarity and accuracy. Many of these observations have provided new insights into neutron star physics. We present an admittedly biased and overly brief review of these observations, highlighting some new discoveries made possible by the Observatory’s unique capabilities. This includes our analysis of recent multiwavelength observations of the putative pulsar and its pulsar-wind nebula in the IC443 SNR.   相似文献