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111.
Monometamorphic metasediments of Paleozoic or Mesozoic age constituting Schneeberg and Radenthein Complex experienced coherent deformation and metamorphism during Late Cretaceous times. Both complexes are part of the Eoalpine high-pressure wedge that formed an intracontinental suture and occur between the polymetamorphosed Ötztal–Bundschuh nappe system on top and the Texel–Millstatt Complex below. During Eoalpine orogeny Schneeberg and Radenthein Complexes were south-dipping and they experienced a common tectonometamorphic history from ca. 115 Ma onwards until unroofing of the Tauern Window in Miocene times. This evolution is subdivided into four distinct tectonometamorphic phases. Deformation stage D1 is characterized by WNW-directed shearing at high temperature conditions (550–600°C) and related to the initial exhumation of the high-pressure wedge. D2 and D3 are largely coaxial and evolved during high- to medium-temperature conditions (ca. 450 to ≥550°C). These stages are related to advanced exhumation and associated with large-scale folding of the high-pressure wedge including the Ötztal-Bundschuh nappe system above and the Texel–Millstatt Complex below. For the area west of the Tauern Window, F2/F3 fold interference results in the formation of large-scale sheath-folds in the frontal part of the nappe stack (formerly called “Schlingentektonik” by previous authors). Earlier thrusts were reactivated during Late Cretaceous normal faulting at the base of the Ötztal–Bundschuh nappe system and its cover. Deformation stage D4 is of Oligo-Miocene age and accounted for tilting of individual basement blocks along large-scale strike-slip shear zones. This tilting phase resulted from indentation of the Southern Alps accompanied by the formation of the Tauern Window.  相似文献   
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We report on the detection of H2 as seen in our analysis of twilight observations of the lunar atmosphere observed by the LAMP instrument aboard NASA’s Lunar Reconnaissance Orbiter. Using a large amount of data collected on the lunar atmosphere between September 2009 and March 2013, we have detected and identified, the presence of H2 in the native lunar atmosphere, for the first time. We derive a surface density for H2 of 1.2 ± 0.4 × 103 cm−3 at 120 K. This is about 10 times smaller than originally predicted, and several times smaller than previous upper limits from the Apollo era data.  相似文献   
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We investigated rutile needles with a clear shape preferred orientation in garnet from (ultra) high-pressure metapelites from the Kimi Complex of the Greek Rhodope by electron microprobe, electron backscatter diffraction and TEM techniques. A definite though complex crystallographic orientation relationship between the garnet host and rutile was identified in that Rt[001] is either parallel to Grt<111> or describes cones with opening angle 27.6° around Grt<111>. Each Rt[001] small circle representing a cone on the pole figure displays six maxima in the density plots. This evidence together with microchemical observations in TEM, when compared to various possible mechanisms of formation, corroborates a precipitate origin. A review of exchange vectors for Ti substitution in garnet indicates that rutile formation from garnet cannot occur in a closed system. It requires that components are exchanged between the garnet interior and the rock matrix by solid-state diffusion, a process we refer to as “open-system precipitation” (OSP). The kinetically most feasible reaction of this type will dominate the overall process. The perhaps most efficient reaction involves internal oxidation of Fe2+ to Fe3+ and transfer from the dodecahedral to the octahedral site just vacated by $ {\text{Ti}}^{ 4+ }: 6\,{\text{M}}^{ 2+ }_{ 3} {\text{TiAl}}\left[ {{\text{AlSi}}_{ 2} } \right]{\text{O}}_{ 1 2} + 6\,{\text{M}}^{ 2+ }_{ 2, 5} {\text{TiAlSi}}_{ 3} {\text{O}}_{ 1 2} = 10\,{\text{M}}^{ 2+ }_{ 3.0} {\text{Al}}_{ 1. 8} {\text{Fe}}_{0. 2} {\text{Si}}_{ 3} {\text{O}}_{ 1 2} + {\text{M}}^{2+} + 2 {\text{e}}^{-} + 1 2\,{\text{TiO}}_{ 2} . $ OSP is likely to occur at conditions where the transition of natural systems to open-system behaviour becomes apparent, as in the granulite and high-temperature eclogite facies.  相似文献   
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Stilbite is locally present as a very late mineral on fractures and fissures of granitic basement in the Central Swiss Alps. Stilbite samples from the Gotthard rail base tunnel provide evidence that they originally formed as a K-absent variety at depth. However, all stilbite samples from surface outcrops above the tunnel display significant potassium concentrations. Interestingly, water from fractures in the tunnel (at 50 °C) is oversaturated with respect to stilbite and essentially potassium-free whereas waters from high-Alpine brooks above the tunnel (and at other high-Alpine areas) have unusually high K/Na ratios. The data suggest that stilbite that may actively form on fissures at tunnel level as a K-absent variety by precipitation from water. Older stilbite that originally formed as coatings on fracture walls was gradually exhumed and uplifted and finally reached the today’s erosion surface about 2,000 m above the tunnel. However, the stilbite reaches the erosion surface as a K-rich variety as a result of interaction of the original low-K stilbite with surface water and near-surface groundwater. This leads to the conclusion that minerals once formed at depth may significantly change their composition once they reach the ground water zone on their way to the erosion surface. In the case of the stilbite, if surface outcrops would have been the only source of samples and data, the K-rich composition could have been mistaken for the composition of the mineral when it formed, which is not the case. Late-stage compositional readjustments may be difficult to discern in samples from surface outcrops. The provided data show that original mineral compositions may be adjusted by late-stage water–rock interaction in a highly selective way.  相似文献   
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Representatives of the Antarctic food web (krill, cephalopod, fish, penguin, seal) of the area around Elephant Island and from the Weddell Sea were analysed for the most recalcitrant organochlorine compounds. Due to sorption of the compounds to sinking particles and accumulation in sediments, two benthic fish species (Gobionotothen gibberifrons, Chaenocephalus aceratus) feeding on benthos invertebrates and fish reflected significantly increasing concentrations within a decade (1987-1996), while a benthopelagic species (Champsocephalus gunnari) feeding on krill did not. In the pelagic food chain, lipid normalised concentrations of all compounds increased from Antarctic krill to fish proving that biomagnification of highly lipophilic pollutants (log octanol-water partition coefficient>5) occurs in water-breathing animals. As top predators Weddell and southern elephant seals (Leptonychotes weddellii, Mirounga leonina) biomagnified the persistent organic pollutants relative to krill 30-160 fold with the exception of hexachlorobenzene, the levels of which were lower than in fish indicating its intense specific elimination.  相似文献   
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Abstract— The “tektite-like bodies” reported recently from Lonar Crater, India (Murali et al., 1987) are, in fact, high sodium (up to 22% Na2O) artificial glasses and so need not be explained by unrealistic, natural mixing models. These bodies have no bearing on the problem of impactite chemistry or tektite generation.  相似文献   
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