Role of Fe(II) and phosphate in arsenic uptake by coprecipitation     

Nita Sahai  Young J. Lee  Huifang Xu  Jean-Francois Gaillard 《Geochimica et cosmochimica acta》2007,71(13):3193-3210

Natural attenuation of arsenic by simple adsorption on oxyhydroxides may be limited due to competing oxyanions, but uptake by coprecipitation may locally sequester arsenic. We have systematically investigated the mechanism and mode (adsorption versus coprecipitation) of arsenic uptake in the presence of carbonate and phosphate, from solutions of inorganic composition similar to many groundwaters. Efficient arsenic removal, >95% As(V) and ∼55% in initial As(III) systems, occurred over 24 h at pHs 5.5-6.5 when Fe(II) and hydroxylapatite (Ca₅(PO₄)₃OH, HAP) “seed” crystals were added to solutions that had been previously reacted with HAP, atmospheric CO_2(g) and O_2(g). Arsenic adsorption was insignificant (<10%) on HAP without Fe(II). Greater uptake in the As(III) system in the presence of Fe(II) was interpreted as due to faster As(III) to As(V) oxidation by molecular oxygen in a putative pathway involving Fe(IV) and As(IV) intermediate species. HAP acts as a pH buffer that allows faster Fe(II) oxidation. Solution analyses coupled with high-resolution transmission electron microscopy (HRTEM), X-ray Energy-Dispersive Spectroscopy (EDS), and X-Ray Absorption Spectroscopy (XAS) indicated the precipitation of sub-spherical particles of an amorphous, chemically-mixed, nanophase, Fe^III[(OH)₃(PO₄)(As^VO₄)]·nH₂O or Fe^III[(OH)₃( PO₄)(As^VO₄)(As^IIIO₃)_minor]·nH₂O, where As^IIIO₃ is a minor component.The mode of As uptake was further investigated in binary coprecipitation (Fe(II) + As(III) or P), and ternary coprecipitation and adsorption experiments (Fe(II) + As(III) + P) at variable As/Fe, P/Fe and As/P/Fe ratios. Foil-like, poorly crystalline, nanoparticles of Fe^III(OH)₃ and sub-spherical, amorphous, chemically-mixed, metastable nanoparticles of Fe^III[(OH)₃, PO₄]·nH₂O coexisted at lower P/Fe ratios than predicted by bulk solubilities of strengite (FePO₄·2H₂O) and goethite (FeOOH). Uptake of As and P in these systems decreased as binary coprecipitation > ternary coprecipitation > ternary adsorption.Significantly, the chemically-mixed, ferric oxyhydroxide-phosphate-arsenate nanophases found here are very similar to those found in the natural environment at slightly acidic to circum-neutral pHs in sub-oxic to oxic systems, such phases may naturally attenuate As mobility in the environment, but it is important to recognize that our system and the natural environment are kinetically evolving, and the ultimate environmental fate of As will depend on the long-term stability and potential phase transformations of these mixed nanophases. Our results also underscore the importance of using sufficiently complex, yet systematically designed, model systems to accurately represent the natural environment.  相似文献   

Present-day deformation of the Dauphine Alpine and Subalpine massifs (SE France)     

Joseph Martinod  Francois Jouanne  Xavier Darmendrail  Jean-Cyrille Notter  Christophe Basile  Joel Taverna  Gilles Mhard  Jean-Francois Gamond 《Geophysical Journal International》1996,127(1):189-200

The positions of 20 geodetic points surveyed in 1946-1952 by the Institut Géographique National in the Grenoble area (western Alps) were remeasured in 1993-1994 using GPS. We evaluate the displacements of the common points of the networks between the two surveys, and calculate the strain-rate tensors for different sets of three adjacent points. The significant N70° shortening direction observed at the boundary of the Belledonne and Taillefer massifs suggests that the dextral strike-slip motion between the External Crystalline Massifs (ECM) and the Subalpine domain is still active. Geological evidence suggests that this deformation, which is compatible with the few focal mechanisms available for the area, occurred throughout the late Neogene. Our data also suggest a roughly 3-5 mm yr⁻¹ active shortening concentrated at the external front of the Subalpine chains. This thrust motion results in a principal axis of compression orientated N130°, oblique to the direction of shortening observed in the ECM. This change in direction is also seen in in situ stress measurements. This motion may mark the southward continuation of the active fault observed in the Jura mountains by Jouanne, Ménard & Darmendrail (1995).  相似文献   

The role of money and the financial sector in energy-economy models used for assessing climate and energy policy     

Hector Pollitt  Jean-Francois Mercure 《Climate Policy》2018,18(2):184-197

This article outlines a critical gap in the assessment methodology used to estimate the macroeconomic costs and benefits of climate and energy policy, which could lead to misleading information being used for policy-making. We show that the Computable General Equilibrium (CGE) models that are typically used for assessing climate policy use assumptions about the financial system that sit at odds with the observed reality. These assumptions lead to ‘crowding out’ of capital and, because of the way the models are constructed, negative economic impacts (in terms of gross domestic product (GDP) and welfare) from climate policy in virtually all cases.

In contrast, macro-econometric models, which follow non-equilibrium economic theory and adopt a more empirical approach, apply a treatment of the financial system that is more consistent with reality. Although these models also have major limitations, they show that green investment need not crowd out investment in other parts of the economy – and may therefore offer an economic stimulus. Our conclusion is that improvements in both modelling approaches should be sought with some urgency – both to provide a better assessment of potential climate and energy policy and to improve understanding of the dynamics of the global financial system more generally.

POLICY RELEVANCE

This article discusses the treatment of the financial system in the macroeconomic models that are used in assessments of climate and energy policy. It shows major limitations in approach that could result in misleading information being provided to policy-makers.  相似文献   

Latitude distributions and lifetimes of star-spots on G dwarfs in the α Persei cluster     

J. R. Barnes  A. Collier Cameron  Y. C. Unruh  J. F. Donati  & G. A. J. Hussain 《Monthly notices of the Royal Astronomical Society》1998,299(3):904-920

We present a set of maximum-entropy reconstructions of the star-spot distributions on two rapidly rotating G dwarfs in the α Persei cluster, from spectra taken at the William Herschel Telescope on three nights in 1996 October and November. Since these stars are too faint for conventional Doppler imaging, which makes use of only one or a few lines, we take the large number of photospheric metal lines available in an echelle spectrum, and deconvolve them into a single, high signal-to-noise ratio profile. We show that this technique results in a typical multiplex gain of 22.5 in signal-to-noise ratio for a given spectrum, the equivalent of using a single line obtained on a 63-m telescope. The image reconstructions demonstrate that both these stars have cool high-latitude regions or polar crowns, and low-latitude features, in contradiction to the suggestion that only high-latitude spots should be present. Cross-correlation between image reconstructions of He 699, 31 days apart, reveals a lack of correlation between detailed small-scale structures. This places an upper limit for the lifetime of the observed features at less than one month. The Hα profiles are also found to exhibit absorption features indicating the presence of prominence clouds, at or below the corotation radius.  相似文献   

Surface differential rotation and prominences of the Lupus post T Tauri star RX J1508.6–4423     

J.-F. Donati  M. Mengel  B. D. Carter  S. Marsden  A. Collier Cameron  R. Wichmann 《Monthly notices of the Royal Astronomical Society》2000,316(3):699-715

  相似文献   

Doppler imaging of G‐dwarfs in two young open clusters     

S. C. Marsden  I. A. Waite  B. D. Carter  J.‐F. Donati 《Astronomische Nachrichten》2004,325(3):246-246

  相似文献   

The coherence of kilohertz quasi-periodic oscillations in the X-rays from accreting neutron stars   总被引：1，自引：0，他引：1  

Didier Barret  Jean-Francois Olive  M. Coleman Miller 《Monthly notices of the Royal Astronomical Society》2006,370(3):1140-1146

We study in a systematic way the quality factor of the lower and upper kilohertz quasi-periodic oscillations (kHz QPOs) in a sample of low-luminosity neutron star X-ray binaries, showing both QPOs varying over a wide frequency range. The sample includes 4U 1636−536, 4U 1608−522, 4U 1735−44, 4U 1728−34, 4U 1820−303 and 4U 0614+09. We find that all sources except 4U 0614+09 show evidence of a drop in the quality factor of their lower kHz QPOs at high frequency. For 4U 0614+09 only the rising part of the quality factor versus frequency curve has been sampled so far. At the same time, in all sources but 4U 1728−34, the quality factor of the upper kHz QPO increases all the way to the highest detectable frequencies. We show that the high-frequency behaviours of both the lower and the upper kHz QPO quality factors are consistent with what is expected if the drop is produced by the approach of an active oscillating region to the innermost stable circular orbit: the existence of which is a key feature of general relativity in the strong field regime. Within this interpretation, our results imply gravitational masses around 2 M_⊙ for the neutron stars in those systems.  相似文献   

Modelling innovation and the macroeconomics of low-carbon transitions: theory,perspectives and practical use     

Jean-Francois Mercure  Florian Knobloch  Hector Pollitt  Leonidas Paroussos  S. Serban Scrieciu  Richard Lewney 《Climate Policy》2019,19(8):1019-1037

Energy and climate policies may have significant economy-wide impacts, which are regularly assessed based on quantitative energy-environment-economy models. These tend to vary in their conclusions on the scale and direction of the likely macroeconomic impacts of a low-carbon transition. This paper traces the characteristic discrepancies in models’ outcomes to their origins in different macro-economic theories, most importantly their treatment of technological innovation and finance. We comprehensively analyse the relevant branches of macro-innovation theory and group them into two classes: ‘Equilibrium’ and ‘Non-equilibrium’. While both approaches are rigorous and self-consistent, they frequently yield opposite conclusions for the economic impacts of low-carbon policies. We show that model outcomes are mainly determined by their representations of monetary and finance dimensions, and their interactions with investment, innovation and technological change. Improving these in all modelling approaches is crucial for strengthening the evidence base for policy making and gaining a more consistent picture of the macroeconomic impacts of achieving emissions reductions objectives. The paper contributes towards the ongoing effort of enhancing the transparency and understanding of sophisticated model mechanisms applied to energy and climate policy analysis. It helps tackle the overall ‘black box’ critique, much-cited in policy circles and elsewhere.

Key policy insights

• Quantitative models commissioned by policy-makers to assess the macroeconomic impacts of climate policy generate contradictory outcomes and interpretations.

• The source of the differences in model outcomes originates primarily from assumptions on the workings of the financial sector and the nature of money, and of how these interact with processes of low-carbon energy innovation and technological change.

• Representations of innovation and technological change are incomplete in energy-economy-environment models, leading to limitations in the assessment of the impacts of climate-related policies.

• All modelling studies should state clearly their underpinning theoretical school and their treatment of finance and innovation.

• A strong recommendation is given for modellers of energy-economy systems to improve their representations of money and finance.

  相似文献   

Emission scenarios for a global hydrogen economy and the consequences for global air pollution     

Bas van Ruijven  Jean-Francois Lamarque  Detlef P. van Vuuren  Tom Kram  Hans Eerens 《Global Environmental Change》2011,21(3):983-994

Hydrogen is named as possible energy carrier for future energy systems. However, the impact of large-scale hydrogen use on the atmosphere is uncertain. Application of hydrogen in clean fuel cells reduces emissions of air pollutants, but emissions from hydrogen production and leakages of molecular hydrogen could influence atmospheric chemistry. This paper combines a global energy system model and a global atmospheric model to explore the range of impacts of hydrogen on atmospheric chemistry. We found that emissions of molecular hydrogen may range from 0.2 up to 10% (or 25-167 Tg hydrogen/yr) for a global hydrogen energy system. The lower end of this range would in fact be equal to current emissions from fossil fuel combustion. Hydrogen energy use leads to a clear decrease in emissions of carbon monoxide, nitrogen oxides and sulphur dioxide, but large-scale hydrogen production from coal may lead to net increase in emissions of nitrous oxide and volatile organic compound. Compared to a reference scenario, this would lead to positive impacts on surface concentrations of carbon monoxide, nitrogen oxides and ozone. However, if hydrogen leakage would not be minimised it leads to an increase in methane lifetimes and a decrease in stratospheric ozone concentrations.  相似文献   

Large-scale magnetic field of the G8 dwarf ξ Bootis A     

P. Petit  J.-F. Donati  M. Aurière  J. D. Landstreet  F. Lignières  S. Marsden  D. Mouillet  F. Paletou  N. Toqué  G. A. Wade 《Monthly notices of the Royal Astronomical Society》2005,361(3):837-849

We investigate the magnetic geometry of the active G8 dwarf ξ Bootis A (ξ Boo A), from spectropolarimetric observations obtained in 2003 with the MuSiCoS échelle spectropolarimeter at the Télescope Bernard Lyot (Observatoire du Pic du Midi, France). We repeatedly detect a photospheric magnetic field, with periodic variations consistent with rotational modulation. Circularly polarized (Stokes V) line profiles present a systematic asymmetry, showing up as an excess in amplitude and area of the blue lobe of the profiles. Direct modelling of Stokes V profiles suggests that the global magnetic field is composed of two main components, with an inclined dipole and a large-scale toroidal field. We derive a dipole intensity of about 40 G, with an inclination of 35° of the dipole with respect to the rotation axis. The toroidal field strength is of the order of 120 G. A noticeable evolution of the field geometry is observed over the 40 nights of our observation window and results in an increase in field strength and dipole inclination.
This study is the first step of a long-term monitoring of ξ Boo A and other active solar-type stars, with the aim of investigating secular fluctuations of stellar magnetic geometries induced by activity cycles.  相似文献