Trace element partitioning in the Fe-S-C system and its implications for planetary differentiation and the thermal history of ureilites     

Leslie A. Hayden  James A. Van Orman  Cyrena A. Goodrich 《Geochimica et cosmochimica acta》2011,75(21):6570-6583

Element partitioning in metal-light element systems is important to our understanding of planetary differentiation processes. In this study, solid-metal/liquid-sulfide, liquid-metal/liquid-sulfide and solid-metal/troilite partition coefficients (D) were determined for 18 elements (Ag, As, Au, Co, Cr, Cu, Ge, Ir, Ni, Os, Pd, Pt, Mo, Mn, Re, Ru, Se and W) in the graphite-saturated Fe-S-C system at 1 atm. Compared at the same liquid S concentration, the solid/liquid partition coefficients are similar to those in the Fe-S system, but there are systematic differences that appear to be related to interactions with carbon dissolved in the solid metal. Elements previously shown to be “anthracophile” generally have larger solid/liquid partition coefficients in the Fe-S-C system, whereas those that are not have similar or smaller partition coefficients in the Fe-S-C system. The partitioning of trace elements between C-rich and S-rich liquids is, in most cases, broadly similar to the partitioning between solid metal and S-rich liquid. The highly siderophile elements Os, Re, Ir and W are partitioned strongly into the C-rich liquid, with D ? 100. The partition coefficients for Pt, Ge and W decrease significantly at the transition to liquid immiscibility, while the partition coefficient for Mo increases sharply. The bulk siderophile element patterns of ureilite meteorities appear to be better explained by separation of S-rich liquid from residual C-rich metallic liquid at temperatures above the silicate solidus, rather than by separation of S-rich liquid from residual solid metal at lower temperatures.  相似文献   

Evolution of a Carboniferous carbonate-hosted sphalerite breccia deposit,Isle of Man     

Kevin L. Shelton  Justin M. Beasley  Jay M. Gregg  Martin S. Appold  Stephen F. Crowley  James P. Hendry  Ian D. Somerville 《Mineralium Deposita》2011,46(8):859-880

A newly discovered, extensive sphalerite-bearing breccia (~7.5 wt.% Zn) is hosted in dolomitised Carboniferous limestones overlying Ordovician–Silurian metasedimentary rocks on the Isle of Man. Although base metal sulphide deposits have been mined historically on the island, they are nearly all quartz vein deposits in the metamorphic basement. This study investigates the origin of the unusual sphalerite breccia and its relationship to basement-hosted deposits, through a combination of petrographic, cathodoluminescence, fluid inclusion, stable isotope and hydrogeologic modelling techniques. Breccia mineralisation comprises four stages, marked by episodes of structural deformation and abrupt changes in fluid temperature and chemistry. In stage I, high-temperature (T _h > 300°C), high-salinity (20–45 wt.% equiv. NaCl) fluid of likely basement origin deposited a discontinuous quartz vein. This vein was subsequently dismembered during a major brecciation event. Stages II–IV are dominated by open-space filling sphalerite, quartz and dolomite, respectively. Fluid inclusions in these minerals record temperatures of ~105–180°C and salinities of ~15–20 wt.% equiv. NaCl. The δ³⁴S values of sphalerite (6.5–6.9‰ Vienna-Canyon Diablo troilite) are nearly identical to those of ore sulphides from mines in the Lower Palaeozoic metamorphic rocks. The δ¹⁸O values for quartz and dolomite indicate two main fluid sources in the breccia’s hydrothermal system, local Carboniferous-hosted brines (~0.5–6.0‰ Vienna standard mean ocean water) and basement-involved fluids (~5.5–11.5‰). Ore sulphide deposition in the breccia is compatible with the introduction and cooling of a hot, basement-derived fluid that interacted with local sedimentary brines.  相似文献   

New constraints on the provenance of hopanoids in the marine geologic record: Bacteriohopanepolyols in marine suboxic and anoxic environments     

James P. Sáenz  Stuart G. Wakeham  Timothy I. Eglinton  Roger E. Summons 《Organic Geochemistry》2011,42(11):1351-1362

The abundance and structural diversity of bacteriohopanepolyols (BHPs) was examined in three marine pelagic environments that are characterized by strong vertical redox gradients and water column suboxia or anoxia. The abundance and, in most instances, structural diversity of BHPs was highest at depths where conditions were suboxic or anoxic. However, the majority of the BHP structures that were identified are environmentally cosmopolitan and their biological sources are presently not well constrained. An isomer of bacteriohopanetetrol (denoted BHT II) was observed at all three study sites in association with anoxic and suboxic conditions within the water column. Based on the absence of BHT II from terrigenous and oxic marine environments studied to date, and its strong association with suboxic and anoxic marine pelagic environments, we propose that BHT II is a promising candidate biomarker for water column suboxia and anoxia in the marine geologic record. The molecular fingerprint of BHPs in suspended and sinking particles and core-top sediments indicates that hopanoids produced within the water column are exported to marine sediments and that their biological source is most likely associated with settling particles and not the free-water phase. Based on our observations, BHPs likely represent an important input to the sedimentary hopanoid inventory, particularly in upwelling environments characterized by pelagic oxygen minimum zones (OMZ) and anoxic marine basins.  相似文献   

Time series analysis of CO concentrations from an Eastern Kentucky coal fire     

James C. Hower  Jennifer M.K. O'Keefe  Kevin R. Henke  Amirhossein Bagherieh 《International Journal of Coal Geology》2011,88(4):227

Coal fires in natural outcrops, in abandoned and active coal mines, and in coal and coal-refuse piles are responsible for the uncontrolled emissions of gases, including CO, CO₂, H₂S, hydrocarbons, and volatile aromatics. Typically, measurements of gases at a mine vent are made over a short time interval, perhaps no more than 10 min, including the time for replicate measurements. Such timing provides little information on longer-term variations in emissions, although comparisons of seasonal measurements suggest such changes do occur. To address this problem, we placed temperature and CO data loggers in coal fire vents to collect time series measurements for a period of up to three weeks. For one experiment, 11 days of data at one-minute intervals indicated that the CO emissions were generally in the 400–550 ppmv range. However near daily depressions in CO concentrations occurred and in some cases fell below 50 ppmv; followed by an increase to ~ 700–800 ppmv; in turn followed by a return to the ambient conditions. Data for a separate 21-day collection period in a different vent of the same fire exhibited similar trends, albeit at a higher CO concentration. The drop in CO concentration may be associated with a meteorologically-driven inhalation cycle of the fire, whereby air diluted the combustion generated CO. We propose this was followed by an increase in the intensity of the fire due to increased O₂ from the inhaled air, producing increased CO concentrations, before settling back to the ambient conditions.  相似文献   

What kind of countryside do the public want: community visions from Wales UK?     

Alister J. Scott  James Shorten  Rosalind Owen  Iwan Owen 《GeoJournal》2011,76(4):417-436

This paper assesses how far community led rural visions accord with the current thrust of rural planning policy delivery in the UK. Adapting conventional visioning methods, qualitative techniques were used on eight different communities across urban, exurban and rural Wales to elicit views relating to the kind of local countryside(s) that were desired. The results show that the communities’ visions reflect an emerging consensus around local countryside priorities: multifunctionality, integration, wider countryside protection, development based on need, and local distinctiveness according with the thrust of current planning policy at national and local levels. However, there is a clear dichotomy between this and the reality of what communities actually experienced in developments affecting their countryside. Here, universal criticism was encountered over the type, pace and scale of development, the lack of rural specificity and the failure to take account of local community needs and priorities. It is hypothesized that tensions between national and local politics and stakeholder power relations are playing a crucial role in distorting the delivery of town and country planning. It is recommended that rural policy delivery must become more “joined up” and rural proofed at national and local levels concomitant with a change in the operational culture of agencies at the forefront of rural delivery. Essentially, effective engagement of top down approaches synergising with bottom up community led ideas is long overdue.  相似文献   

A comparative study of the modelling of cement hydration and cement-rock laboratory experiments     

David Savage  Josep M. SolerKohei Yamaguchi  Colin WalkerAkira Honda  Manabu InagakiClaire Watson  James WilsonSteven Benbow  Irina GausJoerg Rueedi 《Applied Geochemistry》2011,26(7):1138-1152

The use of cement and concrete as fracture grouting or as tunnel seals in a geological disposal facility for radioactive wastes creates potential issues concerning chemical reactivity. From a long-term safety perspective, it is desirable to be able model these interactions and changes quantitatively. The ‘Long-term Cement Studies’ (LCS) project was formulated with an emphasis on in situ field experiments with more realistic boundary conditions and longer time scales compared with former experiments. As part of the project programme, a modelling inter-comparison has been conducted, involving the modelling of two experiments describing cement hydration on one hand and cement-rock reaction on the other, with teams representing the NDA (UK), Posiva (Finland), and JAEA (Japan).This modelling exercise showed that the dominant reaction pathways in the two experiments are fairly well understood and are consistent between the different modelling teams, although significant differences existed amongst the precise parameterisation (e.g. reactive surface areas, dependences of rate upon pH, types of secondary minerals), and in some instances, processes (e.g. partition of alkali elements between solids and liquid during cement hydration; kinetic models of cement hydration). It was not conclusive if certain processes such as surface complexation (preferred by some modellers, but not by others) played a role in the cement-rock experiment or not. These processes appear to be more relevant at early times in the experiment and the evolution at longer timescales was not affected. The observed permeability profile with time could not be matched. The fact that no secondary minerals could be observed and that the precipitated mass calculated during the simulations is minor might suggest that the permeability reduction does not have a chemical origin, although a small amount of precipitates at pore throats could have a large impact on permeability.The modelling exercises showed that there is an interest in keeping the numerical models as simple as possible and trying to obtain a reasonable fit with a minimum of processes, minerals and parameters. However, up-scaling processes and model parameterisation to the timescales appropriate to repository safety assessment are of considerable concern. Future modelling exercises of this type should focus on a suitable natural or industrial analogue that might aid assessing mineral-fluid reactions at these longer timescales.  相似文献   

Landscape response to tipping points in granite weathering: The case of stepped topography in the Southern Sierra Critical Zone Observatory     

Barbara S. Jessup  W. Jesse Hahm  Scott N. Miller  James W. Kirchner  Clifford S. Riebe 《Applied Geochemistry》2011

The dynamics of granitic landscapes are modulated by bimodal weathering, which produces patchy granular soils and expanses of bare rock ranging from meter-scale boulders to mountain-scale domes. We used terrain analysis and with cosmogenic nuclide measurements of erosion rates to quantitatively explore Wahrhaftig’s decades-old hypothesis for the development of “stepped topography” by differential weathering of bare and soil-mantled granite. According to Wahrhaftig’s hypothesis, bare granite weathers slower than soil-mantled granite; thus random erosional exposure of bare rock leads to an alternating sequence of steep, slowly weathering bedrock “steps” and gently sloped, but rapidly weathering, soil-mantled “treads.” Our investigation focused on the terrain surrounding the Southern Sierra Critical Zone Observatory (CZO), which is underlain by granitic bedrock and lies outside the limits of recent glaciation, in the heart of the stepped topography described by Wahrhaftig. Our digital terrain analysis confirms that steep steps often grade into gentle treads, consistent with Wahrhaftig’s hypothesis. However, we observe a mix-and-match of soil and bare rock on treads and steps, contrary to one of the hypothesis’ major underpinnings – that bare rock should be much more common on steps than on treads. Moreover, the data show that bare rock is not as common as expected at step tops; Wahrhaftig’s hypothesis dictates that step tops should act as slowly eroding base levels for the treads above them. The data indicate that, within each landscape class (i.e., the steps and treads), bare rock erodes more slowly than surrounding soil. This suggests that the coupling between soil production and denudation in granitic landscapes harbors a tipping point wherein erosion rates decrease when soils are stripped to bedrock. Although broadly consistent with the differential weathering invoked by Wahrhaftig, the data also show that steps are eroding faster than treads, undermining Wahrhaftig’s explanation for the origins of the steps. The revised interpretation proposed here is that the landscape evolves by back-wearing of steps in addition to differential erosion due to differences in weathering of bare and soil-mantled granite.  相似文献   

藏北低速体存在的地震学证据——INDEPTH4宽频地震结果   总被引：1，自引：0，他引：1  

薛光琦  赵文津  宿和平  钱辉  冯梅  James Mechie 《地球学报》2011,32(3):331-335

位于青藏高原东北部的INDEPTH-IV地震探测剖面,始于柴达木盆地南缘,穿越东昆仑造山带、金沙江缝合线,终止于羌塘地体.本文作者利用天然地震体波完成了该区的三维走时残差反演,勾划出了青藏高原东北部的深部构造格局.研究区最显著的现象则是分布在昆仑地体、可可西里地体、羌塘地体北部下地壳、上地幔中的低速体.对其成因,有可能...  相似文献   

The Regional Ocean Modeling System (ROMS) 4-dimensional variational data assimilation systems: Part II - Performance and application to the California Current System     

Andrew M. Moore  Hernan G. ArangoGregoire Broquet  Chris EdwardsMilena Veneziani  Brian PowellDave Foley  James D. DoyleDan Costa  Patrick Robinson 《Progress in Oceanography》2011,91(1):50-73

The Regional Ocean Modeling System (ROMS) 4-dimensional variational (4D-Var) data assimilation systems have been systematically applied to the mesoscale circulation environment of the California Current to demonstrate the performance and practical utility of the various components of ROMS 4D-Var. In particular, we present a comparison of three approaches to 4D-Var, namely: the primal formulation of the incremental strong constraint approach; the dual formulation “physical-space statistical analysis system”; and the dual formulation indirect representer approach. In agreement with theoretical considerations all three approaches converge to the same ocean circulation estimate when using the same observations and prior information. However, the rate of convergence of the dual formulation was found to be inferior to that of the primal formulation. Other aspects of the 4D-Var performance that relate to the use of multiple outer-loops, preconditioning, and the weak constraint are also explored. A systematic evaluation of the impact of the various components of the 4D-Var control vector (i.e. the initial conditions, surface forcing and open boundary conditions) is also presented. It is shown that correcting for uncertainties in the model initial conditions exerts the largest influence on the ability of the model to fit the available observations. Various important diagnostics of 4D-Var are also examined, including estimates of the posterior error, the information content of the observation array, and innovation-based consistency checks on the prior error assumptions. Using these diagnostic tools, we find that more than 90% of the observations assimilated into the model provide redundant information. This is a symptom of the large percentage of satellite data that are used and to some extent the nature of the data processing employed. This is the second in a series of three papers describing the ROMS 4D-Var systems.  相似文献   

The Mount Wright Arc: A Cambrian subduction system developed on the continental margin of East Gondwana,Koonenberry Belt,eastern Australia     

J.E. Greenfield  R.J. Musgrave  M.C. Bruce  P.J. Gilmore  K.J. Mills 《Gondwana Research》2011,19(3):650-669

The Mount Wright Arc, in the Koonenberry Belt in eastern Australia, is associated with two early to middle Cambrian lithostratigraphic groups developed onto the Late Neoproterozoic volcanic passive margin of East Gondwana. The Gnalta Group includes a calc-alkaline basalt-andesite-dacite suite (Mount Wright Volcanics), interpreted to represent the volcanic component of the arc. Volcaniclastic Gnalta Group rocks now buried in the Bancannia Trough represent the continental back-arc, developed immediately behind the arc in a manner analogous to the modern Taupo Volcanic Zone of New Zealand. East of the Gnalta Group is the Ponto Group, a deep marine sedimentary package that includes tholeiitic lavas (Bittles Tank Volcanics) and felsic tuffs, interpreted as part of a fore-arc sequence. The configuration of these units suggests the Mount Wright Arc developed on continental crust in response to west-dipping subduction along the East Gondwana margin, in contrast with some models for Cambrian convergence on other sections of the Delamerian Orogen, which invoke east-dipping subduction and arc accretion by arc-continent collision.This convergent margin was deformed by the middle Cambrian Delamerian Orogeny, which involved initial co-axial shortening followed by sinistral transpression, and oroclinal folding around the edge of the Curnamona Province.  相似文献