Onboard experiment investigating metal leaching of fresh hydrothermal sulfide cores into seawater     

Shigeshi Fuchida  Jun-ichiro Ishibashi  Kazuhiko Shimada  Tatsuo Nozaki  Masanobu Kawachi  Yoshitaka Matsushita  Hiroshi Koshikawa 《Geochemical transactions》2018,19(1):15

We observed the initial release rate of metals from four fresh (i.e., without long time exposure to the atmosphere) hydrothermal sulfide cores into artificial seawater. The sulfide samples were collected by seafloor drilling from the Okinawa Trough by D/V Chikyu, powdered under inert gas, and immediately subjected to onboard metal-leaching experiments at different temperatures (5 °C and 20 °C), and under different redox conditions (oxic and anoxic), for 1–30 h. Zinc and Pb were preferentially released from sulfide samples containing various metals (i.e., Mn, Fe, Cu, Zn, Cd, and Pb) into seawater. Under oxic experimental conditions, Zn and Pb dissolution rates from two sulfide samples composed mainly of iron disulfide minerals (pyrite and marcasite) were higher than those from two other sulfide samples with abundant sphalerite, galena, and/or silicate minerals. Scanning electron microscopy confirmed that the high metal-releasing sample contained several galvanic couples of iron disulfide with other sulfide minerals, whereas the low metal-releasing sample contained fewer galvanic couples or were coated by a silicate mineral. The experiments overall confirmed that the galvanic effects with iron disulfide minerals greatly induce the initial release of Zn and Pb from hydrothermal sulfides into seawater, especially under warm oxic conditions.  相似文献   

U–Pb and fission‐track dating of a submarine pyroclastic rock from southwest Japan          下载免费PDF全文

Takashi Ninomiya  Sho Taniguchi  Shoichi Shimoyama  Koichiro Watanabe  Tohru Danhara  Hideki Iwano  Kazuyuki Shiraishi  Chitaro Gouzu 《Island Arc》2017,26(6)

The Okinoshima Formation crops out on Okinoshima Island and comprises a thick sequence (> 200 m) of pyroclastic rocks and alternating beds of sandstone and mudstone. Because Okinoshima Island is located between Honshu and Tsushima Island, the Okinoshima Formation potentially provides an important record of volcanism during the opening of the Japan Sea in northwest Kyushu, as well as a record of the formation of the present Genkai Sea region. In consideration of the lack of previous geochronological work, dating (fission‐track and U–Pb) of igneous zircons extracted from the Okinoshima Formation were undertaken and studied the clay mineral alteration in the pyroclastic material in order to reveal its thermal history. These data are used to constrain the age of the Okinoshima Formation and the present Genkai Sea region. Our results show that no thermal event has reset the fission‐track age after deposition of the pyroclastic rocks, and that the Okinoshima Formation was deposited at 16.2 Ma. The present Genkai Sea region is a deep‐sea basin, and its formation at 16.2 Ma was accompanied by submarine volcanism and rapid subsidence that marked the climactic stage of Japan Sea formation. After 16 Ma, the tectonic setting of the present Genkai Sea region changed from one of extension (related to the formation of the Japan Sea) to one of compression, with uplift occurring under the influence of the clockwise rotation of southwest Japan. Consequently, after 16 Ma the present Genkai Sea region became isolated from the forming processes of the Japan Sea.  相似文献   

Heating experiments of the Tagish Lake meteorite: Investigation of the effects of short‐term heating on chondritic organics     

Queenie H. S. Chan  Aiko Nakato  Yoko Kebukawa  Michael E. Zolensky  Tomoki Nakamura  Jessica A. Maisano  Matthew W. Colbert  James E. Martinez  A. L. David Kilcoyne  Hiroki Suga  Yoshio Takahashi  Yasuo Takeichi  Kazuhiko Mase  Ian P. Wright 《Meteoritics & planetary science》2019,54(1):104-125

We present in this study the effects of short‐term heating on organics in the Tagish Lake meteorite and how the difference in the heating conditions can modify the organic matter (OM) in a way that complicates the interpretation of a parent body's heating extent with common cosmothermometers. The kinetics of short‐term heating and its influence on the organic structure are not well understood, and any study of OM is further complicated by the complex alteration processes of the thermally metamorphosed carbonaceous chondrites—potential analogues of the target asteroid Ryugu of the Hayabusa2 mission—which had experienced posthydration, short‐duration local heating. In an attempt to understand the effects of short‐term heating on chondritic OM, we investigated the change in the OM contents of the experimentally heated Tagish Lake meteorite samples using Raman spectroscopy, scanning transmission X‐ray microscopy utilizing X‐ray absorption near edge structure spectroscopy, and ultraperformance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry. Our experiment suggests that graphitization of OM did not take place despite the samples being heated to 900 °C for 96 h, as the OM maturity trend was influenced by the heating conditions, kinetics, and the nature of the OM precursor, such as the presence of abundant oxygenated moieties. Although both the intensity of the 1s?σ* exciton cannot be used to accurately interpret the peak metamorphic temperature of the experimentally heated Tagish Lake sample, the Raman graphite band widths of the heated products significantly differ from that of chondritic OM modified by long‐term internal heating.  相似文献   

Small-Amplitude Disturbances in a Radiating and ScatteringGrey MediumI. Solutions of Given Real Frequency ω     

Noboru Kaneko  Kazuhiko Morita  Tetsuya Satoh  Kiyotaka Toyama  Masaki Nishimura  Makoto Maekawa 《Astrophysics and Space Science》2000,274(3):601-641

We reanalyze the propagation of one-dimensional small-amplitude disturbances of given real frequency ω in a radiating and scattering grey medium using the Eddington approximation, which has been studied previously by us (Kaneko et al., 1976). Numerical results reveals three frequency regimes to be distinguished, and two wave modes always appear in each frequency regime. The governing equations and analytic solutions are derived for all wave modes using Whitham's method modified into quadratic form and approximate methods based on radiation thermodynamics. In the high-frequency regime appear the radiation-wave and adiabatic sound modes, which are damped by opacity and radiative cooling, respectively. Wave patterns in the intermediate-frequency and low-frequency regimes depend critically on the importance of radiation, for which the criterion is given in terms of the ratio of total specific heats at constant pressure and constant volume. When the radition overwhelms the matter (radiation-dominated case), the radiative mode in the intermediate-frequency regime is the constant-volume diffusion mode. When the matter overwhelms the radiation (matter-dominated case), damped radiation-wave and damped radiation-diffusion modes newly appear between the radiation-wave and constant-volume diffusion modes. The acoustic mode in the intermediate-frequency regime is the isothermal sound mode,which is damped by radiative cooling at higher frequencies and by radiation-thermal drag force at lower frequencies. Two modes appearing in the low-frequency regime are the isentropic radiation-acoustic and constant-pressure diffusion modes. The absorption coefficient derived for the former is shown to be a radiation-thermodynamic extension of that of Landau and Lifshitz (1987). The transition frequencies between all adjacent two modes are also derived to discuss the implications of them. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Simple estimation of penetration rate of light in intertidal sediments     

Kazuhiko Ichimi  Kuninao Tada  Shigeru Montani 《Journal of Oceanography》2008,64(3):399-404

A simple estimation of light penetration in tidal flat sediments was developed using various sediment size fractions and their attenuation rate of irradiance. The attenuation coefficients of the sediment size fractions of 63–125, 125–250, 250–500, 500–1000 μm and 1000–2000 μm were 8.10, 4.08, 2.92, 2.12 and 1.44 mm⁻¹, respectively. Using the average attenuation coefficient of the particle size fractions in the sediment, the calculated attenuation coefficient agreed well with the actual attenuation coefficient. The method presented gives a photo-parameter to predict productivity in intertidal sediments, given only the particle size fraction.  相似文献   

Polycyclic aromatic hydrocarbons (PAHs) associated with atmospheric particles in Higashi Hiroshima, Japan: Influence of meteorological conditions and seasonal variations   总被引：3，自引：0，他引：3  

Yasmin W.F. Tham  Kazuhiko Takeda  Hiroshi Sakugawa   《Atmospheric Research》2008,88(3-4):224-233

This work studied the influence of meteorological conditions on particulate polycyclic aromatic hydrocarbons (PAHs) in the atmosphere of Higashi Hiroshima, Japan. The seasonal variation of particulate PAHs was also covered. It was found that ambient temperature, solar intensity and weekly rainfall had significant influence on the particulate PAH concentration based on correlation studies. Correlation of particulate PAHs with ambient temperature, solar intensity, weekly rainfall, wind speed and humidity was studied by using Pearson correlation analysis. Particulate PAHs had a strong negative correlation with ambient temperature and solar intensity. A moderate negative correlation with weekly rainfall was also observed. There was no significant correlation between particulate PAHs with wind speed as well as humidity. Besides, particulate PAHs were found to have significant positive correlation with sulfur dioxide and nitrogen dioxide while having a moderate negative correlation with ozone. The particulate PAHs in Higashi Hiroshima exerted distinct seasonal variation with a higher concentration in winter and lower concentration in summer. When compared among PAHs with different numbers of aromatic rings; 5-ring PAHs was found to exert the most distinct seasonal variation. The contribution of carcinogenic PAHs to total particulate PAH concentration was fairly constant at about 50% throughout the year.  相似文献   

An attempt to characterize phase Q: Noble gas, Raman spectroscopy and transmission electron microscopy in residues prepared from the Allende meteorite     

Jun-ichi Matsuda  Kazuhiko Morishita  Chie Miyakawa  Sachiko Amari  Seiji Takeda 《Geochimica et cosmochimica acta》2010,74(18):5398-5409

We have prepared a HF-HCl residue and its oxidized residue of the Allende meteorite and have measured the elemental concentrations and the isotopic compositions of noble gases. In the HF-HCl reside, noble gases are enriched in colloidal fraction compared to the non-colloidal fraction by a factor of 2-4. The heavy noble gases were evidently lost after the oxidization, indicating that phase Q (carrier of planetary heavy noble gases) was removed by the oxidation. The Raman spectroscopic parameters show that the colloidal fraction of the HF-HCl residue is more amorphous compared to the non-colloidal fraction. As the ion irradiation converts carbon into a more amorphous form, our result indicates that the “plasma model” is more plausible than the “labyrinth model” as the origin of phase Q. TEM (Transmission Electron Microscope) observations also show such a trace of ion irradiation. While the TEM observations did not show any large difference between the HF-HCl residue and its oxidized residue, the Raman spectroscopic parameters changed discretely resulting from the oxidization. This observation indicates that the oxidization not only dissolved and removed oxidized carbon, but also changed the carbon structure itself to a more amorphous (disordered) state. The Raman spectroscopic results indicate the possibility that release of Q-gas during oxidation is not accompanied by mass loss and that the release of Q-gas simply resulted from rearrangement of carbon structure during oxidation.  相似文献   

POC fluxes estimated from 234Th in late spring–early summer in the western subarctic North Pacific     

Hajime Kawakami  Makio C. Honda  Kazuhiko Matsumoto  Masahide Wakita  Minoru Kitamura  Tetsuichi Fujiki  Shuichi Watanabe 《Journal of Oceanography》2015,71(3):311-324

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Installing single-propeller twin-rudder system with less asymmetric maneuvering motions     

Donghoon Kang  Vishwanath Nagarajan  Yoshiaki Gonno  Kazuhiko Hasegawa 《Ocean Engineering》2011,38(10):1184-1196

The inflow characteristics to each one of the rudders of single-propeller twin-rudder system are investigated. It is shown that this inflow is not parallel to ship's centerline. This may result in asymmetric maneuvering characteristic of the ship thereby reducing ship's maneuvering performance. For this purpose, a method of installing single-propeller twin-rudder system is proposed. This method is called “virtual zero rudder angle” arrangement. Here, each one of the twin-rudder is set at an angle corresponding to the inflow to the rudder. The improvement in ship's maneuvering characteristics with “virtual zero rudder angle” arrangement is investigated using experiments and numerical simulations for different ship types. It is shown that this arrangement may also improve ship's propulsion performance.  相似文献   

Surface deformation related to the 2008 Wenchuan earthquake,and mountain building of the Longmen Shan,eastern Tibetan Plateau     

Bihong Fu  Pilong Shi  Huadong Guo  Satoshi Okuyama  Yoshiki Ninomiya  Sarah Wright 《Journal of Asian Earth Sciences》2011,40(4):805-824

The 12 May 2008 M_s 8.0 Wenchuan earthquake, China, was one of largest continental thrusting events worldwide. Based on interpretations of post-earthquake high-resolution remote sensing images and field surveys, we investigated the geometry, geomorphology, and kinematics of co-seismic surface ruptures, as well as seismic and geologic hazards along the Longmen Shan fold-and-thrust belt. Our results indicate that the Wenchuan earthquake occurred along the NE–SW-trending Yingxiu–Beichuan and Guanxian–Anxian faults in the Longmen Shan fold-and-thrust belt. The main surface rupture zones along the Yingxiu–Beichuan and Guanxian–Anxian fault zones are approximately 235 and 72 km in length, respectively. These sub-parallel ruptures may merge at depth. The Yingxiu–Donghekou surface rupture zone can be divided into four segments separated by discontinuities that appear as step-overs or bends in map view. Surface deformation is characterized by oblique reverse faulting with a maximum vertical displacement of approximately 10 m in areas around Beichuan County. Earthquake-related disasters (e.g., landslides) are linearly distributed along the surface rupture zones and associated river valleys.The Wenchuan earthquake provides new insights into the nature of mountain building within the Longmen Shan, eastern Tibetan Plateau. The total crustal shortening accommodated by this great earthquake was as much as 8.5 m, with a maximum vertical uplift of approximately 10 m. The present results suggest that ongoing mountain building of the Longmen Shan is driven mainly by crustal shortening and uplift related to repeated large seismic events such as the 2008 Wenchuan earthquake. Furthermore, rapid erosion within the Longmen Shan fold-and-thrust belt occurs along deep valleys and rupture zones following the occurrence of large-scale landslides triggered by earthquakes. Consequently, we suggest that crustal shortening related to repeated great seismic events, together with isostatic rebound induced by rapid erosion-related unloading, is a key component of the geodynamics that drive ongoing mountain building on the eastern Tibetan Plateau.  相似文献