Modeling the hydro-mechanical responses of strip and circular punch loadings on water-saturated collapsible geomaterials   总被引：1，自引：1，他引：0  

WaiChing Sun  Qiushi Chen  Jakob T. Ostien 《Acta Geotechnica》2014,9(5):903-934

A stabilized enhanced strain finite element procedure for poromechanics is fully integrated with an elasto-plastic cap model to simulate the hydro-mechanical interactions of fluid-infiltrating porous rocks with associative and non-associative plastic flow. We present a quantitative analysis on how macroscopic plastic volumetric response caused by pore collapse and grain rearrangement affects the seepage of pore fluid, and vice versa. Results of finite element simulations imply that the dissipation of excess pore pressure may significantly affect the stress path and thus alter the volumetric plastic responses.  相似文献   

Palaeoglaciology of Bayan Har Shan,NE Tibetan Plateau: exposure ages reveal a missing LGM expansion     

Jakob Heyman  Arjen P. Stroeven  Marc W. Caffee  Clas Hättestrand  Jonathan M. Harbor  Yingkui Li  Helena Alexanderson  Liping Zhou  Alun Hubbard 《Quaternary Science Reviews》2011,30(15-16):1988-2001

The Bayan Har Shan, a prominent upland area in the northeastern sector of the Tibetan Plateau, hosts an extensive glacial geological record. To reconstruct its palaeoglaciology we have determined ¹⁰Be exposure ages based on 67 samples from boulders, surface pebbles, and sediment sections in conjunction with studies of the glacial geology (remote sensing and field studies) and numerical glacier modelling. Exposure ages from moraines and glacial sediments in Bayan Har Shan range from 3 ka to 129 ka, with a large disparity in exposure ages for individual sites and within the recognised four morphostratigraphical groups. The exposure age disparity cannot be explained by differences in inheritance without using unrealistic assumptions but it can be explained by differences in post-depositional shielding which produces exposure ages younger than the deglaciation age. We present a palaeoglaciological time-slice reconstruction in which the most restricted glaciation, with glaciers less than 10 km long, occurred before 40–65 ka. More extensive glaciations occurred before 60–100 ka and 95–165 ka. Maximum glaciation is poorly constrained but probably even older. The Bayan Har Shan exposure age dataset indicates that glaciers on the northeastern Tibetan Plateau have remained surprisingly restricted for at least 40 ka, including the global last glacial maximum (LGM). This case of a missing LGM is further supported by high-resolution glacier modelling experiments.  相似文献   

Iron isotope fractionation during proton- and ligand-promoted dissolution of primary phyllosilicates     

Mirjam Kiczka  Jan G. Wiederhold  Jakob Frommer  Bernard Bourdon 《Geochimica et cosmochimica acta》2010,74(11):3112-6415

We studied stable iron isotope fractionation during dissolution of a biotite and chlorite enriched mineral fraction from granite by HCl and 5 mM oxalic acid in a pH range of 4-5.9. Batch experiments covered a time period from 2 h to 100 days and were performed at initial potassium concentrations of 0, 0.5, and 5 mM to induce different levels of biotite exfoliation. All experiments were kept anoxic to investigate solely the dissolution step without the influence of oxidation and precipitation of secondary Fe oxyhydroxides. Oxalic acid increased the release of Fe by a factor of ∼15 compared with the HCl experiments. Addition of 0.5 mM K to initial solutions in proton-promoted dissolution decreased the release of Fe by 30-65% depending on the dissolution stage. In ligand-controlled dissolution, K reduced the Fe release only to a minor extent. All solutions of the early dissolution stages were enriched in light Fe isotopes by up to −1.4‰ in δ⁵⁶Fe compared with the isotopic composition of biotite and chlorite mineral separates, which we explained by a kinetic isotope effect. In proton-promoted dissolution, early released fractions of K-enriched experiments were significantly lighter (−0.7‰ to −0.9‰) than in the initially K-free experiments. The evolution of Fe isotope ratios in solution was modeled by a linear combination of kinetic isotope effects during two independent dissolution processes attacking different crystallographic sites. In ligand-controlled dissolution, K did not influence the kinetic isotope effect and the Fe isotope composition in solution in the late dissolution stages remained slightly lighter than the bulk composition of the biotite/chlorite enriched mineral fraction. This study demonstrates that the initial Fe weathering flux should be enriched in light Fe isotopes and that Fe isotope data in combination with dissolution kinetics and stoichiometry provide new insights into dissolution mechanisms.  相似文献   

Effect of citrate on the local Fe coordination in ferrihydrite, arsenate binding, and ternary arsenate complex formation     

Christian Mikutta  Jakob Frommer  Ralf Kaegi 《Geochimica et cosmochimica acta》2010,74(19):5574-6504

In oxic environments contaminated with arsenate (As(V)), small polyhydroxycarboxylates such as citrate may impact the structure of precipitating ferrihydrite (Fh) and thus the surface speciation of As(V). In this study, ‘2-line’ Fh was precipitated from ferric nitrate solutions that were neutralized to pH 6.5 in the presence of increasing citrate concentrations and in the absence or presence of As(V). The initial citrate/Fe and As/Fe ratios were 0-50 mol% and 5 mol%, respectively. The reaction products, enriched with up to 0.32 mol citrate per mole Fe, were characterized by X-ray diffraction, transmission electron microscopy, and Fe and As K-edge X-ray absorption spectroscopy. Citrate decreased the particle size of Fh by impairing the polymerization of Fe(O,OH)₆ octahedra via edge and corner linkages. In the presence of citrate and As(V), coordination numbers of Fe decreased by up to 28% relative to pure Fh. Citrate significantly reduced the static disorder of Fe-O bonds, implying a decreased octahedral distortion in Fh. Mean bond distances in Fh were not affected by citrate and remained constant within error at 1.98 Å for Fe-O, 3.03 Å for Fe-Fe1, and 3.45 Å for Fe-Fe2. Likewise, citrate had no effect on the As-Fe (3.31 Å) bond distance in As(V) coprecipitated with Fh. The As K-edge EXAFS data comply with the formation of (i) only monodentate binuclear (²C) As(V) surface complexes and (ii) combinations of ²C, monodentate mononuclear (¹V), and outersphere As(V) surface complexes. Our results suggest that increasing citrate concentrations led to a decreasing ¹V/²C ratio and/or that citrate increasingly impaired the formation of outersphere As(V) complexes. Moreover, citrate stabilized colloidal suspensions of Fh (pH 4.3-6.6, I ∼0.45 M) and reduced Fh formation at the expense of soluble Fe(III)-citrate complexes. At initial citrate/Fe ratios ?25 mol%, between 8% and 41% of total Fe was bound in Fe(III)-citrate complexes after Fh formation. Polynuclear Fe(III)-citrate species were found to bind As(V) via surface complexes indistinguishable by EXAFS from those of As(V) adsorbed to or coprecipitated with Fh. Our study implies that low molecular weight polyhydroxycarboxylates may enhance the mobility of As(V) in aqueous systems of high ionic strength (e.g., neutralizing acid mine drainage) by colloidal stabilization of suspended Fh particles and the formation of ternary As(V) complexes.  相似文献   

Cancrinite and sodalite formation in the presence of cesium, potassium, magnesium, calcium and strontium in Hanford tank waste simulants   总被引：1，自引：0，他引：1  

Youjun Deng  Markus Flury  James B. Harsh  Andrew R. Felmy  Odeta Qafoku 《Applied Geochemistry》2006,21(12):2049-2063

  相似文献   

Future Satellite Gravimetry for Geodesy     

J. Flury  R. Rummel 《Earth, Moon, and Planets》2004,94(1-2):13-29

After GRACE and GOCE there will still be need and room for improvement of the knowledge (1) of the static gravity field at spatial scales between 40 km and 100 km, and (2) of the time varying gravity field at scales smaller than 500 km. This is shown based on the analysis of spectral signal power of various gravity field components and on the comparison with current knowledge and expected performance of GRACE and GOCE. Both, accuracy and resolution can be improved by future dedicated gravity satellite missions. For applications in geodesy, the spectral omission error due to the limited spatial resolution of a gravity satellite mission is a limiting factor. The recommended strategy is to extend as far as possible the spatial resolution of future missions, and to improve at the same time the modelling of the very small scale components using terrestrial gravity information and topographic models.We discuss the geodetic needs in improved gravity models in the areas of precise height systems, GNSS levelling, inertial navigation and precise orbit determination. Today global height systems with a 1 cm accuracy are required for sea level and ocean circulation studies. This can be achieved by a future satellite mission with higher spatial resolution in combination with improved local and regional gravity field modelling. A similar strategy could improve the very economic method of determination of physical heights by GNSS levelling from the decimeter to the centimeter level. In inertial vehicle navigation, in particular in sub-marine, aircraft and missile guidance, any improvement of global gravity field models would help to improve reliability and the radius of operation.  相似文献   

Ice Mass Balance and Ice Dynamics from Satellite Gravity Missions     

J. Flury 《Earth, Moon, and Planets》2004,94(1-2):83-91

An overview of advances in ice research which can be expected from future satellite gravity missions is given. We compare present and expected future accuracies of the ice mass balance of Antarctica which might be constrained to 0.1–0.3 mm/year of sea level equivalent by satellite gravity data. A key issue for the understanding of ice mass balance is the separation of secular and interannual variations. For this aim, one would strongly benefit from longer uninterrupted time series of gravity field variations (10 years or more). An accuracy of 0.01 mm/year for geoid time variability with a spatial resolution of 100 km would improve the separability of ice mass balance from mass change due to glacial isostatic adjustment and enable the determination of regional variations in ice mass balance within the ice sheets. Thereby the determination of ice compaction is critical for the exploitation of such high accuracy data. A further benefit of improved gravity field models from future satellite missions would be the improvement of the height reference in the polar areas, which is important for the study of coastal ice processes. Sea ice thickness determination and modelling of ice bottom topography could be improved as well.  相似文献   

Eelpout (Zoarces viviparus) in marine environmental monitoring     

Hedman JE  Rüdel H  Gercken J  Bergek S  Strand J  Quack M  Appelberg M  Förlin L  Tuvikene A  Bignert A 《Marine pollution bulletin》2011,62(10):2015-2029

The implementation of the EU Marine Strategy Framework Directive necessitates the development of common criteria and methodological standards for marine environmental monitoring and assessment across Europe. Eelpout (Zoarces viviparus) is proposed as a key indicator organism in the Baltic and North Sea regions. This benthic fish species is widely used in ecotoxicological studies and as a bioindicator of local pollution due to its stationary behavior. Eelpout is included in the environmental monitoring program of several Baltic States, covering both chemical and biological effects measurements, and samples have been archived in environmental specimen banks for >15 years. A method for evaluating the frequency of larval aberrations has been suggested as a standardized assessment tool. The large scientific knowledge-base and considerable experience of long-term chemical and biological effects monitoring and specimen banking, make eelpout a suitable species for the assessment of Good Environmental Status in the Baltic and North Seas.  相似文献   

Paleo-climate of the central European uplands during the last glacial maximum based on glacier mass-balance modeling     

Barbara M. Heyman  Jakob Heyman  Thomas Fickert  Jonathan M. Harbor 《Quaternary Research》2013,79(1):49-54

During the last glacial maximum (LGM), glaciers existed in scattered mountainous locations in central Europe between the major ice masses of Fennoscandia and the Alps. A positive degree-day glacier mass-balance model is used to constrain paleo-climate conditions associated with reconstructed LGM glacier extents of four central European upland regions: the Vosges Mountains, the Black Forest, the Bavarian Forest, and the Giant Mountains. With reduced precipitation (25–75%), reflecting a drier LGM climate, the modeling yields temperature depressions of 8–15°C. To reproduce past glaciers more severe cooling is required in the west than in the east, indicating a strong west–east temperature anomaly gradient.  相似文献   

Origin and geodynamic evolution of Late Paleogene magmatic associations along the Periadriatic-Sava-Vardar magmatic belt     

Jakob Pamić  Dražen Balen  Marijan Herak 《Geodinamica Acta》2013,26(4):209-231

Abstract

Along the Periadriatic Lineament in the Alps and the Sava-Vardar Zone of the Dinarides and Hellenides, Paleogene magmatic associations form a continuous belt, about 1700 km long. The following magmatic associations occur: (1) Eocene granitoids; (2) Oligocene granitoids including tonalites; (3) Oligocene shoshonite and calc-alkaline volcanics with lamprophyres; (4) Egerian-Eggenburgian (Chattian) calc-alkaline volcanics and granitoids. All of these magmatic associations are constrained by radiometric ages, which indicate that the magmatic activity was mainly restricted to the time span between 55 and 29 Ma. These igneous rocks form, both at surface and in the subsurface, the distinct linear Periadriatic-Sava-Vardar magmatic belt, with three strikes that are controlled by the indentation of Apulia and Moesia and accompanying strike-slip faulting. The geology, seismicity, seismic tomography and magnetic anomalies within this belt suggest that it has been generated in the African-Eurasian suture zone. Based on published analytical data, the petrology, major and trace element contents and Sr, Nd and O isotopie composition of each magmatic association are briefly defined. These data show that Eocene and Oligocene magmatic associations of the Late Paleogene Periadriatic-Sava-Vardar magmatic belt originated along a consuming plate margin. Based on isotopie systems, two main rock groups can be distinguished: (1) ⁸⁷Sr/⁸⁶Sr = 0.7036–0.7080 and δ¹⁸O = 5.9–7.2‰, indicating basaltic partial melts derived from a continental mantle-lithosphere, and (2) ⁸⁷Sr/⁸⁶Sr = 0.7090–72131 and δ¹⁸O = 7.3–11.5‰, indicating crustal assimilation and melting. The mantle sources for the primary basalt melts are metasomatized garnet peridotites and/or spinel lherzolites and phlogopite lherzolites of upper mantle wedge origin. The geodynamic evolution of the plutonic and volcanic associations of the Periadriatic-Sava-Vardar magmatic belt was related to the Africa-Eurasia suture zone that was dominated by break-off of the subducted lithospheric slab of Mesozoic oceanic crust, at depths of 90–100 km. This is indicated by their contemporaneity along the 1700 km long belt. © 2002 Éditions scientifiques et médicales Elsevier SAS. All rights reserved.  相似文献