Atmospheric nitrogen inputs into the North Sea: effect on productivity     

Gerrit de Leeuw  Lucinda Spokes  Tim Jickells  Carsten Ambelas Skjth  Ole Hertel  Elisabetta Vignati  Susanne Tamm  Michael Schulz  Lise-Lotte Srensen  Britta Pedersen  Laura Klein  K. Heinke Schlünzen 《Continental Shelf Research》2003,23(17-19):1743

The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m⁻² day⁻¹, which has the potential to promote primary productivity of 5.3 mmol C m⁻² day⁻¹. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km⁻¹, i.e. 0.19 mmol N m⁻² day⁻¹ which has the potential to promote primary productivity of 1.2 mmol C m⁻² day⁻¹. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NO_x and NH₃ are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m⁻² day⁻¹, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m² is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem.  相似文献   

Shallow Water Table Fluctuations in Relation to Soil Penetration Resistance     

James B. Shanley  K. Niclas Hjerdt  Jeffrey J. McDonnell    Carol Kendall 《Ground water》2003,41(7):964-972

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Feldspathic lunar meteorites and their implications for compositional remote sensing of the lunar surface and the composition of the lunar crust     

Randy L Korotev  Bradley L Jolliff  Jeffrey J Gillis 《Geochimica et cosmochimica acta》2003,67(24):4895-4923

We present new compositional data for six feldspathic lunar meteorites, two from cold deserts (Yamato 791197 and 82192) and four from hot deserts (Dhofar 025, Northwest Africa 482, and Dar al Gani 262 and 400). The concentrations of FeO (or Al₂O₃) and Th (or any other incompatible element) together provide first-order compositional information about lunar polymict samples (breccias and regoliths) and regions of the lunar surface observed from orbit. Concentrations of both elements on the lunar surface have been determined from data acquired by orbiting spacecraft, although the derived concentrations have large uncertainties and some systematic errors compared to sample data. Within the uncertainties and errors in the concentrations derived from orbital data, the distribution of FeO and Th concentrations among lunar meteorites, which represent ∼18 source regions on the lunar surface, is consistent with that of 18 random samples from the surface. Approximately 11 of the lunar meteorites are low-FeO and low-Th breccias, consistent with large regions of the lunar surface, particularly the northern farside highlands. Almost all regoliths from Apollo sites, on the other hand, have larger concentrations of both elements because they contain Fe-rich volcanic lithologies from the nearside maria and Th-rich lithologies from the high-Th anomaly in the northwestern nearside. The feldspathic lunar meteorites thus offer our best estimate of the composition of the surface of the feldspathic highlands, and we provide such an estimate based on the eight most well-characterized feldspathic lunar meteorites. The variable but high (on average) Mg/Fe ratio of the feldspathic lunar meteorites compared to ferroan anorthosites confirms a hypothesis that much of the plagioclase at the surface of the feldspathic highlands is associated with high-Mg/Fe feldspathic rocks such as magnesian granulitic breccia, not ferroan anorthosite. Geochemically, the high-Mg/Fe breccias appear to be unrelated to the mafic magnesian-suite rocks of the Apollo collection. Models for the formation of the upper lunar crust as a simple flotation cumulate composed mainly of ferroan anorthosite do not account for the complexity of the crust as inferred from the feldspathic lunar meteorites.  相似文献   

Increased sediment accretion rates following invasion byPhragmites australis: The role of litter     

Rooth  Jill E.  Stevenson  J. Court  Cornwell  Jeffrey C. 《Estuaries and Coasts》2003,26(2):475-483

Negative connotations of invasive plants worldwide have implicated them as the bearers of unfavorable ecosystem change. We contrasted 5-yr-old and 20-yr-oldPhragmites populations with pre-invasion areas occupied byTypha spp. andPanicum virgatum in an oligohaline tidal marsh of Chesapeake Bay. Peak live biomass was 3 times greater, while standing dead and litter was twice as great in the 20-yr-oldPhragmites. It is this abundance of concentrated litter on the marsh surface of maturePhragmites populations that we implicate as encouraging the trapping of organic and mineral matter. The rate of vertical accretion in 20-yr-oldPhragmites populations is 3–4 mm yr⁻¹ above the adjacent populations. By integrating the constant initial concentration and constant rate of supply models on individual²¹⁰Pb cores, we estimate thatPhragmites populations require a minimum of 7-yr post-colonization to enhance rates of accretion in this system. In ligh of the considerable loss of marsh habitat from relative sea-level rise, this finding contests the view that invasion creates strictly undesirable change at the ecosystem level.  相似文献   

A method for precise measurement of argon 40/36 and krypton/argon ratios in trapped air in polar ice with applications to past firn thickness and abrupt climate change in Greenland and at Siple Dome, Antarctica     

Jeffrey P. Severinghaus  Alexi Grachev  Nicolas Caillon 《Geochimica et cosmochimica acta》2003,67(3):325-343

We describe a method for measuring the ⁴⁰Ar/³⁶Ar ratio and the ⁸⁴Kr/³⁶Ar ratio in air from bubbles trapped in ice cores. These ratios can provide constraints on the past thickness of the firn layer at the ice core site and on the magnitude of past rapid temperature variations when combined with measured ¹⁵N/¹⁴N. Both variables contribute to paleoclimatic studies and ultimately to the understanding of the controls on Earth’s climate. The overall precision of the ⁴⁰Ar/³⁶Ar method (1 standard error of the mean) is 0.012‰ for a sample analyzed in duplicate, corresponding to ±0.6 m in reconstructed firn thickness. We use conventional dynamic isotope ratio mass spectrometry with minor modifications and special gas handling techniques designed to avoid fractionation. About 100 g of ice is used for a duplicate pair of analyses. An example of the technique applied to the GISP2 ice core yields an estimate of 11 ± 3K of abrupt warming at the end of the last glacial period 15,000 years ago. The krypton/argon ratio can provide a diagnostic of argon leakage out of the bubbles, which may happen (naturally) during bubble close-off or (artifactually) if samples are warmed near the freezing point during core retrieval or storage. Argon leakage may fractionate the remaining ⁴⁰Ar/³⁶Ar ratio by +0.007‰ per ‰ change in ⁸⁴Kr/³⁶Ar, introducing a possible bias in reconstructed firn thickness of about +2 m if thermal diffusion is not accounted for or +6 m if thermal diffusion effects are quantified with measured ¹⁵N/¹⁴N. Reproducibility of ⁸⁴Kr/³⁶Ar measured in air is about ±0.2‰ (1 standard error of the mean) but is about ±1‰ for ice core samples. Ice core samples are systematically enriched in ⁸⁴Kr/³⁶Ar relative to atmosphere by ∼5‰, probably reflecting preferential size-dependent exclusion of the smaller argon atom during bubble entrapment. Recent results from the Siple Dome ice core reveal two climate events during the last deglaciation, including an 18-m reduction in firn thickness associated with an abrupt warming at sometime between 18 and 22 kyr BP and a partial or total removal of the firn during an ablation event at 15.3 kyr BP.  相似文献   

Serpentinization of abyssal peridotites from the MARK area, Mid-Atlantic Ridge: sulfur geochemistry and reaction modeling   总被引：1，自引：0，他引：1  

Jeffrey C. Alt  Wayne C. Shanks III 《Geochimica et cosmochimica acta》2003,67(4):641-653

The opaque mineralogy and the contents and isotope compositions of sulfur in serpentinized peridotites from the MARK (Mid-Atlantic Ridge, Kane Fracture Zone) area were examined to understand the conditions of serpentinization and evaluate this process as a sink for seawater sulfur. The serpentinites contain a sulfur-rich secondary mineral assemblage and have high sulfur contents (up to 1 wt.%) and elevated δ³⁴S_sulfide (3.7 to 12.7‰). Geochemical reaction modeling indicates that seawater-peridotite interaction at 300 to 400°C alone cannot account for both the high sulfur contents and high δ³⁴S_sulfide. These require a multistage reaction with leaching of sulfide from subjacent gabbro during higher temperature (∼400°C) reactions with seawater and subsequent deposition of sulfide during serpentinization of peridotite at ∼300°C. Serpentinization produces highly reducing conditions and significant amounts of H₂ and results in the partial reduction of seawater carbonate to methane. The latter is documented by formation of carbonate veins enriched in ¹³C (up to 4.5‰) at temperatures above 250°C. Although different processes produce variable sulfur isotope effects in other oceanic serpentinites, sulfur is consistently added to abyssal peridotites during serpentinization. Data for serpentinites drilled and dredged from oceanic crust and from ophiolites indicate that oceanic peridotites are a sink for up to 0.4 to 6.0 × 10¹² g seawater S yr⁻¹. This is comparable to sulfur exchange that occurs in hydrothermal systems in mafic oceanic crust at midocean ridges and on ridge flanks and amounts to 2 to 30% of the riverine sulfate source and sedimentary sulfide sink in the oceans. The high concentrations and modified isotope compositions of sulfur in serpentinites could be important for mantle metasomatism during subduction of crust generated at slow spreading rates.  相似文献   

P-SH conversions in a flat-layered medium with anisotropy of arbitrary orientation   总被引：3，自引：0，他引：3  

Vadim Levin  Jeffrey Park 《Geophysical Journal International》1997,131(2):253-266

P-SH conversion is commonly observed in teleseismic P waves, and is often attributed to dipping interfaces beneath the receiver. Our modelling suggests an alternative explanation in terms of flat-layered anisotropy. We use reflectivity techniques to compute three-component synthetic seismograms in a 1-D anisotropic layered medium. For each layer of the medium, we prescribe values of seismic velocities and hexagonally symmetric anisotropy about a common symmetry axis of arbitrary orientation. A compressional wave in an anisotropic velocity structure suffers conversion to both SV -and SH -polarized shear waves, unless the axis of symmetry is everywhere vertical or the wave travels parallel to all symmetry axes. The P-SV conversion forms the basis of the widely used 'receiver function' technique. The P-SH conversion occurs at interfaces where one or both layers are anisotropic. A tilted axis of symmetry and a dipping interface in isotropic media produce similar amplitudes of both direct ( P ) and converted ( Ps ) phases, leaving the backazimuth variation of the P-Ps delay as the main discriminant. Seismic anisotropy with a tilted symmetry axis leads to complex synthetic seismograms in velocity models composed of just a few flat homogeneous layers. It is possible therefore to model observations of P coda with prominent transverse components with relatively simple 1-D velocity structures. Successful retrieval of salient model characteristics appears possible using multiple realizations of a genetic-algorithm (GA) inversion of P coda from several backazimuths. Using GA inversion, we determine that six P coda recorded at station ARU in central Russia are consistent with models that possess strong (> 10 per cent) anisotropy in the top 5 km and between 30 and 43 km depth. The symmetry axes are tilted, and appear aligned with the seismic anisotropy orientation in the mantle under ARU suggested by SKS splitting.  相似文献   

Mitigating the Effects of Climate Change on the Water Resources of the Columbia River Basin   总被引：5，自引：3，他引：5  

Jeffrey T. Payne  Andrew W. Wood  Alan F. Hamlet  Richard N. Palmer  Dennis P. Lettenmaier 《Climatic change》2004,62(1-3):233-256

The potential effects of climate change on the hydrology and water resources of the Columbia River Basin (CRB) were evaluated using simulations from the U.S. Department of Energy and National Center for Atmospheric Research Parallel Climate Model (DOE/NCAR PCM). This study focuses on three climate projections for the 21st century based on a `business as usual' (BAU) global emissions scenario, evaluated with respect to a control climate scenario based on static 1995 emissions. Time-varying monthly PCM temperature and precipitation changes were statistically downscaled and temporally disaggregated to produce daily forcings that drove a macro-scale hydrologic simulation model of the Columbia River basin at 1/4-degree spatial resolution. For comparison with the direct statistical downscaling approach, a dynamical downscaling approach using a regional climate model (RCM) was also used to derive hydrologic model forcings for 20-year subsets from the PCM control climate (1995–2015) scenario and from the three BAU climate(2040–2060) projections. The statistically downscaled PCM scenario results were assessed for three analysis periods (denoted Periods 1–3: 2010–2039,2040–2069, 2070–2098) in which changes in annual average temperature were +0.5,+1.3 and +2.1 °C, respectively, while critical winter season precipitation changes were –3, +5 and +1 percent. For RCM, the predicted temperature change for the 2040–2060 period was +1.2 °C and the average winter precipitation change was –3 percent, relative to the RCM controlclimate. Due to the modest changes in winter precipitation, temperature changes dominated the simulated hydrologic effects by reducing winter snow accumulation, thus shifting summer streamflow to the winter. The hydrologic changes caused increased competition for reservoir storage between firm hydropower and instream flow targets developed pursuant to the Endangered Species Act listing of Columbia River salmonids. We examined several alternative reservoir operating policies designed to mitigate reservoir system performance losses. In general, the combination of earlier reservoir refill with greater storage allocations for instream flow targets mitigated some of the negative impacts to flow, but only with significant losses in firm hydropower production (ranging from –9 percent in Period1 to –35 percent for RCM). Simulated hydropower revenue changes were lessthan 5 percent for all scenarios, however, primarily due to small changes inannual runoff.  相似文献   

Using Eigenpattern Analysis to Constrain Seasonal Signals in Southern California     

K. F. Tiampo  J. B. Rundle  W. Klein  Y. Ben-Zion  S. McGinnis 《Pure and Applied Geophysics》2004,161(9-10):1991-2003

— Earthquake fault systems are now thought to be an example of a complex nonlinear system (Bak, et al., 1987; Rundle and Klein, 1995). The spatial and temporal complexity of this system translates into a similar complexity in the surface expression of the underlying physics, including deformation and seismicity. Here we show that a new pattern dynamic methodology can be used to define a unique, finite set of deformation patterns for the Southern California Integrated GPS Network (SCIGN). Similar in nature to the empirical orthogonal functions historically employed in the analysis of atmospheric and oceanographic phenomena (Preisendorfer, 1988), the method derives the eigenvalues and eigenstates from the diagonalization of the correlation matrix using a Karhunen-Loeve expansion (KLE) (Fukunaga, 1970; Rundle et al., 2000; Tiampo et al., 2002). This KLE technique may be used to determine the important modes in both time and space for the southern California GPS data, modes that potentially include such time-dependent signals as plate velocities, viscoelasticity, and seasonal effects. Here we attempt to characterize several of the seasonal vertical signals on various spatial scales. These, in turn, can be used to better model geophysical signals of interest such as coseismic deformation, viscoelastic effects, and creep, as well as provide data assimilation and model verification for large-scale numerical simulations of southern California.  相似文献   

Dislocating modernity: Identity, space and representations of street trade in Durban, South Africa     

E. Jeffrey Popke  Richard Ballard 《Geoforum》2004,35(1):99-110

South Africa’s cities have experienced dramatic changes over the past decade. Cities are now home to a multiracial population, and have been transformed by new forms of economic and social interaction. For some, these changes have become a significant source of fear and anxiety. In this paper, we examine reactions to urban spatial change in the city of Durban, as expressed in local newspapers and interviews with suburban residents. We describe how the discourses of urban change in Durban have centred on the increased presence of street traders within the city’s public spaces, and the various ways in which the activity of street trade has disrupted long-established modernist norms governing the occupation and use of the urban space. Specifically, we offer a detailed reading of three prominent narratives within the discussion of street traders in Durban--chaos, congestion and pollution. We argue that street traders have come to embody a wide range of more deeply seated cultural anxieties, which have been brought to the fore in the context of South Africa’s transition. These anxieties arise from the ways in which modern understandings of order, agency and subjectivity have been called into question by material changes in the city, and have implications for the nature of citizenship and civic engagement in post-apartheid South Africa.  相似文献