Binary gas sorption/desorption experiments on a bituminous coal: Simultaneous measurements on sorption kinetics,volumetric strain and acoustic emission     

Zofia Majewska  Grażyna Ceglarska-Stefańska  Stanisław Majewski  Jerzy Ziętek 《International Journal of Coal Geology》2009,77(1-2):90-102

There is still no clear understanding of the specific interactions between coal and gas molecules. In this context sorption–desorption studies of methane and carbon dioxide, both in a single gas environment and gas mixtures, are of fundamental interest. This paper presents the results of unique simultaneous measurements of sorption kinetics, volumetric strain and acoustic emission (AE) on three tetragonal coal samples subjected to sorption of carbon dioxide and methane mixtures. The coal was a high volatile bituminous C coal taken from the Budryk mine in the Upper Silesia Basin, Poland. Three different gas mixtures were used in the sorption tests, with dominant CO₂, with dominant CH₄ and a 50/50 mixture.The experimental set-up was designed specially for this study. It consisted of three individual units working together: (i) a unit for gas sorption experiments using a volumetric method, (ii) an AE apparatus for detecting, recording and analysing AE, and (iii) a strain meter for measuring strains induced in the coal sample by gas sorption/desorption. All measurements were computer aided.The experiments indicated that the coal tested showed preferential sorption of CH₄ at 2.6 MPa pressure and exhibited comparable affinities for CH₄ and CO₂ at higher pressures (4.0 MPa). The results of chromatographic analysis of the gas released on desorption suggested that the desorption of methane from the coal was favoured. The relationship between the volumetric strain and the amount of sorbed gas was found to be non-linear. These results were contrary to common opinions on the coal behaviour. Furthermore, it appeared that the swelling/shrinkage of coal was clearly influenced by the network of fractures. Besides, the AE and strain characteristics suggested common sources of sorption induced AE and strain.The present results may have implications for the sequestration of carbon dioxide in coal seams and enhanced coalbed methane recovery (ECBM).  相似文献   

High-frequency X-ray variability as a mass estimator of stellar and supermassive black holes     

Marek Gierli&#;ski  Marek Niko&#;ajuk  Bo&#;ena Czerny 《Monthly notices of the Royal Astronomical Society》2008,383(2):741-749

There is increasing evidence that supermassive black holes in active galactic nuclei (AGN) are scaled-up versions of Galactic black holes. We show that the amplitude of high-frequency X-ray variability in the hard spectral state is inversely proportional to the black hole mass over eight orders of magnitude. We have analysed all available hard-state data from RXTE of seven Galactic black holes. Their power density spectra change dramatically from observation to observation, except for the high-frequency (≳10 Hz) tail, which seems to have a universal shape, roughly represented by a power law of index −2. The amplitude of the tail,   C _M   (extrapolated to 1 Hz), remains approximately constant for a given source, regardless of the luminosity, unlike the break or quasi-periodic oscillation frequencies, which are usually strongly correlated with luminosity. Comparison with a moderate-luminosity sample of AGN shows that the amplitude of the tail is a simple function of black hole mass,   C _M = C / M   , where   C ≈ 1.25 M_⊙ Hz⁻¹  . This makes   C _M   a robust estimator of the black hole mass which is easy to apply to low- to moderate-luminosity supermassive black holes. The high-frequency tail with its universal shape is an invariant feature of a black hole and, possibly, an imprint of the last stable orbit.  相似文献   

Meteoroid Stream Searching: The Use of the Vectorial Elements     

Tadeusz J. Jopek  Regina Rudawska  Przemysław Bartczak 《Earth, Moon, and Planets》2008,102(1-4):73-78

In this initial study, we propose a new distance function D _V involving heliocentric vectorial orbital elements. The function measures differences between: the orbital energies, the angular momentums vectors and the Laplace vectors. In comparison with the widely used D _SH criterion of Southworth and Hawkins, D _D criterion of Drummond and their hybrid D _H by Jopek, the new function contains one invariant with respect to the principal secular perturbation: the orbital energy. The new function proved to be useful in the classification amongst the IAU2003 meteoroids which we searched for streams by D _V function and also using D _SH and D _N -function given by Valsecchi et al. For major streams, the results agree very well. For minor, and near-ecliptical streams the results sometimes differ markedly.  相似文献   

Spacetime is not just space and time     

Marek A. Abramowicz   《New Astronomy Reviews》2008,51(10-12):799

Our physical intuition usually separates space from time, ignoring the spacetime character of the physical reality. In strongly curved spacetimes this may lead to confusion and paradoxes. I present here two examples: (1) in the non-static cosmological spacetimes with flat space sections, the cosmological expansion of space is a true physical effect. Contrary to what the intuition imagines, it cannot be explained as a motion of matter in a non-expanding flat space. (2) Contrary to intuition, for static spacetimes the mathematically simplest 3+1 split is not given by the direct projection as in the standard ADM scheme. The simplest split is defined by a counter intuitive “optical geometry” that redshifts both space and time by the same conformal factor.  相似文献   

Intercomparison of measurements of bulk snow density and water equivalent of snow cover with snow core samplers: Instrumental bias and variability induced by observers     

J. Ignacio López-Moreno  Leena Leppänen  Bartłomiej Luks  Ladislav Holko  Ghislain Picard  Alba Sanmiguel-Vallelado  Esteban Alonso-González  David C. Finger  Ali N. Arslan  Katalin Gillemot  Aynur Sensoy  Arda Sorman  M. Cansaran Ertaş  Steven R. Fassnacht  Charles Fierz  Christoph Marty 《水文研究》2020,34(14):3120-3133

Manually collected snow data are often considered as ground truth for many applications such as climatological or hydrological studies. However, there are many sources of uncertainty that are not quantified in detail. For the determination of water equivalent of snow cover (SWE), different snow core samplers and scales are used, but they are all based on the same measurement principle. We conducted two field campaigns with 9 samplers commonly used in observational measurements and research in Europe and northern America to better quantify uncertainties when measuring depth, density and SWE with core samplers. During the first campaign, as a first approach to distinguish snow variability measured at the plot and at the point scale, repeated measurements were taken along two 20 m long snow pits. The results revealed a much higher variability of SWE at the plot scale (resulting from both natural variability and instrumental bias) compared to repeated measurements at the same spot (resulting mostly from error induced by observers or very small scale variability of snow depth). The exceptionally homogeneous snowpack found in the second campaign permitted to almost neglect the natural variability of the snowpack properties and focus on the separation between instrumental bias and error induced by observers. Reported uncertainties refer to a shallow, homogeneous tundra-taiga snowpack less than 1 m deep (loose, mostly recrystallised snow and no wind impact). Under such measurement conditions, the uncertainty in bulk snow density estimation is about 5% for an individual instrument and is close to 10% among different instruments. Results confirmed that instrumental bias exceeded both the natural variability and the error induced by observers, even in the case when observers were not familiar with a given snow core sampler.  相似文献   

Tropospheric refractivity and zenith path delays from least-squares collocation of meteorological and GNSS data   总被引：1，自引：0，他引：1  

Karina Wilgan  Fabian Hurter  Alain Geiger  Witold Rohm  Jarosław Bosy 《Journal of Geodesy》2017,91(2):117-134

Precise positioning requires an accurate a priori troposphere model to enhance the solution quality. Several empirical models are available, but they may not properly characterize the state of troposphere, especially in severe weather conditions. Another possible solution is to use regional troposphere models based on real-time or near-real time measurements. In this study, we present the total refractivity and zenith total delay (ZTD) models based on a numerical weather prediction (NWP) model, Global Navigation Satellite System (GNSS) data and ground-based meteorological observations. We reconstruct the total refractivity profiles over the western part of Switzerland and the total refractivity profiles as well as ZTDs over Poland using the least-squares collocation software COMEDIE (Collocation of Meteorological Data for Interpretation and Estimation of Tropospheric Pathdelays) developed at ETH Zürich. In these two case studies, profiles of the total refractivity and ZTDs are calculated from different data sets. For Switzerland, the data set with the best agreement with the reference radiosonde (RS) measurements is the combination of ground-based meteorological observations and GNSS ZTDs. Introducing the horizontal gradients does not improve the vertical interpolation, and results in slightly larger biases and standard deviations. For Poland, the data set based on meteorological parameters from the NWP Weather Research and Forecasting (WRF) model and from a combination of the NWP model and GNSS ZTDs shows the best agreement with the reference RS data. In terms of ZTD, the combined NWP-GNSS observations and GNSS-only data set exhibit the best accuracy with an average bias (from all stations) of 3.7 mm and average standard deviations of 17.0 mm w.r.t. the reference GNSS stations.  相似文献   

The integrated use of GPS/GLONASS observations in network code differential positioning     

Przestrzelski  Paweł  Bakuła  Mieczysław  Galas  Roman 《GPS Solutions》2017,21(2):627-638

GPS Solutions - We present the methodology and results of GPS/GLONASS integration in network code differential positioning for regional coverage across Poland using single frequency. Previous...  相似文献   

A comparison of results from geomorphological diversity evaluation methods in the Polish Lowland (Toruń Basin and Chełmno Lakeland)     

Rafał Kot 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2018,118(1):17-35

Geomorphological diversity is part of geodiversity. Study and evaluation of geodiversity, including geomorphological diversity, is often conducted in uplands and mountains, despite the fact that lowland areas are of equal importance. This paper evaluates geomorphological diversity in a small area of the Polish Lowland, using a variety of methods that have been applied in recent times for evaluating geodiversity, and presents the results on maps. By comparing these maps and analyzing the correlation coefficients of the results obtained, it was possible to identify the two methods that were best suited to indicating areas with the greatest geomorphological diversity in the lowlands. These two methods are least affected by the choice of elementary fields and data classification methods applied. The study identified the two areas with the greatest relief diversity and showed that they distinctly differ from one another. They demonstrate the major influence of processes, not only on the topographic parameters and landform types, but above all on identifying and defining total geomorphological diversity. These methods, which can be used to identify the areas with the greatest total geomorphological diversity, could readily be used in applied studies relating to abiotic ecosystem services and landscape management.  相似文献   

Holocene paleohydrological reconstruction of Lake Strzeszyńskie (western Poland) and its implications for the central European climatic transition zone     

Krzysztof Pleskot  Rik Tjallingii  Mirosław Makohonienko  Norbert Nowaczyk  Witold Szczuciński 《Journal of Paleolimnology》2018,59(4):443-459

Western Poland is located in the central European climatic transition zone, which separates the mild and humid Atlantic climate of Western Europe and the East European continental climate. This region is sensitive to lateral shifts of the European climate zones and is particularly suitable for reconstructing Holocene climate variability. This paper presents detailed analyses of the sedimentary record from Lake Strzeszyńskie since the Late Pleistocene. These include smear-slide and thin-section observations, X-ray fluorescence core scanning, magnetic susceptibility measurements, pollen analyses, and radiocarbon dating. The sediment record reveals three distinct sedimentary units consisting of: (1) an alternation of sand layers and laminated silt and clay deposits accumulated prior to 14,600 cal yr BP; (2) faintly laminated calcareous sediments intercalated with organic matter-rich layers deposited between 14,600 and 10,200 cal yr BP; and (3) massive calcareous mud deposited after 10,200 cal yr BP. The Holocene period is marked by nine phases of organic-rich sedimentation and enhanced Fe deposition, which occurred at ca. 10.1, 9.3, 6.4–6.1, 5.5–5.1, 4.7–4.5, 2.7–2.4, 1.3–1.2, 0.8–0.6, 0.4–0.2 kyr cal BP. These phases are associated with high lake levels and correspond with wet periods recognized in several other records from Poland and central Europe. These phases partly coincide with North Atlantic cold periods, which may suggest that high lake levels are triggered by an ocean-continent linking mechanism.  相似文献   

Sea water surface energy balance in the Arctic fjord (Hornsund,SW Spitsbergen) in May–November 2014     

Fortuniak  Krzysztof  Przybylak  Rajmund  Araźny  Andrzej  Pawlak  Włodzimierz  Wyszyński  Przemysław 《Theoretical and Applied Climatology》2017,130(3-4):959-970

Maize is grown by millions of smallholder farmers in South Asia (SA) under diverse environments. The crop is grown in different seasons in a year with varying exposure to weather extremes, including high temperatures at critical growth stages which are expected to increase with climate change. This study assesses the impact of current and future heat stress on maize and the benefit of heat-tolerant varieties in SA. Annual mean maximum temperatures may increase by 1.4–1.8 °C in 2030 and 2.1–2.6 °C in 2050, with large monthly, seasonal, and spatial variations across SA. The extent of heat stressed areas in SA could increase by up to 12 % in 2030 and 21 % in 2050 relative to the baseline. The impact of heat stress and the benefit from heat-tolerant varieties vary with the level of temperature increase and planting season. At a regional scale, climate change would reduce rainfed maize yield by an average of 3.3–6.4 % in 2030 and 5.2–12.2 % in 2050 and irrigated yield by 3–8 % in 2030 and 5–14 % in 2050 if current varieties were grown under the future climate. Under projected climate, heat-tolerant varieties could minimize yield loss (relative to current maize varieties) by up to 36 and 93 % in 2030 and 33 and 86 % in 2050 under rainfed and irrigated conditions, respectively. Heat-tolerant maize varieties, therefore, have the potential to shield maize farmers from severe yield loss due to heat stress and help them adapt to climate change impacts.  相似文献