Assessment of factors of periodicity in Phanerozoic carbonate accumulation     

V. P. Aparin  A. V. Kuz’min 《Doklady Earth Sciences》2006,409(1):754-757

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Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

Biostratigraphy of Jurassic-Cretaceous boundary sediments in the Eastern Crimea     

V. V. Arkad’ev  A. A. Fedorova  Yu. N. Savel’eva  E. M. Tesakova 《Stratigraphy and Geological Correlation》2006,14(3):302-330

The Dvuyakornaya Formation section in the eastern Crimea is described and subdivided into biostratigraphic units based on ammonites, foraminifers, and ostracodes. The lower part of the formation contains first discovered ammonites of the upper Kimmeridgian (Lingulaticears cf. procurvum (Ziegler), Pseudowaagenia gemmellariana Olóriz, Euvirgalithacoceras cf. tantalus (Herbich), Subplanites sp.) and Tithonian (?(Lingulaticeras efimovi (Rogov), Phylloceras consaguineum Gemmellaro, Oloriziceras cf. schneidi Tavera, and Paraulacosphinctes cf. transitorius (Oppel)). Based on the assemblage of characteristic ammonite species, the upper part of the formation is attributed to the Berriasian Jacobi Zone. Five biostratigraphic units (zones and beds with fauna) distinguished based on foraminifers are the Epistomina ventriosa-Melathrokerion eospirialis Beds and Anchispirocyclina lusitanica-Melathrokerion spirialis Zone in the upper Kimmeridgian-Tithonian, the Protopeneroplis ultragranulatus-Siphoninella antiqua, Frondicularia cuspidiata-Saracenaria inflanta zones, and Textularia crimica Beds in the Berriasian. The Cyrherelloidea tortuosa-Palaeocytheridea grossi Beds of the Upper Jurassic and Raymoorea peculiaris-Eucytherura ardescae-Protocythere revili Beds of the Berriasian are defined based on ostracodes. A new biostratigraphic scale is proposed for the upper Kimmeridgian-Berriasian of the eastern Crimea. The Dvyyakornaya Formation sediments are considered as deepwater facies accumulated on the continental slope.  相似文献   

Early Paleozoic granitoids of the Aqtau-Dzungar microcontinent (Central Kazakhstan)     

K. E. Degtyarev  K. N. Shatagin  A. B. Kotov  E. B. Sal’nikova  M. V. Luchitskaya  S. Z. Yakovleva  Yu. V. Plotkina  A. M. Fedoseenko 《Doklady Earth Sciences》2006,411(1):1204-1208

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Moving Geochemical Transactions forward as an open access journal     

Martin AA Schoonen  Ken B Anderson  Scott A Wood 《Geochemical transactions》2006,7(1):1-2

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Geodynamic setting of gold ore deposits of the neoproterozoic bodaibo trough     

Academician of the RAS M. I. Kuz’min  V. V. Yarmolyuk  A. I. Spiridonov  V. K. Nemerov  A. I. Ivanov  G. L. Mitrofanov 《Doklady Earth Sciences》2006,407(2):397-400

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Platinum-and gold-bearing rodingites of the Ust’-Dep ophiolite block (middle Amur region)     

V. P. Molchanov  L. P. Plyusnina  Corresponding Member of the RAS A. I. Khanchuk  S. S. Zimin  R. A. Oktyabr’skii 《Doklady Earth Sciences》2006,407(1):250-253

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Degree of thermal impact on the periphery of the Siberian craton in the Phanerozoic     

F. A. Letnikov  Yu. A. Kostitsyn  E. E. Krasil’nikova  E. I. Mishina 《Doklady Earth Sciences》2006,409(1):706-708

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The vibrational frequencies of forsterite Mg2SiO4: an all-electron ab initio study with the CRYSTAL code     

Y. Noel  M. Catti  Ph. D’Arco  R. Dovesi 《Physics and Chemistry of Minerals》2006,33(6):383-393

The vibrational spectrum of Mg₂SiO₄ olivine was calculated at the Γ point by using the periodic ab initio CRYSTAL program. An all electron localized Gaussian-type basis set and the B3LYP Hamiltonian were employed. The full set of frequencies (35 IR active, 36 Raman active, 10 “silent” modes) was computed and compared to experimental data from different sources (four for IR and four for Raman). A generally good agreement is observed with experiment (the mean absolute difference ranging from 7 to 10 cm⁻¹ for the various sets), when some of the experimental frequencies, whose attribution is uncertain or appears to be affected by large errors, are not taken into account. A small number of observed peaks are not consistent with calculated frequencies, and a few theoretical peaks do not correspond to measured values. The implications are discussed in detail. The full set of modes are characterized using different tools, namely isotopic substitution, direct inspection of the eigenvectors and graphical representation, so as to obtain a consistent mode assignment.  相似文献   

Evolution of stress fields in the Por’ya Guba dike field (Kandalaksha Gulf, White Sea)     

T. I. Vasil’eva  E. S. Przhiyalgovskii 《Geotectonics》2006,40(1):53-63

The tectonic evolution of the Por’ya Guba segment of the White Sea Rift System began in the late Paleoproterozoic, i.e., soon after completion of the Svecofennian collision. The fracture system that controlled localization of the lamproite dike complex was formed under conditions of horizontal compression combined with shear. Subsequently, this system predetermined the location of a rift-graben segment that formed as a result of simple shear. The reactivation of the rift system in the Middle Paleozoic proceeded in two stages. The first stage, when strike-slip movements along previously formed faults predominated, resulted in formation of quartz-carbonate veins bearing base-metal mineralization. The veins that filled the shear fractures opened owing to local reorientation of the stress field. The second stage fitted the transtension conditions, and the Late Devonian alkaline ultramafic dikes of this stage introded into the already existing fracture system, which was oriented at a roughly right angle to the predominant stress orientation.  相似文献