Origin of organic sulphur compounds and sulphur-containing high molecular weight substances in sediments and immature crude oils     

Jaap S. Sinninghe Damst  W. Irene  C. Rijpstra  Jan W. de Leeuw  P.A. Schenck 《Organic Geochemistry》1988,13(4-6)

The distribution patterns of Organic Sulphur Compounds (OSC), occurring in certain sediments and immature crude oils, were compared with those of the corresponding hydrocarbons. Because of the complexity of the OSC mixtures, they were desulphurized to hydrocarbons (n-alkanes, isoprenoid alkanes, steranes, triterpanes and branched alkanes). The hydrocarbons produced by desulphurization of the OSC exhibited distribution patterns different from those of the hydrocarbons originally present. Therefore reaction of elemental sulphur with these hydrocarbons at elevated temperatures must be considered as an unlikely origin for these OSC. Sulphur incorporation reactions on an intramolecular basis with suitable functionalized precursors at the early stages of diagenesis are probably the major origin for these OSc. Desulphurization of high molecular weight fractions also produced hydrocarbons, dominated by n-alkanes up to C₄₀. Therefore it is assumed that these substances contain n-alkanes, 2,5-dialkyl-thiophenes and -thiolanes linked to each other by sulphur briddges. These findings stronly suggest that sulphur-containing high molecular weight substances are formed by the same sulphur incorporation reactions as OSC, but in an intermolecular fashion.  相似文献   

Application of the TEX₈₆ temperature proxy to the southern North Sea     

Lydie Herfort  Stefan Schouten  Jan P. Boon  Jaap S. Sinninghe Damst 《Organic Geochemistry》2006,37(12):1715

A novel temperature proxy, the tetraether index of lipids with 86 carbon atoms (TEX₈₆), was applied to the suspended particulate organic matter (POM) and sediment core tops from eight sites in the southern North Sea in different seasons. The TEX₈₆-derived temperatures in many samples did not correlate with mean annual sea surface temperature (SST), but were shifted toward winter SST, apparently because Crenarchaeota are more abundant and metabolically active during periods of low primary production. This indicates that TEX₈₆-derived SST estimates do not necessarily reflect annual mean SST and may provide essential information about seasonal SST palaeoreconstruction. High TEX₈₆-derived SSTs were measured in the water of the river Rhine and in the sediment core tops and seawater from several stations in the southern North Sea. These sites were all characterised by important input of organic matter from soil and peat, as revealed by the relatively high values obtained with the new terrestrial proxy, the branched and isoprenoid tetraether (BIT) index. These data demonstrate that to reconstruct palaeotemperatures it is essential to estimate both TEX₈₆ and BIT indices to check that TEX₈₆ temperatures are not biased as a result of large terrestrial input. Important seasonal variations in TEX₈₆-derived SST were also evident for the surface sediments of several stations characterised by extremely low sedimentation rates, indicating temporary settlement of laterally transported organic matter with a warmer temperature signal. This implies that sediment core top correlations between TEX₈₆ and mean annual SST should not be carried out in areas characterised by transient sediment deposition.  相似文献   

Lithotype discrimination within a gridded model by inverting gravity data     

Tim van Zon  Pavel Ditmar  Kabir Roy Chowdhury  Jaap Mondt 《Geophysical Journal International》2007,170(2):481-491

In this paper we present a method which allows delineation of geologic structures in a bi-modal lithotype setting. We propose to use gravity data in combination with a priori information about the density contrast between the two lithotypes. The iterative method uses an objective function with five tunable parameters which need to be set. Using an efficient parameter search, suitable ranges of these are investigated to determine their optimal values, respectively, which in turn, ensures good inversion results.
The approach produces structural images of the subsurface, without the need of an a priori density model; the depth to the top of the inhomogeneity is also retrieved.
Besides synthetic simulations, the methodology has also been applied to a small gravity data set, acquired by the industry over a basinal structure. A consistent, bi-modal image of the bedrock depression is obtained from the data, which, in this case, was the goal. Other potential areas of application include delineation of salt structures and ore deposits.  相似文献   

Estudos do Quaternario. Revista de Associação Portuguesa para o Estudio do Quaternario (Quaternary Studies. Journal of the Portuguese Association for Quaternary Research) Price in EU is US$ 17.50, outside EU it is US$ 20.     

Jaap J. M. Van Der Meer 《第四纪科学杂志》1999,14(5):471-471

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Tetraether membrane lipid distributions in water-column particulate matter and sediments: a study of 47 European lakes along a north–south transect     

Cornelia Iulia Blaga  Gert-Jan Reichart  Oliver Heiri  Jaap S. Sinninghe Damsté 《Journal of Paleolimnology》2009,41(3):523-540

We studied the distribution of glycerol dialkyl glycerol tetraethers (GDGTs) in water-column particulate matter and the top 5 cm of sediment from 47 lakes along a transect from southern Italy to the northern part of Scandinavia. Our objective was to investigate the biological sources and potential palaeoenvironmental applications of GDGTs in lacustrine sediments. Both archaea-derived isoprenoid and bacteria-derived branched GDGTs, produced by yet unknown soil bacteria, were identified in all lake sediments. GDGT distributions varied substantially. Crenarchaeotal GDGTs, including the characteristic GDGT crenarchaeol, were found in varying relative concentrations, and were more dominant in lakes from the Alps and some of the lakes from the more southern part of the latitudinal transect. In some lakes, we observed high amounts of the GDGT with no cyclopentane moieties relative to crenarchaeol. As methanogenic Euryarchaeota are known to biosynthesise this GDGT predominantly, these Archaea, rather than Crenarchaeota, may be its dominant biological source. In most of the lakes, high amounts of soil-bacteria-derived, branched GDGTs (>40% of total GDGTs) indicated a substantial contribution from soil erosion. Branched GDGTs dominated, especially in the northern lakes, possibly related to high soil-erosion rates. In many of the lakes, soil input affects the distribution of isoprenoidal GDGTs and prevents the reliable application of the TEX₈₆ temperature proxy for lake water temperature, which is based on in situ crenarchaeotal GDGTs production. In 9 out of the 47 lakes studied, the TEX₈₆ temperature proxy could be used reliably. When we compared the TEX₈₆ correlation with annual and winter lake-surface temperature, respectively, the relationship between TEX₈₆ and winter temperature was slightly stronger. This may indicate the season in which these GDGT-producing organisms have their peak production.  相似文献   

Predictive land value modelling in Guatemala City using a geostatistical approach and Space Syntax     

Jose Morales  Alfred Stein  Johannes Flacke  Jaap Zevenbergen 《International journal of geographical information science》2020,34(7):1451-1474

ABSTRACT

Spatial information of land values is fundamental for planners and policy makers. Individual appraisals are costly, explaining the need for predictive modelling. Recent work has investigated using Space Syntax to analyse urban access and explain land values. However, the spatial dependence of urban land markets has not been addressed in such studies. Further, the selection of meaningful variables is commonly conducted under non-spatialized modelling conditions. The objective of this paper is to construct a land value map using a geostatistical approach using Space Syntax and a spatialized variable selection. The methodology is applied in Guatemala City. We used an existing dataset of residential land value appraisals and accessibility metrics. Regression-kriging was used to conduct variable selection and derive a model for spatial prediction. The prediction accuracy is compared with a multivariate regression. The results show that a spatialized variable selection yields a more parsimonious model with higher prediction accuracy. New insights were found on how Space Syntax explains land value variability when also modelling the spatial dependence. Space Syntax can contribute with relevant spatialized information for predictive land value modelling purposes. Finally, the spatial modelling framework facilitates the production of spatial information of land values that is relevant for planning practice.  相似文献   

Distribution of branched tetraether lipids in geothermally heated soils: Implications for the MBT/CBT temperature proxy     

Francien Peterse  Stefan Schouten  Jaap van der Meer  Marcel T.J. van der Meer  Jaap S. Sinninghe Damsté 《Organic Geochemistry》2009,40(2):201-205

Branched glycerol dialkyl glycerol tetraether (GDGT) membrane lipids occur in soils and peat bogs and are assumed to be produced by anaerobic bacteria. Two indices based on the distribution of these lipids in soils, the Cyclisation of Branched Tetraethers (CBT) and the Methylation of Branched Tetraethers (MBT) index have been shown to linearly relate to pH, and to mean annual air temperature (MAT) and pH, respectively. To directly evaluate the impact of changes in soil temperature on the MBT/CBT proxy, we determined these indices in soils sampled from a transect away from two hot springs in California, which provided a set of soils similar in composition but with different temperatures (12–41 °C). The CBT values of these geothermally heated soils show a good relation with pH (R² 0.76), similar to that of a global MBT/CBT calibration set. Also, the relationship between MBT, soil pH and temperature for the geothermally heated soils is similar to that of a global soil calibration set, although the intercept for the geothermally heated soils is significantly lower, likely because our data set is based on in situ soil temperatures rather than MAT. The results confirm the dependence of the MBT index on soil temperature and pH and support the applicability of the MBT/CBT indices as a proxy for continental palaeotemperatures and past soil pH.  相似文献   

Distribution of Crenarchaeota tetraether membrane lipids in surface sediments from the Red Sea     

Gabriele Trommer  Michael Siccha  Marcel T.J. van der Meer  Stefan Schouten  Jaap S. Sinninghe Damsté  Hartmut Schulz  Christoph Hemleben  Michal Kucera 《Organic Geochemistry》2009,40(6):724-731

The Red Sea represents an extreme marine environment, with high salinity, high temperature and low level of nutrients, complicating the application of standard geochemical palaeotemperature proxies. In order to investigate the applicability of the TEX₈₆ (TetraEther indeX of GDGTs with 86 carbons) proxy for sea surface temperature (SST) in the Red Sea, the distribution of glycerol dialkyl glycerol tetraether membrane lipids (GDGTs) in sediments from the Red Sea and the Gulf of Aden were examined. Against expectations, TEX₈₆ values for the Red Sea do not show a simple linear relationship with SST and deviate from the global core top calibration. In the northern Red Sea, at temperatures between 25 and 28 °C, the values increase linearly with SST, whereas in the southern Red Sea, at temperatures above 28 °C, TEX₈₆ decreases with increasing temperature. Factors like seasonality and depth of production, salinity and nutrient availability, as well as diagenetic overprint or influence of allochtonous terrestrial lipids, cannot explain this pattern. However, the observed TEX₈₆ relationship with SST could be explained by the presence of a hypothetical endemic Crenarchaeota population in the Red Sea with a specific TEX₈₆ vs. SST relationship. In the Southern Red Sea, a two-component mixing model implies an exponential decrease in the endemic population towards the Gulf of Aden. Thus, the application of the TEX₈₆ as a palaeotemperature proxy in the Red Sea is likely only possible for the northern Red Sea area with the specific SST vs. TEX₈₆ relationship determined in this study and potentially for the whole Red Sea basin during glacials, when water exchange with the Indian Ocean was more restricted than today and the endemic archaeal lipid distribution was not affected by transport from the Indian Ocean. Our results suggest that distinct populations of Crenarchaeota in extreme environments such as evaporitic basins may have different membrane composition, necessitating application of another calibration than the global core top calibration for TEX₈₆ palaeothermometry.  相似文献   

A biomarker and δ15N study of thermally altered Silurian cyanobacterial mats     

Thorsten Bauersachs  Barbara Kremer  Stefan Schouten  Jaap S. Sinninghe Damsté 《Organic Geochemistry》2009,40(2):149-157

Early Silurian cherts from the Holy Cross and Bardzkie Mountains (Poland) contain abundant microfossils morphologically resembling contemporary cyanobacteria. Most of the organic matter preserved in the cherts is highly mature and extensively degraded because of biological decomposition and progressive thermal alteration. These processes may have changed the original morphology of the deposited microbial remains, so the microfossil origin could be easily misinterpreted. The cherts were therefore examined using organic geochemical and stable isotope techniques to provide support for the presence of cyanobacterial remains. The nitrogen isotopic composition of bulk sediments and extractable organic matter ranged from +0.1‰ to ?2.2‰ and from +1.8‰ to ?1.7‰, respectively. The δ¹⁵N values are thus in good agreement with a contribution of diazotrophic cyanobacteria for both locations. Biomarkers in the Holy Cross Mts. cherts included mid-chain branched monomethyl alkanes, indicative of a cyanobacterial contribution. However, molecular fossils of a cyanobacterial origin were not detected in the Bardzkie Mts. cherts, most likely because of the greater maturity than those from the Holy Cross Mts.  相似文献   

Fluxes and distribution of tetraether lipids in an equatorial African lake: Constraints on the application of the TEX₈₆ palaeothermometer and BIT index in lacustrine settings   总被引：1，自引：0，他引：1  

Jaap S. Sinninghe Damsté  Jort Ossebaar  Stefan Schouten 《Geochimica et cosmochimica acta》2009,73(14):4232-4249

The distribution of isoprenoid and branched glycerol dialkyl glycerol tetraether (GDGT) lipids was studied in material from various sources in and around Lake Challa, a crater lake on the southeastern slope of Mt. Kilimanjaro (Tanzania), to examine the provenance of GDGTs in lake sediments and their potential application as palaeoenvironmental and palaeoclimatic proxies. The study material included samples collected at monthly intervals in a sediment trap over one complete annual cycle, particles suspended in the stratified water column, profundal surface sediments, and soils surrounding the lake. The sediment trap time series revealed that crenarchaeol and related isoprenoid GDGTs were predominantly produced in January and February, following the locally prominent short rain season (November-December). The TEX₈₆-inferred temperature derived from sedimenting particles corresponded well with lake surface-water temperature at this time of largest crenarchaeol flux. Molecular ecological analysis showed that Group 1.1a and 1.1b crenarchaeota are the most likely source organisms of these GDGTs. GDGT-0 in the lake sediments does not only originate from lake surface-dwelling crenarchaeota but seems predominantly derived from archaea residing in the deeper, anoxic part of the water column. The main flux of branched GDGTs to the sediment was during the short rain season and is most probably derived from eroded catchment soils in surface run-off. However, a contribution from in-situ production of branched GDGTs in the lake sediment or water, or in groundwater cannot be fully excluded. We conclude that palaeoclimatic reconstruction based on branched GDGT distributions in lake sediments should only be performed when the origin of those branched GDGTs is well constrained.  相似文献