Structure of the Mérida Andes, Venezuela: relations with the South America–Caribbean geodynamic interaction     

Felipe E. Audemard  Franck A. Audemard   《Tectonophysics》2002,345(1-4)

For over 50 years, several models based on diverse geologic concepts and variable quality of data have been proposed to explain the major structure and history of the Mérida Andes (MA), in western Venezuela. Lately, this chain growth and associated flexural basins deepening have been related to incipient type-A subductions of either polarity, accounting for the across-chain asymmetry. However, these recent models have not well integrated the present tectonically active setting driven by neighboring major plate interactions. At present, this chain exhibits ongoing strain partitioning where cumulative right-lateral slip along chain axis is as much as half of, or about the same, as the transverse shortening since late Miocene, thus implying that the NNE-directed Maracaibo block extrusion with respect to the South America (SA) plate is not a secondary feature. Consequently, this paper discusses some limitations exhibited by the SE-directed continental subduction models—Maracaibo crust underthrusting the Mérida Andes—in the light of available geological and geophysical data. Besides, it is herein proposed that the Mérida Andes structuration is related to a NW-directed, gently dipping, incipient type-A subduction, where chain growth and evolution are similar to those of a sedimentary accretionary wedge (i.e., Barbados), but at crustal scale and with ongoing strain partitioning. This continental subduction is the SE portion of a major orogenic float that also comprises the Perijá range and the Santa Marta block.  相似文献   

热带印度-太平洋浮游有孔虫Pulleniatina obliquiloculata的B/Ca和Cd/Ca指标：次表层海水碳化学参数计算的应用     

党皓文  王婷婷  乔培军  BASSINOT Franck  翦知湣 《海洋学报(英文版)》2019,38(3):138-150

Pulleniatina obliquiloculata shells from 16 core-top samples from the tropical Indo-Pacific Oceans are analyzed for the ratios of boron and cadmium to calcium(B/Ca and Cd/Ca). The B/Ca ratios show a very weak positive relationship with [B(OH)_4~-] and the dissolved carbonate species at the apparent calcification depth of P.obliquiloculata. The boron partition coefficients(K_D) between P. obliquiloculata B/Ca and seawater[B(OH)_4~-]/[HCO_3~-] distribute around 1.1×10~(-3)-1.3×10~(-3) with a mean value of(1.19±0.12)×10~(-3),and are significantly related to the nutrient concentration, especially phosphate. The lack of any clear correlation between the P. obliquiloculata B/Ca and seawater carbonate chemical parameters suggests that the physiochemical controls on boron incorporation are masked by the complexity of natural seawater condition. But the significant dependence of Ku on nutrient may likely be explained by a nutrient related growth-rate effect. Cd/Ca of P.obliquiloculata shows significant correlation with seawater phosphate concentration, and its partition coefficients(D_(cd)) are significantly related to temperature. A first-principle methodology of P. obliquiloculata B/Ca is applied;with the aid of Cd/Ca as a phosphate proxy and a constraint on K_D, to estimating sea water carbonate chemistry(e.g., pH). The results are fairly promising and allow us to propose the possibility to apply the combination of B/Ca and Cd/Ca proxies(and also Mg/Ca and δ~(18)O for estimating temperature and salinity) for the paleoreconstruction of seawater carbonate chemistry.  相似文献   

Observations of contrasted glacial-interglacial dissolution of foraminifera above the lysocline in the Bay of Bengal,northeastern Indian Ocean     

Duo Wang  Xuan Ding  Franck Bassinot 《海洋学报(英文版)》2021,40(1):155-161

Site U1446 (19°50’N, 85°44’E, at water depth 1 430 m) was drilled during Expedition 353 (Indian monsoon rainfall) of the International Ocean Discovery Program (IODP). It is located in the Mahanadi offshore basin, on the northern Bay of Bengal. Sedimentation rates and contents of biocarbonates are high at this relatively shallow site. Using a micropaleontological approach, we examined planktonic and benthic foraminifera in the upper around 40 m of this site, spanning the last around 190 ka. A striking feature of the foraminiferal record is the occurrence of strong but varying dissolution although the site is located well above the modern lysocline. Such strong dissolution has never been reported in this area. We estimated the flux of foraminifera and quantified the ratio of benthic foraminifera over total foraminifera (benthic/total foraminifera) along with the foraminifer fragmentation index in order to characterize past changes in this above-lysocline dissolution. This study reveals a clear glacial-interglacial contrast, with a stronger dissolution during marine isotope stages (MISs) 1 and 5 than during MISs 2–4 and 6. Such a difference in preservation is likely to have a strong impact on geochemical proxies measured on foraminifera. Our new observations call for an in-depth study of the causes of such above-lysocline dissolution in the region, and an evaluation of its impact on the foraminifera-based proxies used for paleoenvironmental reconstruction.  相似文献   

Sand blows as a potential tool for magnitude estimation of pre-instrumental earthquakes     

Raymi A. Castilla  Franck A. Audemard 《Journal of Seismology》2007,11(4):473-487

A worldwide database of liquefaction-induced sand blows has been compiled to generate empirical relationships between earthquake parameters and sand blow geometries. Curves resulting from these empirical relationships can be used afterwards for the study of historic and pre-historic earthquakes that formed sand blows. This database only incorporates instrumental earthquakes inducing sand blows, characterised in terms of magnitude (Mw), hypocentral location and focal mechanism solution. Two relationships are herein presented. The first curve, minimum likelihood of liquefaction occurrence (magnitude/epicentral distance), displays a logarithmic behaviour, as others already proposed. The second curve of sand-blow diameter vs epicentral distance is the first proposal of this kind, whose shape follows a negative power-law. Magnitude estimations of (pre-)historic earthquakes then may be attempted through these empirical relationships. Resulting magnitudes derived from these curves should be mostly considered as underestimated. The curves will reflect actual magnitudes only if, correspondingly, the farthest and largest blow has ever been reported during the after-earthquake survey. Following the same principle, a magnitude estimation resulting from the measuring of a sand blow can only be considered as minimal because it is almost impossible to ascertain that the measured feature is the biggest one produced by the earthquake under evaluation. Finally, these results call for thorough surveys of induced effects after every future moderate-to-large earthquake, as any empirical relationship simply improves by incorporating new data.  相似文献   

CO₂-Laser Extraction-Static Mass Spectrometry Analysis of Ultra-Low Concentrations of Nitrogen in Silicates     

Franck Humbert  Guy Libourel  Christian France-Lanord  Laurent Zimmermann  Bernard Marty 《Geostandards and Geoanalytical Research》2000,24(2):255-260

A new installation for the analysis of picomole quantities of nitrogen has been designed and constructed. It permits the simultaneous analysis of N and rare gases extracted from silicates by heating. The extraction procedure involves the use of a CO₂ laser as a heater, and the analysis is made by static mass spectrometry using a high sensitivity, high resolution mass spectrometer. Procedural blanks of 2 picomoles N₂ (60 picogram N) allow us to analyse routinely N in mg-sized samples such as mantle-derived and meteoritic minerals, and Lunar soil grains.  相似文献   

First experimental determination of iron isotope fractionation between hematite and aqueous solution at hydrothermal conditions     

Gaëlle Saunier  Franck Poitrasson 《Geochimica et cosmochimica acta》2011,75(21):6629-6654

Although iron isotopes provide a new powerful tool for tracing a variety of geochemical processes, the unambiguous interpretation of iron isotope ratios in natural systems and the development of predictive theoretical models require accurate data on equilibrium isotope fractionation between fluids and minerals. We investigated Fe isotope fractionation between hematite (Fe₂O₃) and aqueous acidic NaCl fluids via hematite dissolution and precipitation experiments at temperatures from 200 to 450 °C and pressures from saturated vapor pressure (P_sat) to 600 bar. Precipitation experiments at 200 °C and P_sat from aqueous solution, in which Fe aqueous speciation is dominated by ferric iron (Fe^III) chloride complexes, show no detectable Fe isotope fractionation between hematite and fluid, Δ⁵⁷Fe_{fluid-hematite} = δ⁵⁷Fe_fluid − δ⁵⁷Fe_hematite = 0.01 ± 0.08‰ (2 × standard error, 2SE). In contrast, experiments at 300 °C and P_sat, where ferrous iron chloride species (FeCl₂ and FeCl⁺) dominate in the fluid, yield significant fluid enrichment in the light isotope, with identical values of Δ⁵⁷Fe_{fluid-hematite} = −0.54 ± 0.15‰ (2SE) both for dissolution and precipitation runs. Hematite dissolution experiments at 450 °C and 600 bar, in which Fe speciation is also dominated by ferrous chloride species, yield Δ⁵⁷Fe_{fluid-hematite} values close to zero within errors, 0.15 ± 0.17‰ (2SE). In most experiments, chemical, redox, and isotopic equilibrium was attained, as shown by constancy over time of total dissolved Fe concentrations, aqueous Fe^II and Fe^III fractions, and Fe isotope ratios in solution, and identical Δ⁵⁷Fe values from dissolution and precipitation runs. Our measured equilibrium Δ⁵⁷Fe_{fluid-hematite} values at different temperatures, fluid compositions and iron redox state are within the range of fractionations in the system fluid-hematite estimated using reported theoretical β-factors for hematite and aqueous Fe species and the distribution of Fe aqueous complexes in solution. These theoretical predictions are however affected by large discrepancies among different studies, typically ±1‰ for the Δ⁵⁷Fe _{Fe(aq)-hematite} value at 200 °C. Our data may thus help to refine theoretical models for β-factors of aqueous iron species. This study provides the first experimental calibration of Fe isotope fractionation in the system hematite-saline aqueous fluid at elevated temperatures; it demonstrates the importance of redox control on Fe isotope fractionation at hydrothermal conditions.  相似文献   

Precise Determination of Silicon Isotopes in Silicate Rock Reference Materials by MC‐ICP‐MS     

Thomas Zambardi  Franck Poitrasson 《Geostandards and Geoanalytical Research》2011,35(1):89-99

A HF‐free sample preparation method was used to purify silicon in twelve geological RMs. Silicon isotope compositions were determined using a Neptune instrument multi‐collector‐ICP‐MS in high‐resolution mode, which allowed separation of the silicon isotope plateaus from their interferences. A 1 μg g^‐1 Mg spike was added to each sample and standard solution for online mass bias drift correction. δ³⁰Si and δ²⁹Si values are expressed in per mil (‰), relative to the NIST SRM 8546 (NBS‐28) international isotopic RM. The total variation of δ³⁰Si in the geological reference samples analysed in this study ranged from ‐0.13‰ to ‐0.29‰. Comparison with δ²⁹Si values shows that these isotopic fractionations were mass dependent. IRMM‐17 yielded a δ³⁰Si value of ‐1.41 ± 0.07‰ (2s, n = 12) in agreement with previous data. The long‐term reproducibility for natural samples obtained on BHVO‐2 yielded δ³⁰Si = ‐0.27 ± 0.08‰ (2s, n = 42) on a 12 month time scale. An in‐house Si reference sample was produced to check for the long‐term reproducibility of a mono‐elemental sample solution; this yielded a comparable uncertainty of ± 0.07‰ (2s, n = 24) over 5 months.  相似文献   

Stable isotopes of oxygen and carbon compositions in the Neoproterozoic of South Gabon (Schisto-Calcaire Subgroup, Nyanga Basin): Are cap carbonates and lithoherms recording a particular destabilization event after the Marinoan glaciation?     

Alain Prat  Jean-Pierre Prian  Denis Thiblemont  Rolf Mabicka Obame  Franck Delpomdor 《Journal of African Earth Sciences》2011,60(4):273

  相似文献   

Weathering of sandstone lotus petals at the Angkor site: a 1,000-year stone durability trial   总被引：1，自引：1，他引：0  

Marie-Françoise André  Bruno Phalip  Olivier Voldoire  Franck Vautier  Yves Géraud  Mhammed Benbakkar  Christophe Constantin  Fabienne Huber  Gilles Morvan 《Environmental Earth Sciences》2011,63(7-8):1723-1739

This article is based on field investigations carried out at Ta Keo and Banteay Srei temples (Angkor, Cambodia), which have similar environmental histories and display the same recurrent decorative pattern (lotus petal) in three different sandstone lithotypes. Based on two original scales of mechanical and chemical weathering, the degree of deterioration of c.2000 sandstone petals was visually assessed, resulting in the proposal of a durability scale. An explanatory scheme was provided, based on laboratory analyses of stone materials (ICP-AES, XRD, SEM-EDS, polarizing microscopy and mercury injection). The key drivers of sandstone durability are both mineralogical and petrophysical. The remarkable preservation of the pink sandstone is due to the quartzose nature of its clasts, the non-swelling clay content of its abundant matrix (kaolinite) and its porosity structure (large connected pores and probable non-connected porosity). The overall good preservation of the green sandstone is due to its extremely low porosity and specific surface area, associated with its strong cementation. The severe deterioration of the grey sandstone is due to its laminated structure (oriented biotites), the susceptibility to hygric swelling and solution of its binding agents (chlorite/smectite and calcite) and its porosity structure, which evolves during a two-stage weathering sequence. The first stage is characterized by a bimodal porosity due to the partial clogging of macropores by swelling clays, and the second stage by a substantial increase in porosity and the penetration of salts (barite and anhydrite). Conversely, oxidation phenomena associated with weathering can lead to a drastic reduction of porosity.  相似文献   

Carbon pools in an arid shrubland in Chile under natural and afforested conditions   总被引：1，自引：0，他引：1  

J.F. Perez-Quezada  C.A. DelpianoK.A. Snyder  D.A. JohnsonN. Franck 《Journal of Arid Environments》2011,75(1):29-37

The pattern of carbon (C) allocation among the different pools is an important ecosystem structural feature, which can be modified as a result of changes in environmental conditions that can occur gradually (e.g., climatic change) or abruptly (e.g., management practices). This study quantified the C pools of plant biomass, litter and soil in an arid shrubland in Chile, comparing the natural condition (moderately disturbed by grazing) vs. the afforested condition (two-year-old plantation with Acacia saligna (Labill.) H.L. Wendl.), each represented by a 60 ha plot. To estimate plant biomass, allometric functions were constructed for the four dominant woody species, based on the volume according to their shape, which showed high correlation (R² > 0.73). The soil was the largest C pool in both natural and afforested conditions (89% and 94%, respectively) and was significantly lower in the afforested than natural condition at all five soil depths. The natural condition had in total 36.5 ton (t) C ha⁻¹ compared to 21.1 t C ha⁻¹ in the afforested condition, mainly due to C loss during soil preparation, prior to plantation of A. saligna. These measurements serve as an important baseline to assess long-term effects of afforestation on ecosystem C pools.  相似文献