Total mercury in terrestrial systems (air-soil-plant-water) at the mining region of San Joaquín,Queretaro, Mexico     

Sergio Martínez-Trinidad  Gilberto Hernández Silva  Juventino Martínez Reyes  Gregorio Solorio Munguía  Sara Solís Valdez  Martha Elena Ramírez Islas  Rocío García Martínez 《Geofísica Internacional》2013,52(1):43-58

Deficient management of cinnabar mining left the San Joaquín region with high concentrations of mercury in its soils (2.4 – 4164 mg kg^-1). Numerous cinnabar mines have contributed to the dispersion of mercury into agricultural (0.5 –314 mg kg^-1) and forest (0.2 – 69 mg kg^-1) soils. Sediments are a natural means of transportation for mercury, causing its spreading, especially in areas near mine entrances (0.6 – 687 mg kg^-1). The nearness of maize crops to mines favors mercury accumulation in the different plant structures, such as roots, stems, leaves, and grain (0.04 – 8.2 mg kg^-1); these being related to mercury volatilization and accumulation in soils. Mercury vapor present in the settlements could indicate a constant volatilization from lands and soils (22 – 153 ng m^-3). The mercury levels found in the soils, in maize grain, and in the air resulted greater than the standards reported by the Official Mexican Norm (NOM) and the World Health Organization (WHO). Mercury in rainwater is due mainly to the presence of suspended atmospheric particles, later deposited on the surface (1.5 – 339 μg |^-1). Mercury dissolution was found in the drinking water (10 – 170 ng |^-1), with concentrations below those established by the NOM and the WHO. The contamination existing in the San Joaquín region does not reach the levels of the world’s greatest mercury producers: Almaden (Spain) and Idrija (Slovenia). It is, however, like that found in other important second degree world producers such as Guizhou (China). The population of San Joaquín, as well as its surrounding environment, are constantly exposed to mercury contamination, thus making a long term monitoring necessary to determine its effects, especially to people.  相似文献   

Microscopy and rock magnetism of fine grain-size titanomagnetite from the Jacupiranga Alkaline Complex,Brazil: unearthing Ti-magnesioferrite nanoparticles     

Luis M. Alva-Valdivia  María de la Luz Rivas-Sánchez  Jesús Arenas-Alatorre  Avto Goguitchaishvili  Omar Ferreira Lopes 《Geofísica Internacional》2013,52(2):93-110

Very fine samples from the mineralized zones of the Jacupiranga complex at the Cajati mine were selected for crystallographic identification of Ti-magnesioferrite (TMf) nanostructures embedded in titanomagnetite (TM) using high-resolution transmission electron microscopy (TEM). A magnetic concentrate obtained of pyroxenite samples (sites 4 to 7) was reduced and divided into fractions of distinct range sizes: 26±2 μm, 19±1 μm, 13±1 μm, 9±1 μm, 6±1 μm and 6-0.1 μm. The mineralized samples of carbonatite and pyroxenite were characterized by X-ray diffraction, transmitted and reflected light microscope, and scanning electron microscope with multielemental analysis. The finest magnetic concentrate sample (MC₆) was analyzed under high-resolution transmitted electron microscopy (TEM) and high angle annular dark field and Raman spectroscopy. Magnetic properties were measured for the distinct granulometric fractions, showing drastic changes when grain sizes go beyond the frontier from micro to nanometer sizes. Frequency-dependent magnetic susceptibility percentage (÷_fd%) report higher values (10.2%) for the finer fractions (6±1 μm and 6-0.1 μm) attributed to dominant fractions of superparamagnetic particles. Nanometer and < 6 μm grain size TMf in TM particles require a magnetic field up to 249 mT to reach saturation during the isothermal remanent magnetization experiment. Coercivity and remanent magnetization of these samples increase when the particle size decreases, probably due to parallel coupling effects. Magnetic susceptibility versus temperature experiments were conducted two times on the same (< 35 nm) sample, showing that the repetition during the second heating is probably due to the formation of new TMf nanoparticles and growth of those already present during the first heating process.  相似文献   

Crustal structure and tectonic setting of the south central Andes from gravimetric analysis     

Cecilia Weidmann  Silvana Spagnotto  Orlando Álvarez  Marcos Sánchez  Federico Lince Klinger  Mario Giménez  Patricia Martínez 《Geofísica Internacional》2013,52(3):197-208

Based on terrestrial gravity data, in this paper we prepared a map of Bouguer anomalies, which was filtered to separate shallow and deep gravity sources. Based on a density model and gravimetric inversion techniques, the discontinuous crust-mantle boundary and the top of crystalline basement were modeled. Subsequently, the equivalent elastic thickness (Te) was evaluated, considering information from the crust-mantle discontinuity and topographic load, finding high Te values in the eastern Andean foothills and west of the Velasco range. These results are consistent with the positive isostatic and residual Bouguer anomaly values, which suggest the presence of high-density rocks in the mid-to upper crust. In addition, petrographic and geochemical analysis conducted in surface outcrops suggest a mantle origin.  相似文献   

Reliable Procedure for Molecular Analysis of Airborne Microflora in Three Indoor Environments: An Office and Two Different Museum Contexts     

Carole Gaüzère  Marina Moletta‐Denat  Faisl Bousta  Stéphane Moularat  Geneviève Orial  Sébastien Ritoux  Jean‐Jacques Godon  Enric Robine 《洁净——土壤、空气、水》2013,41(3):226-234

Biological aerosols from air constitute a significant source of exposure to microorganisms in public places. Airborne microorganisms are involved in the development of certain respiratory symptoms, allergies, or infections among users and occupants. Various sampling instruments have commonly been used in aerobiology to collect bacteria and fungi suspended in the air. The objective of this study was to develop a reliable procedure for sampling in indoor public environments presenting different levels of occupancy, airborne bacteria and fungi to be subjected to molecular analysis (bacteria and fungi quantitative PCR, capillary electrophoresis single strand conformation polymorphism fingerprinting). Four different sampling devices were tested in situ in an office building (open‐plan type) and the sampling strategy chosen was tested in two museum contexts. In accordance with the drawbacks involved to our study (quantitative and qualitative aspects, cost, and overcrowding), cyclone device appeared to be most suitable. The results underline the effectiveness of this high‐volume aerosol sampling device for both qualitative and quantitative molecular analysis. Four in situ sampling collections were carried out in 1 day in the Louvre Museum to study quantitative and qualitative variations of airborne bacterial and fungal diversity. The quantitative results revealed a similar order of magnitude for the numbers of both bacteria and fungi. In the Louvre Museum, the samples yielded between 3.7 × 10⁴ and 4.1 × 10⁴ genome equivalent (GE) bacteria/m³ air and between 5.0 × 10⁴ and 5.9 × 10⁴ GE fungi/m³ air and in the Decorative Arts Museum between, 2.1 × 10⁴ and 2.5 × 10⁴ GE bacteria/m³ air and between 1.4 × 10⁴ and 1.7 × 10⁴ GE fungi/m³ air. The results also indicate that the dominant bacterial community displayed a stable structure over a short period of time whereas dominant eukaryotic airborne community appeared more variable.  相似文献   

Robust Regulation of Alkalinity in Highly Uncertain Continuous Anaerobic Digestion Processes     

Víctor Alcaraz‐González  Fabián Azael Fregoso‐Sanchez  Hugo Oscar Mendez‐Acosta  Victor Gonzalez‐Alvarez 《洁净——土壤、空气、水》2013,41(12):1157-1164

In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances.  相似文献   

Strike‐slip tectonics and basin inversion in the Western Mediterranean: the Post‐Messinian evolution of the Alboran Sea     

P. Martínez‐García  M. Comas  J. I. Soto  L. Lonergan  A. B. Watts 《Basin Research》2013,25(4):361-387

A comprehensive interpretation of single and multichannel seismic reflection profiles integrated with biostratigraphical data and log information from nearby DSDP and ODP wells has been used to constrain the late Messinian to Quaternary basin evolution of the central part of the Alboran Sea Basin. We found that deformation is heterogeneously distributed in space and time and that three major shortening phases have affected the basin as a result of convergence between the Eurasian and African plates. During the Messinian salinity crisis, significant erosion and local subsidence resulted in the formation of small, isolated, basins with shallow marine and lacustrine sedimentation. The first shortening event occurred during the Early Pliocene (ca. 5.33–4.57 Ma) along the Alboran Ridge. This was followed by a major transgression that widened the basin and was accompanied by increased sediment accumulation rates. The second, and main, phase of shortening on the Alboran Ridge took place during the Late Pliocene (ca. 3.28–2.59 Ma) as a result of thrusting and folding which was accompanied by a change in the Eurasian/African plate convergence vector from NW‐SE to WNW‐ESE. This phase also caused uplift of the southern basins and right‐lateral transtension along the WNW‐ENE Yusuf fault zone. Deformation along the Yusuf and Alboran ridges continued during the early Pleistocene (ca. 1.81–1.19 Ma) and appears to continue at the present day together with the active NNE‐SSW trending Al‐Idrisi strike‐slip fault. The Alboran Sea Basin is a region of complex interplay between sediment supply from the surrounding Betic and Rif mountains and tectonics in a zone of transpression between the converging African and European plates. The partitioning of the deformation since the Pliocene, and the resulting subsidence and uplift in the basin was partially controlled by the inherited pre‐Messinian basin geometry.  相似文献   

The Problem of Double Longitudes on Glavač’s Map     

Marina Viličić  Miljenko Lapaine 《The Cartographic journal》2013,50(3):217-234

Abstract

Exploring large volumes of geospatial data is difficult. This paper presents an approach that combines visual and computational analysis to make this process easier. This approach is based on the effective application of computational algorithms, such as the Self-Organizing Map (SOM). These are used to uncover the structure, patterns, relationships and trends in the data, and for the creation of abstractions where conventional methods may be limited. In addition, graphical representations are applied to portray extracted patterns in a visual form that allows for better understanding of the derived structures and possible geographical processes, and should facilitate knowledge construction.  相似文献   

Possibilities of GPS kinematic measurements for geological survey in East Slovakia     

Vladimír Sedlák  Viera Hurčíková  Soňa Molčíková 《地球空间信息科学学报》2013,16(4):21-25

This paper deals with transformation procedures for observed GPS data from the world geodetic system WGS-84 into the national geodetic grid datum S-UTCN (system of united trigonometric cadaster network) and Baa (the Baltic Sea after adjustment). Transformation from WGS-84 into SUTCN is performed most frequently by means of the 7-element Helmert transformation with three identical points. Geodetic network was adjusted by two ways.  相似文献   

Deforestation and fragmentation of seasonal tropical forests in the southern Yucatán,Mexico (1990–2006)     

Juan Pablo Ramírez-Delgado  Birgit Schmook 《国际地球制图》2013,28(8):822-841

The southern Yucatán (SY) has been recognized as a hotspot of biodiversity with great risk of deforestation. Land change analysis, based on classified Landsat TM and ETM?+?satellite imagery (1990, 2000 and 2006), was used to estimate the annual deforestation rates of 141 land management units of the SY, and spatial patterns of forest fragmentation around and within the Calakmul Biosphere Reserve (CBR), which comprises approximately one-third of the region. Results indicate a decrease in annual deforestation rates over 1990–2006, from 0.15% year^?1 to 0.06% year^?1, but with significant sub-regional variations in the quantity and rate of forest loss. Despite a decline in deforestation during this period, there was considerable fragmentation both inside and outside the CBR. While population pressures and the expansion of pasture have caused deforestation across the region, agricultural intensification, diversified income strategies and reserve conservation may have contributed to reduced forest loss during the study period.  相似文献   

Mapping burns and natural reforestation using thematic Mapper data   总被引：2，自引：0，他引：2  

M.J. López García  V. Caselles 《国际地球制图》2013,28(1):31-37

Remote sensing techniques are specially suitable to detect and to map areas affected by forest fires. In this work, Landsat 5 Thematic Mapper (TM) data has been used to study a number of forest fires that occurred in the province of Valencia (Spain) and to monitor the vegetation regeneration over burnt areas.

A reference area (non‐burnt forest) was established to assess the change produced by fire. The radiance in the thermal band (10.4–12.5 μm) and the normalized difference in reflectance between near 1R (0.76–0.90 μm) and middle IR (2.08–2.35 μm) were the most suitable parameters to map burnt areas. This index can also be used for monitoring vegetation regeneration in burnt areas. About a month after the fire, the burns show temperatures of 5–6 °C higher than those found in the reference area, and the vegetation index shows negative values whereas the reference area values remain positive. The differences between the burns and the reference area for the vegetation index decrease with time as vegetation regenerates.  相似文献