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51.
Geochemistry of surface sediments and heavy metal contamination assessment: Messolonghi lagoon complex,Greece 总被引:2,自引:2,他引:0
Aristomenis P. Karageorgis Andreas Sioulas Evangelia Krasakopoulou Christos L. Anagnostou George A. Hatiris Harikleia Kyriakidou Konstantinos Vasilopoulos 《Environmental Earth Sciences》2012,65(6):1619-1629
The Messolonghi lagoon complex in Western Greece receives agricultural and domestic effluents both from point and diffused
sources. Surface sediments were analyzed for grain size, organic carbon, total nitrogen, total sulfur, major and minor elements,
aiming at the identification of geochemical relationships between all variables. Enrichment factors and the modified degree
of contamination methods were applied to assess potential heavy metal enrichment related to human activities. Sediment texture
was highly variable, with muddy sediments prevailing. In the central sector of the Messolonghi lagoon, organic carbon contents
were high. Principal factor analysis revealed the following main groups of variables with common geochemical behavior: (1)
terrigenous aluminosilicates (2) organic matter, (3) biogenic carbonates, (4) mineral quartz-aluminosilicates, and (5) Mn-oxides.
Enrichment factors estimated for V, Cr, Mn, Co, Ni, Cu, Zn, and Pb using local pre-industrial sediment showed that all metals
exhibit almost natural background levels, except for Pb, which was found to be slightly elevated (legacy of leaded fuel).
Estimation of contamination factors concluded in similar results, whereas the overall modified degree of contamination was
at the lowest level, therefore suggesting that this transitional water body has not been affected by anthropogenic activities.
The data set may be considered as a baseline for future monitoring projects according to EU policy. 相似文献
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E. Greenberg C. Price Y. Yair C. Haldoupis O. Chanrion T. Neubert 《Journal of Atmospheric and Solar》2009,71(12):1254-1266
During the summer of 2005, transient luminous events were optically imaged from the French Pyrénées as part of the EuroSprite campaign. Simultaneously, extremely low frequency (ELF: 3–3000 Hz) and broadband very low frequency (VLF: 3–30 kHz) data were recorded continuously at two separate receivers in Israel, located about 3300 km from the area of the parent lightning discharges responsible for the generation of sprites. Additionally, narrowband VLF data were collected in Crete, at about 2300 km away from the region of sprites.The motivation for the present study was to identify the signature of the sprite-producing lightning discharges in the ELF and VLF electromagnetic frequency bands, to qualify and compare their parameters, and to study the influence of the thunderstorm-activated region on its overlaying ionosphere. For the 15 sprites analyzed, their causative positive cloud-to-ground (+CG) discharges had peak current intensities between +8 and +130 kA whereas their charge moment changes (CMC) ranged from 500 to 3500 C km. Furthermore, the peak current reported by the Météorage lightning network are well correlated with the amplitudes of the VLF bursts, while showing poor correlation with the CMCs which were estimated using ELF methods.Additionally, more than one +CG was associated with six of the sprites, implying that lightning discharges that produce sprites can sometimes have multiple ground connections separated in time and space. Finally, for a significant number of events (33%) an ELF transient was not associated with sprite occurrence, suggesting that long continuing current of tens of ms may not always be a necessary condition for sprite production, a finding which influences the estimation of the global sprite rate based on Schumann resonance (SR) measurements. 相似文献
54.
Stylianos Bitharis Christos Pikridas Aristeidis Fotiou Dimitrios Rossikopoulos Harald Schuh 《Marine Geodesy》2017,40(5):297-314
In this study, we show how the Global Navigation Satellite System (GNSS)-derived vertical velocities contribute to the correction of tide gauge (TG) measurements used for the sea level rise estimation in Greece. Twelve sites with records of local sea level heights are processed in order to estimate their trend. Certain error sources related to TGs, e.g. equipment changes, data noise, may lead to biased or erroneous estimations of the sea level height. Therefore, it would be preferred to follow a robust estimation technique in order to detect and reduce outlier effects. The geocentric sea level rise is estimated by taking into account the land vertical motion of co-located GNSS permanent stations at the Hellenic area. TGs measure the height of the water relative to a monitored geodetic benchmark on land. On the other hand, using GNSS-based methods the vertical land motion can be derived. By means of extended models fitted to the GNSS time-series position, obtained from seven years of continuous data analysis, periodic signals are well described. The synergy of the two co-located techniques results in the correction of TG relative sea level heights taking into account the GNSS vertical velocities and consequently obtaining the conversion to absolute (geocentric) sea level trend. 相似文献
55.
For a linear elastic Earth the time derivative of the ground force is considered proportional to the far-field wavelet. Under the assumption that the baseplate is stiff and the bending forces of the baseplate are negligible, the ground force is also approximated by the sum of the accelerations of the baseplate and the reaction mass weighted by the respective masses. Combining these two assumptions, the time derivative of the weighted sum is considered proportional to the far-field wavelet. This result, often referred to as the far-field wavelet assumption, although convenient and most often employed is not always valid. We explore its validity using the spectral harmonic ratios of recorded data, which are used extensively in data filtering and analysis of vibratory data. We show that the far-field wavelet assumption fails particularly for harmonic components of even order. More compact soil after repeated shots further invalidates this assumption. Non-linear modelling of the ground under the vibrator point may provide a direction towards solving this discrepancy. Finally, we describe a method for the estimation of the harmonic spectral ratios. 相似文献
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Linear structural relations express the linear relationship between random variables when each of the variables under consideration is subjected to inherent variability and measurement error. The linear structural method is more general than the classical regression, which is often used incorrectly in calibration of altimeter data or validation of wave model results. In this work the linear structural method is elaborated and applied for the adjustment of TOPEX/Poseidon (T/P) data by means of in situ measured wave data in the Aegean Sea. In addition, a comparison of the buoy and T/P data with the WAM wave model predictions is performed revealing an underestimation trend of the model. 相似文献
58.
The rapidly expanding industry of marine cage fish farming of sea bream (Sparus aurata) and sea bass (Dicentrarchus labrax) in the Mediterranean Sea over the last decade has often had damaging effects on the benthic aquatic environment near the fish farm installations. It has been observed that the food-remains, together with the pellets and metabolic products from fish, frequently form a “nepheloid” sediment layer covering large areas of the seabed. Under these conditions anoxia and/or hypoxia develop and affect benthic communities while the quality of the marine environment deteriorates for long periods, extending even beyond the life span of the fish farm itself. In most cases the affected areas act initially as sediment traps and in a second phase as secondary sources of organic carbon, nutrients and other substances.The aim of this paper is to explore the behaviour of such an affected area under different redox regimes by measuring the fluxes of ammonium, nitrite, nitrate, TDN, phosphate, TDP and silicate between the surface sediment and the overlying waters. To achieve this goal we constructed a prototype benthic chamber capable of sampling considerable quantities of affected undisturbed sediment along with its overlying water. The chamber was transported to the laboratory where simulation experiments reproducing the conditions occurring in nature, including the extreme ones, were carried out and studied carefully. The chamber allows the full and fine control of the dissolved oxygen concentration – and thus of the redox potential – as well as water temperature while subsamples of both water and sediment could be obtained and analysed for a series of chemical substances. The controlled laboratory chamber experiments reproduced four successional phases: 1) deoxygenation, 2) hypoxia, 3) reoxygenation and 4) anoxia.The results showed that even minor changes in the redox conditions at a relatively narrow zone near the water sediment interface have significant impacts on the concentrations of dissolved nitrogen, phosphorus and silicate compounds.With decreasing oxygen supply (phases 1, 2 and 4), the concentrations of ammonium, nitrite, TDN, phosphate, TDP and silicate rapidly increase, those of nitrate decrease. DON and DOP exhibit remarkable fluctuations.During reoxygenation (phase 3) the concentrations of ammonium stabilise, the nitrate concentration decreases while nitrite shows an increasing trend. Decreases in phosphate and silicate concentrations were also observed paralleled by TDP stabilization and DOP increasing trend. TDN shows a relatively small increase while the DON concentration fluctuates significantly. 相似文献
59.
Pandi Zdruli Christos G. Karydas Klarent Dedaj Ilir Salillari Florjana Cela Sherif Lushaj Panos Panagos 《Earth Science Informatics》2016,9(4):481-495
Some recent land use changes in Albania, such as deforestation, cropland abandonment, and urban sprawl, have caused serious increase of erosion risk. The main objective of this study was to map erosion risk in Korçe region and assess the degree at which every land use is concerned. The G2 erosion model was applied, which can provide erosion maps and statistical figures at month-time intervals using input from free European and global geodatabases. The mapping results in Korçe region were derived at a 30-m cell size, which is an innovation for G2. Autumn-winter months were found to be the most erosive, with average erosion rates reaching the maximum in November and December, i.e. 2.62 and 2.36 t/ha, respectively, while the annual rate was estimated at 10.25 t/ha/yr. Natural grasslands, shurblands, mixed forests, and vineyards showed to exhibit the highest mean erosion rates, while shrublands, broad-leaved forests and natural grasslands were found to be the most extended land covers risky for non-sustainable erosion rates (i.e. >10 t/ha/yr). A detailed examination of the detected hot spots is now necessary by the competent authorities, in order to apply appropriate, site-specific conservation measures. Notably, use of SPOT VGT data did not prevent the maps from having extended gaps due to cloudiness. Sentinel-2 time series, freely available by the European Space Agency (ESA), have the potential to improve spatiotemporal coverage of V-factor, thus further empowering the G2 model, in the near future. 相似文献
60.