Evaluating TCE Abiotic and Biotic Degradation Pathways in a Permeable Reactive Barrier Using Compound Specific Isotope Analysis     

Paulo Lojkasek‐Lima  Ramon Aravena  Orfan Shouakar‐Stash  Shaun K. Frape  Massimo Marchesi  Stephanie Fiorenza  John Vogan 《Ground Water Monitoring & Remediation》2012,32(4):53-62

A pilot‐scale zero valent iron (ZVI) Permeable Reactive Barrier (PRB) was installed using an azimuth‐controlled ‐vertical hydrofracturing at an industrial facility to treat a chlorinated Volatile Organic Compound (VOC) plume. Following ZVI injection, no significant reduction in concentration was observed to occur with the exception of some multilevel monitoring wells, which also showed high levels of total organic carbon (TOC). These patterns suggested that the zero valent iron was not well distributed in the PRB creating leaky conditions. The geochemical data indicated reducing conditions in these areas where VOC reduction was observed, suggesting that biotic processes, associated to the guar used in the injection of the iron, could be a major mechanism of VOC degradation. Compound‐Specific Isotope Analysis (CSIA) using both carbon and chlorine stable isotopes were used as a complementary tool for evaluating the contribution of abiotic and biotic processes to VOC trends in the vicinity of the PRB. The isotopic data showed enriched isotope values around the PRB compared to the isotope composition of the VOC source confirming that VOC degradation is occurring along the PRB. A batch experiment using site groundwater collected near the VOC source and the ZVI used in the PRB was performed to evaluate the site‐specific abiotic isotopic fractionation patterns. Field isotopic trends, typical of biodegradations were observed at the site and were different from those obtained during the batch abiotic experiment. These differences in isotopic trends combined with changes in VOC concentrations and redox parameters suggested that biotic processes are the predominant pathways involved in the degradation of VOCs in the vicinity of the PRB.  相似文献   

Facies analysis of Pleistocene sediments from the Bannock Basin area: A key to the reconstruction of its tectonic evolution     

Vilia Nolli  Massimo Redaelli  Maria Bianca Cita 《Marine Geology》1991,100(1-4):5-20

Facies analysis was carried out on 21 selected cores from the Bannock area in order to investigate the relationships between sedimentation and tectonism. Bannock Basin is a large, > 3500 m (uncorrected) deep subcircular depression near the deformation front of the Mediterranean Ridge facing the Sirte Abyssal Plain. The basin is divided into several sub-basins aligned along a rim-syncline surrounding a central elevated area (salt dome?). High-density brines and anoxic sediments occupy the deepest part of the depressions.

The facies distribution is controlled by the bottom configuration in that pelagic facies typically occur on plateaus and domes, debris-flow deposits in base-of-slope settings, and turbidites in basinal settings. The facies distribution may therefore be used to reconstruct the evolution of the various parts of the rim-syncline.

Erosional gaps may be related to tectonism or may be features created by the passage of major turbiditic events.

The results of our study of the facies associations, and of the rates of sediment accumulation, indicate that the collapse of the eastern part of the rim-syncline pre-dates the collapse of the western part. The western basins are deeper and larger than the eastern ones and (unlike the latter) are aligned at the foot of a strike-slip fault with a vertical offset of at least 700 m.  相似文献   

The value of technology and of its evolution towards a low carbon economy   总被引：2，自引：1，他引：1  

Massimo Tavoni  Enrica De Cian  Gunnar Luderer  Jan Christoph Steckel  Henri Waisman 《Climatic change》2012,114(1):39-57

This paper assesses the economic value associated with the development of various low-carbon technologies in the context of climate stabilization. We analyze the impact of restrictions on the development of specific mitigation technologies, comparing three integrated assessment models used in the RECIPE comparison exercise. Our results indicate that the diversification of the carbon mitigation portfolio is an important determinant of the feasibility of climate policy. Foregoing specific low carbon technologies raises the cost of achieving the climate policy, though at different rates. CCS and renewables are shown to have the highest value, given their flexibility and wide coverage. The costs associated with technology failure are shown to be related to the role that each technology plays in the stabilization scenario, but also to the expectations about their technological progress. In particular, the costs of restriction of mature technologies can be partly compensated by more innovation and technological advancement.  相似文献   

Hydrogeochemical and multi-tracer investigations of arsenic-affected aquifers in semi-arid West Africa     

Anja Bretzler  Lucien Stolze  Julien Nikiema  Franck Lalanne  Elaheh Ghadiri  Matthias S.Brennwald  Massimo Rolle  Mario Schirmer 《地学前缘(英文版)》2019,10(5):1685-1699

The semi-arid Sahel regions of West Africa rely heavily on groundwater from shallow to moderately deep(100 m b.g.l.)crystalline bedrock aquifers for drinking water production.Groundwater quality may be affected by high geogenic arsenic(As)concentrations(10μg/L)stemming from the oxidation of sulphide minerals(pyrite,arsenopyrite)in mineralised zones.These aquifers are still little investigated,especially concerning groundwater residence times and the influence of the annual monsoon season on groundwater chemistry.To gain insights on the temporal aspects of As contamination,we have used isotope tracers(noble gases,~3H,stable water isotopes(~2 H,~(18)O))and performed hydrochemical analyses on groundwater abstracted from tube wells and dug wells in a small study area in southwestern Burkina Faso.Results revealed a great variability in groundwater properties(e.g.redox conditions,As concentrations,water level,residence time)over spatial scales of only a few hundred metres,characteristic of the highly heterogeneous fractured underground.Elevated As levels are found in oxic groundwater of circum-neutral pH and show little relation with any of the measured parameters.Arsenic concentrations are relatively stable over the course of the year,with little effect seen by the monsoon.Groundwater residence time does not seem to have an influence on As concentrations,as elevated As can be found both in groundwater with short(50 a)and long(10~3 a)residence times as indicated by ~3He/~4He ratios spanning three orders of magnitude.These results support the hypothesis that the proximity to mineralised zones is the most crucial factor controlling As concentrations in the observed redox/pH conditions.The existence of very old water portions with residence times10~3 years already at depths of50 m b.g.l.is a new finding for the shallow fractured bedrock aquifers of Burkina Faso,suggesting that overexploitation of these relatively low-yielding aquifers may be an issue in the future.  相似文献   

Late Cretaceous porphyry Cu and epithermal Cu–Au association in the Southern Panagyurishte District,Bulgaria: the paired Vlaykov Vruh and Elshitsa deposits     

Kalin Kouzmanov  Robert Moritz  Albrecht von Quadt  Massimo Chiaradia  Irena Peytcheva  Denis Fontignie  Claire Ramboz  Kamen Bogdanov 《Mineralium Deposita》2009,44(6):611-646

Vlaykov Vruh–Elshitsa represents the best example of paired porphyry Cu and epithermal Cu–Au deposits within the Late Cretaceous Apuseni–Banat–Timok–Srednogorie magmatic and metallogenic belt of Eastern Europe. The two deposits are part of the NW trending Panagyurishte magmato-tectonic corridor of central Bulgaria. The deposits were formed along the SW flank of the Elshitsa volcano-intrusive complex and are spatially associated with N110-120-trending hypabyssal and subvolcanic bodies of granodioritic composition. At Elshitsa, more than ten lenticular to columnar massive ore bodies are discordant with respect to the host rock and are structurally controlled. A particular feature of the mineralization is the overprinting of an early stage high-sulfidation mineral assemblage (pyrite ± enargite ± covellite ± goldfieldite) by an intermediate-sulfidation paragenesis with a characteristic Cu–Bi–Te–Pb–Zn signature forming the main economic parts of the ore bodies. The two stages of mineralization produced two compositionally different types of ores—massive pyrite and copper–pyrite bodies. Vlaykov Vruh shares features with typical porphyry Cu systems. Their common geological and structural setting, ore-forming processes, and paragenesis, as well as the observed alteration and geochemical lateral and vertical zonation, allow us to interpret the Elshitsa and Vlaykov Vruh deposits as the deep part of a high-sulfidation epithermal system and its spatially and genetically related porphyry Cu counterpart, respectively. The magmatic–hydrothermal system at Vlaykov Vruh–Elshitsa produced much smaller deposits than similar complexes in the northern part of the Panagyurishte district (Chelopech, Elatsite, Assarel). Magma chemistry and isotopic signature are some of the main differences between the northern and southern parts of the district. Major and trace element geochemistry of the Elshitsa magmatic complex are indicative for the medium- to high-K calc-alkaline character of the magmas. ⁸⁷Sr/⁸⁶Sr_(i) ratios of igneous rocks in the range of 0.70464 to 0.70612 and ¹⁴³Nd/¹⁴⁴Nd_(i) ratios in the range of 0.51241 to 0.51255 indicate mixed crustal–mantle components of the magmas dominated by mantellic signatures. The epsilon Hf composition of magmatic zircons (+6.2 to +9.6) also suggests mixed mantellic–crustal sources of the magmas. However, Pb isotopic signatures of whole rocks (²⁰⁶Pb/²⁰⁴Pb = 18.13–18.64, ²⁰⁷Pb/²⁰⁴Pb = 15.58–15.64, and ²⁰⁸Pb/²⁰⁴Pb = 37.69–38.56) along with common inheritance component detected in magmatic zircons also imply assimilation processes of pre-Variscan and Variscan basement at various scales. U–Pb zircon and rutile dating allowed determination of the timing of porphyry ore formation at Vlaykov Vruh (85.6 ± 0.9 Ma), which immediately followed the crystallization of the subvolcanic dacitic bodies at Elshitsa (86.11 ± 0.23 Ma) and the Elshitsa granite (86.62 ± 0.02 Ma). Strontium isotope analyses of hydrothermal sulfates and carbonates (⁸⁷Sr/⁸⁶Sr = 0.70581–0.70729) suggest large-scale interaction between mineralizing fluids and basement lithologies at Elshitsa–Vlaykov Vruh. Lead isotope compositions of hydrothermal sulfides (²⁰⁶Pb/²⁰⁴Pb = 18.432–18.534, ²⁰⁷Pb/²⁰⁴Pb = 15.608–15.647, and ²⁰⁸Pb/²⁰⁴Pb = 37.497–38.630) allow attribution of ore-formation in the porphyry and epithermal deposits in the Southern Panagyurishte district to a single metallogenic event with a common source of metals.  相似文献   

卫星遥感藏北高原非均匀陆表地表特征参数和植被参数   总被引：20，自引：0，他引：20  

马耀明  刘东升  苏中波  李召良  Massimo Menenti  王介民 《大气科学》2004,28(1):23-31

卫星遥感在研究青藏高原北部地区(藏北高原地区)非均匀陆表地表特征参数和植被参数时有其独到的作用.作者提出了基于NOAA-14 AVHRR资料推算藏北高原地区地表特征参数和植被参数的方案,并把其用于全球能量水循环之亚洲季风青藏高原试验(GAME/Tibet)试验区.同时利用3个景的NOAA-14 AVHRR资料进行了分析研究,得到了一些有关藏北地区非均匀地表的区域地表特征参数(地表反射率、地表温度)和植被参数(INDV、植被覆盖度和叶面指数ILA).  相似文献   

Are we going to live in a post-NATO world? A critical perspective on trends,obstacles and possibilities     

Fabio Massimo Parenti  Iacopo Adda 《GeoJournal》2017,82(2):345-354

The main research question investigated in this paper is the following: will a post-NATO world emerge during the next decades? The relevance of such a question is a consequence of the political and economic changes that have seen the light as a result of the power shift of international relations after the end of the Cold War. In spite of this, some contradictory tendencies, such as the weakening of the European pole within the NATO block, the US-NATO enlargement and its military aggressiveness, are generating a number of significant obstacles to the emergence of a post-NATO world. We will argue that the existence of these obstacles could be interpreted as some steps toward the historical downsizing of the US-EU-NATO hegemony. A “post-NATO” world does not necessarily imply the end of NATO, but rather the end of its hegemonic military presence on the global stage. Firstly, we will put the question into context mentioning the debates around NATO’s future and underlining the path undertaken by the Alliance in the frame of the redefinition of the aims of its “strategic concepts”. In this perspective, we will underline the direct link which exists between US strategic needs and NATO’s evolution in the post-Cold war era. Secondly, we will argue that the recent process of military expansionism led by NATO is remarkably de-legitimizing its actions on the global stage. Such a process, along with the current world system shift toward the end of unipolarity, is likely to provoke dramatic consequences in terms of international insecurity and the spreading of war. Thirdly, we will briefly compare the US and Chinese foreign actions, arguing that the space of international legitimacy is radically changing. This fact represents another brick supporting the idea of the emergence of a post-NATO world system in the future of international relations.  相似文献   

Assessing space–time variations of denudation processes and related soil loss from 1955 to 2016 in southern Italy (Calabria region)     

Massimo Conforti  Gabriele Buttafuoco 《Environmental Earth Sciences》2017,76(13):457

Studies on denudation processes and soil loss rates can provide insight into the landscape evolution, climate change, and human activities, as well as on land degradation risk. The aims of this study were to analyze the space–time distribution of denudation processes and evaluate the soil loss changes occurred during the period 1955–2016 by using an approach integrating geomorphological, geospatial and modeling analysis. The study area is a representative stream catchment of the Crati Valley (Calabria, southern Italy), which is affected by severe erosion processes. The combined use of aerial photographs interpretation, field survey, geostatistics, and GIS processing has allowed to characterize the types of denudation processes and land use change in space and time. Revised universal soil loss equation implemented in GIS environment was used to estimate the space–time pattern of soil loss and the soil erosion rates for each investigated year. The results showed that from 1955 to 2016, the study area was highly affected by denudation processes, mainly related to landslides and water erosion (slope wash erosion and gully erosion). Comparison of denudation processes maps showed that the total area affected by erosion processes has increased by about 31% and the distribution of geomorphic processes and their space–time evolution resulted from the complex interrelation between geoenvironmental features and human activities. The main land use changes concerned a decrease in areas covered by woodland, scrubland and pasture and an increase in croplands and barren lands that favored erosion processes. The most susceptible areas to soil loss in both years were mapped, and the mean soil loss rates for the study area were 6.33 Mg ha^?1 y^?1 in 1955 and 10.38 Mg ha^?1 y^?1 in 2016. Furthermore, the soil loss in 2016 has increased by about 64% compared to 1955. Finally, the results showed that integrating multi-temporal analysis of denudation processes, land use changes and soil loss rates might provide significant information on landscape evolution which supports decision makers in defining soil management and conservation practices.  相似文献   

Spatio‐temporal patterns of channel changes in response to a major flood event: the case of the Magra River (central–northern Italy)          下载免费PDF全文

Laura Nardi  Massimo Rinaldi 《地球表面变化过程与地形》2015,40(3):326-339

On October 25^th 2011, the Magra River (central–northern Italy) was affected by a significant flood event with an estimated return interval ranging from 30 to 200 years. This study investigates the morphological responses of the Magra River to this major flood event with the aims of (i) documenting the channel changes which occurred in response to the flood; (ii) analysing this response within the context of the historical trend of width changes; (iii) investigating the possible factors controlling the spatial pattern and the intensity of the observed changes. Significant channel widening was documented along the entire length studied (about 34 km), ranging from 3% to 90% of the pre‐flood channel width. Braided reaches were characterized by the most severe planimetric changes. Although characterized by high rates of change, these variations are, however, amply included in the historical range of channel width variability over approximately the last 150 years (from 1877 to present day), and are comparable with ( though generally lower than) the channel width of the 1950s. Statistical analyses (simple and multiple regressions) between the observed changes in channel width and a series of selected morphological and hydraulic controlling factors showed no robust correlations to explain the spatial pattern and the variability of channel adjustments. Instead, major adjustments occurred along reaches characterized by the confluence of those streams draining the sub‐catchments where the storm was concentrated. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Comparison between rocking analysis and kinematic analysis for the dynamic out‐of‐plane behavior of masonry walls          下载免费PDF全文

Linda Giresini  Massimo Fragiacomo  Paulo B. Lourenço 《地震工程与结构动力学》2015,44(13):2359-2376

This paper provides a contribution to the rocking analysis of masonry walls by making a comparison with the kinematic analysis suggested by the Italian code. It is shown that the latter approach is generally over‐conservative and therefore potentially inappropriate for historic buildings, where rehabilitation can be expensive and can affect their cultural value. The equation of motion given by the Housner formulation, corresponding to the movement of a rigid block, is here modified to account for different boundary conditions at different heights of the wall. These boundary conditions or horizontal restraints can represent vaults, transverse walls, or retrofitting devices such as steel tie‐rods. A systemic analysis of walls having different dimensions and slenderness is performed, and the results from the Italian code and rocking analysis are compared. Finally, the improvement in the response offered by retrofitting devices is discussed in terms of reduction of amplitude ratio. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献