Evaluating new fault-controlled hydrothermal dolomitization models: Insights from the Cambrian Dolomite,Western Canadian Sedimentary Basin     

Ardiansyah Koeshidayatullah  Hilary Corlett  Jack Stacey  Peter K. Swart  Adrian Boyce  Hamish Robertson  Fiona Whitaker  Cathy Hollis 《Sedimentology》2020,67(6):2945-2973

Fault-controlled hydrothermal dolomitization in tectonically complex basins can occur at any depth and from different fluid compositions, including ‘deep-seated’, ‘crustal’ or ‘basinal’ brines. Nevertheless, many studies have failed to identify the actual source of these fluids, resulting in a gap in our knowledge on the likely source of magnesium of hydrothermal dolomitization. With development of new concepts in hydrothermal dolomitization, the study aims in particular to test the hypothesis that dolomitizing fluids were sourced from either seawater, ultramafic carbonation or a mixture between the two by utilizing the Cambrian Mount Whyte Formation as an example. Here, the large-scale dolostone bodies are fabric-destructive with a range of crystal fabrics, including euhedral replacement (RD1) and anhedral replacement (RD2). Since dolomite is cross-cut by low amplitude stylolites, dolomitization is interpreted to have occurred shortly after deposition, at a very shallow depth (<1 km). At this time, there would have been sufficient porosity in the mudstones for extensive dolomitization to occur, and the necessary high heat flows and faulting associated with Cambrian rifting to transfer hot brines into the near surface. While the δ¹⁸O_water and ⁸⁷Sr/⁸⁶Sr ratios values of RD1 are comparable with Cambrian seawater, RD2 shows higher values in both parameters. Therefore, although aspects of the fluid geochemistry are consistent with dolomitization from seawater, very high fluid temperature and salinity could be suggestive of mixing with another, hydrothermal fluid. The very hot temperature, positive Eu anomaly, enriched metal concentrations, and cogenetic relation with quartz could indicate that hot brines were at least partially sourced from ultramafic rocks, potentially as a result of interaction between the underlying Proterozoic serpentinites and CO₂-rich fluids. This study highlights that large-scale hydrothermal dolostone bodies can form at shallow burial depths via mixing during fluid pulses, providing a potential explanation for the mass balance problem often associated with their genesis.  相似文献   

Climatic signals in lacustrine deposits of the Upper Yacoraite Formation,Western Argentina: Evidence from clay minerals,analcime, dolomite and fibrous calcite     

João Paulo B. Gomes  Rodrigo B. Bunevich  Sandra N. Tonietto  Daisy B. Alves  Julice F. Santos  Fiona F. Whitaker 《Sedimentology》2020,67(5):2282-2309

Authigenic clays are an important control on reservoir quality in lacustrine carbonates but remain challenging to predict. Lacustrine depositional systems respond to climatic variations in rainfall, surface runoff and groundwater input, and evaporation, and result in rapid and frequent changes in lake volume; this is expressed through changing water depth and shoreline position. In the upper portion of the Early Palaeocene Yacoraite Formation of the Salta Basin in Argentina, extensive lacustrine deposits were deposited during the sag phase of rifting. Prior high-resolution stratigraphic studies have suggested that climatic factors control microbial carbonate sequences within a ‘balanced fill’ lake, with variation in the lake level having a major influence on facies association changes. This study characterizes the evolution of facies and mineralogy within the Yacoraite Formation, focusing on the distribution of clay minerals, making a link between the high, medium and low-frequency sequence stratigraphic cycles. The low-frequency transgressive hemicycle of the upper portion of the Yacoraite Formation is comprised of abundant siliciclastic facies, suggesting a wetter period. Microbialites occurring in this interval are coarse-grained and agglutinated. Detrital clay minerals such as illite and chlorite and associated siliciclastic sediments were input to the lake during high-frequency transgressive periods. During high-frequency regressive hemicycles, sedimentation was dominated by carbonate facies with Ca-rich dolomite and the authigenic clays are comprised of chlorite/smectite mixed-layers. By contrast, the low frequency regressive hemicycle records fine-grained agglutinated microbialite with horizons of fibrous calcite, more stoichiometric dolomite, barite and authigenic magnesian smectite. This indicates elevated ion concentrations in the lake under intense evaporation during an arid period. Understanding the conditions that are favourable for formation and preservation of authigenic clays within the lacustrine environment can improve understanding of reservoir quality in comparable economically important deposits.  相似文献   

Field Demonstration of the Horizontal Treatment Well (HRX Well®) for Passive In Situ Remediation     

Craig E. Divine  Jesse Wright  Michelle Crimi  J.F. Devlin  Michael Lubrecht  Jack Wang  Jeff McDonough  Michael Kladias  Jesse Hinkle  Allison Cormican  Trevor Osorno  Blossom N. Nzeribe  Fiona Laramay  Daniel Ombalski  Kathleen Gerber  Hunter Anderson 《Ground Water Monitoring & Remediation》2020,40(3):42-54

The horizontal reactive media treatment well (HRX Well®) uses directionally drilled horizontal wells filled with a treatment media to induce flow-focusing behavior created by the well-to-aquifer permeability contrast to passively capture proportionally large volumes of groundwater. Groundwater is treated in situ as it flows through the HRX Well and downgradient portions of the aquifer are cleaned via elution as these zones are flushed with clean water discharging from the HRX Well. The HRX Well concept is particularly well suited for sites where long-term mass discharge control is a primary performance objective. This concept is appropriate for recalcitrant and difficult-to-treat constituents, including chlorinated solvents, per- and polyfluoroalkyl substances (PFAS), 1,4-dioxane, and metals. A full-scale HRX Well was installed and operated to treat trichloroethene (TCE) with zero valent iron (ZVI). The model-predicted enhanced flow through the HRX Well (compared to the flow in and equivalent cross-sectional area orthogonal to flow in the natural formation before HRX Well installation) and treatment zone width was consistent with flows and widths estimated independently by point velocity probe (PVP) testing, HRX Well tracer testing, and observed treatment in downgradient monitoring wells. The actual average capture zone width was estimated to be between 45 and 69 feet. Total TCE mass discharge reduction was maintained through the duration of the performance monitoring period and exceeded 99.99% (%). Decreases in TCE concentrations were observed at all four downgradient monitoring wells within the treatment zone (ranging from 50 to 74% at day 436), and the first arrival of treated water was consistent with model predictions. The field demonstration confirmed the HRX Well technology is best suited for long-term mass discharge control, can be installed under active infrastructure, requires limited ongoing operation and maintenance, and has low life cycle energy and water requirements.  相似文献   

Lava penetrating water: the different behaviours of pāhoehoe and ‘a‘ā at the Nesjahraun, Tingvellir, Iceland     

John Alexander Stevenson  Neil Charles Mitchell  Fiona Mochrie  Michael Cassidy  Harry Pinkerton 《Bulletin of Volcanology》2012,74(1):33-46

The Nesjahraun is a basaltic lava flow erupted from a subaerial fissure, extending NE along the Tingvellir graben from the Hengill central volcano that produced pāhoehoe lava followed by ‘a‘ā. The Nesjahraun entered Iceland’s largest lake, Tingvallavatn, along its southern shore during both phases of the eruption and exemplifies lava flowing into water in a lacustrine environment in the absence of powerful wave action. This study combines airborne light detection and ranging, sidescan sonar and Chirp seismic data with field observations to investigate the behaviour of the lava as it entered the water. Pāhoehoe sheet lava was formed during the early stages of the eruption. Along the shoreline, stacks of thin (5–20 cm thick), vesicular, flows rest upon and surround low (<5 m) piles of coarse, unconsolidated, variably oxidised spatter. Clefts within the lava run inland from the lake. These are 2–5 m wide, >2 m deep, ∼50 m long, spaced ∼50 m apart and have sub-horizontal striations on the walls. They likely represent channels or collapsed tubes along which lava was delivered into the water. A circular rootless cone, Eldborg, formed when water infiltrated a lava tube. Offshore from the pāhoehoe lavas, the gradient of the flow surface steepens, suggesting a change in flow regime and the development of a talus ramp. Later, the flow was focused into a channel of ‘a‘ā lava, ∼200–350 m wide. This split into individual flow lobes 20–50 m wide along the shore. ‘A‘ā clinker is exposed on the water’s edge, as well as glassy sand and gravel, which has been locally intruded by small (<1 m), irregularly shaped, lava bodies. The cores of the flow lobes contain coherent, but hackly fractured lava. Mounds consisting predominantly of scoria lapilli and the large paired half-cone of Grámelur were formed in phreatomagmatic explosions. The ‘a‘ā flow can be identified underwater over 1 km offshore, and the sidescan data suggest that the flow lobes remained coherent flowing down a gradient of <10°. The Nesjahraun demonstrates that, even in the absence of ocean waves, phreatomagmatic explosions are ubiquitous and that pāhoehoe flows are much more likely to break up on entering the water than ‘a‘ā flows, which, with a higher flux and shallow underlying surface gradient, can penetrate water and remain coherent over distances of at least 1 km.  相似文献   

Abyssal and hydrated mantle wedge serpentinised peridotites: a comparison of the 15$$^\circ$$20$$'$$′N fracture zone and New Caledonia serpentinites     

Fiona?Elizabeth?Mothersole  Katy?EvansEmail authorView author&#;s OrcID profile  B.?Ronald?Frost 《Contributions to Mineralogy and Petrology》2017,172(8):69

Subduction of serpentinised mantle transfers oxidised and hydrated mantle lithosphere into the Earth, with consequences for the oxidation state of sub-arc mantle and the genesis of arc-related ore deposits. The role of subducted serpentinised mantle lithosphere in earth system processes is uncertain because subduction fluxes are poorly constrained. Most subducted serpentinised mantle is serpentinised on the ocean floor settings. Yet this material is poorly represented in the literature because it is difficult to access. Large volumes of accessible serpentinite are available in ophiolite complexes, and most interpretations of subduction fluxes associated with ultramafic rocks are based on ophiolite studies. Seafloor and ophiolite serpentinisation can occur under different conditions, so it is necessary to assess if ophiolite serpentinites are a good proxy for seafloor serpentinites. Serpentinites sampled during ODP cruise 209 were compared with serpentinites from New Caledonia. The ODP209 serpentinites were serpentinised by modified seawater in a shallow hydrothermal seafloor setting. The New Caledonia serpentinites were serpentinised in a mantle wedge setting by slab-derived fluids, with possible contributions from oceanic serpentinisation and post-obduction serpentinisation. Petrological, whole rock and mineralogical analyses were combined to compare the two sample sets. Petrologically, the evolution of serpentinisation was close to identical in the two environments. However, more oxidised iron, Cl, S and C is present in serpentine from the ODP209 serpentinites relative to the New Caledonia serpentinites. Given these observations, the use of serpentinites from different geodynamic settings as a proxy for abyssal serpentinites from spreading settings must be undertaken with caution.  相似文献   

Low temperature (LT) combustion of sediments does not necessarily provide accurate radiocarbon ages for site chronology     

Fiona Brock  Duane G. Froese  Richard G. Roberts 《Quaternary Geochronology》2010,5(6):625-630

Radiocarbon dating of soils and sediments is notoriously problematic for the purposes of dating a specific event due to their heterogeneous mix of multiple organic fractions, each of which may have a different radiocarbon age. Numerous studies have failed to agree on which sedimentary fraction or radiocarbon pre-treatment method, if any, provides the closest agreement between the age of a sedimentary fraction and that of associated plant macrofossils or charcoal. We tested the stepped-combustion method of McGeehin et al. (2001), as well as standard radiocarbon humin and humic extraction techniques, using samples from a chronologically well-constrained perennially-frozen site at Quartz Creek, Yukon Territory, Canada. The ages in closest agreement with associated radiocarbon-dated plant macrofossils and with the overlying Dawson tephra were given by the humic and humin fractions, but even these were still older than the macrofossil ages by up to 4195 ± 260 radiocarbon years. The low temperature (LT) humin method recommended by McGeehin et al. (2001) yielded ages older than the macrofossils by up to nearly 4425 ± 240 radiocarbon years. These fractions, while still providing information on the mobility and potential residence times of carbon in soils and sediments, should not be relied upon to provide consistently accurate site chronologies.  相似文献   

Fisheries mismanagement     

O'Leary BC  Smart JC  Neale FC  Hawkins JP  Newman S  Milman AC  Roberts CM 《Marine pollution bulletin》2011,62(12):2642-2648

We analysed the extent to which European politicians have adhered to scientific recommendations on annual total allowable catches (TACs) from 1987 to 2011, covering most of the period of the Common Fisheries Policy (CFP). For the 11 stocks examined, TACs were set higher than scientific recommendations in 68% of decisions. Politically-adjusted TACs averaged 33% above scientifically recommended levels. There was no evidence that the 2002 reform of the CFP improved decision-making, as was claimed at the time. We modelled the effects of such politically-driven decision-making on stock sustainability. Our results suggest that political adjustment of scientific recommendations dramatically increases the probability of a stock collapsing within 40 years.In 2012 European fisheries policy will undergo a once-a-decade reform. Ten years ago radical reforms were promised but the changes failed to improve sustainability. It is likely that the 2012 reform will be similarly ineffective unless decision-making is changed so that catch allocations are based on science rather than politics.  相似文献   

Comparison of nitrate attenuation characterization methods at the Uranium mill tailing site in Monument Valley, Arizona     

Kenneth C. Carroll  Fiona L. Jordan  Edward P. Glenn  W. Jody Waugh  Mark L. Brusseau   《Journal of Hydrology》2009,378(1-2):72-81

Several methods for characterizing the occurrence and rate of nitrate attenuation were tested at a field site near Monument Valley, Arizona. Spatial and temporal nitrate concentration data collected from a transect of monitoring wells located along the plume centerline were analyzed to evaluate the overall rates of natural attenuation. The occurrence and rate of denitrification was evaluated through microcosm experiments, nitrogen isotopic fractionation analysis, and solute-transport modeling. First-order denitrification-rate coefficients calculated with each method were comparable. In addition, the composite natural attenuation rate coefficient was similar to the denitrification-rate coefficients, which suggests that microbially induced decay primarily controls nitrate attenuation at the site. This research highlights the benefits associated with a multiple-method approach for the characterization of natural attenuation.  相似文献   

Higher order clustering in the Durham/UKST and Stromlo–APM Galaxy Redshift Surveys     

Fiona Hoyle  Istvan Szapudi†  Carlton M. Baugh 《Monthly notices of the Royal Astronomical Society》2000,317(3):L51-L56

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Collating Historic Weather Observations for the East Asian Region:Challenges,Solutions,and Reanalyses     

Fiona WILLIAMSON  Rob ALLAN  Guoyu REN  Tsz-cheung LEE  Wing-hong LUI  Hisayuki KUBOTA  Jun MATSUMOTO  Jürg LUTERBACHER  Clive WILKINSON  Kevin WOOD 《大气科学进展》2018,35(8):899-904

正1.Introduction Historic instrumental weather observations,made on land or at sea from as early as the 17th century(e.g.,Camuffo et al.,2010),are integral to extending our understanding of the decadal and centennial variations of Earth’s climate and for comparison with paleo-proxy data.The potential of such data is shown to best effect when used in dynamical 4D global  相似文献