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Gold mineralisation in the White River area, 80 km south of the highly productive Klondike alluvial goldfield, is hosted in amphibolite facies gneisses in the same Permian metamorphic pile as the basement for the Klondike goldfield. Hydrothermal fluid which introduced the gold was controlled by fracture systems associated with middle Cretaceous to early Tertiary extensional faults. Gold deposition occurred where highly fractured and chemically reactive rocks allowed intense water–rock interaction and hydrothermal alteration, with only minor development of quartz veins. Felsic gneisses were sericitised with recrystallisation of hematite and minor arsenic mobility, and extensively pyritised zones contain gold and minor arsenic (ca 10 ppm). Graphitic quartzites (up to 5 wt.% carbon) caused chemical reduction of mineralising fluids, with associated recrystallisation of metamorphic minerals (graphite, pyrrhotite, pyrite, chalcopyrite) in host rocks and veins, and introduction of arsenic (up to 1 wt.%) to form arsenopyrite in veins and disseminated through host rock. Veins have little or no hydrothermal quartz, and up to 19 wt.% carbon as graphite. Late-stage oxidation of arsenopyrite in some graphitic veins has formed pharmacosiderite. Gold is closely associated with disseminated and vein sulphides in these two rock types, with grades of up to 3 ppm on the metre scale. Other rock types in the White River basement rocks, including biotite gneiss, hornblende gneiss, pyroxenite, and serpentinite, have not developed through-going fracture systems because of their individual mineralogical and rheological characteristics, and hence have been little hydrothermally altered themselves, have little hydrothermal gold, and have restricted flow of fluids through the rock mass. Some small post-metamorphic quartz veins (metre scale) have been intensely fractured and contain abundant gold on fractures (up to 40 ppm), but these are volumetrically minor. The style of gold mineralisation in the White River area is younger than, and distinctly different from, that of the Klondike area. Some of the mineralised zones in the White River area resemble, mineralogically and geochemically, nearby coeval igneous-hosted gold deposits, but this resemblance is superficial only. The White River mineralisation is an entirely new style of Yukon gold deposit, in which host rocks control the mineralogy and geochemistry of disseminated gold, without quartz veins.  相似文献   
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Dolomitization of a carbonate platform can occur at different times and in different diagenetic environments, from synsedimentary to deep burial settings. Numerical simulations are valuable tools to test and select the model that, among different hypotheses compatible with field and geochemical data, best honour mass balance, kinetic and thermodynamic constraints. Moreover, the simulation can predict the distribution of the dolomitized bodies in the subsurface and evaluate porosity changes; valuable information for the oil industry. This study is the first attempt to reproduce and investigate the compaction dolomitization model. The diagenetic study of the Jurassic carbonate basin and palaeohigh system of the Po Plain indicates that the carbonates of the palaeohighs were dolomitized by basin compaction fluids. The main goal of the simulations is to evaluate the origin and evolution of the dolomitizing fluids and to provide insights regarding the distribution of the potential reservoir‐dolomitized bodies in the Po Plain. The modelling process is subdivided into two steps: basin modelling and reactive transport modelling. The SEBE3 basin simulator (Eni proprietary) was used to create a three‐dimensional model of the compacting system. The results include compaction fluid flow rate from the basin to the palaeohigh, compaction duration and a determination of the total amount of fluid introduced into the palaeohigh. These data are then used to perform reactive transport modelling with the TOUGHREACT code. Sensitivities on dolomite kinetic parameters suggest that dolomitization was an efficient process even at low temperatures, with differences mainly related to the dynamics of the process. Fluid composition is one of the main constraints, the sea water derived compaction fluid is proven to be efficient for dolomitization due to its relatively high Mg content. Simulations also confirmed that permeability is the most important factor influencing fluid flow and, consequently, the dolomite distribution in the formation. Permeable fractured zones have a strong influence, diverting the dolomitizing fluids from their normal path towards overlying or lateral zones. Moreover, the simulations showed that, after dolomite replacement is complete, the dolomitizing fluids can precipitate dolomite cement, causing over‐dolomitization, with related localized plugging effects in the zone of influx. Mass balance calculations indicate that in the dolomitization compaction model, the amount of compaction water fluxed from the basin to the carbonate is the main constraint on dolomitization efficiency. This observation implies that the ratio between the volume of the basin undergoing compaction and the volume of the palaeohigh is a limiting factor on the final size of the dolomitized bodies. An isolated palaeohigh could be an ideal site for pervasive replacement dolomitization due to the large volume of compaction fluids available compared with the carbonate rock volume. In the case of large platforms, the more permeable margin lithofacies are the most likely sites for compaction model dolomitization. The combined use of a basin simulator and reactive transport modelling has proved to be a successful method to verify model reliability and it provides insights into the volumetric distribution of diagenetic products.  相似文献   
37.
Ecological restoration of the Wangaloa coal mine in southern New Zealand is hindered by a range of geoecological factors. The site has some substrate acidification (down to pH 1) and acid rock drainage with discharge waters initially down to pH 4, although this has since risen to ca. pH 6. Surface and ground waters develop elevated sulfate (up to 700 mg/kg) during oxidation of pyrite in coal and quartz in waste rock. Coal has elevated boron content (up to 450 mg/kg) and surface waters on coal-rich waste rock have up to 6 mg/L dissolved boron. Evaporation causes formation of salt encrustations dominated by gypsum with minor boron salts. Boron is bioavailable and may be at toxic levels (>200 mg/kg) in some plants. Quartz-rich waste rock is readily eroded, and develops a cm-scale low-nutrient quartz pebble armouring layer with low water retention properties. All waste rocks including loess siltstone have low nutrient contents, and low moisture retention properties, that are barely sufficient for plant establishment. Native plants introduced to the site during rehabilitation have grown on loess substrate (up to fivefold increase in height over 3 years), with poor or no growth on coal-rich and quartz-rich substrates. In contrast, natural colonisation of manuka (Leptospermum scoparium) has been most effective at revegetation on even the most hostile substrates. This natural revegetation has been facilitated by islands of manuka established accidentally during 60 years of mining history. Manuka from local genetic stock is most viable for this revegetation, and introduced manuka seedlings have had a 70% mortality rate. Natural plant colonisation is the key step in overall ecosystem recovery, and invertebrates rapidly colonise beneath new shrubs irrespective of the nature of the substrate from vegetation islands that have high invertebrate numbers and species richness.  相似文献   
38.
This study examined the impacts of reservoir properties on carbon dioxide (CO2) migration after subsurface injection and evaluated the possibility of characterizing reservoir properties using CO2 monitoring data such as spatial–temporal distributions of gas pressure, which can be reasonably monitored in practice. The injection reservoir was assumed to be located 1,400–1,500 m below the ground surface such that CO2 remained in the supercritical state. The reservoir was assumed to contain layers with alternating conductive and resistive properties, which is analogous to actual geological formations such as the Mount Simon Sandstone unit. The CO2 injection simulation used a cylindrical grid setting in which the injection well was situated at the center of the domain, which extended out 8,000 m from the injection well. The CO2 migration was simulated using the latest version of the simulator, subsurface transport over multiple phases (the water–salt–CO2–energy module), developed by Pacific Northwest National Laboratory. A nonlinear parameter estimation and optimization modeling software package, Parameter ESTimation (PEST), is adopted for automated reservoir parameter estimation. The effects of data quality, data worth, and data redundancy were explored regarding the detectability of reservoir parameters using gas pressure monitoring data, by comparing PEST inversion results using data with different levels of noises, various numbers of monitoring wells and locations, and different data collection spacing and temporal sampling intervals. This study yielded insight into the use of CO2 monitoring data for reservoir characterization and how to design the monitoring system to optimize data worth and reduce data redundancy. The feasibility of using CO2 saturation data for improving reservoir characterization was also discussed.  相似文献   
39.
Crossing structures are an effective method for mitigating habitat fragmentation and reducing wildlife‐vehicle collisions, although high construction costs limit the number that can be implemented in practice. Therefore, optimizing the placement of crossing structures in road networks is suggested as a strategic conservation planning method. This research explores two approaches for using the maximal covering location problem (MCLP) to determine optimal sites to install new wildlife crossing structures. The first approach is based on records of traffic mortality, while the second uses animal tracking data for the species of interest. The objective of the first is to cover the maximum number of collision sites, given a specified number of proposed structures to build, while the second covers as many animal tracking locations as possible under a similar scenario. These two approaches were used to locate potential wildlife crossing structures for endangered Florida panthers (Puma concolor coryi) in Collier, Lee, and Hendry Counties, Florida, a population whose survival is threatened by excessive traffic mortality. Historical traffic mortality records and an extensive radio‐tracking dataset were used in the analyses. Although the two approaches largely select different sites for crossing structures, both models highlight key locations in the landscape where these structures can remedy traffic mortality and habitat fragmentation. These applications demonstrate how the MCLP can serve as a useful conservation planning tool when traffic mortality or animal tracking data are available to researchers.  相似文献   
40.
Any viable theory of modified Newtonian dynamics (MOND) as modified gravity is likely to require fields in addition to the usual tensor field of General Relativity. For these theories, the MOND phenomenology emerges as an effective fifth force probably associated with a scalar field. Here, I consider the constraints imposed on such theories by Solar system phenomenology, primarily by the absence of significant deviations from inverse-square attraction in the inner Solar system as well as detectable local preferred frame effects. The current examples of multifield theories can be constructed to satisfy these constraints and such theories lead inevitably to an anomalous non-inverse-square force in the outer Solar system.  相似文献   
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