Effect of chloride concentration on the decomposition of aqueous sodium nitrate by sunlight     

Gianna L. Petriconi  Enrico G. Gori  Henry M. Papée 《Pure and Applied Geophysics》1969,72(1):299-306

Summary Rates and yields of nitrite formation in solutions, upon irradiation of aqueous sodium nitrate with ultraviolet light, are found to be consistently and considerably enhanced by their chloride content. The process is investigated under conditions met both, in the laboratory and under sunlight illumination, and the effects of altitude and temperature on the reaction studied in the field, are evaluated.  相似文献   

An Experimental Study of the Statistics of Temperature Fluctuations in the Atmospheric Boundary Layer     

Elena Costa Frola  Andrea Mazzino  Federico Cassola  Luca Mortarini  Enrico Ferrero 《Boundary-Layer Meteorology》2014,150(1):91-106

A statistical characterization for two-point temperature fluctuations in the planetary boundary layer (PBL) is analyzed and its implications on the long-standing closure problem discussed. Despite the non-triviality of the dynamics of temperature fluctuations, our analysis supports the idea that the most relevant statistical properties can be captured solely in terms of two scaling exponents. They turned out to be weakly dependent on the stability properties of the PBL. Its statistics have been investigated by collecting data from a field experiment carried out in the urban area of Turin (Italy) from January 2007 to March 2008. Our results confirm those from a large-eddy simulation (LES) analysis carried out for the convective PBL with different level of convection. We extend the scenario to the stable PBL, a regime much more difficult to simulate when exploiting LES.  相似文献   

Mutual Interference of Two Debris Flow Deposits Delivered in a Downstream River Reach   总被引：1，自引：0，他引：1  

STANCANELLI Laura Maria  LANZONI Stefano  FOTI Enrico 《山地科学学报》2014,(6):1385-1395

We investigate experimentally the depositions of two contiguous debris flows flowing into a main river reach.The aim of the present experimental research is to analyze the geometry and the mutual interactions of debris flow deposits conveyed by these tributaries in the main channel.A set of 19 experiments has been conducted considering three values of the confluence angle,two slopes of the tributary,and three different triggering conditions（debris flows occurring simultaneously in the tributaries,or occurring first either in the upstream or in the downstream tributary）.The flow rate along the main channel was always kept constant.During each experiment the two tributaries had the same slope and confluence angle.The analysis of the data collected during the experimental tests indicates that the volume of the debris fan is mainly controlled by the slope angle,as expected,while the shape of the debris deposit is strongly influenced by the confluence angle.Moreover,in the case of multiple debris flows,the deposit shape is sensitive to the triggering conditions.Critical index for damming formation available in literature has been considered and applied to the present case,and,on the basis of the collected data,considerations about possible extension of such indexes to the case of multiple confluences are finally proposed.  相似文献   

Al Huwaysah 010: The most reduced brachinite,so far     

Cristian Carli  Anna Barbaro  Mara Murri  Maria Chiara Domeneghetti  Antonio Langone  Enrico Bruschini  Alice Stephant  Matteo Alvaro  Stefania Stefani  Tiberio Cuppone  Martina Casalini  Alessandra Migliorini  Ted L. Roush  Giovanni Pratesi 《Meteoritics & planetary science》2023,58(6):855-874

Al Huwaysah 010 is an ungrouped achondrite meteorite, recently referred to as a brachinite-like meteorite. This meteorite, showing a fine-grained assemblage of low-Ca pyroxene and opaque phases, is strongly reduced in comparison to other reduced brachinites. The occurrence of some tiny plates of graphite and oldhamite in this meteorite suggests that a partial melt residue has experienced a further reduction process. Olivine, the most abundant phase, is compositionally homogeneous (Fo_83.3) as well as the clinopyroxene (En_45.5Fs_10.8Wo_43.7) and the plagioclase (Ab_69.5). Orthopyroxene (En_85.4Fs_13.9Wo_0.7) also occurs but only in a fine intergrowth. Other accessory phases are Fe metal grains (Ni-free or Cr-bearing Fe-Ni alloy), troilite, chlorapatite, pentlandite (as inclusions in chromite). The sample shows two different closure temperatures: the highest (≈900°C) is determined via the olivine–chromite intercrystalline geothermometer and the lowest temperature (≈520°C) is determined via the pyroxene-based intracrystalline geothermometer. These temperatures may represent, respectively, the closure temperature associated with the formation and a subsequent impact event excavating the sample from the parental body. The visible to near-infrared (VNIR) reflectance spectra of Al Huwaysah 010 exhibit low reflectance, consistent with the presence of darkening components, and weak absorptions indicative of olivine and pyroxene. Comparing the spectral parameters of Al Huwaysah 010 to potential parent bodies characterized by olivine–pyroxene mineralogy, we find that it falls within the field previously attributed to the SIII type asteroids. These results lead us to classify the Al Huwaysah 010 meteorite as the most reduced brachinite, whose VNIR spectral features show strong affinities with those of SIII asteroids.  相似文献   

Resolution dependence of tropical cyclone formation in CMIP3 and finer resolution models   总被引：1，自引：0，他引：1  

Kevin Walsh  Sally Lavender  Enrico Scoccimarro  Hiroyuki Murakami 《Climate Dynamics》2013,40(3-4):585-599

Detection of tropical lows is performed in a suite of climate model simulations using objectively-determined detection thresholds that are resolution-dependent. It is found that there is some relationship between model resolution and tropical cyclone formation rate even after the resolution-dependent tropical cyclone detection threshold is applied. The relationship is investigated between model-simulated tropical cyclone formation and a climate-based tropical cyclone Genesis Potential Index (GPI). It is found that coarser-resolution models simulate the GPI better than they simulate formation of tropical cyclones directly. As a result, there appears to be little relationship from model to model between model GPI and the directly-simulated cyclone formation rate. Statistical analysis of the results shows that the main advantage of increasing model resolution is to give a considerably better pattern of cyclone formation. Finer resolution models also simulate a slightly better pattern of GPI, and for these models there is some relationship between the pattern of GPI simulated by each model and that model’s pattern of simulated tropical cyclone formation.  相似文献   

Climate change in the Paraná state,Brazil: responses to increasing atmospheric CO 2 in reference evapotranspiration     

Lucas da Costa Santos  Jefferson Vieira Jos&#;  Fabiani Denise Bender  Daniel Soares Alves  Pablo Ricardo Nitsche  Elton Fialho dos Reis  Rubens Duarte Coelho 《Theoretical and Applied Climatology》2020,140(1):55-68

The hydrological variable evapotranspiration (ET) is challenging to estimate because it cannot be measured directly in natural environments (except in small plots). The uncertainties associated with the models used for its prediction have increased under climate change conditions. We studied the influence of stomatal resistance on ET estimates using the Penman-Monteith method as projected by three general circulation models in two emission scenarios (RCP4.5 and RCP8.5) for future climates throughout the twenty-first century (2010–2039, 2040–2069, and 2070–2099). We also investigated the probable ET rate changes in relation to the current (30 years average, 1980–2009) climate conditions for the Paraná state in the southern region of Brazil. The results were regionalized to help policymakers assess climate change impacts and design adaptation measures. ET increases of up to 15% were found in future climate conditions, which may lead to a significant increase in the water demand for agricultural crops. However, we believe that plant morphophysiological changes may occur under atmospheric CO2 enrichment conditions and that a possible reduction in stomatal conductance will result in lower ET increases than those obtained with the traditional Penman-Monteith method. When considering future climate scenarios, we propose the equation be adjusted to consider stomatal resistance as a function of CO2 concentrations.  相似文献   

Gaussian Processes for history-matching: application to an unconventional gas reservoir     

Hamidreza Hamdi  Ivo Couckuyt  Mario Costa Sousa  Tom Dhaene 《Computational Geosciences》2017,21(2):267-287

The process of reservoir history-matching is a costly task. Many available history-matching algorithms either fail to perform such a task or they require a large number of simulation runs. To overcome such struggles, we apply the Gaussian Process (GP) modeling technique to approximate the costly objective functions and to expedite finding the global optima. A GP model is a proxy, which is employed to model the input-output relationships by assuming a multi-Gaussian distribution on the output values. An infill criterion is used in conjunction with a GP model to help sequentially add the samples with potentially lower outputs. The IC fault model is used to compare the efficiency of GP-based optimization method with other typical optimization methods for minimizing the objective function. In this paper, we present the applicability of using a GP modeling approach for reservoir history-matching problems, which is exemplified by numerical analysis of production data from a horizontal multi-stage fractured tight gas condensate well. The results for the case that is studied here show a quick convergence to the lowest objective values in less than 100 simulations for this 20-dimensional problem. This amounts to an almost 10 times faster performance compared to the Differential Evolution (DE) algorithm that is also known to be a powerful optimization technique. The sensitivities are conducted to explain the performance of the GP-based optimization technique with various correlation functions.  相似文献   

Numerical modelling assessment of climate-change impacts and mitigation measures on the Querença-Silves coastal aquifer (Algarve,Portugal)     

Rui Hugman  Tibor Stigter  Luis Costa  José Paulo Monteiro 《Hydrogeology Journal》2017,25(7):2105-2121

Predicted changes in climate will lead to seawater intrusion in the Querença-Silves (QS) coastal aquifer (south Portugal) during the coming century if the current water-resource-management strategy is maintained. As for much of the Mediterranean, average rainfall is predicted to decrease along with increasing seasonal and inter-annual variability and there is a need to understand how these changes will affect the sustainable use of groundwater resources. A density-coupled flow and transport model of the QS was used to simulate an ensemble of climate, water-use and adaptation scenarios from 2010 to 2099 taking into account intra- and inter-annual variability in recharge and groundwater use. By considering several climate models, bias correction and recharge calculation methods, a degree of uncertainty was included. Changes in rainfall regimes will have an immediate effect on groundwater discharge; however, the effect on saltwater intrusion is attenuated by the freshwater–saltwater interfaces’ comparatively slow rate of movement. Comparing the effects of adaptation measures demonstrates that the extent of intrusion in the QS is controlled by the long-term water budget, as the effectiveness of both demand and supply oriented measures is proportional to the change in water budget, and that to maintain the current position, average groundwater discharge should be in the order of 50 × 10⁶ m³ yr^?1.  相似文献   

Relationship between geoacoustic properties and chemical content of submarine polymetallic crusts from offshore Brazil     

Arthur Ayres Neto  Vanessa Alves da Costa  Clara Pinto Ferreira Maia Porto  Thais Cristina Vargas Garrido  Jean-Pierre Hermand 《Marine Georesources & Geotechnology》2020,38(4):437-449

Abstract

Marine mining is the ocean’s new exploration frontier, and polymetallic crusts (PMCs) and ferromanganese nodules are considered a strategic resource for the future. Acoustic geophysical methods are a valuable tool for oceanic research and have been employed for several decades in the exploration of marine resources and environmental evaluations. The main objective of this work was to investigate the correlation between the chemical composition of PMCs from three different areas along the Brazilian continental margin and their physico-acoustic attributes (P-wave velocity, density and acoustic impedance). The results show that the geoacoustic properties of PMCs are correlated to their chemical composition. Measurements showed positive and negative trends between acoustic impedance and studied elements (Fe, Mn, Co, Cu, Zn, W and Ni) according to the direction of measurement, indicting high anisotropy levels. Our study sheds initial light on the correlation between acoustic properties and metal content of PMCs. The study facilitates assessments of the acoustic responses of PMCs allowing more efficient prospection and exploitation compared to ship-board geophysical techniques that are too qualitative to identify PMCs. The results can contribute to determining the best procedures and techniques for more efficient future exploration of this resource.  相似文献   

New Reference Materials,Analytical Procedures and Data Reduction Strategies for Sr Isotope Measurements in Geological Materials by LA-MC-ICP-MS     

Jacob Mulder  Graham Hagen-Peter  Teresa Ubide  Rasmus Andreasen  Ellen Kooijman  Melanie Kielman-Schmitt  Yue-Xing Feng  Bence Paul  Andreas Karlsson  Christian Tegner  Charles Lesher  Fidel Costa 《Geostandards and Geoanalytical Research》2023,47(2):311-336

Laser ablation multi-collector mass spectrometry (LA-MC-ICP-MS) has emerged as the technique of choice for in situ measurements of Sr isotopes in geological minerals. However, the method poses analytical challenges and there is no widely adopted standardised approach to collecting these data or correcting the numerous potential isobaric inferences. Here, we outline practical analytical procedures and data reduction strategies to help establish a consistent framework for collecting and correcting Sr isotope measurements in geological materials by LA-MC-ICP-MS. We characterise a new set of plagioclase reference materials, which are available for distribution to the community, and present a new data reduction scheme for the Iolite software package to correct isobaric interferences for different materials and analytical conditions. Our tests show that a combination of Kr-baseline subtraction, Rb-peak-stripping using βRb derived from a bracketing glass reference material, and a CaCa or CaAr correction for plagioclase and CaCa or CaAr + REE²⁺ correction for rock glasses, yields the most accurate and precise ⁸⁷Sr/⁸⁶Sr measurements for these materials. Using the analytical and correction procedures outlined herein, spot analyses using a beam diameter of 100 μm or rastering with a 50–65 μm diameter beam can readily achieve < 100 ppm 2SE repeatability ("internal") precision for ⁸⁷Sr/⁸⁶Sr measurements for materials with < 1000 μg g^-1 Sr.  相似文献