Borehole diffusive flux apparatus for characterizing diffusive mass-transfer in subsurface systems     

Mark L. Brusseau  Kenneth C. Carroll  Zhilin Guo  Jon Mainhagu 《Environmental Earth Sciences》2018,77(18):648

The concept of the Borehole Diffusive Flux Apparatus (BDFA) is presented herein. The BDFA is an innovative apparatus designed to provide continuous direct access to an undisturbed column of sediment that can be monitored at multiple discrete vertical intervals to provide high-resolution characterization of local-scale mass transfer and attenuation. The conceptual basis and technical design of the device are presented, along with an example of borehole design and installation at a field site. Mathematical simulations are used to illustrate its application for two scenarios. The results of these simulations indicate that test periods of several weeks to a few months should be sufficient to obtain robust results. The device has the potential to improve our ability to characterize critical mass-transfer and attenuation processes and to quantify the associated rates. This information is key to the evaluation of remediation alternatives, for enhancing the accuracy of mathematical models, and to support more effective long-term management of large groundwater contaminant plumes present at many sites.  相似文献   

Magma evolution beneath Bequia,Lesser Antilles,deduced from petrology of lavas and plutonic xenoliths   总被引：1，自引：0，他引：1  

Michal?Camejo-HarryEmail authorView author&#;s OrcID profile  Elena?Melekhova  Jon?Blundy  William?Attridge  Richard?Robertson  Thomas?Christopher 《Contributions to Mineralogy and Petrology》2018,173(10):77

Extrusive and intrusive igneous rocks represent different parts of a magmatic system and ultimately provide complementary information about the processes operating beneath volcanoes. To shed light on such processes, we have examined and quantified the textures and mineral compositions of plutonic and cumulate xenoliths and lavas from Bequia, Lesser Antilles arc. Both suites contain assemblages of iddingsitized olivine, plagioclase, clinopyroxene and spinel with rare orthopyroxene and ilmenite. Mineral zoning is widespread, but more protracted in lavas than xenoliths. Plagioclase cores and olivine have high anorthite (An?≤?98) and low forsterite (Fo?≤?84) compositions respectively, implying crystallisation from a hydrous mafic melt that was already fractionated. Xenolith textures range from adcumulate to orthocumulate with variable mineral crystallisation sequences. Textural criteria are used to organize the xenoliths into six groups. Amphibole, notably absent from lavas, is a common feature of xenoliths, together with minor biotite and apatite. Bulk compositions of xenoliths deviate from the liquid line of descent of lavas supporting a cumulate origin with varying degrees of reactive infiltration by evolved hydrous melts, preserved as melt inclusions in xenolith crystals. Volatile saturation pressures in melt inclusions indicate cumulate crystallization over a 162–571 MPa pressure range under conditions of high dissolved water contents (up to 7.8 wt% H₂O), consistent with a variety of other thermobarometric estimates. Phase assemblages of xenoliths are consistent with published experimental data on volatile-saturated low-magnesium and high-alumina basalts and basaltic andesite from the Lesser Antilles at pressures of 200–1000 MPa, temperatures of 950–1050 °C and dissolved H₂O contents of 4–7 wt%. Once extracted from mid-crustal mushes, residual melts ascend to higher levels and undergo H₂O-saturated crystallization in shallow, pre-eruptive reservoirs to form phenocrysts and glomerocrysts. The absence of amphibole from lavas reflects instability at low pressures, whereas its abundance in xenoliths testifies to its importance in mid-crustal differentiation processes. A complex, vertically extensive (6 to at least 21 km depth) magmatic system is inferred beneath Bequia. Xenoliths represent fragments of the mush incorporated into ascending magmas. The widespread occurrence of evolved melts in the mush, but the absence of erupted evolved magmas, in contrast to islands in the northern Lesser Antilles, may reflect the relative immaturity of the Bequia magmatic system.  相似文献   

Detailing the impact of the Storegga Tsunami at Montrose,Scotland     

Mark D. Bateman  Tim C. Kinnaird  Jon Hill  Robert A. Ashurst  Jenna Mohan  Rebecca B. I. Bateman  Ruth Robinson 《Boreas: An International Journal of Quaternary Research》2021,50(4):1059-1078

The Storegga tsunami, dated in Norway to 8150±30 cal. years BP, hit many countries bordering the North Sea. Run-ups of >30 m occurred and 1000s of kilometres of coast were impacted. Whilst recent modelling successfully generated a tsunami wave train, the wave heights and velocities, it under-estimated wave run-ups. Work presented here used luminescence to directly date the Storegga tsunami deposits at the type site of Maryton, Aberdeenshire in Scotland. It also undertook sedimentological characterization to establish provenance, and number and relative power of the tsunami waves. Tsunami model refinement used this to better understand coastal inundation. Luminescence ages successfully date Scottish Storegga tsunami deposits to 8100±250 years. Sedimentology showed that at Montrose, three tsunami waves came from the northeast or east, over-ran pre-existing marine sands and weathered igneous bedrock on the coastal plain. Incorporation of an inundation model predicts well a tsunami impacting on the Montrose Basin in terms of replicate direction and sediment size. However, under-estimation of run-up persisted requiring further consideration of palaeotopography and palaeo-near-shore bathymetry for it to agree with sedimentary evidence. Future model evolution incorporating this will be better able to inform on the hazard risk and potential impacts for future high-magnitude submarine generated tsunami events.  相似文献   

A syn‐depositional age for Earth’s deepest δ13C excursion required by isotope conglomerate tests     

Jon M. Husson  Adam C. Maloof  Blair Schoene 《地学学报》2012,24(4):318-325

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Governance and technology transfer in the Clean Development Mechanism in India     

Jon Phillips  Kasturi Das  Peter Newell 《Global Environmental Change》2013,23(6):1594-1604

Despite significant technological advances in emerging economies, the further development of clean energy technologies in developing countries remains crucial to reducing the greenhouse gas emissions associated with economic development. In this paper we address two significant gaps in the growing body of literature that has assessed the role of the Clean Development Mechanism in promoting the transfer of clean technologies to developing countries. First, we present a qualitative analysis of the governance of the Clean Development Mechanism in India. This provides a basis for understanding the extent to which and the ways in which governance may impact upon the likelihood that projects promote technology transfer. Second, we provide a novel quantification of the level and nature of technology transfer that has occurred in Indian Clean Development Mechanism projects, based on insights from literature on technological capability building. We find that the Clean Development Mechanism in India has produced a negligible number of projects that promote technology transfer if technology transfer is understood as a process of learning about technology. Together these qualitative and quantitative analyses show how politics and governance have contributed to the current form of the Clean Development Mechanism market in India, in which processes of building indigenous technological capabilities have been neglected.  相似文献   

“Lessons for marine conservation planning: A comparison of three marine protected area planning processes”     

Michael Osmond  Satie Airame  Margaret Caldwell  Jon Day 《Ocean & Coastal Management》2010,53(2):41-51

Various approaches have been used to establish marine protected areas (MPAs) in different countries. In this paper we compare and review three processes to establish MPAs within the United States and Australia. These two countries share many similarities in their cultures, but their approaches to managing marine resources differ considerably. Each of these efforts to establish or review MPAs was motivated by concern about declines of targeted marine species or habitats. However, the government actions varied because of differences in governance, planning process including public input, and the role of science. Comparing these processes highlights effective approaches for protecting marine ecosystems and gaining public support.  相似文献   

Isotopic and trace-element profiles across the New Britain island arc,Papua New Guinea     

Jon D. Woodhead  R. W. Johnson 《Contributions to Mineralogy and Petrology》1993,113(4):479-491

New Pb-, Sr-, and Nd-isotopic data have been obtained for the rocks of volcanoes overlying a wide range of depths (100–580 km) to the Wadati-Benioff Zone (WBZ) in the New Britain island arc, Papua New Guinea. Well-defined trends consistent with two-component mixing are observed in combined Pb-isotope/trace-element plots. One of the components is believed to represent a slab contribution whose isotopic signature, unlike those noted for several other arcs, appears to be dominated by subducted, altered, oceanic crust rather than by sediment. This conclusion is consistent with the results of a recent Be–B study of New Britain rocks. The influence of the slab component is considered to decrease as depth to the WBZ increases. Higher abundances of high-field-strength elements correlate with increasing depths to the WBZ, and may be indicative of smaller degrees of partial melting of the mantle wedge as WBZ depths increase. Abundances of other incompatible elements appear to reflect a complex interplay between the slab-derived flux and melting process.  相似文献   

Structure proof and significance of stereoisomeric 28,30-bisnorhopanes in petroleum and petroleum source rocks     

J.Michael Moldowan  Wolfgang K. Seifert  Edward Arnold  Jon Clardy 《Geochimica et cosmochimica acta》1984,48(8):1651-1661

Two C₂₈H₄₈-pentacyclic triterpanes were isolated from Monterey shale. X-ray crystallography of a crystal containing both compounds proved their structures as 17β,18α,21α(H)-28,30-bisnorhopane and 17β,18α,21β(H)-28,30-bisnorhopane. Several differences are found between 28,30-bisnorhopanes and the regular hopanes. Unlike the regular hopane epimers, for practical purposes the three epimeric 28,30-bisnorhopanes [17α,21β(H)-, 17β,21α(H)-, and 17β,21β(H)-]cannot be distinguished by their mass spectra. Special conditions are needed to separate them by gas chromatography. The diagenetically first-formed epimer is thought to be 17α,21β(H)- because it predominates in immature shales. The order of thermodynamic stability is 17β,2lα(H) < > 17α,21β(H) > 17β,21β(H), and all three epimers are present in petroleum. 25,28,30-Trisnorhopanes can be analyzed in similar fashion and are found to have similar thermodynamic characteristics. The percent of the ring D/E cis epimer of 28,30-bisnorhopane and/or 25,28,30-trisnorhopane is a useful maturation parameter similar to the 20S/20R sterane ratio. Evidence indicates 25-demethylation of 28,30-bisnorhopane to 25,28,30-trisnorhopane during advanced stages of biodegradation. Hence, percent ring $\text{D}\text{E}$cis 25,28,30-trisnorhopane has an application to maturation assessment in heavily biodegraded oils.  相似文献   

OCCURRENCE OF VOLATILE ORGANIC CHEMICALS IN NEBRASKA GROUND WATER     

Owen Goodenkauf  Jon C. Atkinson 《Ground water》1986,24(2):231-233

Abstract. This report summarizes results of monitoring programs for volatile synthetic organic chemicals (VOCs) in Nebraska's private and public water-supply wells conducted by two State agencies. Of 97 community water-supply systems sampled as of June 1984, 16.5 percent (16 systems) showed quantifiable levels of at least one VOC. Detectable amounts of one or more VOCs were measured in samples from 15.9 percent (10) of 63 private wells sampled in 1982. These percentages are consistent with results of other State and national surveys.  相似文献   

O, S, Sr, and Pb isotope variations in volcanic rocks from the Northern Mariana Islands: implications for crustal recycling in intra-oceanic arcs     

Jon D. Woodhead  Russell S. Harmon  Donald G. Fraser 《Earth and Planetary Science Letters》1987,83(1-4)

Quaternary lavas from the Northern Mariana Islands have respective O- and S-isotope ranges ofδ¹⁸O = +5.7 to +6.6 (‰ SMOW) andδ³⁴S = +2.0to+20.7 (‰ CDT). Chemically evolved andesites and dacites with meanδ¹⁸O = +6.3 ± 0.2 are slightly enriched in¹⁸O with respect to unfractionated basalts of<53%SiO₂ with meanδ¹⁸O = +6.0 ± 0.1. This¹⁸O enrichment can be explained in terms of differentiation of parental mafic magmas havingδ¹⁸O values between +5.7 to +6.2‰ through closed-system crystal fractionation because the lavas from all nine islands of the arc define a coherentδ¹⁸OSiO₂ trend. The S-isotope composition of oxidized magmas is not modified extensively through the degassing of SO₂; therefore, the meanδ³⁴S value of ca. +11‰ for the Mariana lavas is considered to be representative of their source region.The enrichment of¹⁸O and³⁴S in Mariana Arc parental magmas relative to ocean floor basalts withδ¹⁸O ca. + 5.7‰ andδ³⁴S = ca.0.3‰ is attributed to the recycling of¹⁸O- and³⁴S-rich crustal components (sediment withδ¹⁸O = ca. + 25‰ and seawater sulfate withδ³⁴S = ca. +20‰ into the upper mantle source region for these arc magmas. This interpretation is consistent with enrichments of radiogenic Sr and Pb in the same lavas relative to ocean-floor basalts erupted either side of the arc, which are presumed to share a common upper mantle source. This enrichment is considered to reflect the mixing of two components, one having a typical upper mantle composition and the other having a more radiogenic character similar to that of western Pacific pelagic sediments.  相似文献