The gas-phase reaction of ClONO2 with hydrogen chloride     

Roger Atkinson  Sara M. Aschmann  Ernesto C. Tuazon  Mark A. Goodman  Arthur M. Winer 《Journal of Atmospheric Chemistry》1987,5(1):83-90

The gas-phase reaction of ClONO₂ with HCl was investigated using two large-volume environmental chambers with analysis by in situ long pathlength Fourier transform infrared absorption spectroscopy. In these chambers the reaction was observed to proceed, at least in part, by heterogenous routes, and an upper limit to the rate constant for the homogeneous gas-phase reaction of geneous routes, and an upper limit to the rate constant for the homogeneous gas-phase reaction of $$k\left( {{\text{ClONO}}_{\text{2}} + {\text{HCl}}} \right) < 1.5 \times 10^{ - 19} {\text{ cm}}^{\text{3}} {\text{ molecule}}^{{\text{ - 1}}} {\text{ s}}^{{\text{ - 1}}}$$ Was derived at 298±2K. Assuming that this room-temperature upper limit to the rate constant is applicable to stratospheric temperatures, this homogeneous gas-phase reaction can be estimated to be of negligible importance as a ClONO₂ loss process in the stratosphere.  相似文献   

Quantifying the reefscape transformation of a coastal Caribbean coral reef during a phase shift and the associated coastal landscape change          下载免费PDF全文

Abigail Martínez‐ Rendis  Gilberto Acosta González  José Luis Hernández‐Stefanoni  Jesús Ernesto Arias González 《Marine Ecology》2016,37(3):697-710

Caribbean coral reefs are under strong natural and human pressures and many have undergone phase shifts as a result of local and global change. However few studies have quantified the extent of these phase shifts and the potential impacts that they have on coral reef communities. A temporal comparative analysis of several coral reefscape and landscape metrics was conducted for data from Mahahual, Quintana Roo, Mexico, between the years 2000 and 2006, when a phase shift occurred. Landscape metrics were calculated from coral reef and coastal cover maps obtained by multispectral satellite image classification using IKONOS satellite imagery. These metrics showed that the coastal landscape and reefscape of Mahahual lost 85 ha of vegetation cover and 43 ha of coral cover over 6 years, respectively. Coastal landscape transformation was induced by the construction of a cruise ship pier and multiple associated tourist developments along the coast, such as hotels and restaurants, meanwhile alteration of the reefscape may be associated with potential stressors such as coastal development, bleaching events and hurricanes.  相似文献   

Atmospheric electricity at Brébeuf college geophysical observatory in Montréal,Canada     

Ernesto E. Gherzi 《Pure and Applied Geophysics》1967,67(1):239-265

Summary The author gives the results obtained by means of nine years (1957–1965 inclusive) of recordings of the potential gradient and two years (1964–1965 inclusive) of the current density. Some general aspects of these registrations are discussed.  相似文献   

Water regime in soils and plants along an aridity gradient in central Baja California, Mexico     

Ernesto Franco-Vizcaíno 《Journal of Arid Environments》1994,27(4)

The Central Desert of Baja California has pronounced climatic gradients. Water storage in the upper metre of soil and leaf water potentials in Larrea tridentata, Simmondsia chinensis and Fouquieria columnaris were monitored during 28 months at six sites. Estimated annual evapotranspiration was 75-150 mm in sandy loams, and 45-60 mm in sandy soils. Cumulative recharge accounted for 80% of precipitation in loams, but only 50% in sands. During the study period, increased aridity was expressed as longer periods of drought, but there was no less recharge. Weak to moderate relationships were found between soil water content and predawn leaf water potential.  相似文献   

Analysis of crustal deformation in Luzon, Philippines using geodetic observations and earthquake focal mechanisms   总被引：1，自引：0，他引：1  

Gerald Galgana  Michael Hamburger  Robert McCaffrey  Ernesto Corpuz  Qizhi Chen 《Tectonophysics》2007,432(1-4):63-87

We utilize regional GPS velocities from Luzon, Philippines, with focal mechanism data from the Harvard Centroid Moment Tensor (CMT) Catalog, to constrain tectonic deformation in the complex plate boundary zone between the Philippine Sea Plate and Eurasia (the Sundaland block). Processed satellite imagery and digital elevation models are used with existing gravity anomaly, seismicity, and geologic maps to define a suite of six elastic blocks. Geodetic and focal mechanism data are inverted simultaneously to estimate plate rotations and fault-locking parameters for each of the tectonic blocks and faults comprising Luzon. Major tectonic structures that were found to absorb the plate convergence include the Manila Trench (20–100 mm yr^− 1) and East Luzon Trough ( 9–15 mm yr^− 1)/Philippine Trench ( 29–34 mm yr^− 1), which accommodate eastward and westward subduction beneath Luzon, respectively; the left-lateral strike-slip Philippine Fault ( 20–40 mm yr^− 1), and its northward extensions, the Northern Cordillera Fault ( 17–37 mm yr^− 1 transtension), and the Digdig Fault ( 17–27 mm yr^− 1 transpression). The Macolod Corridor, a zone of active volcanism, crustal thinning, extension, and extensive normal and strike-slip faulting in southwestern Luzon, is associated with left-lateral, transtensional slip of  5–10 mm yr^− 1. The Marikina Fault, which separates the Central Luzon block from the Southwestern Luzon block, reveals  10–12 mm yr^− 1 of left-lateral transpression. Our analysis suggests that much of the Philippine Fault and associated splays are locked to partly coupled, while the Manila and Philippine trenches appear to be poorly coupled. Luzon is best characterized as a tectonically active plate boundary zone, comprising six mobile elastic tectonic blocks between two active subduction zones. The Philippine Fault and associated intra-arc faults accommodate much of the trench-parallel component of relative plate motion.  相似文献   

Combined electromagnetic, geochemical and thermal surveys of Taal volcano (Philippines) during the period 2005–2006     

J. Zlotnicki  Y. Sasai  J. P. Toutain  E. U. Villacorte  A. Bernard  Julio P. Sabit  Juan M. Gordon Jr  Ernesto G. Corpuz  M. Harada  J. T. Punongbayan  H. Hase  T. Nagao 《Bulletin of Volcanology》2009,71(1):29-47

Since 1572, 33 phreatic to phreatomagmatic eruptions have occurred on Taal volcano (Philippines), some of them causing several hundred casualties. Considering the time delay between two consecutive eruptions, there is an 88% probability that Taal volcano should have already erupted. Since 1992, several phases of seismic activity have been recorded accompanied by ground deformation, opening of fissures, and surface activity. The volcanic activity of Taal appears to be controlled by dike injections and magma supply, buffered by a hydrothermal system that releases fluids and heat through boiling and subsequent steaming. In early 2005, a multidisciplinary project was launched for studying the hydrothermal activity. To map the hydrothermal system, combined surveys were carried out to investigate self-potential, total magnetic field, ground temperature and carbon dioxide soil degassing, along with satellite thermal imaging of the Main Crater Lake. The elevated temperatures and high concentrations of carbon dioxide, as well as electromagnetic anomalies, indicate large-scale hydrothermal degassing. This process is enhanced along the tectonic features (e.g., crater rim and faults) of the volcano, while active fissures opened along the E–W northern flank during the 1992–1994 seismic activity. Heat and fluids from the hydrothermal system are essentially released in the northern part of the crater, which is bounded to the South by a suspected NW–SE fault along which seismicity seems to take place, and dikes are thought to be intruded. During the January 2005 surveys, a new seismic crisis started, and the felt earthquakes prompted spontaneous evacuation of hundreds of inhabitants living on the volcano. Repeated surveys show changes of self-potential, total magnetic field, and ground temperature with time, without any noticeable spatial enlargement. These observations suggest that the northern flank located between the crater rim and the 1992–1994 fissures is connected with a deep thermal source in Main crater and is reactivated during seismic crises. This sector could be subjected to flank failure.  相似文献   

Corrigendum to “Assessment of non-point sources of fecal pollution in coastal waters of Puerto Rico and Trinidad” [Marine Pollution Bulletin 60 (2010) 1117–1121]     

Dave S. Bachoon  Shanu Markand  Ernesto Otero  Garvin Perry  Adesh Ramsubhag 《Marine pollution bulletin》2010,60(12):2358

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A baroclinic coastal trapped wave event in the Gulf of Naples (Tyrrhenian Sea)     

Paola de Ruggiero  Ernesto Napolitano  Roberto Iacono  Stefano Pierini  Giancarlo Spezie 《Ocean Dynamics》2018,68(12):1683-1694

In this study, a baroclinic coastal trapped wave, with period ~?4.5 days and cross-shore scale ~?3 km, is identified in the outputs of a very-high-resolution ocean circulation model of the Campania coastal system (central Tyrrhenian Sea; including the Gulfs of Salerno, Naples, and Gaeta). The outputs are from a simulation spanning June 2003, a month in which the surface winds were always weak, except for a strong northeasterly wind event that lasted 1 day (20 June). This event is found to generate a strong upwelling along the Campania coasts, whose relaxation—virtually free, because of the weakness of the winds—produces coastal current fluctuations that propagate to the north, spanning the three gulfs. The dynamics (analyzed with a focus on the Gulf of Naples) is found to share important features with baroclinic Kelvin waves in a two-layer model, such as the sharp cross-shore decrease of the perturbation amplitude and the vertical reversal of the long-shore current velocities. The simulated phase speed, cross-shore extension, and wavelength of the perturbation are also close to those obtained using a two-layer approximation of the dynamics. Moreover, the propagation described by the models is shown to be compatible with current measurements that were made in June 2003 at the southern entrance of the Gulf of Naples. Experimental implications related to the specific oceanographic problem are finally discussed, and an experimental strategy—inspired by our modeling approach—aimed at identifying the phenomenon is proposed.  相似文献   

Depositional controls on mixed carbonate–siliciclastic cycles and sequences on gently inclined shelf profiles          下载免费PDF全文

Michael Zeller  Klaas Verwer  Gregor P. Eberli  Jose Luis Massaferro  Ernesto Schwarz  Luis Spalletti 《Sedimentology》2015,62(7):2009-2037

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Multimodal ensemble Kalman filtering using Gaussian mixture models     

Laura Dovera  Ernesto Della Rossa 《Computational Geosciences》2011,15(2):307-323

In this paper we present an extension of the ensemble Kalman filter (EnKF) specifically designed for multimodal systems. EnKF data assimilation scheme is less accurate when it is used to approximate systems with multimodal distribution such as reservoir facies models. The algorithm is based on the assumption that both prior and posterior distribution can be approximated by Gaussian mixture and it is validated by the introduction of the concept of finite ensemble representation. The effectiveness of the approach is shown with two applications. The first example is based on Lorenz model. In the second example, the proposed methodology combined with a localization technique is used to update a 2D reservoir facies models. Both applications give evidence of an improved performance of the proposed method respect to the EnKF.  相似文献