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21.
Different types of methane monooxygenases produce similar carbon and hydrogen isotope fractionation patterns during methane oxidation 总被引：1，自引：0，他引：1
Stefan Feisthauer Jakub Modrzynski Martin Krüger Hans-Hermann Richnow 《Geochimica et cosmochimica acta》2011,75(5):1173-1184
We determined the stable carbon and hydrogen isotope fractionation factors for methane oxidation under oxic conditions using strains with known degradation pathways. The aerobic oxidation of methane can be initiated by two different forms of enzymes known as methane monooxygenases (MMO). The expression of these enzymes is type-specific and dependent upon the adjusted copper concentration in the medium (or environment). In this study, the expression of either the soluble MMO or the particulate MMO was supported by adjusting the copper concentrations in the growth medium. Taxonomically different aerobic methanotrophic strains, mainly belonging to the alpha- and gamma- classes of Proteobacteria, produced methane isotope enrichment factors (εbulk) ranging from −14.8 to −27.9‰ for carbon, and from −110.0 to −231.5‰ for hydrogen. The ratio of hydrogen versus carbon discrimination (Λ = (αH−1 − 1)/(αC−1 − 1) ≈ Δ(δ2H)/Δ(δ13C)) were similar for all tested cultures, and are also identical to values calculated from previously published enrichment factors for aerobic and anaerobic methane degradation. In contrast, Λ-values for the abiotic oxidation of methane with OH radicals (this process is considered as the main removal process for methane from the atmosphere) were significantly higher than the values derived from biotic oxidation. Due to the low variability of microbial methane isotope fractionation patterns, we propose that combined carbon and hydrogen isotope fractionation analyses can be used to monitor and assess the occurrence of microbial methane oxidation in marine or terrestrial environments. However, it is not possible to distinguish distinct aerobic or anaerobic methane-oxidation pathways by this approach. 相似文献
22.
P. Bačík D. Ozdín M. Miglierini P. Kardošová M. Pentrák J. Haloda 《Physics and Chemistry of Minerals》2011,38(8):599-611
Heat treatment was performed on selected Fe-dominant tourmalines to establish the nature of any change in optical properties. Two tourmaline samples from Dolní Bory, Czech Republic (TDB) and Vlachovo, Slovakia (TVL) were heated at 450, 700 and 900°C at 0.1 mPa and ambient oxidation conditions for 8 h. EMPA study shows that tourmaline from Vlachovo has schorlitic composition and tourmaline from Dolní Bory is alkali-depleted schorl to foitite. Although the black colour remained unchanged after heating at 450°C, it changed to brown at 700°C and reddish brown at 900°C. No significant changes of chemical composition were observed during heating. X-ray diffraction, infrared and Mössbauer study showed negligible oxidation of tourmaline heated at 450°C, but a significant change in iron valency state and deprotonization at 700°C. The oxidation of Fe is the main cause of tourmaline colour change, and the substitution vector for oxidation of Fe is Fe3+OFe ?1 2+ (OH)?1. The predicted deprotonization of OH was confirmed by infrared spectroscopy, which documented a decrease in OH groups in both samples, mainly at the V site. The oxidation of Fe is mostly significant in the Y site as documented on the compression of the Y-site octahedra and subsequent decrease in the a lattice parameter. This feature is consistent with lattice dimensions in the transition from schorl and foitite dimensions to those consistent with fluor-buergerite. The Z-site octahedra did not compressed and were not affected by heating-induced Fe oxidation, which indicates only negligible content of Z Fe2+ in original samples. After heating at 900°C, the tourmaline structure collapsed likely due to the thermally induced weakening of bonds in Y and Z octahedra, which results in amorphization of tourmaline. Subsequently, breakdown products including Fe-oxides and mullite replaced alkali-depleted amorphized tourmaline. 相似文献
23.
Kohút Milan Hofmann Mandy Havrila Milan Linnemann Ulf Havrila Jakub 《International Journal of Earth Sciences》2018,107(1):321-335
International Journal of Earth Sciences - The Late Triassic timescale, especially the Carnian–Norian boundary, is poorly constrained mainly due to a paucity of high-precision radio-isotopic... 相似文献
24.
AbstractIntensive forest management is one of the main land cover changes over the last century in Central Europe, resulting in forest monoculture. It has been proposed that these monoculture stands impact hydrological processes, water yield, water quality and ecosystem services. At the Lysina Critical Zone Observatory, a forest catchment in the western Czech Republic, a distributed physics-based hydrologic model, Penn State Integrated Hydrologic Model (PIHM), was used to simulate long-term hydrological change under different forest management practices, and to evaluate the comparative scenarios of the hydrological consequences of changing land cover. Stand-age-adjusted LAI (leaf area index) curves were generated from an empirical relationship to represent changes in seasonal tree growth. By consideration of age-adjusted LAI, the spatially-distributed model was able to successfully simulate the integrated hydrological response from snowmelt, recharge, evapotranspiration, groundwater levels, soil moisture and streamflow, as well as spatial patterns of each state and flux. Simulation scenarios of forest management (historical management, unmanaged, clear cutting to cropland) were compared. One of the critical findings of the study indicates that selective (patch) forest cutting results in a modest increase in runoff (water yield) as compared to the simulated unmanaged (no cutting) scenario over a 29-year period at Lysina, suggesting the model is sensitive to selective cutting practices. A simulation scenario of cropland or complete forest cutting leads to extreme increases in annual water yield and peak flow. The model sensitivity to forest management practices examined here suggests the utility of models and scenario development to future management strategies for assessing sustainable water resources and ecosystem services.
Editor D. Koutsoyiannis 相似文献
25.
Hydrochemical patterns resulting from differing bedrock geochemistry were ascertained by concurrent streamwater sampling in three small catchments, each underlain by geochemically contrasting silicate rock types in the western Czech Republic, Central Europe in 2001–2010. The catchments are situated 5–7 km apart in the Slavkov Forest and are occupied by Norway spruce (Picea abies) plantations. They have similar altitude, area, topography, mean annual air temperature, and atmospheric deposition fluxes. The amount of base cations oxides (Ca + Mg + Na + K) is markedly different among the three studied rocks (leucogranite 8%, amphibolite 22%, serpentinite 36%). The leucogranite contains a very small amount of MgO, while the serpentinite contains extremely large amounts of MgO. The amphibolite contains an intermediate amount of MgO and elevated CaO. The Lysina, on leucogranite, exhibited very small concentrations of Mg (median 0.4 mg L−1) in streamwater; Pluh?v Bor, on serpentinite, contained extremely high concentrations of streamwater Mg (18 mg L−1). Streamwater in the Na Zeleném catchment, on amphibolite, contained an intermediate amount of Mg and an elevated Ca. Very low pH (4.2), negative alkalinity (−60 μeq L−1) and high inorganic monomeric Al concentrations (0.3 mg L−1) were found in the stream draining leucogranite. Serpentinite streamwater exhibited the highest pH (7.6), alkalinity (+940 μeq L−1) and Ni concentrations (100 μg L−1). Aquatic chemistry reflected the composition of the underlying rocks within the studied catchments. Contrasting streamwater compositions of the studied catchments were generated according to the MAGIC model simulations mainly by differences in chemical weathering rates of base cations (65 meq m−2 a−1 at Lysina, 198 meq m−2 a−1 at Na Zeleném, and 241 meq m−2 a−1 at Pluh?v Bor). 相似文献
26.
Bačík Peter Dikej Jakub Fridrichová Jana Miglierini Marcel Števko Martin 《Mineralogy and Petrology》2017,111(4):609-624
Mineralogy and Petrology - Tourmaline-supergroup minerals are common gangue minerals in Sb-hydrothermal veins on Betliar – Straková, Čučma – Gabriela and... 相似文献
27.
Tomáš Lepeška Artur Radecki-Pawlik Jakub Wojkowski Andrzej Walega 《Acta Geophysica》2017,65(6):1253-1267
Human society deals with floods, drought and water pollution. Facing those problems, the question how to prevent or at least to minimalize the adverse effects of water-related issues is asked of the landscape managers. In this way, any help given to landscape managers seems to be an additional useful tool. Within this paper, an approach leading to mitigation of water-related problems is presented that relates the retention of precipitation and the use of ecosystems as a tool for improving the quality, quantity of water resources and availability throughout the region. One approach is the determination of the landscape’s hydric potential (LHP). This study examines one example of using this method within the conditions of Poland. The results of the research show that national data are entirely appropriate for implementation of the LHP method. Further, this approach revealed the classes of the hydric potential of the Pr?dnik river basin which was selected as the experimental territory. LHP results reflect the ecosystem attributes of the model river basin; areas of average LHP cover 63.26%, areas of high and limited hydric potential cover approximately 18.3% each. The spatial distribution of LHP means the results of this study provide a baseline for management of the river basin. 相似文献
28.
Łukasz Kaczmarek Tomasz Wejrzanowski Jakub Skibiński Michał Maksimczuk Artur Krzyżak 《Acta Geophysica》2017,65(1):259-268
This paper addresses the issue of the quantitative characterization of the structure of the calibration model (phantom) for b-matrix spatial distribution diffusion tensor imaging (BSD-DTI) scanners. The aim of this study was to verify manufacturing assumptions of the structure of materials, since phantoms are used for BSD-DTI calibration directly after manufacturing. Visualization of the phantoms’ structure was achieved through optical microscopy and high-resolution computed microtomography (µCT). Using µCT images, a numerical model of the materials structure was developed for further quantitative analysis. 3D image characterization was performed to determine crucial structural parameters of the phantom: porosity, uniformity and distribution of equivalent diameter of capillary bundles. Additionally calculations of hypothetical flow streamlines were also performed based on the numerical model that was developed. The results obtained in this study can be used in the calibration of DTI-BST measurements. However, it was found that the structure of the phantom exhibits flaws and discrepancies from the assumed geometry which might affect BSD-DTI calibration. 相似文献
29.
Timothy Paulsen Chad Deering Jakub Sliwinski Snehamoy Chatterjee Olivier Bachmann Marcel Guillong 《地学学报》2021,33(1):12-20
Orogenic crustal thickening leads to increased continental elevation and runoff into the oceans, but there are fundamental uncertainties in the temporal patterns of thickening through Earth history. U‐Pb age and trace element data in detrital zircons from Antarctica are consistent with recent global analyses suggesting two dominant peaks in average crustal thickness from ~2.6 to 2.0 Ga and ~0.8 to 0.5 Ga. Shifts in marine carbonate 87Sr/86Sr ratios show two primary peaks that post‐date these crustal thickness peaks, suggesting significant weathering and erosion of global continental relief. Both episodes correlate well with zircon trace element and isotope proxies indicating enhanced crustal and fluid input into subduction zone magmas. Increased crustal thickness correlates with increased passive margin abundance and overlaps with snowball Earth glaciations and atmospheric oxygenation, suggesting a causal link between continental rift‐drift phases and major transitions in Earth's atmospheric and oceanic evolution. 相似文献
30.
Pavel Raška Vilém Zábranský Jakub Dubišar Antonín Kadlec Alena Hrbáčová Tomáš Strnad 《Natural Hazards》2014,70(1):705-732
During the last two decades, documentary data (written and iconographic sources) have been increasingly employed in geomorphologic research aiming at reconstruction of territorial distribution, temporal occurrence and social and economic impacts of various geomorphologic hazards. The goal of this paper is to broaden the previous discussion (Glade et al. The use of historical data in natural hazard assessments. Kluwer, Dordrecht, 2001) of the methodological constraints on the use of documentary data for geomorphologic hazard research. Using the interdisciplinary approach of geomorphology, historiography and medial studies, we firstly summarise the major finding of papers that have employed various types of documentary data sources to study geomorphologic hazards in different regions. In the second section, we present case studies from the Czech Republic resulting from the ongoing research project that is devoted to the assessment of the potential of documentary data to reconstruct past occurrences of and mitigation strategies for geomorphologic hazards. Finally, we discuss three main methodological issues emerging from our research: (a) problems emerging from the positivist approach to documentary data sources and the necessity for critical analyses of documentary data sources based on modern historiographic approaches, (b) constraints arising from the combination of documentary data from different spatiotemporal scales and (c) lacks in the use of documentary data to study local-based adaptation strategies to cope with geomorphologic hazards. 相似文献