Chemical and structural study of 1M- and 2M 1-phlogopites coexisting in the same Kasenyi kamafugitic rock (SW Uganda)     

Maria Lacalamita  Ernesto Mesto  Fernando Scordari  Emanuela Schingaro 《Physics and Chemistry of Minerals》2012,39(8):601-611

In the present work, crystal chemical variations between 1M and 2M ₁ phlogopites coexisting in the same rock sample from kamafugite of Kasenyi (southwest Uganda, west branch of the East African Rift) were explored by electron probe microanalyses, single crystal X-ray diffraction and M?ssbauer spectroscopy. Chemical analyses revealed close similarity both within and between the two polytypic arrangements as well as high TiO₂ (~4.9?wt%) and Al₂O₃ (~12.9?wt%), and low Cr₂O₃ (~0.8?wt%), F (~0.3?wt%) and BaO (~0.2?wt%) contents. Room temperature ⁵⁷Fe M?ssbauer investigation proved that the studied mica is a tetraferriphlogopite with: ^IVFe³⁺?=?19(1)?%, ^VIFe²⁺?=?58(1)?%, ^VIFe³⁺?=?23(1)?%. Single crystal refinement showed that both polytypes have narrow range of variation in terms of some relevant unit cell parameters and similar values in terms of mean bond lengths, mean atomic numbers and distortion parameters. Similar substitutions were active in the structure of the 1M and 2M ₁ studied phlogopites. However, in 2M ₁ polytypes the oxy-type substitutions were found to occur to a greater extent. Comparison of unit layer of 1M mica (in the 2M ₁ setting) with that of the 2M ₁ ones showed that the 2M ₁ polytypes are affected to different extent by relative shifts of the upper and lower triads of octahedral oxygens along the ±b directions. This effect did not cause any symmetry lowering in the T-O-T layer of the studied samples.  相似文献   

Ostreopsis cf. ovata bloom in the northern Adriatic Sea during summer 2009: ecology, molecular characterization and toxin profile     

Accoroni S  Romagnoli T  Colombo F  Pennesi C  Di Camillo CG  Marini M  Battocchi C  Ciminiello P  Dell'Aversano C  Dello Iacovo E  Fattorusso E  Tartaglione L  Penna A  Totti C 《Marine pollution bulletin》2011,62(11):2512-2519

Intense blooms of the benthic dinoflagellate Ostreopsis cf. ovata have occurred in the northern Adriatic Sea since 2006. These blooms are associated with noxious effects on human health and with the mortality of benthic organisms because of the production of palytoxin-like compounds. The O. cf. ovata bloom and its relationships with nutrient concentrations at two stations on the Conero Riviera (northern Adriatic Sea) were investigated in the summer of 2009. O. cf. ovata developed from August to November, with the highest abundances in September (1.3 × 10⁶ cells g⁻¹ fw corresponding to 63.8 × 10³ cells cm⁻²). The presence of the single O. cf. ovata genotype was confirmed by a PCR assay. Bloom developed when the seawater temperature was decreasing. Nutrient concentrations did not seem to affect bloom dynamics. Toxin analysis performed by high resolution liquid chromatography-mass spectrometry revealed a high total toxin content (up to 75 pg cell⁻¹), including putative palytoxin and all the ovatoxins known so far.  相似文献   

Quantifying Multipath Using MNR Ratios     

Ricardo Ernesto Schaal  Nicola Paciléo Netto 《GPS Solutions》2000,3(3):44-48

The global positioning system (GPS) is used increasingly to control horizontal and vertical displacement of large civil constructions. The displacements can occur over varius time scales. For example, in case of the loading test of a bridge, the time span between measurements is on the order of 30 min. The achievable precision in the vertical component and its relation to residual multiplath effects become critically important in such aaplications. A multipath-to-noise ratio (MNR) on individual satellites is introduced to quantify the multipath effects. ? 2000 John Wiley & Sons, Inc.  相似文献   

Symbiodinium (internal transcribed spacer 2) diversity in the coral host Agaricia lamarcki (Cnidaria: Scleractinia) between shallow and mesophotic reefs in the Northern Caribbean (20–70 m)          下载免费PDF全文

Matthew Q. Lucas  Michael Stat  Matthew C. Smith  Ernesto Weil  Nikolaos V. Schizas 《Marine Ecology》2016,37(5):1079-1087

This study investigated differences in Symbiodinium diversity in the scleractinian coral species Agaricia lamarcki between shallow (20–25 m) and mesophotic (50–70 m) depths in the Northern Caribbean. Corals were sampled in each of four shallow sites (20–25 m; n = 18) and three mesophotic sites (50–70 m; n = 18) from Mona Island (Puerto Rico) and the US Virgin Islands during a mesophotic exploratory cruise and from the La Parguera shelf edge, off Southwestern Puerto Rico. Symbiodinium diversity was assessed using internal transcribed spacer 2 sequences clustered into operational taxonomic units (OTUs). Clustering resulted in eight clade C OTUs and one clade D OTU. Of these, there were three common Symbiodinium OTUs consisting of C3 and D1a.N14 in shallow reefs and C11.N4 in mesophotic reefs. Statistical tests (permutational multivariate analysis of variance and analysis of similarity) showed significant differences between clade C Symbiodinium OTUs in A. lamarcki colonies located at shallow and mesophotic depths, indicating symbiont zonation. Symbiodinium diversity in A. lamarcki from the Northern Caribbean is comparable to previous reports in the Southern Caribbean for this species. This is the first report of the thermal tolerant species Symbiodinium trenchii (D1a) in A. lamarcki.  相似文献   

Isotopic signatures of organic matter in sediments of the continental shelf facing the Orinoco Delta: Possible contribution of organic carbon from savannas     

Ernesto Medina  Marta Francisco  Leonel Sternberg  William T. Anderson 《Estuarine, Coastal and Shelf Science》2005,63(4):527-536

The ⁸⁷Sr, ¹³C, and ¹⁵N isotopic signatures of organic matter in sediments from the continental shelf facing the Orinoco Delta were measured to determine the contribution of sediments transported from the Amazon River by the coastal Guayana current and the sediments transported by the Orinoco River. Box core samples between 60 and 300 m water depth collected along 4 transects located eastwards to the Orinoco Delta were analyzed. Carbon and nitrogen concentrations decreased with depth under water on the shelf, and were strongly correlated indicating homogeneity of organic matter composition. Phosphorus content was also associated to organic matter in most samples, but some of them revealed deposition of P-enriched sediments. The ⁸⁷Sr/⁸⁶Sr ratios showed a strong continental signature averaging 0.7117, therefore, limiting the possible carbon and nitrogen sources associated with these sediments to C3 trees, C4 grasses, or freshwater phytoplankton. The δ¹³C values were relatively high averaging −21‰, above values reported for sediments on the Amapá shelf and the Amazon River in Brazil. Average δ¹³C values did not differ significantly among transects. High δ¹³C values point to the influence of organic matter transported from the C4-plants dominated savannas in the northern fringe of the Orinoco River. δ¹⁵N values were positive and averaged 5‰, being within the range of values measured in the Marajo island (Amazon River) and the estuary of the Pará River. The δ¹⁵N values differed significantly among transects (4.9–5.2‰), lowest values corresponding to the northernmost transect near the coast of Trinidad, and the highest values corresponding to the transect located at the southernmost position.  相似文献   

The distribution and δC of dissolved organic carbon and its humic fraction in estuaries of southeastern USA     

Ernesto Otero  Randolph Culp  John E. Noakes  Robert E. Hodson 《Estuarine, Coastal and Shelf Science》2003,56(5-6):1187-1194

In this study, we examine the distribution and carbon stable isotope signature of dissolved organic carbon (DOC) and humic substances (HS) along a salinity gradient in the Altamaha and Satilla River estuaries. The maximum DOC concentrations in the Altamaha and Satilla were 10 and 29 mg C l⁻¹, respectively, though concentrations were similar at the mouth of both estuaries. There was a decrease in HS content of DOC from 50 to 80% at the head of the estuaries to 10% at salinities higher than 30‰. The δ¹³C DOC varied between −25.5 and −19‰ and between −27 and −21‰ in the Altamaha and Satilla estuaries, respectively. The tendency towards more depleted δ¹³C DOC in the Satilla, especially in the lower salinity portion of this estuary, suggests greater terrestrial inputs in the Satilla than in the Altamaha. Seasonal fluctuations were observed in the form of increased (two to three times) range in DOC concentration, heavier δ¹³C DOC and increased proportion of estuarine–marine-derived DOC (average enrichment of δ¹³C DOC from +1 to +2) during low river flow (July–October). The δ¹³C HS in both rivers showed a similar trend, but was consistently more depleted than DOC, with an average range from −28 to −24.5‰. This suggests that HS have larger proportions of terrestrial components (a maximum of >60% at the mouth of the estuary) than DOC. The less depleted δ¹³C values of DOC in comparison with HS indicate a different source for the non-humic (non-HS) component of DOC (range in δ¹³C non-HS, −22 to −16‰). That source could either be the decomposition of detrital material derived from saltmarsh environments or microalgal-derived DOC of estuarine or marine origins.  相似文献   

On the Misuse of the Simplest Transport Model     

Ernesto Baca 《Ground water》1999,37(4):483-483

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Contamination of Caribbean coastal waters by the antifouling herbicide Irgarol 1051     

Carbery K  Owen R  Frickers T  Otero E  Readman J 《Marine pollution bulletin》2006,52(6):635-644

Irgarol 1051 is a s-triazine herbicide used in popular slime-resistant antifouling paints. It has been shown to be acutely toxic to corals, mangroves and sea grasses, inhibiting photosynthesis at low concentrations (>50 ng l(-1)). We present the first data describing the occurrence of Irgarol 1051 in coastal waters of the Northeastern Caribbean (Puerto Rico (PR) and the US Virgin Islands (USVI)). Low level contamination of coastal waters by Irgarol 1051 is reported, the herbicide being present in 85% of the 31 sites sampled. It was not detected in water from two oceanic reference sites. In general, Irgarol 1051was present at concentrations below 100 ng l(-1), although far higher concentrations were reported at three locations within Benner Bay, USVI (223-1,300 ng l(-1)). The known toxicity of Irgarol 1051 to corals and sea grasses and our findings of significant contamination of the Northeastern Caribbean marine environment by this herbicide underscore the importance of understanding, more fully, local and regional exposure of reef and sea grass habitats to Irgarol 1051 and, where necessary, implementing actions to ensure adequate protection of these important ecosystems.  相似文献   

Infrared micro-spectroscopy of the martian meteorite Zagami: Extraction of individual mineral phase spectra     

Ernesto Palomba  Alessandra Rotundi 《Icarus》2006,182(1):68-79

Zagami, a well characterized SNC meteorite, represents a reference sample to verify the feasibility of the non-destructive infrared micro-spectroscopy technique to extract spectral signatures from individual mineral phases in a meteorite sample. For the first time individual infrared spectra of the major mineral phases, in the 6000-600 cm⁻¹ (1.67-16.7 μm) spectral interval, whose identification is confirmed by energy dispersive X-ray analysis and backscattered imaging, are measured. The signatures of the main mineral phases we identified in the Zagami chip are: (1) maskelynite characterized by broad and smooth SiO vibrational bands in the 1000 cm⁻¹ spectral region; (2) crystalline pyroxenes showing well defined fine structures; and (3) an oxide mineral phase with an almost featureless and flat spectrum. In the part of the spectrum centered around 2 μm, by analyzing the different positions of the Fe²⁺ bands, we were able to discern the high-Ca from the low-Ca pyroxene phases. This result demonstrates that by means of the infrared micro-spectroscopy technique it is possible to retrieve directly the composition of pyroxenes in the En-Fs-Wo system, without relying on the use of deconvolution techniques. In addition IR signatures due to water and aliphatic hydrocarbons were observed to be more abundant in the pyroxenes than in maskelynite. This could be an indication that the organic and water signatures are due to indigenous compounds in Zagami rather than laboratory contamination, however, further investigations are necessary before this conclusion can be confirmed.  相似文献   

Kinematic analysis of a transtensional fault system: The Atuel depocenter of the Neuquén basin,southern Central Andes,Argentina     

Florencia Bechis  Laura Giambiagi  Víctor García  Silvia Lanés  Ernesto Cristallini  Maisa Tunik 《Journal of Structural Geology》2010,32(7):886-899

The Atuel depocenter of the Neuquén basin originated as an Upper Triassic to Lower Jurassic rift system, later inverted during the Andean contractional deformation. In order to study the extensional architecture and the kinematic evolution of this depocenter, we collected a large amount of field and sub-surface data, consisting of slip data from outcrop-scale normal faults, thickness and facies distribution within the synrift deposits, and structural data from angular and progressive unconformities. The Atuel depocenter has a NNW trend, showing a bimodal distribution of NNW and WNW major faults (first and second order faults). On the other hand, from kinematic indicators measured on outcrop-scale faults (third and fourth order faults), we found a mean NE internal extension direction, which is oblique to the general trend of the sub-basin. Taking these particular characteristics into account, we interpreted the Atuel depocenter as an oblique rift system. We evaluated two mechanisms in order to explain the development of this transtensional system: 1) reactivation of upper-crustal NNW-oriented Paleozoic shear zones, and 2) oblique stretching of a previous NNW-oriented lithospheric weakness zone.  相似文献