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91.
Thirteen Cr-bearing spinels from major horizons of magma replenishment in the open-system Rum Layered Suite have been analysed by X-ray single crystal diffraction and electron microprobe analyses. On the basis of the structural parameters and the chemistry of these spinels the so-called Rum trend, in which Al-content increases at the expense of Cr and Fe3+, has been easily recognised. In addition, natural spinels with Fe3+ content similar to synthetic spinels on the MgCr2O4?CMgFe2O4 join have been analysed for the first time. Layers of chromitite, anorthosite and peridotite situated within several cm of one another have yielded different intracrystalline exchange temperatures using an intercrystalline spinel-olivine thermometer. The Rum anorthosite Cr-spinels are interpreted as having crystallised within the cumulus pile following rejuvenation of the crystal mush. Their low Al-content is a function of simultaneous plagioclase crystallisation, reducing the amount of Al3+ present for the Cr-spinel. By contrast, Cr-spinels in well-known Archean anorthosites (e.g. Ujaragssuit nunat and Fisken?sset, western Greenland) and Sittampundi (southern India) are very aluminous in composition, attributed to crystallisation of Cr-spinel from high-alumina basalts in lower crustal magma chambers and linked to the control exerted by plagioclase crystallisation on Al content of the melt, in the absence of clinopyroxene crystallisation. The compositional differences between the Rum anorthosite Cr-spinels and the Fisken?sset and Sittampundi Cr-spinels suggest that postcumulus reaction of Cr-spinel and melt to low (800?C900°C) temperatures, as invoked for the Rum crystals, may not have been as important a process in the Archean anorthosites.  相似文献   
92.
The intra-crystalline cation partitioning over T- and M-sites in a synthetic Mg(Fe,Al)2O4 spinel sample has been determined as a function of temperature by Rietveld structure refinements from powder diffraction data, combining in situ high-temperature neutron powder diffraction (NPD; POLARIS diffractometer, at ISIS, Rutherford Appleton Laboratory, UK), to determine the Mg and Al occupancy factors, with in situ high-temperature X-ray powder diffraction, to fix the Fe3+ distribution. The results obtained agree with a two-stage reaction, in which an initial exchange between Fe3+ and Mg, the former leaving and the latter entering tetrahedral sites, is successively followed by a rearrangement involving also Al. The measured cation distribution has then been compared and discussed with that calculated by the Maximum Configuration Entropy principle, for which only NPD patterns have been used. The cation partitioning has finally been interpreted in the light of the configuration model of O’Neill and Navrotsky.  相似文献   
93.
We investigate European summer (July–August) precipitation variability and its global teleconnections using the NCEP/NCAR reanalysis data (1950–2010) and a historical Coupled Model Intercomparison Project climate simulation (1901–2005) carried out using the ECHAM6/MPIOM climate model. A wavelike pattern is found in the upper tropospheric levels (200 hPa) similar to the summer circumglobal wave train (CGT) extending from the North Pacific to the Eurasian region. The positive phase of the CGT is associated with upper level anomalous low (high) pressure over western (eastern) Europe. It is further associated with a dipole-like precipitation pattern over Europe entailing significantly enhanced (reduced) precipitation over the western (eastern) region. The anomalous circulation features and associated summer precipitation pattern over Europe inverts for the negative CGT phase. Accordingly, the global teleconnection pattern of a precipitation index summarizing summer precipitation over Western Europe entails an upper level signature which consists of a CGT-like wave pattern extending from the North Pacific to Eurasia. The imprint of the CGT on European summer precipitation is distinct from that of the summer North Atlantic Oscillation, despite the two modes of variability bear strong similarities in their upper level atmospheric pattern over Western Europe. The analysis of simulated CGT features and of its climatic implications for the European region substantiates the existence of the CGT-European summer precipitation connection. The summer CGT in the mid-latitude therefore adds to the list of the modes of large-scale atmospheric variability significantly influencing European summer precipitation variability.  相似文献   
94.
A composite analysis of Northern Hemisphere’s mid-winter tropospheric anomalies under the conditions of strong and weak stratospheric polar vortex was performed on NCEP/NCAR reanalysis data from 1948 to 2013 considering, as additional grouping criteria, the coincidental states of major seasonally relevant climate phenomena, such as El Niño-Southern Oscillation (ENSO), Quasi Biennial Oscillation and strong volcanic eruptions. The analysis reveals that samples of strong polar vortex nearly exclusively occur during cold ENSO states, while a weak polar vortex is observed for both cold and warm ENSO. The strongest tropospheric and near-surface anomalies are found for warm ENSO and weak polar vortex conditions, suggesting that internal tropospheric circulation anomalies related to warm ENSO constructively superpose on dynamical effects from the stratosphere. Additionally, substantial differences are found between the continental winter warming patterns under strong polar vortex conditions in volcanically-disturbed and volcanically-undisturbed winters. However, the small-size samples obtained from the multi-compositing prevent conclusive statements about typical patterns, dominating effects and mechanisms of stratosphere-troposphere interaction on the seasonal time scale based on observational/reanalysis data alone. Hence, our analysis demonstrates that patterns derived from observational/reanalysis time series need to be taken with caution as they not always provide sufficiently robust constraints to the inferred mechanisms implicated with stratospheric polar vortex variability and its tropospheric and near-surface signature. Notwithstanding this argument, we propose a limited set of mechanisms that together may explain a relevant part of observed climate variability. These may serve to define future numerical model experiments minimizing the sample biases and, thus, improving process understanding.  相似文献   
95.
Different flavors of the Atlantic Multidecadal Variability   总被引:2,自引:2,他引:0  
We investigate how differently-constructed indices for North Atlantic sea-surface temperatures (NASSTs) describe the “Atlantic Multidecadal Variability” (AMV) in a suite of unperturbed as well as externally-forced millennial (pre-industrial period) climate simulations. The simulations stem from an ensemble of Earth system models differing in both resolution and complexity. Different criteria exist to construct AMV indices capturing different aspects of the phenomenon. Although all representations of the AMV maintain strong multidecadal variability, they depict different characteristics of simulated low-frequency NASST variability, evolve differently in time and relate to different hemispheric teleconnections. Due to such multifaceted signatures in the ocean-surface as well as in the atmosphere, reconstructions of past AMV may not univocally reproduce multidecadal NASST variability. AMV features under simulated externally-forced pre-industrial climate conditions are not unambiguously distinguishable, within a linear framework, from AMV features in corresponding unperturbed simulations. This prevents a robust diagnosis of the simulated pre-industrial AMV as a predominantly internal rather than externally-forced phenomenon. We conclude that a multi-perspective assessment of multidecadal NASSTs variability is necessary for understanding the origin of the AMV, its physics and its climatic implications.  相似文献   
96.
We consider a network of telescopes capable of scanning all the observable sky each night and targeting Near-Earth objects (NEOs) in the size range of the Tunguska-like asteroids, from 160 m down to 10 m. We measure the performance of this telescope network in terms of the time needed to discover at least 50% of the impactors in the considered population with a warning time large enough to undertake proper mitigation actions. The warning times are described by a trimodal distribution and the telescope network has a 50% probability of discovering an impactor of the Tunguska class with at least one week of advance already in the first 10 yr of operations of the survey. These results suggest that the studied survey would be a significant addition to the current NEO discovery efforts.  相似文献   
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The lower Pliocene Belvedere Formation, cropping out in the Crotone Basin, southern Italy, exhibits a metre‐scale to decametre‐scale shallow‐marine cyclicity that shares features of both high‐frequency sequences linked to shoreline shifts and controlled by minor relative sea‐level and/or sediment supply changes, and sedimentological cycles unrelated to shoreline shifts. In order to better understand the high‐frequency sequence stratigraphic framework of this succession, an integration of sedimentological, micropalaeontological (micro‐foraminifera assemblages) and mineralogical (heavy mineral abundance) data is used. From a sedimentological/stratigraphic point of view, wave‐ravinement surfaces bounding high‐frequency sequences, and associated substrate‐controlled ichnofacies, are prominent in outcrop and document environmental and water‐depth changes, whereas bedset boundaries separating sedimentological cycles have a more subtle field appearance and are only associated with changes of environmental energy. Moreover, condensed deposits are present only above wave‐ravinement surfaces, and the high‐frequency sequences bounded by these surfaces have a thickness that is an order of magnitude greater than that of the bedsets. Micro‐foraminifera assemblages may change, and the content of heavy minerals usually increases, across wave‐ravinement surfaces, whereas both parameters do not change significantly across bedset boundaries. The abundance of heavy minerals is systematically higher, with respect to the underlying and overlying deposits, in the condensed shell beds that overlie wave‐ravinement surfaces. An integrated sedimentological, micropalaeontological and mineralogical approach represents a powerful tool to discriminate between wave‐ravinement surfaces bounding high‐frequency sequences and bedset boundaries, and in general to investigate at the intra high‐frequency sequence scale. This integrated approach is expected to be very useful in the study of potentially all shallow‐marine successions composed of small‐scale cycles, in order to delineate a detailed sequence stratigraphic framework and understand the factors that controlled the cyclicity.  相似文献   
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