Synchronous annual variations in the geoelectric and geomagnetic field are studied on the basis of long-term electromagnetic monitoring. It is shown that the annual geoelectric variations have intraterrestrial origin and are not related to the annual geomagnetic variations. Temporal variations in the magnetotelluric impedance and magnetic tipper, which characterize the electrical conductivity of the geological environment, are analyzed. It is established that annual variations in the magnetotelluric impedance mainly describe the variations in the electrical conductivity of surface crustal layers and are less sensitive to the deep electrical conductivity of the Earth. The annual variations in the imaginary magnetic tipper at the periods of 1000–3000 s probably reflect the changes in conductivity of a deep transversal low-resistive zone (the fault). It is suggested that annual variations in the geoelectrical and geomagnetic fields, as well as in the electrical conductivity of the geological environment, arise as a response to the changes in the geodynamical processes caused by the revolution of the Earth around the Sun.
Formation of noble metal nanoparticles is related to various geological processes in the supergene zone. Dispersed mineral phases appear during weathering of rocks with active participation of microorganisms, formation of soil, in aqueous medium and atmosphere. Invisible gold and other noble metals are incorporated into oxides, hydroxides, and sulfides, as well as in dispersed organic and inorganic carbonic matter. Sulfide minerals that occur in bedrocks and ores unaltered by exogenic processes and in cementation zone are among the main concentrators of noble metal nanoparticles. The ability of gold particles to disaggregate is well-known and creates problems in technological and analytical practice. When Au and PGE nanoparticles and clusters occur, these problems are augmented because of their unusual reactions and physicochemical properties. The studied gold, magnetite, titanomagnetite and pyrite microspherules from cementation zone and clay minerals of laterites in Republic of Guinea widen the knowledge of their abundance and inferred formation conditions, in particular, in the contemporary supergene zone. Morphology and composition of micrometer-sized Au mineral spherules were studied with SEM and laser microprobe. The newly formed segregations of secondary gold on the surface of its residual grains were also an object of investigation. The character of such overgrowths is the most indicative for nanoparticles. The newly formed Au particles provide evidence for redistribution of ultradispersed gold during weathering. There are serious prerequisites to state that microorganisms substantially control unusual nano-sized microspherical morphology of gold particles in the supergene zone. This is supported by experiments indicating active absorption of gold by microorganisms and direct evidence for participation of Ralstonia metallidurans bacteria in the formation of peculiar corroded bacteriomorphic surface of gold grains. In addition, the areas enriched in carbon and nitrogen have been detected with SEM on the surface of gold spherules from Guinea. Such organic compounds as serine, alanine, and glycine are identified on their surface with Raman spectroscopy. The experiments have been carried out and new data have been obtained indicating the role of micromycetes in concentration and distribution of noble metals in ferromanganese nodules of the World Ocean. Au and Pt were detected in the system with radioisotopes. It has been established that two forms of gold distribution develop within pseudomorphs of fungi colonies: (1) as pseudomorphic concentrates and (2) dispersed form unrelated to the colony structure. Inhomogeneities in distribution of dispersed platinum are manifested in the form of linear anomalies with elevated concentrations at the margins of the colonies. 相似文献
The results of the magnetotelluric (MT) soundings before and after an earthquake are analyzed. The interpretation is based on the longitudinal and transverse MT curves (along and across the strike of the main tectonic elements, respectively). The MT curves are distorted by the ρ- and coast effect. The distortions due to the coast effect are estimated by the testing three-dimensional (3D) model. It is established that the coast effect distortion at the periods up to 1000 s is small and can be disregarded. The divergence of the longitudinal and transverse MT curves, which points to the presence of the deep faults, is thoroughly studied. The inversion of the MTsounding curves is carried out by the REBOCC program of the numerical two-dimensional modeling. This program implements the procedures of elimination of the ρ-effect and the joint inversion of the longitudinal and transverse MT sounding curves. The obtained geoelectrical cross sections provide an insight into the structure of electrical conductivity of the lithosphere before and after the earthquake. The more intense variations in the electric conductivity are observed in the zone of the deep faults. These variations are related to the changes in the porosity and saturation of the rocks by the highly mineralized fluids. 相似文献
We consider the methods and results of magnetotelluric sounding in the AMTS and MTS modifications. Audiomagnetotelluric sounding (AMTS) was carried out for the first time in the area of a recent Tolbachik eruption. The results from our analysis of the magnetotelluric parameters show that the geoelectric medium involving a regional fault can be fitted by a 2D inhomogeneous model. The longitudinal and transverse sounding curves were assumed as the leading elements for interpretation. A joint analysis of these curves and of pseudo-sections of impedance phases provides evidence of a geoelectric inhomogeneity in the area where the Naboko Vent is situated. A bimodal inversion of the AMTS curves yielded a geoelectric section that contains a conductive inhomogeneity that is possibly related to a fault that carried fluids up to the ground surface. Along with AMTS, we used MTS curves in a broader range to identify a crustal conductive anomaly at depths of 15–35 km. The data from AMTS, MTS, and other geological and geophysical information were used to develop a conceptual model for the area of study that characterizes a possible origin of the anomalous zones. We obtained approximate estimates of rock porosity in the fault zone that transported magma melts upward into the overlying rocks in the area of the Naboko Vent. 相似文献
Ions and water molecules mobilities were studied by the 7Li, 23Na, 1H nuclear magnetic resonance in the framework aluminosilicate mineral analcime and in its cation-exchanged (lithium) form. It has been found that cation exchange as well as dehydration alter radically dynamics of particles interposed in channels of the zeolite framework. The highest mobility of alkali cations with the diffusion activation energy of 0.52 eV was detected in hydrated Li-analcime. The ion diffusion increase with temperature is accompanied by an increase in the dynamic orientational disordering of water sublattice. The energy of formation of structural defects responsible for ion diffusion and water disordering was deduced to be 0.2 eV. As a possible defect, the occupation of water positions by cations is discussed (model of bridging-type ion diffusion). 相似文献
Analysis of major- and trace-element compositions of water in hypersaline soda closed basin lakes of Northwestern Mongolia
and Chuya basin (Gorny Altai) shows high enrichment in 238U (up to 1 mg/l). Proceeding from new data, uranium accumulation in water has been attributed to (i) location of the lakes
and their watersheds in potential provinces of U-bearing rocks and (ii) uranium complexing with carbonate in presence of carbonate
(bicarbonate) anions. Among the explored hypersaline soda lakes of the area, the greatest uranium resources are stored in
Lake Hyargas Nuur (about 6000 ton). 相似文献
The results of magnetotelluric and magnetovariational studies in the Uzon caldera are considered. An analysis of magnetotelluric parameters yielded the required method of interpretation. The MTS curves were interpreted in the framework of a 2D model using the REBOCC program. Geoelectric cross sections of the caldera were constructed along two orthogonal lines. Anomalies of high electrical conductivity were identified in the sediments and in the basement and were found to be confined to the locations of geothermal springs. The higher conductivity of these anomalies is here related to the presence of highly mineralized hydrothermal solutions. Electrical conductivity was used for an approximate estimation of porosity in the sediments and basement. A subvertical zone of higher porosity was identified at depths of 1.5–3.5 km in the caldera with a connection to the channelways of fluids rising into the sediments. It is hypothesized that highly mineralized solutions are diluted with vadose water in that zone and come through fissures onto the ground surface in the form of hot springs. The totality of these data suggested a conceptual model to characterize the main features in the generation of hydrothermal springs in the Uzon caldera. 相似文献
The qualitative characteristics of the vertical structure of the atmospheres of Venus and the Earth essentially differ. For instance, there are at least two, instead of one, zones with normal (thermal) convection on Venus. The first one is near the surface (a boundary layer); the second is at the altitudes of the lower part of the main cloud layer between 49 and 55 km. Contrary to the hypotheses proposed by Izakov (2001, 2002), the upper convective zone prevents energy transfer from the upper clouds to the subcloud atmosphere by anomalous turbulent heat conductivity. It is possible, however, that the anomalous turbulent heat conductivity takes part in the redistribution of the heat fluxes within the lower (subcloud) atmosphere. 相似文献