Chemical evolution and petrogenetic implications of loparite in the layered,agpaitic Lovozero complex,Kola Peninsula,Russia     

L. N. Kogarko  C. T. Williams  A. R. Woolley 《Mineralogy and Petrology》2002,74(1):1-24

Summary Lovozero, the largest of the world’s layered peralkaline intrusions, includes gigantic deposits of Nb + REE-loparite ore. Loparite, (Na,Ce,Ca)₂(Ti,Nb)₂O₆, became a cumulus phase after crystallisation of about 35% of the ‘Differentiated Complex’, and its compositional evolution has been investigated through a 2.35 km section of the intrusion. The composition of the cumulus loparite changes systematically upwards through the intrusion with an increase in Na, Sr, Nb and Th and decrease in REE and Ti. This main trend of loparite evolution records differentiation of the peralkaline magma through crystallisation of 1600 m of the intrusion. The formation of the loparite ores was the result of several factors including the chemical evolution of the highly alkaline magma and mechanical accumulation of loparite at the base of a convecting unit. At later stages of evolution, when concentrations of alkalis and volatiles reached very high levels, loparite reacted with the residual melt to form a variety of minerals including barytolamprophyllite, lomonosovite, steenstrupine-(Ce), vuonnemite, nordite, nenadkevichite, REE, Sr-rich apatite, vitusite-(Ce), mosandrite, monazite-(Ce), cerite and Ba, Si-rich belovite. The absence of loparite ore in the “Eudialyte complex” is likely to be a result of the wide crystallisation field of lamprophyllite, which here became a cumulus phase. Received November 6, 2000; revised version accepted January 18, 2001  相似文献   

Geochemical Studies of Sodium Enriched Metavolcanite Series in the Area of Longbohe Copper Deposit,Yunnan Province,SW China：Nd,Sr and Pb Isotopic Characteristics and Chronology     

常向阳  朱炳泉  莫向云 《中国地球化学学报》2002,21(2):163-169

The chronological data obtained by a variety of dating methods have confirmed that the sodium enriched metavolcanite series in the area of the Longbohe copper deposit at Jinping, Yunnan Province, was formed during the Proterozoic (its Pb−Pb isochron age=1595±75 Ma), corresponding to the Dahongshan Group sodium enriched metavolcanites. The Sm−Nd isochron age of 1336±46Ma should represent the time at which this series of volcanic rocks experienced spilitization in response to sodium metasomatism, equivalent to the time of sedimentation of the Ailaoshan Group and Yashan Group rocks. The Rb−Sr ages of the volcanic rocks and the Pb−Pb ages of copper ores have recorded the events of strong dynamic metamorphism and of strong reworking-metallogenesis of copper during the Jinningian period. Similarities in forming age, rock assemblage and isotopic characteristics between the sodium enriched metavolcanite series and the Dahongshan Group sodium enriched metavolcanite series have provided new clues to the exploration of the Dahongshan-type copper deposits in this area. Granted jointly by the National Natural Science Foundation of China (Nos. 49702022, 40073001) and the State 973 Program (No. G1999043215).  相似文献   

Anhydrite-bearing rocks from the Rožná district (Moldanubian zone,Czech Republic): high-grade metamorphosed exhalites?     

Bohdan Kříbek  Jana Hladíková  Daniel Holeczy 《Mineralium Deposita》2002,37(5):465-479

Several types of anhydrite-bearing rocks have been found in the amphibolite-facies metamorphosed rocks at the north-eastern margin of the Moldanubian Zone. Anhydrite either forms monomineralic bands up to 40 cm thick, or occurs in the form of disseminated grains in surrounding calc-silicate gneiss together with feldspar, scapolite, amphibole, pyroxene, epidote and pyrite. The isotopic composition of sulphur ('³⁴S=30.6 to 32.3‰) and strontium (⁸⁷Sr/⁸⁶Sr=0.70797 to 0.70781) in anhydrite may indicate a marine source of sulphate. The isotopic ratio of strontium is in the same range as that of metamorphosed strata-bound barite-sulphide ores, which have been previously described in the same area. The '³⁴S values of coexisting pyrite range from 21.4 to 22.5‰, the (³⁴S_{anhydrite-pyrite} corresponding to the metamorphic temperature of 600 to 660 °C. In contrast to many submarine-exhalative deposits, the oxygen isotopic compositions of anhydrite ('¹⁸O=9.3 to 10.2‰) are lighter than that of barite ('¹⁸O=10.4 to 13.8‰). This indicates that the both minerals are not in isotopic equilibrium. Therefore, it is probable that anhydrite and barite from the Ro—ná district were deposited from fluids that contained different proportions of seawater and hydrothermal fluids or from hydrothermal fluids that underwent variable extent of oxygen isotope exchange with seafloor rocks. The '¹³C values in calcite ('¹³C=-17.2 to -18.7‰) from anhydrite-bearing rock are lower than those in distant marbles. As graphite is absent in anhydrite- and calcite-bearing rocks, impoverishment in the ¹³C isotope cannot be attributed to the graphite-carbonate isotopic exchange during metamorphism. It is proposed that low '¹³C values in carbonates are caused by pre-metamorphic oxidation of organic matter in course of hydrothermal processes. Anhydrite and anhydrite-bearing calc-silicate gneiss from the north-eastern part of the Moldanubian Zone are interpreted to be the high-grade metamorphosed analogue of anhydrite-rich exhalites commonly found in submarine-exhalative hydrothermal deposits.  相似文献   

KARSTIC: a sensitivity method for carbonate aquifers in karst terrain   总被引：5，自引：2，他引：5  

A. Davis  A. Long  M. Wireman 《Environmental Geology》2002,42(1):65-72

. Groundwater in karstic aquifers can be dangerously sensitive to contamination. Many cities in the western USA rely on karstic carbonate aquifers for municipal water supplies. For example, Rapid City, South Dakota, pumps more than half of its drinking water from wells in the Madison Limestone. This work examined the sensitivity of karstic aquifers to surface contamination in mountainous terrain. Where karstic carbonate aquifers are exposed at their outcrop areas, they are particularly susceptible to the introduction of contamination through diffuse recharge or through point recharge at swallow holes along streams. Residential developments in mountainous regions of the western USA are encroaching on the recharge areas of karstic aquifers. Many of these residential developments are served by onsite wastewater disposal systems such as septic tanks and drain fields, with the attendant danger of introduction of pathogens from malfunctioning treatment systems above fractured limestone which offers little filtering. Where streams disappear into karstic aquifers at swallow holes, microbial contaminants such as Giardia or Cryptosporidium are a concern, as well as potential spills, leaks, or accidents along roads near these streams. The KARSTIC method developed and modified in this work puts greater emphasis on karst features than previous sensitivity procedures such as the US Environmental Protection Agency's DRASTIC method. The modified method gives increased attention to highly sensitive areas of karstic carbonate aquifers by weighting the synergistic effects of fracturing, karst development, and swallow holes of recharging streams. In a field application, hydrogeologic maps of a watershed in the Black Hills, USA, were digitized into a geographic information system. The resulting sensitivity map and report can be used by planners, managers, and the public as a screening tool for assessing groundwater sensitivity in regions which include karstic aquifers.  相似文献   

Poroelastic analysis of cover-collapse sinkhole formation by piezometric surface drawdown   总被引：1，自引：0，他引：1  

T. Tharp 《Environmental Geology》2002,42(5):447-456

Where the water table is above the soil-rock contact in karst regions, cover-collapse sinkholes in the soil and soft sediment above the rock commonly occur as a result of drawdown of the piezometric surface in the karst aquifer. Transient stresses and pore pressures around soil voids at the soil-rock contact can cause hydraulic fracturing of the soil near the wall of the void. After the first such fracture, successive sloughing of soil propagates the soil void rapidly to the surface, resulting in a cover-collapse sinkhole. Sinkhole formation by this mechanism should be strongly a function of rate and magnitude of piezometric surface drawdown, permeability and tensile strength of the soil, and the size, depth, and geometry of the initial soil void. Large soil voids and those with walls that are partly planar or of low curvature are most susceptible to hydraulic fracture and the resulting progression to sinkhole formation.  相似文献   

Heavy metal concentrations in surficial sediments from accreting and eroding areas along the coast of Guyana   总被引：1，自引：0，他引：1  

V. Lakhan  K. Cabana  P. LaValle 《Environmental Geology》2002,42(1):73-80

. Surficial sediments sampled from accreting and eroding areas along the coast of Guyana were examined for concentrations of heavy metals; aluminum, copper, chromium, iron, nickel, lead, vanadium and zinc. Twenty-four samples were collected, 12 from each of the eroding and accreting areas. For granulometric composition determination, samples were separated into particle-size fractions using sieving and hydrometer procedures. The consideration of three grain-size fractions (4.0, 5.0, and greater than 5.0 phi), plus 24 bulk samples less than 4.0 phi in diameter, required analyzing a total of 96 samples for the presence of heavy metals. The analysis employed was aquaregia digestion, followed by inductively coupled plasma optical emission spectroscopy. The statistical techniques of discriminant analysis, analysis of variance, and correlation and regression were used to analyze all obtained data. Discriminant analysis revealed that metal concentrations were statistically unique to each area. From the analysis of variance, and correlation and regression, it was discovered that the grain size of the sediment had a pronounced effect on the spatial distribution of heavy metals. The accreting area, with finer sediments, accumulated higher concentrations of heavy metals.  相似文献   

The effect of acoustic waves on spectral-line profiles in the solar atmosphere: Observations and theory     

R. I. Kostyk  E. V. Khomenko 《Astronomy Reports》2002,46(11):925-931

The fine structure of the FeI λ 532.4185-nm line of neutral iron is studied with high spatial (0.5″) and temporal (9.3 s) resolution using observations of a quiet region at the center of the solar disk. The character of the line asymmetry depends strongly on the nature of the velocity field, i.e., on whether it is due to convective or wave motions. The magnitude of the asymmetry due to acoustic waves is comparable to that due to convective motions. The propagation of acoustic waves in moving granules and intergranular lanes is studied by solving a system of hydrodynamical equations in a three-dimensional model for the solar atmosphere. The temporal variations in the bisector of the line synthesized in a non-LTE approximation agree well with the observational data.  相似文献   

Disk wind in young binaries and its impact on the infrared excesses of young stars     

V. P. Grinin 《Astronomy Reports》2002,46(5):380-389

We consider the effect of binarity of young stars on the spectral energy distribution of the IR radiation from circumstellar dust. The formation of a common dust envelope in a binary system with a low-mass secondary component is strongly affected by the disk wind from the secondary. The small velocities in peripheral areas of the wind are such that it can be partially or entirely captured by the primary, even when the distance between the components is up to several astronomical units. As a result, an envelope with a rather complex spatial and kinematic structure is formed. Its mass is many orders of magnitude smaller than that of the accretion disk around the binary. However, the thermal radiation emitted by dust particles of the envelope can be comparable to the total radiation of the accretion disk. This result is discussed in the context of the deficit at near-IR wavelengths (2–10µm) in current models for accretion disks around young stars.  相似文献   

The possible formation of massive tori in white-dwarf binary systems     

D. P. Savokhin  E. I. Staritsyn 《Astronomy Reports》2002,46(6):481-488

Mass exchange in white-dwarf binary systems with mass ratios 0.35–0.55 and total masses exceeding the Chandrasekhar limit could lead to the disruption of the less massive component of the system and the formation of a torus around the more massive component.  相似文献   

A Model for the polar motion of the deformable Earth adequate for astrometric data     

L. D. Akulenko  S. A. Kumakshev  Yu. G. Markov  L. V. Rykhlova 《Astronomy Reports》2002,46(1):74-82

Refined analytical expressions for the frequencies corresponding to the Chandler motion of the pole and the diurnal rotation of the deformable Earth are derived. Numerical estimates of the period and amplitude of the polar oscillations are presented. The trajectory of the Chandler polar motion derived via numerical modeling is in qualitative and quantitative agreement with experimental data from the International Earth Rotation Service (IERS). An evolutionary model describing slow variations in the Earth’s rotation parameters under the action of the dissipative moments of the tidal gravitational forces on time scales considerably longer than the precession period of the Earth’s axis is constructed. The axis of the Earth’s figure tends to approach the angular momentum vector of the proper rotation.  相似文献