Surface current and vertical thermal structure on the continental slope in Tosa Bay     

Hiroshi Kuroda  Manabu Shimizu  Yuuichi Hirota  Daisuke Ambe  Hideki Akiyama 《Journal of Oceanography》2008,64(1):81-91

In order to specify a vertical thermal structure related to surface current variation on the continental slope in Tosa Bay, Japan, we analyzed monthly regular hydrographic measurements in the years 1991–2004. Subsurface temperature below 200 m on the slope was found to vary synchronously with the vertical displacement of the main thermocline around 200 m. It is shown that the vertical-averaged temperature below 200 m is significantly correlated with an along-isobath/southwestward surface current velocity on the slope. This correlation indicates that when a strong (weak) southwestward surface current is observed, temperature below 200 m decreases (increases) simultaneously, that is, isotherms below the 200 m are displaced upward (downward) together with the main thermocline. Moreover, when the strong southwestward flow is detected, across-isobath isotherms around 200 m slope upward toward the offshore direction. Furthermore, it is suggested that as the Kuroshio axis moves offshore south of the bay, the southwestward flow tends to be weakened by the combined effect of other Kuroshio parameters such as transport and stream width as well as the Kuroshio axis position. As a result, it is inferred that the correlation between the surface current and subsurface temperature can be interpreted in terms of the formation and decay of an anticlockwise circulation interacting with a cold eddy.  相似文献   

Rapid contamination during storage of carbonaceous chondrites prepared for micro FTIR measurements     

Yoko KEBUKAWA  Satoru NAKASHIMA  Takahiro OTSUKA  Keiko NAKAMURA‐MESSENGER  Michael E. ZOLENSKY 《Meteoritics & planetary science》2009,44(4):545-557

Abstract— Organic contamination (?2965 and ?1260 cm^?1peaks) was found on Tagish Lake (C2) and Murchison (CM2) carbonaceous chondrites containing abundant hydrous minerals by Fourier transform infrared (FTIR) microspectroscopy on the samples pressed on Al plates. On the other hand, anhydrous chondrite (Moss, CO3) was not contaminated. This contamination occurred within one day of storage, when the samples pressed on Al were stored within containers including silicone rubber mats. Volatile molecules having similar peaks to the contaminants were detected by long‐path gas cell FTIR measurements for the silicone rubber mat. Rapid adsorption of the volatile contaminants also occurred when silica gel and hydrous minerals such as serpentine were stored in containers including silicone rubber, silicone grease, or adhesive tape. However, they did not show any contamination when stored in glass and polystyrene containers without these compounds. Therefore, precious astronomical samples such as meteorites, interplanetary dust particles (IDPs), and mission‐returned samples from comets, asteroids, and Mars, should be measured by micro FTIR within one day of storage in glass containers without silicone rubber, silicone grease, or adhesive tape.  相似文献   

Kinetics of organic matter degradation in the Murchison meteorite for the evaluation of parent‐body temperature history     

Yoko KEBUKAWA  Satoru NAKASHIMA  Michael E. ZOLENSKY 《Meteoritics & planetary science》2010,45(1):99-113

Abstract– To evaluate kinetic parameters for thermal degradation of organic matter, in situ heating experiments of insoluble organic matter (IOM) and bulk of Murchison (CM2) meteorite were conducted under Fourier transform infrared micro‐spectroscopy combined with a heating stage. Decreases of aliphatic C–H band area under Ar flow were well fitted with Ginstling‐Brounshtein three‐dimensional diffusion model, and the rate constants for decreases of aliphatic C–H were determined. Activation energies E_a and frequency factors A obtained from these rate constants at different temperatures using the Arrhenius equation were E_a = 109 ± 3 kJ mol^?1 and A = 8.7 × 10⁴ s^?1 for IOM, and E_a = 61 ± 6 kJ mol^?1 and A = 3.8 s^?1 for bulk, respectively. Activation energy values of aliphatic C–H decrease are larger for IOM than bulk. Hence, the mineral assemblage of the Murchison meteorite might have catalytic effects for the organic matter degradation. Using obtained kinetic expressions, the time scale for metamorphism can be estimated for a given temperature with aliphatic C–H band area, or the temperature of metamorphism can be estimated for a given time scale. For example, using the obtained kinetic parameters of IOM, aliphatic C–H is lost approximately within 200 years at 100 °C and 100 Myr at 0 °C. Assuming alteration period of 7.5 Myr, alteration temperatures could be calculated to be <15 ± 12 °C. Aliphatic C–H decrease profiles in a parent body can be estimated using time–temperature history model. The kinetic expression obtained by the infrared spectral band of aliphatic C–H could be used as an alternative method to evaluate thermal processes of organic matter in carbonaceous chondrites.  相似文献   

PP-P differential traveltime measurement with crustal correction     

Masayuki Obayashi  Daisuke Suetsugu  Yoshio Fukao 《Geophysical Journal International》2004,157(3):1152-1162

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Stability and P–V–T equation of state of KAlSi3O8-hollandite determined by in situ X-ray observations and implications for dynamics of subducted continental crust material     

Norimasa Nishiyama  Robert Paul Rapp  Tetsuo Irifune  Takeshi Sanehira  Daisuke Yamazaki  Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2005,32(8-9):627-637

In situ X-ray diffraction measurements of KAlSi₃O₈-hollandite (K-hollandite) were performed at pressures of 15–27 GPa and temperatures of 300–1,800 K using a Kawai-type apparatus. Unit-cell volumes obtained at various pressure and temperature conditions in a series of measurements were fitted to the high-temperature Birch-Murnaghan equation of state and a complete set of thermoelastic parameters was obtained with an assumed K′_300,0=4. The determined parameters are V _300,0=237.6(2) Å³, K _300,0=183(3) GPa, (?K _T,0/?T) _P =?0.033(2) GPa K^?1, a ₀=3.32(5)×10^?5 K^?1, and b ₀=1.09(1)×10^?8 K^?2, where a ₀ and b ₀ are coefficients describing the zero-pressure thermal expansion: α _T,0 = a ₀ + b ₀ T. We observed broadening and splitting of diffraction peaks of K-hollandite at pressures of 20–23 GPa and temperatures of 300–1,000 K. We attribute this to the phase transitions from hollandite to hollandite II that is an unquenchable high-pressure phase recently found. We determined the phase boundary to be P (GPa)=16.6 + 0.007 T (K). Using the equation of state parameters of K-hollandite determined in the present study, we calculated a density profile of a hypothetical continental crust (HCC), which consists only of K-hollandite, majorite garnet, and stishovite with 1:1:1 ratio in volume. Density of HCC is higher than the surrounding mantle by about 0.2 g cm^?3 in the mantle transition zone while this relation is reversed below 660-km depth and HCC becomes less dense than the surrounding mantle by about 0.15 g cm^?3 in the uppermost lower mantle. Thus the 660-km seismic discontinuity can be a barrier to prevent the transportation of subducted continental crust materials to the lower mantle and the subducted continental crust may reside at the bottom of the mantle transition zone.  相似文献   

Phase boundary between ilmenite and perovskite structures in MnGeO3 determined by in situ X-ray diffraction measurements     

Daisuke Yamazaki  Eiji Ito  Yoshinori Tange  Takashi Yoshino  Shuangmeng Zhai  Hiroshi Fukui  Anton Shatskiy  Tomoo Katsura  Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2007,34(4):269-273

In situ X-ray observations of the phase transition from ilmenite to perovskite structure in MnGeO₃ were carried out in a Kawai-type high-pressure apparatus interfaced with synchrotron radiation. The phase boundary between the ilmenite and perovskite structures in the temperature range of 700–1,400°C was determined to be P (GPa) = 16.5(±0.6) − 0.0034(±0.0006)T (°C) based on Anderson’s gold pressure scale. The Clapeyron slope, dP/dT, determined in this study is consistent with that for the transition boundary between the ilmenite and the perovskite structure in MgSiO₃.  相似文献   

Experimental study of a low-alkali tholeiite at 1–5 kbar: optimal condition for the crystallization of high-An plagioclase in hydrous arc tholeiite     

Daisuke?Takagi  Hiroaki?SatoEmail author  Mitsuhiro?Nakagawa 《Contributions to Mineralogy and Petrology》2005,149(5):527-540

We conducted melting experiments on a low-alkali tholeiite (SiO₂ ~52 wt%, MgO ~6.5 wt%, CaO/Na₂O~4.4, Al₂O₃/SiO₂ ~0.33) under both H₂O-undersaturated and H₂O-saturated conditions to investigate the effect of H₂O on the Ca–Na partitioning between plagioclase and melt. Experiments were performed in the temperature and pressure ranges of 1,000–1,300°C and 1–5 kbar, respectively, with varying H₂O contents of 0–12wt%. Redox condition was 0–2 log unit above NNO (nickel–nickel oxide) buffer. Temperature-bulk H₂O diagrams for the low-alkali tholeiite are constructed at 1, 2, and 5 kbar, and compositions of near-liquidus plagioclase and coexisting melt are determined. To exclude the effect of melt composition (CaO/Na₂O and Al₂O₃/SiO₂ ratios) on plagioclase composition and to reveal the effect of H₂O on An (=100×Ca/(Ca+Na)) content and (=(Ca/Na)_pl/(Ca/Na)_melt), we focused on the composition of near-liquidus plagioclases which crystallized from melts with nearly constant CaO/Na₂O and Al₂O₃/SiO₂ ratios. Our experimental results show that, at each experimental pressure, An content of the near-liquidus plagioclase and the K_D^Ca-Na almost linearly increases as H₂O content in melt increases. Each of the An content and the variations in a low-alkali tholeiitic system (CaO/Na₂O~4.0–4.5, Al₂O₃/SiO₂ ~0.27–0.33) can be described by one equation using temperature, pressure, and melt H₂O content as parameters. An content and of liquidus plagioclase increases with increasing melt H₂O and with decreasing pressure, elucidating that nearly H₂O-saturated conditions of 2–3 kbar is optimal for the crystallization of the most An-rich plagioclase (>An₈₈). We suggest this pressure condition of 2–3 kbar, corresponding to depth of 7–11 km, plays an important role for the origin of An-rich plagioclase in H₂O-rich low-alkali tholeiite. At pressures more than ca. 4 kbar, crystallization of liquidus Ca-rich clinopyroxene decreases the CaO/Na₂O ratio of liquid, thus prohibiting the crystallization of high-An plagioclase from hydrous tholeiite.  相似文献   

Proximal–distal fall deposit correlation of VEI-5 tephra (Towada-Chuseri) from Towada volcano,northeast Japan     

Daisuke Ishimura  Reona Hiramine 《第四纪科学杂志》2020,35(1-2):334-348

A tephra layer offers an isochronous surface in sediments, thus serving as a key bed and/or an age marker. Recent high-resolution sediment research (e.g. varved sediments) has revealed optically invisible tephra fingerprints and provided high-precision tephra ages. However, a tephra-based correlation cannot succeed without detailed knowledge of the tephra characteristics in a proximal area to correlate with tephra in high-resolution sediments in remote areas. Here we documented the detailed characteristics of Towada-Chuseri (To-Cu) tephra, which is associated with the Middle Holocene volcanic explosivity index 5 eruption of Towada volcano, northeast Japan. We used To-Cu tephra samples to achieve the proximal–distal correlation of three members: Chuseri pumice (Cu), Kanegasawa pumice (Kn) and Utarube ash (Ut). These distal occurrences correlate with proximal To-Cu tephra based on volcanic glass morphology and refractive index, as well as on major element composition of volcanic glass shards. Refractive indices allow the preliminary correlation of each member, and major element composition helps in distinguishing Ut from the other members. Glass morphology provides additional support. These correlations reveal that To-Cu, especially Cu, covered central to northeast Japan while confirming that To-Cu is the representative tephra in the Middle Holocene of the Tohoku region.  相似文献   

Decadal variability of Subtropical Mode Water subduction and its impact on biogeochemistry     

Eitarou Oka  Bo Qiu  Yusuke Takatani  Kazutaka Enyo  Daisuke Sasano  Naohiro Kosugi  Masao Ishii  Toshiya Nakano  Toshio Suga 《Journal of Oceanography》2015,71(4):389-400

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Reconnaissance report on landslide disasters in northeast Japan following the M 9 T��hoku earthquake     

Toyohiko Miyagi  Daisuke Higaki  Hiroshi Yagi  Shoji Doshida  Noriyuki Chiba  Jun Umemura  Go Satoh 《Landslides》2011,8(3):339-342

An earthquake of M_w 9.0 struck the Pacific coast in northeast Japan on March 11, 2011 and was followed by a hugely damaging tsunami along 500 km of the Japanese coastline. An inland aftershock of M. 7.0 occurred on April 11; during which, surface fault ruptures appeared on land. A large variety of landslide disasters resulted from these earthquakes in various parts of northeastern Honshu, Japan. The full extent of the landslides is still being determined. This brief report introduces some of the landslide phenomena so far investigated by the Japanese Landslide Society. These are (1) failure of a water reservoir embankment dam in Sukagawa, Fukushima prefecture, (2) landslides and surface seismic fault rupture from the April 11 aftershock in Iwaki, Fukushima, (3) a concentration of surface failures at Matsushima Bay in Miyagi prefecture, and (4) small landslides on modified slopes in residential areas around Sendai city.  相似文献