A subregional-scale method to assess aquifer vulnerability to pesticides   总被引：4，自引：0，他引：4  

Schlosser SA  McCray JE  Murray KE  Austin B 《Ground water》2002,40(4):361-367

A method to predict aquifer vulnerability to pesticide contamination at the subregional scale was developed. The assessment method was designed to incorporate relevant hydrologic and pesticide-transport information and to use generally available data. The method assumes steady-state advection of pesticides in the vadose zone, including sorption and biological decay. The solution is presented as a vulnerability index (VI) that increases as the aquifer vulnerability increases. The hydrologic input data for the VI model are obtained from the soil survey geographic database. Pesticides were grouped into three leachability classes using a leachability ratio (half-life divided by organic carbon partition coefficient). Pesticide transformation is assumed to occur in the surface layer. The influence of vertical transport in the remainder of the vadose zone has been incorporated by applying a multiplying factor to the VI that varies with depth to ground water. Hydraulic conductivity is used as a surrogate for soil-water velocity for practical purposes. The performance of the VI model is evaluated using ground water data from Weld County, Colorado. The model is demonstrated to be successful at predicting relative vulnerability, defined as the magnitude of pesticide concentration and percent of wells in a unit that exhibit a pesticide detection. Areas of low, medium, and high vulnerability are assigned. Results indicate that the vulnerability classifications are most dependent on the leachability ratio, hydraulic conductivity, and organic carbon content.  相似文献   

Report on British vulcanological research during the period September 1939 – March 1954     

Arthur Holmes  R. W. Willett 《Bulletin of Volcanology》1955,16(1):115-145

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Chemical and physical studies of type 3 chondrites XII: The metamorphic history of CV chondrites and their components     

R. Kyle Guimon  Steven J. K. Symes  Derek W. G. Sears  Paul H. Benoit 《Meteoritics & planetary science》1995,30(6):704-714

Abstract— The induced thermoluminescence (TL) properties of 16 CV and CV-related chondrites, four CK chondrites and Renazzo (CR2) have been measured in order to investigate their metamorphic history. The petrographic, mineralogical and bulk compositional differences among the CV chondrites indicate that the TL sensitivity of the ～130 °C TL peak is reflecting the abundance of ordered feldspar, especially in chondrule mesostasis, which in turn reflects parent-body metamorphism. The TL properties of 18 samples of homogenized Allende powder heated at a variety of times and temperatures, and cathodoluminescence mosaics of Axtell and Coolidge, showed results consistent with this conclusion. Five refractory inclusions from Allende, and separates from those inclusions, were also examined and yielded trends reflecting variations in mineralogy indicative of high peak temperatures (either metamorphic or igneous) and fairly rapid cooling. The CK chondrites are unique among metamorphosed chondrites in showing no detectable induced TL, which is consistent with literature data that suggests very unusual feldspar in these meteorites. Using TL sensitivity and several mineral systems and allowing for the differences in the oxidized and reduced subgroups, the CV and CV-related meteorites can be divided into petrologic types analogous to those of the ordinary and CO type 3 chondrites. Axtell, Kaba, Leoville, Bali, Arch and ALHA81003 are type 3.0–3.1, while ALH84018, Efremovka, Grosnaja, Allende and Vigarano are type 3.2–3.3 and Coolidge and Loongana 001 are type 3.8. Mokoia is probably a breccia with regions ranging in petrologic type from 3.0 to 3.2. Renazzo often plots at the end of the reduced and oxidized CV chondrite trends, even when those trends diverge, suggesting that in many respects it resembles the unmetamorphosed precursors of the CV chondrites. The low-petrographic types and low-TL peak temperatures of all samples, including the CV3.8 chondrites, indicates metamorphism in the stability field of low feldspar (i.e., <800 °C) and a metamorphic history similar to that of the CO chondrites but unlike that of the ordinary chondrites.  相似文献   

Metamorphism and aqueous alteration in low petrographic type ordinary chondrites     

Derek W. G. Sears  Andrew D. Morse  Robert Hutchison  R. Kyle Guimon  Lu Jie  C. M. O'D. Alexander  Paul H. Benoit  Ian Wright  Colin Pillinger  Tian Xie  Michael E. Lipschutz 《Meteoritics & planetary science》1995,30(2):169-181

Abstract— In order to investigate the relative importance of dry metamorphism and aqueous alteration in the history of chondrules, chondrules were hand-picked from the Semarkona (petrographic type 3.0), Bishunpur (3.1), Chainpur (3.4), Dhajala (3.8) and Allegan (5) chondrites, and matrix samples were extracted from the first three ordinary chondrites. The thermoluminescence (TL) properties of all the samples were measured, and appropriate subsets of the samples were analyzed by electron-microprobe and radiochemical neutron activation and the water and H-isotopic composition determined. The TL data for chondrules from Semarkona and Bishunpur scatter widely showing no unambiguous trends, although group B1 chondrules tend to have lower sensitivities and lower peak temperatures compared with group A5 chondrules. It is argued that these data reflect the variety of processes accompanying chondrule formation. The chondrules show remarkably uniform contents of the highly labile elements, indicating mineralogical control on abundance and volatile loss from silicates and loss and recondensation of mobile chalcophiles and siderophiles in some cases. Very high D/H values (up to ～8000‰ SMOW) are observed in certain Semarkona chondrules, a confirmation of earlier work. With increasing petrographic type, mean TL sensitivities of the chondrules increase, the spread of values within an individual meteorite decreases, and peak temperatures and peak widths show trends indicating that the TL is mainly produced by feldspar and that dry, thermal metamorphism is the dominant secondary process experienced by the chondrules. The TL sensitivities of matrix samples also increase with petrographic type. Chainpur matrix samples show the same spread of peak temperatures and peak widths as Chainpur chondrules, indicating metamorphism-related changes in the feldspar are responsible for the TL of the matrix. The TL data for the Semarkona and Bishunpur matrix samples provide, at best, only weak evidence for aqueous alteration, but the matrix contains H with approximately terrestrial D/H values, even though it contains much water. Secondary processes (probably aqueous alteration) presumably lowered the D/H of the matrix and certain chondrules. While chondrule properties appear to be governed primarily by formation processes and subsequent metamorphism, the matrix of Semarkona has a more complex history involving aqueous alteration as a meteorite-wide process.  相似文献   

Stochastic inversion of thermal data in a sedimentary basin: resolving spatial variability     

Sean D. Willett 《Geophysical Journal International》1990,103(2):321-339

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Ultramafic rocks of the Widgiemooltha-Norseman area,Western Australia: Petrological diversity,geochemistry and mineralisation     

G. Willett  E. Eshuys  B. Guy 《Precambrian Research》1978,6(2):133-156

Mineral exploration of the Widgiemooltha-Norseman region of Western Australia has located massive and disseminated nickel sulphide mineralisation.This paper discusses the geological setting of the nickel sulphide mineralisation with reference to the stratigraphy, structure and metamorphism of the ultramafic sequence and spatially associated rocks. The amphibolite facies metamorphosed ultramafic rocks of the Widgiemooltha area are compared with greenschist metamorphosed ultramafic rocks at Eundynie, which exhibit excellently preserved pseudomorphs of primary igneous textures.Some 2000 ultramafic rock samples were analysed for 13 element/oxides and divided into four major mineralogically and texturally distinct groups. The data were analysed statistically by determination of means and standard deviations and multiple regression analyses.The data suggest differentiation of a magma at depth followed by a vast outpouring of lava to produce picritic-peridotitic rocks. The flows crystallised with upper spinifex zones and lower euhedral-olivine zones in varying proportions dependent on magma composition. The development of spinifex texture is compositionally controlled. This texture is not developed in rocks with MgO contents greater than 26% (± 2%).The comparison of the ultramafics of the Widgiemooltha and Eundynie areas indicates that talc-carbonate formation and serpentinization have modified primary igneous textures and geochemistries, resulting in the production of a diverse group of rock types. Such post-magmatic alteration processes in association with structural elements are considered important in the upgrading of nickel sulphide mineralisation.  相似文献   

Trenching studies of active faults in Kamchatka, eastern Russia: Palaeoseismic, tectonic and hazard implications   总被引：2，自引：0，他引：2  

A. Kozhurin  V. Acocella  P.R. Kyle  F.M. Lagmay  I.V. Melekestsev  V. Ponomareva  D. Rust  A. Tibaldi  A. Tunesi  C. Corazzato  A. Rovida  A. Sakharov  A. Tengonciang  H. Uy 《Tectonophysics》2006,417(3-4):285-304

The central part of the Kamchatka Peninsula is characterized by a well defined depression associated with active volcanism, aligned NE–SW. On the east, the depression is bounded by a prominent system of active faults known as the East Kamchatka Fault Zone (EKFZ). In order to improve understanding of the behaviour and kinematic role of this fault zone a fieldwork programme, including study of trenches, was conducted in the north-central part of this system. Aerial photograph analysis, ground-truthed, indicates a westward fault dip with predominantly normal slip, while lateral offsets of river terraces and stream channels demonstrate a combined dextral component. Over 20 excavated pits and natural exposures were examined to confirm a detailed tephra succession extending from the early Holocene to recent historic eruptions. This chronological framework then provided age control on five past faulting events recognised in three trenches. These events took place at about 10.5, 6.0, 4.5 and, in a two-event succession within a short time span, at 3.3–3.2 ka BP. Event clustering may be characteristic and fault length–displacement values suggest earthquakes of M6.5, thus representing a significant new element in regional seismic hazard evaluations; additional to events generated at the subduction interface. The relatively long gap in faulting since the two most recent events may also be significant for hazard scenarios and there is a possible link between the faulting and volcanic activity in the depression. Overall, the EKFZ, together with the Nachiki Transverse Zone farther south, is thought to define a regional-scale block that is extending eastwards independently from the rest of Kamchatka.  相似文献   

A novel triggerless approach for mass wasting susceptibility modeling applied to the Boston Mountains of Arkansas,USA     

Kyle W. Rowden  Mohamed H. Aly 《Natural Hazards》2018,92(1):347-367

This research deploys a novel mass wasting susceptibility modeling approach for cases where temporal information is unavailable and circumstances are prejudiced to merit applying traditional susceptibility modeling strategies. Conventional models typically employ approaches deemed problematic for this study, e.g., biased weighted input; a “more is better” approach pertaining to voluminous inputs; neglecting geologic structural influence; and establishing temporal linkages between cause (trigger) and effect (failure) with a trigger being defined as a catalyst for failure, such as timed events like earthquakes or precipitation as well as physical changes like vegetation removal or slope disturbance. Road bias may also influence modeling dramatically when event data are derived from observations of road-related failures, which become unreliable at predicting susceptibility in regions with no roads. However, a triggerless approach can extrapolate naturally occurring susceptibility via priori knowledge of local topography and structural geology factors. Two models are then created for comparison: One model has integrated empirical Bayesian kriging and fuzzy logic considering basically local topography and structural geology, while the second model has employed a standard implementation of a weighted overlay using all available (8) input data layers. Statistical comparisons show that the first model has identified ~ 83%, compared to only ~ 28% for the latter model, of the 47 documented mass wasting events in the selected study site. These results demonstrate that the introduced triggerless approach is efficiently capable of modeling mass wasting susceptibility in areas lacking temporal datasets, which in turn can help in mitigating future geohazards.  相似文献   

Persistence of clear-water,shallow-lake ecosystems: the role of protected areas and stable aquatic food webs     

William O. Hobbs  Kevin M. Theissen  Sean M. Hagen  Charles W. Bruchu  Ben C. Czeck  Joy M. Ramstack Hobbs  Kyle D. Zimmer 《Journal of Paleolimnology》2014,51(3):405-420

The roles of both landscape alteration and in-lake processes need to be considered in conservation strategies for shallow lakes in the prairie regions of North America. Here we focus on shallow lakes in west-central Minnesota, USA, highlighting the long-term ecological history and response to known landscape changes of a clear-water, macrophyte-dominated, shallow lake. Contemporary limnological data suggest the aquatic ecosystem has been very stable and fishless for the last ~15 years. Sediment proxies for primary production and ecological change confirm that a stable ecosystem likely prevailed for the last ~200 years. However, sedimentary indicators of catchment erosion detail a distinct response to land-use change during the conversion of native grassland to agricultural land, and following establishment of a protected waterfowl production area (WPA) around the lake. Post-WPA, the rate of sediment accrual decreased dramatically within 5–10 years and sources of organic matter were similar to those of the pre-settlement period. The aquatic ecosystem has been able to withstand nutrient enrichment and allochthonous inputs because stable trophic interactions have likely been in place for more than 200 years. We conclude that lack of hydrologic connectivity and isolated, small catchments are important factors in the promotion of clear-water shallow lake ecosystems, mainly because they prevent colonization by fish and associated ecological consequences. This study highlights the importance of managing both the landscape and in-lake processes to maintain stable, clear-water, shallow lakes.  相似文献