Simple determination of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) using solid-phase microextraction and gas chromatography-mass spectrometry     

Takushi?NikiEmail author  Taiki?Fujinaga  Mariyo?F.?Watanabe  Junji?Kinoshita 《Journal of Oceanography》2004,60(5):913-917

Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide (DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity (minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation ≤7%) and linearity (r ² > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity.  相似文献   

Eddy Shedding from the Kuroshio Bend at Luzon Strait   总被引：16，自引：1，他引：16  

Yinglai?JiaEmail author  Qinyu?Liu 《Journal of Oceanography》2004,60(6):1063-1069

TOPEX/POSEDIENT-ERS satellite altimeter data along with the mean state from the Parallel Ocean Climate Model result have been used to investigate the variation of Kuroshio intrusion and eddy shedding at Luzon Strait during 1992–2001. The Kuroshio penetrates into the South China Sea and forms a bend. The Kuroshio bend varies with time, periodically shedding anticyclonic eddies. Criteria of eddy shedding are identified: 1) When the shedding event occurs, there are usually two centers of high Sea Surface Height (SSH) together with negative geostrophic vorticity in the Kuroshio Bend (KB) area. 2) Between the two centers of high SSH there usually exists positive geostrophic vorticity. These criteria have been used to determine the eddy shedding times and locations. The most frequent eddy shedding intervals are 70, 80 and 90 days. In both the winter and summer monsoon period, the most frequent locations are 119.5°E and 120°E, which means that the seasonal variation of eddy shedding location is unclear.  相似文献   

Geodynamics of the deep sedimentary basin of the Caspian Sea region: paragenetic correlation of seismicity and mud volcanism     

Ibrahim?Guliev  Behrouz?PanahiEmail author 《Geo-Marine Letters》2004,24(3):169-176

In this paper we analyze seismic regime and earthquake depth distribution and correlation of seismicity and mud volcanism in the Azerbaijan and the Caspian Sea region. For the present region we have calculated accurate source locations, seismic activity, earthquake repetition and released earthquake energy parameters. It is shown that the active tectonic processes in the region are concentrated within the thick sedimentary cover that we consider as a general source of contemporary stress and a main structural element responsible for the origin of regional earthquakes. The correlation of seismicity and mud volcanism is of paragenetic character.  相似文献   

Comparison of TOPEX/POSEIDON Altimeter Derived Wind Speed and Wave Parameters with Ocean Buoy Data in the North Indian Ocean   总被引：1，自引：0，他引：1  

Jignesh Kshatriya  Abhijit Sarkar  Raj Kumar 《Marine Geodesy》2001,24(3):131-138

Results of comparison exercises carried out between the state-of-the-art TOPEX/POSEIDON altimeter-derived ocean surface wind speed and ocean wave parameters (significant wave height and wave period) and those measured by a set of ocean data buoys in the North Indian Ocean are presented in this article. Altimeter-derived significant wave height values exhibited rms deviation as small as ±0.3 m, and surface wind speed of ±1.6 m/s. These results are found consistent with those found for the Pacific Ocean. For estimation of ocean wave period, the spectral moments-based semiempirical approach, earlier applied on GEOSAT data, was extended to TOPEX/POSEIDON. For this purpose, distributions of first four years of TOPEX/POSEIDON altimeter data and climatology over the North Indian Ocean were analyzed and a new set of coefficients generated for estimation of wave period. It is shown that wave periods thus estimated from TOPEX/POSEIDON data (for the subsequent two years), when compared with independent data set of ocean data buoys deployed in the North Indian Ocean, exhibit improved accuracy (rms ~ ±1.4 nos) over those determined earlier with GEOSAT data.  相似文献   

Urban cadastral mapping using very high resolution remote sensing data     

K. N. Prudhvi Raju  Sarvajeet Kumar  Kshitij Mohan  Manish Kumar Pandey 《Journal of the Indian Society of Remote Sensing》2008,36(3):283-288

With growing urban expanses, one of the pre-requisites for effective governance is Urban Information Systems (UIS) with content down to individual properties (and individuals). The basic input i.e., a map, in UIS should show individual property boundaries showing the plan outline of all structures existing within, at a scale of 1:1000 and larger with sub-metre to centimeters planimetric and geometric accuracy. With very high resolution remote sensing data of the order of 1m available in hand, it is possible to prepare maps with high resolution spatial content. The present exercise demonstrates a method of preparing a geometrically and planimetrically accurate urban cadastral map on very large scale for a small area of about 5 sq km. IKONOS merged data with 1m resolution is used for the purpose. Mapping was done in conjunction with on-site measurements and sketches. Guides are used to maintain shape symmetry and accuracy of buildings and other features. Working out cost of mapping per unit area is another objective in the present exercise. For want of fully or semi-automatic methods of information extraction from very high resolution remote sensing data, it is imperative that mapping should be carried out in conjunction with some on-site measurements wherever necessary.  相似文献   

Geochemical Eccentricity of Ground Water Allied to Weathering of Basalts from the Deccan Volcanic Province,India: Insinuation on CO<Subscript>2</Subscript> Consumption     

N. J. Pawar  J. B. Pawar  Suyash Kumar  Ashwini Supekar 《Aquatic Geochemistry》2008,14(1):41-71

Analyses of 72 samples from Upper Panjhara basin in the northern part of Deccan Plateau, India, indicate that geochemical incongruity of groundwater is largely a function of mineral composition of the basaltic lithology. Higher proportion of alkaline earth elements to total cations and HCO₃>Cl + SO₄ reflect weathering of primary silicates as chief source of ions. Inputs of Cl, SO₄, and NO₃ are related to rainfall and localized anthropogenic factors. Groundwater from recharge area representing Ca + Mg–HCO₃ type progressively evolves to Ca + Na–HCO₃ and Na–Ca–HCO₃ class along flow direction replicates the role of cation exchange and precipitation processes. While the post-monsoon chemistry is controlled by silicate mineral dissolution + cation exchange reactions, pre-monsoon variability is attributable chiefly to precipitation reactions + anthropogenic factors. Positive correlations between Mg vs HCO₃ and Ca + Mg vs HCO₃ supports selective dissolution of olivine and pyroxene as dominant process in post-monsoon followed by dissolution of plagioclase feldspar and secondary carbonates. The pre-monsoon data however, points toward the dissolution of plagioclase and precipitation of CaCO₃ supported by improved correlation coefficients between Na + Ca vs HCO₃ and negative correlation of Ca vs HCO₃, respectively. It is proposed that the eccentricity in the composition of groundwater from the Panjhara basin is a function of selective dissolution of olivine > pyroxene followed by plagioclase feldspar. The data suggest siallitization (L < R and R _k) as dominant mechanism of chemical weathering of basalts, stimulating monosiallitic (kaolinite) and bisiallitic (montmorillonite) products. The chemical denudation rates for Panjhara basin worked out separately for the ground and surface water component range from 6.98 to 36.65 tons/km²/yr, respectively. The values of the CO₂ consumption rates range between 0.18 × 10⁶ mol//km²/yr (groundwater) and 0.9 × 10⁶ mol/km²/yr (surface water), which indicates that the groundwater forms a considerable fraction of CO₂ consumption, an inference, that is, not taken into contemplation in most of the studies.  相似文献   

Lake bank filtration at Nainital,India: water-quality evaluation   总被引：6，自引：2，他引：4  

R. R. Dash  I. Mehrotra  P. Kumar  T. Grischek 《Hydrogeology Journal》2008,16(6):1089-1099

There are different water-supply schemes in Uttarakhand, India to tap the water from streams, rivers and lakes. At Nainital, seven tube-wells (depths 22.6–36.7 m), located at a distance of <100 m from the lake, are being used to abstract (1) lake water after passage through the soil and (2) subsurface water/groundwater flowing towards the lake. Water samples from the lake and tube-wells were analyzed in monsoon and non-monsoon periods from 1997 to 2006. Total dissolved solids, EC, alkalinity and hardness were found to be marginally greater in tube-well waters. The difference in hydrochemistry of tube-well water was mainly due to variation in flow regimes during monsoon and non-monsoon periods. Results clearly indicate that lake water as such is not potable as it contains unacceptable levels of organic matter in terms of COD (~44 mg/L), coliforms (~15.6 × 10⁴ MPN/100 mL) and nutrients. Coliform bacteria and COD have not been detected in any of the tube-well water samples over the years. Lake water, treated by sand filters did not conform to drinking water standards. These investigations have led to the closure of the treatment facility and installation of two tube-wells in addition to the existing five tube-wells.

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Résumé  Il existe divers projets d’alimentation en eau dans l’état d’Uttarakhand, Inde, afin de capter l’eau de ruisseaux, de rivières et de lacs. A Nainital, sept puits tubés (profondeur de 22.6–36.7 m), situés à une distance < à 100 m du lac, sont utilisés pour prélever (1) de l’eau du lac après transit à travers le sol et (2) de l’eau de sub-surface/eau souterraine s’écoulant vers le lac. Des échantillons d’eau du lac et des puits tubés ont été analysés en périodes de mousson et de celles sans mousson 1997 à 2006. Résidu sec, C.E., alcalinité et dureté ont été trouvés marginalement supérieurs dans l’eau des puits tubés. La différence d’hydrochimie de l’eau des puits tubés était surtout due à la variation des régimes d’écoulement pendant les périodes de mousson et de celles sans mousson. Les résultats indiquent clairement que l’eau du lac en tant que telle n’est pas potable car elle contient des teneurs inacceptables de matière organique en termes de COD (~44 mg/L), de coliformes (~15.6 × 10⁴ MPN/100 mL) et d’éléments nutritifs. Des bactéries coliformes et du COD n’ont été détectés dans aucun des échantillons d’eau de puits tubés au fil des années. L’eau du lac traitée par des filtres à sable ne se conformait pas aux normes de l’eau potable. Ces recherches ont conduit à la fermeture de l’installation de traitement et à l’implantation de deux puits tubés en plus des cinq puits existants.

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Resumen  En el estado de Uttarakhand, India, existen diferentes esquemas de abastecimiento de agua que explotan agua de arroyos, ríos y lagos. En Nainital, siete pozos (profundidades entre 22.6–36.7 m), ubicados a una distancia de <100 m del lago, se usan para extraer (1) agua del lago luego de su pasaje a través del suelo y (2) agua superficial y subterránea que fluye hacia el lago. En períodos de monzón y de no monzón de 1997 a 2006 se han analizado muestras de agua del lago y de las captaciones. Se halló que el agua de los pozos es ligeramente mayor en términos del total de sólidos disueltos, la conductividad eléctrica, la alcalinidad y la dureza. La diferencia en la hidroquímica del agua de las perforaciones se debe principalmente a la variación de los regímenes de flujo durante los períodos de monzón y de no monzón. Los resultados claramente indican que el agua del lago no es potable por su contenido inaceptable de materia orgánica medida como demanda de carbono orgánico/oxígeno –DCO- (~44 mg/L), coliformes (~15.6 × 10⁴ NMP/100 mL) y nutrientes. En el período, no se han detectado bacterias coliformes ni DCO en las muestras de agua de las captaciones. El agua del lago, tratada con filtros de arena, no conformó los estándares de agua para bebida. Estas investigaciones han demostrado la necesidad de clausurar las instalaciones de tratamiento y la adición de dos captaciones a las cinco ya existentes.

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Two-dimensional modelling of contaminant transport through saturated porous media using the radial point interpolation method (RPIM)     

R. Praveen Kumar  G. R. Dodagoudar 《Hydrogeology Journal》2008,16(8):1497-1505

A new numerical tool is presented which models the two-dimensional contaminant transport through saturated porous media using a meshfree method called the radial point interpolation method (RPIM) with polynomial reproduction. In RPIM, an approximate solution is constructed entirely in terms of a set of nodes and no characterisation of the interrelationship of the nodes is needed. An advection-dispersion equation with sorption is considered to illustrate the applicability of the RPIM. The Galerkin weak form of the governing equation is formulated using two-dimensional meshfree shape functions constructed using thin plate spline radial basis functions. A computer program is developed for the implementation of the RPIM procedure. Three numerical examples are presented and the results are compared with those obtained from the analytical solution and finite element method. The experimental results are also used to validate the approach. The proposed RPIM has generated results with no oscillations and they are insensitive to Peclet constraints.  相似文献   

Reflection of waves from the boundary of a random elastic semi-infinite medium     

Rabindra Kumar Bhattacharyya 《Pure and Applied Geophysics》1996,146(3-4):677-688

In this paper the smooth perturbation technique is employed to investigate the problem of reflection of waves incident on the plane boundary of a semi-infinite elastic medium with randomly varying inhomogeneities. Amplitude ratios have been obtained for various types of incident and reflected waves. It has been shown that an incidentSH orSV type of wave gives rise to reflectedSH, P andSV waves, the main components beingSH andP, SV in the respective cases. The reflected amplitudes have been calculated depending upon the randomness of the medium to the square of the small quantity , where measures the deviation of the medium from homogeneity. An incidentP-type wave produces mainly aP component and also a weakSH component to the order of ². The reflected amplitudes obtainable for elastic media are also altered by terms of the same order. The direction of the reflected wave is influenced by randomness in some cases.  相似文献   

Forest cover mapping of East district,Sikkim using IRS-1A LISS II satellite data     

S. Sudhakar  Arvind Kumar  M. L. Arrawatia  S. Sengupta 《Journal of the Indian Society of Remote Sensing》1994,22(3):155-168

Remote sensing techniques have been applied to classify tour density classes within each of the forest type along with other major landuse/landcover classes in the East district, Sikkim using IRS-1A LISS II satellite data pertaining to the period of November, 1988. The shadow problem in rugged terrain and difficulty in acquiring cloud free data for different seasons pose problems to achieve considerable mapping accuracy. In the present study, the forests of the district were delineated through supervised classification techniques using maximum likelihood algorithm into five forest types as sal forests, subtropical broad-leaved forests, Himalayan wet temperate forests, Rhododendron forests and alpine forests. The alpine forests were further stratified into two categories as moist alpine scrub and dry alpine scrub. The statistical data obtained from the present study shows that 55.47 percent of the total geographical area of the East district was under forest cover. An overall accuracy of more than 85 percent in correctly delineating forest classes was achieved.  相似文献