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41.
Apparent Relative Retardation of Tritium and Bromide in Dolomite 总被引:1,自引:0,他引:1
Darrell I. Leap 《Ground water》1992,30(4):549-558
42.
Matthew S. M. Bolton Britta J. L. Jensen Kristi Wallace Nore Praet David Fortin Darrell Kaufman Marc De Batist 《第四纪科学杂志》2020,35(1-2):81-92
Glass composition-based correlations of volcanic ash (tephra) traditionally rely on extensive manual plotting. Many previous statistical methods for testing correlations are limited by using geochemical means, masking diagnostic variability. We suggest that machine learning classifiers can expedite correlation, quickly narrowing the list of likely candidates using well-trained models. Eruptives from Alaska's Aleutian Arc-Alaska Peninsula and Wrangell volcanic field were used as a test environment for 11 supervised classification algorithms, trained on nearly 2000 electron probe microanalysis measurements of glass major oxides, representing 10 volcanic sources. Artificial neural networks and random forests were consistently among the top-performing learners (accuracy and kappa > 0.96). Their combination as an average ensemble effectively improves their performance. Using this combined model on tephras from Eklutna Lake, south-central Alaska, showed that predictions match traditional methods and can speed correlation. Although classifiers are useful tools, they should aid expert analysis, not replace it. The Eklutna Lake tephras are mostly from Redoubt Volcano. Besides tephras from known Holocene-active sources, Holocene tephra geochemically consistent with Pleistocene Emmons Lake Volcanic Center (Dawson tephra), but from a yet unknown source, is evident. These tephras are mostly anchored by a highly resolved varved chronology and represent new important regional stratigraphic markers. 相似文献
43.
44.
The formation of methylamine (CH3NH2) in the upper troposphere and lower stratosphere of Jupiter is investigated. Translationally hot hydrogen atoms are produced in the photolysis of ammonia, phosphine, and acetylene which react with methane to produce methyl (CH3) radicals; the latter recombine with NH2 to form CH3NH2. Also, methane is catalytically dissociated to CH3 + H by the species C2 and C2H produced in the photolysis of acetylene. It is shown that the combined production of CH3NH2 and subsequent photolysis to HCN is unlikely to account for the HCN observed near Jupiter's tropopause. Recombination of NH2 and C2H5N followed by photolysis to HCN is the preferred path. Production of C2H6 by these two processes is negligible in comparison to the downward flux of C2H6 from the Lyman α photolysis region of CH4. An upper limit column density on CH3PH2 is estimated to be ~1013 cm?2 as compared to 1015 cm?2 for CH3NH2. Hot H atoms account for a negligible fraction of the total ortho-para conversion by the reaction H + H2 相似文献
45.
Novaya Zemlya was covered by the eastern part of the Barents–Kara ice sheet during the glacial maximum of marine isotope stage 2 (MIS 2). We obtained 14 C ages on 37 samples of mollusc shells from various sites on the islands. Most samples yielded ages in the range of 48–26 14 C Ky. Such old samples are sensitive to contamination by young 14 C, and therefore their reliability was assessed using replicate analyses and amino acid geochronology. The extent of aspartic acid racemization (Asp D/L) indicates that many of the 14 C ages are correct, whereas some are minimum ages only. The results indicate that a substantial part of Novaya Zemlya was ice-free about 35–27 14 C Kya, and probably even earlier. Corresponding shorelines up to >140 m a.s.l. indicate a large Barents–Kara ice sheet during early MIS 3. These results are consistent with findings from Svalbard and northern Russia: in both places a large MIS 4/3 Barents–Kara ice sheet is postulated to have retreated about 50 Kya, followed by an ice-free interstadial that lasted until up to ca. 25 Kya. The duration of the MIS 2 glaciation in Novaya Zemlya was calculated by applying the D/L values to a kinetic equation for Asp racemization. This indicates that the islands were ice covered for less than 3000 years if the basal temperature was 0o C, and for less than 10 000 years if it was −5o C. 相似文献
46.
Caleb J. Schiff Darrell S. Kaufman Alexander P. Wolfe Justin Dodd Zachary Sharp 《Journal of Paleolimnology》2009,41(1):189-208
The oxygen isotope ratios of diatoms (δ18Odiatom), and the oxygen and hydrogen isotope ratios of lake water (δW) of lakes in south Alaska provide insight into past changes
in atmospheric circulation. Lake water was collected from 31 lakes along an elevation transect and diatoms were isolated from
lake sediment from one lake (Mica Lake) in south Alaska. In general, δW values from coastal lakes overlap the global meteoric
water line (GMWL). δW values from interior lakes do not lie on the GMWL; they fall on a local evaporation line trajectory
suggesting source isotopes are depleted with respect to maritime lakes. Sediment cores were recovered from 58 m depth in Mica
Lake (60.96° N, 148.15° W; 100 m asl), an evaporation-insensitive lake in the western Prince William Sound. Thirteen calibrated
14C ages on terrestrial macrofossil samples were used to construct an age-depth model for core MC-2, which spans 9910 cal years.
Diatoms from 46, 0.5-cm-thick samples were isolated and analyzed for their oxygen isotope ratios. The analyses employed a
newly designed, stepwise fluorination technique, which uses a CO2 laser-ablation system, coupled to a mass spectrometer, and has an external reproducibility of ±0.2‰. δ18Odiatom values from Mica Lake sediment range between 25.2 and 29.8‰. δ18Odiatom values are relatively uniform between 9.6 and 2.6 ka, but exhibit a four-fold increase in variability since 2.6 ka. High-resolution
sampling and analyses of the top 100 cm of our lake cores suggest large climate variability during the last 2000 years. The
20th century shows a +4.0‰ increase of δ18Odiatom values. Shifts of δ18Odiatom values are likely not related to changes in diatom taxa or dissolution effects. Late Holocene excursions to lower δ18Odiatom values suggest a reduction of south-to-north storm trajectories delivered by meridional flow, which likely corresponds to
prolonged intervals when the Aleutian Low pressure system weakened. Comparisons with isotope records of precipitation (δP)
from the region support the storm-track hypothesis, and add to evidence for variability in North Pacific atmospheric circulation
during the Holocene.
相似文献
Zachary SharpEmail: |
47.
Biomass, net primary productivity (NPP), foliar elemental content, and demography of Thalassia testudinum were monitored in populations from five sites across Florida Bay beginning in January 2001. Sites were selected to take advantage
of the spatial variability in phosphorus (P) availability and salinity climates across the bay. Aboveground biomass and NPP
of T. testudinum were determined five to six times annually. Short-shoot demography, belowground biomass, and belowground NPP were assessed
from a single destructive harvest at each site and short-shoot cohorts were estimated from leaf scar counts multiplied by
site-specific leaf production rates. Biomass, relative growth rate (RGR), and overall NPP were positively correlated with
P availability. Additionally, a positive correlation between P availability and the ratio of photosynthetic to non-photosynthetic
biomass suggests that T. testudinum increases allocation to aboveground biomass as P availability increases. Population turnover increased with P availability,
evident in positive correlations of recruitment and mortality rates with P availability. Departures from seasonally modeled
estimates of RGR were found to be influenced by salinity, which depressed RGR when below 20 psu or above 40 psu. Freshwater
management in the headwaters of Florida Bay will alter salinity and nutrient climates. It is becoming clear that such changes
will affect T. testudinum, with likely feedbacks on ecosystem structure, function, and habitat quality. 相似文献
48.
Identifying outliers and assessing the accuracy of amino acid racemization measurements for geochronology: I. Age calibration curves 总被引:1,自引:1,他引:0
Numerical ages derived from amino acid racemization (AAR) geochronology are typically based on calibration curves that relate the extent of AAR to the age of independently dated specimens. Here, we compare options for developing calibration curves and quantifying age uncertainties using AAR data from 481 late Holocene shells, and AMS 14C analyses of 36 shells of four molluscan taxa (Ethalia, Natica, Tellina, and Turbo) collected from shallow sediment cores from a back-reef lagoon of the central Great Barrier Reef. The four taxa differed substantially in the quality of their geochronogical results. Explicitly including data from specimens alive at the time of collection improves calibration curves, but weighting numerical ages based on their uncertainty has no effect. Calibration curve statistics do not adequately assess calibration uncertainty. The relation between ages inferred from different amino acids is recommended for identifying aberrant specimens and quantifying the uncertainty of inferred ages. For this study, the AAR ages based on two amino acids (aspartic acid and glutamic acid) exceed 200 yr or 20% of their mean inferred age in 15% of the specimens. Once these were removed, the mean age error (1σ) for individual specimens based on two amino acids analyzed in duplicate subsamples ranged from 53 to 142 yr for Tellina and Turbo, respectively, or about a 30% age error for these relatively young shells. This compares favorably with analytical errors estimated at 50 yr or 5%. The presence of notable outliers undetectable using data from single amino acids emphasizes the importance of analyzing multiple amino acids. 相似文献
49.
A. Strobel 《Astronomische Nachrichten》1989,310(5):367-373
The paper proposes a division of the local open clusters into two different disklike subpopulations on the base of the metallicity enhancement history, spatial distribution in the Galaxy and morphology of their C-M diagrams. The thin disk population objects exhibit higher metallicities and are more closely concentrated to the center and the disk of the Galaxy than the thick disk clusters. The former contain also frequently blue stragglers while the later exhibit the presence of Clump giant members, typical for the thick disk globular clusters. Kinematical properties of the two considered open cluster subpopulations remain unknown due to the lack of observational data. 相似文献
50.