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Dolomitization of a carbonate platform can occur at different times and in different diagenetic environments, from synsedimentary to deep burial settings. Numerical simulations are valuable tools to test and select the model that, among different hypotheses compatible with field and geochemical data, best honour mass balance, kinetic and thermodynamic constraints. Moreover, the simulation can predict the distribution of the dolomitized bodies in the subsurface and evaluate porosity changes; valuable information for the oil industry. This study is the first attempt to reproduce and investigate the compaction dolomitization model. The diagenetic study of the Jurassic carbonate basin and palaeohigh system of the Po Plain indicates that the carbonates of the palaeohighs were dolomitized by basin compaction fluids. The main goal of the simulations is to evaluate the origin and evolution of the dolomitizing fluids and to provide insights regarding the distribution of the potential reservoir‐dolomitized bodies in the Po Plain. The modelling process is subdivided into two steps: basin modelling and reactive transport modelling. The SEBE3 basin simulator (Eni proprietary) was used to create a three‐dimensional model of the compacting system. The results include compaction fluid flow rate from the basin to the palaeohigh, compaction duration and a determination of the total amount of fluid introduced into the palaeohigh. These data are then used to perform reactive transport modelling with the TOUGHREACT code. Sensitivities on dolomite kinetic parameters suggest that dolomitization was an efficient process even at low temperatures, with differences mainly related to the dynamics of the process. Fluid composition is one of the main constraints, the sea water derived compaction fluid is proven to be efficient for dolomitization due to its relatively high Mg content. Simulations also confirmed that permeability is the most important factor influencing fluid flow and, consequently, the dolomite distribution in the formation. Permeable fractured zones have a strong influence, diverting the dolomitizing fluids from their normal path towards overlying or lateral zones. Moreover, the simulations showed that, after dolomite replacement is complete, the dolomitizing fluids can precipitate dolomite cement, causing over‐dolomitization, with related localized plugging effects in the zone of influx. Mass balance calculations indicate that in the dolomitization compaction model, the amount of compaction water fluxed from the basin to the carbonate is the main constraint on dolomitization efficiency. This observation implies that the ratio between the volume of the basin undergoing compaction and the volume of the palaeohigh is a limiting factor on the final size of the dolomitized bodies. An isolated palaeohigh could be an ideal site for pervasive replacement dolomitization due to the large volume of compaction fluids available compared with the carbonate rock volume. In the case of large platforms, the more permeable margin lithofacies are the most likely sites for compaction model dolomitization. The combined use of a basin simulator and reactive transport modelling has proved to be a successful method to verify model reliability and it provides insights into the volumetric distribution of diagenetic products.  相似文献   
2.
A detailed study of the pyroclastic deposits of the AD 79 ‘Pompei’Plinian eruption of Vesuvius has allowed: (1) reconstructionof the thermal, compositional and isotopic (87Sr/86Sr) pre-eruptivelayering of the shallow magma chamber; (2) quantitative definitionof the syn-eruptive mixing between the different magmas occupyingthe chamber, and its relationships with eruption dynamics; (3)recognition of the variability of mafic magma batches supplyingthe chamber. During the different phases of the eruption 25–30%of the magma was ejected as white K-phonolitic pumice, and 70–75%as grey K-tephri-phonolitic pumice. The white pumice resultsfrom the tapping of progressively deeper magma from a body (T= 850–900%C) consisting of two distinct layers mainlyformed by crystal fractionation. The grey pumice results fromsyn-eruptive mixing involving three main end-members: the phonolitic‘white’ magmas (salic end-member, SEM), mafic cumulates(cumulate end-member, CEM) and a crystal-poor ‘grey’phono-tephritic magma (mafic end-member, MEM), which was nevererupted without first being mixed with ‘white’ magma.Evidence is provided that mixing occurred within the chamberand was characterized by a transition with time from physicalmixing at a microscopic scale to chemical hybridization. TheMEM magma had a homogeneous composition and constant 87Sr86Srisotopic ratio, possibly as a result of sustained convection.No unambiguous liquidus phases were found, suggesting that theMEM magma was superheated (T = 1000–1100C); its verylow viscosity was a main cause in the establishment of a physicaldiscontinuity separating the white and the grey magmas. Thewhite-grey boundary layer possibly consisted of a multiply diffusiveinterface, periodically broken and recreated, supplying thephonolitic body through mixing of moderate amounts of fractionatedgrey melts with the overlying white magma. The presence of alarge overheated mass indicates the young, growing stage ofthe AD 79 chamber, whose main engine was the periodic arrivalof hot mafic magma batches. These were characterized by K-tephriticto K-basanitic compositions, high temperatures (>1150C),high volatile contents (20–25% H2O +Cl+F+S), low viscosities[(1+2 102 poises)] and relatively low densities (2500–2600kg/m3). The birth of the Pompei chamber followed the repeatedarrival of these batches (on average characterized by 87Sr/86Sr070729)into a reservoir containing a tephriticphonolitic, crystal-enriched,magma, a residue from the preceding ‘Avellino’ Plinianeruption (3400 BP).In fact, about half of magma ejected duringthe AD 79 eruption could have been inherited from pre-Avellinotimes. KEY WORDS: Vesuvius; magma chamber; magma mixing; compositional layering phonolites; magma supply; potassic magmas *Correponding author  相似文献   
3.
A series of laboratory experiments has been carried out in which parallel-laminated deposits were produced from an upper-regime plane bed. The laminae had thicknesses of a few mm and could be traced continuously over distances up to the length and width of the depositional area (0–3 m by 1–5m). Fluctuations in bed elevation were measured both during deposition and at equilibrium; much of the bed fluctuation occurs at time scales that are too long to be due directly to turbulence, as most theories for lamina formation would require. We suggest instead that extremely low-amplitude bed forms are present even on apparently flat beds and that the migration of these bed forms produces laterally continuous lamination. All the lamination produced in the laboratory experiments was normally graded. Using high-speed photography it was observed that the normal grading results from rapid deposition of a layer of loosely packed coarse sand several grain-diameters thick followed by the slow sieving-out of a well packed surface layer of finer sand. The initial deposition is the result of small-scale turbulent fluctuations in boundary shear stress. The sieving-out that follows results in a smooth surface whose low friction coefficient temporarily inhibits further deposition; we term this process ‘glazing’. The alignment of small-scale turbulent scour-and-fill structures along the paths traced by migrating bedform troughs produces laterally continuous parallel lamination.  相似文献   
4.
The Early Jurassic dolomitized carbonates are a hydrocarbon exploration target in Northern Italy. Of these carbonates, the Liassic Albenza Formation platform and the overlying Sedrina Formation shelf were studied to define a pervasive dolomitization model and to shed light on dolomite distribution in the sub‐surface. Field work, as well as analyses of well cores, stable isotopes, trace elements and fluid inclusions, was carried out on the outcropping thrust belt and sub‐surface deformed foreland of the Southern Alps. Petrographic analyses showed a first, pervasive, replacement dolomitization phase (D1) followed by volumetrically less important dolomite cement precipitation phases (D2, D3 and D4). The δ18O values fall between ?8·2‰ and 0·1‰ Vienna‐Pee Dee Belemnite with the more depleted samples belonging to dolomite cement‐rich dolostones; the δ13C ranges from 2·6‰ to 3·7‰ Vienna‐Pee Dee Belemnite. Analysis of trace elements showed different Fe and Mn contents in the sub‐surface and outcropping dolostones, and a higher Fe in the younger dolomite cements. An increase in the precipitation temperature (up to 130 °C from fluid inclusion data) and a decrease in diagenetic fluid salinity (from sea water to brackish) are observed from the first pervasive replacement dolomite to the dolomite cement phases. Field observations indicate that, in the Albenza Formation, dolomitization was limited to palaeohighs or faulted platform margins in the Early Jurassic carbonates. The pervasive replacement phase is interpreted based on a ‘compaction model’; the formation fluids expelled from compacting basinal carbonates could have funnelled along faults into permeable palaeohighs. The high homogenization temperature of the dolomite cements and decreased salinities indicate precipitation at great depth with an influx of meteoric water. These data, along with the thermal history, suggest that the dolomite cements precipitated according to the ‘tectonic squeegee’ dolomitization model. The dolomite precipitation temperature was set against the thermal history of the carbonate platform to interpret the timing of dolomite precipitation. The dolomite precipitation temperatures (90 to 100 °C) were reached in the studied formations first in the thrust fold belt (Early Tertiary, 60 Ma), and then in the foreland succession during the Late Tertiary (10 Ma). This observation suggests that the dolomite precipitation fronts moved southwards over time, recording a ‘diagenetic wave’ linked to the migration of the orogenic system. Observations suggest that the porosity increased during the first phase of replacement dolomitization while the dolomite cementation phases partially occluded the pores. The distribution of porous dolomitized bodies is therefore linked to the ‘compaction dolomitization’ model.  相似文献   
5.
Many problems of practical interest involve line-of-sight on a topographic surface. Some such problems can be successfully studied on the basis of the mutual visibility among a finite number of representative points. Such visibility problems can be formalized and resolved as graph problems. In this paper, we show that graph algorithms can be useful to find efficient solutions for discrete visibility problems in several cases. On the basis of results from the theory of complexity, we give some practical rules to apply such an approach. We further investigate the solution of some relevant visibility problems under this perspective.  相似文献   
6.
Reconstructing random topography from preserved stratification   总被引:2,自引:1,他引:2  
One of the fundamental problems of interpreting the sedimentary record is reconstructing the original heights of palaeotopographical features such as bedforms or river channels. This requires an understanding of the relationship between topography and set thickness, but at present an exact theory exists only for periodic topography of uniform height. The applicability of this simple theory is severely limited by the random variability characteristic of many sedimentary systems. In this paper, we develop an exact theory for the probability-density function (PDF) of sets generated from topography of random height. We focus on the limiting case of zero net deposition in order to provide a lower bound for the set thickness, and derive an analytical set-thickness PDF that is determined by one parameter of the PDF for topographical height. This parameter, β, measures the breadth of the tail of the topographical PDF. The mean set thickness is 0.8225 β for bedforms and 1.645 β for river channels. If the topographical height is gamma distributed, the preservation ratio, defined as (mean thickness of preserved sets)/(mean topographical height), is 0.8225 r2 for bedforms and 1.645 r2 for river channels, where r is the coefficient of variation (standard deviation/mean) of the generating topography. In a comparison with data from laboratory current ripples, our analytical predictions compare well with observations of both mean set thickness and thickness distribution. The preservation ratio for the ripples is about 0.5, whilst measured dune heights give a preservation ratio of about 0.12. Depth data from two modern braided streams yield preservation ratios ranging from 0.4 to 0.75. As more data on the distributions of topographical height in modern environments become available, calculations such as these should help provide reliable error bounds for quantitative topographical reconstruction.  相似文献   
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8.
We have measured the mean magnitude and direction, and the rms fluctuation intensity, of the skin friction behind plain hemispherical obstacles and behind hemispheres with tapered artificial tails one and four obstacle heights long. Downstream of reattachment, the mean skin-friction magnitude is about 20% greater than its free-stream value along the centre-line and comparably reduced to either side of it. The horizontal divergence of the skin-friction vector field is positive (divergent) along the centre-line and negative (convergent) to either side of it. Neither of these conditions favours development of a ridge longer than the separation length along the centre line. The development of ridges or tails many obstacle heights long, commonly observed in nature, requires considerable modification of the simple sediment-free wakes we have studied.  相似文献   
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