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31.
Previous work has documented large fluxes of freshwater and nutrients from submarine groundwater discharge (SGD) into the coastal waters of a few volcanic oceanic islands. However, on the majority of such islands, including Moorea (French Polynesia), SGD has not been studied. In this study, we used radium (Ra) isotopes and salinity to investigate SGD and associated nutrient inputs at five coastal sites and Paopao Bay on the north shore of Moorea. Ra activities were highest in coastal groundwater, intermediate in coastal ocean surface water, and lowest in offshore surface water, indicating that high-Ra groundwater was discharging into the coastal ocean. On average, groundwater nitrate and nitrite (N + N), phosphate, ammonium, and silica concentrations were 12, 21, 29, and 33 times greater, respectively, than those in coastal ocean surface water, suggesting that groundwater discharge could be an important source of nutrients to the coastal ocean. Ra and salinity mass balances indicated that most or all SGD at these sites was saline and likely originated from a deeper, unsampled layer of Ra-enriched recirculated seawater. This high-salinity SGD may be less affected by terrestrial nutrient sources, such as fertilizer, sewage, and animal waste, compared to meteoric groundwater; however, nutrient-salinity trends indicate it may still have much higher concentrations of nitrate and phosphate than coastal receiving waters. Coastal ocean nutrient concentrations were virtually identical to those measured offshore, suggesting that nutrient subsidies from SGD are efficiently utilized.  相似文献   
32.
The objective of this study was to evaluate the effect of mine tailings composition on shear behavior and shear strength of co-mixed mine waste rock and tailings (WR&T). Crushed gravel was used as a synthetic waste rock and mixed with four types of tailings: (1) fine-grained garnet, (2) coarse-grained garnet, (3) copper, and (4) soda ash. Co-mixed WR&T specimens were prepared to target mixture ratios of mass of waste rock to mass of tailings (R) such that tailings “just filled” interparticle void space of the waste rock (i.e., optimum mixture ratio, R opt). Triaxial compression tests were conducted on waste rock, tailings, and mixed waste at effective confining stresses (\(\sigma_{\text{c}}^{{\prime }}\)) ranging from 5 to 40 kPa to represent stresses anticipated in final earthen covers for waste containment facilities. Waste rock and co-mixed WR&T specimens were 150 mm in diameter by 300 mm tall, whereas tailings specimens were 38 mm in diameter by 76 mm tall. Shear strength was quantified using effective stress friction angles (?′) from undrained tests: ?′ for waste rock was 37°, ?′ for tailings ranged from 34° to 41°, and ?′ for WR&T mixtures ranged from 38° to 40°. Thus, shear strength of co-mixed WR&T was comparable to waste rock regardless of tailings composition. Shear behavior of WR&T mixtures was a function of R and tailings composition. Tailings influenced shear behavior for R < R opt and when tailings predominantly were silt. Shear behavior was influenced by waste rock for R ≥ R opt and when tailings predominantly were sand or included clay particles.  相似文献   
33.
Cadmium, chromium, nickel, and lead were evaluated in the particulate fraction at one of the most industrialized estuaries at the Southwestern Atlantic Ocean, through Geographic Information System (GIS). Concentrations were analyzed at 21 stations during 2008–2010. The highest metal concentrations (Cd: 8,9; Cr: 256,49; Ni: 27,02; Pb: 78,43 µg g??1 d. w.) were recorded at the stations located near industrial and urban discharges situated along the estuary. In addition, Pb presented a different seasonal and spatial behavior in comparison with Cd, Cr and Ni. Winter and spring presented the higher concentrations of Pb, and the inner stations presented the higher values. The estuary is considered a moderate to strongly polluted and significantly polluted according to the Index of geoaccumulation (Igeo) and the Enrichment Factor of Cd, respectively. The Multidimensional Scaling plot showed three groups of stations: the inner, associated to low levels of metals (G1), middle stations (G2) with intermediate levels and the outer (G3) with the highest ones. In addition, this work reveals the usefulness of the GIS-mapping techniques in the distribution of pollutants along an estuarine environment and the environmental quality assessment of estuarine systems.  相似文献   
34.
The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.  相似文献   
35.
The factors that explain the speed of recovery after disaster remain contested. While many have argued that physical infrastructure, social capital, and disaster damage influence the arc of recovery, empirical studies that test these various factors within a unified modeling framework are few. We conducted a mail survey to collect data on household recovery in four small towns in southern Indiana that were hit by deadly tornadoes in March 2012. The recovery effort is ongoing; while many of the homes, businesses, and community facilities were rebuilt in 2013, some are still under construction. We investigate how households in these communities are recovering from damage that they experienced and the role of social capital, personal networks, and assistance from emergency responders on the overall recovery experience. We used an ordered probit modeling framework to test the combined as well as relative effects of (a) damage to physical infrastructures (houses, vehicles, etc.); (b) recovery assistance from emergency responders (FEMA) as well as friends and neighbors; (c) personal network characteristics (size, network density, proximity, length of relationship); (d) social capital (civic engagement, contact with neighbors, trust); and (e) household characteristics. Results show that while households with higher levels of damage experienced slower recovery, those with recovery assistance from neighbors, stronger personal networks, and higher levels of social capital experienced faster recovery. The insights gained in this study will enable emergency managers and disaster response personnel to implement targeted strategies in facilitating post-disaster recovery and community resilience.  相似文献   
36.
NASA's Genesis mission was flown to capture samples of the solar wind and return them to the Earth for measurement. The purpose of the mission was to determine the chemical and isotopic composition of the Sun with significantly better precision than known before. Abundance data are now available for noble gases, magnesium, sodium, calcium, potassium, aluminum, chromium, iron, and other elements. Here, we report abundance data for hydrogen in four solar wind regimes collected by the Genesis mission (bulk solar wind, interstream low‐energy wind, coronal hole high‐energy wind, and coronal mass ejections). The mission was not designed to collect hydrogen, and in order to measure it, we had to overcome a variety of technical problems, as described herein. The relative hydrogen fluences among the four regimes should be accurate to better than ±5–6%, and the absolute fluences should be accurate to ±10%. We use the data to investigate elemental fractionations due to the first ionization potential during acceleration of the solar wind. We also use our data, combined with regime data for neon and argon, to estimate the solar neon and argon abundances, elements that cannot be measured spectroscopically in the solar photosphere.  相似文献   
37.
We studied a data set of 28 well‐preserved lunar craters in the transitional (simple‐to‐complex) regime with the aim of investigating the underlying cause(s) for morphological differences of these craters in mare versus highland terrains. These transitional craters range from 15 to 42 km in diameter, demonstrating that the transition from simple to complex craters is not abrupt and occurs over a broad diameter range. We examined and measured the following crater attributes: depth (d), diameter (D), floor diameter (Df), rim height (h), and wall width (w), as well as the number and onset of terraces and rock slides. The number of terraces increases with increasing crater size and, in general, mare craters possess more terraces than highland craters of the same diameter. There are also clear differences in the d/D ratio of mare versus highland craters, with transitional craters in mare targets being noticeably shallower than similarly sized highland craters. We propose that layering in mare targets is a major driver for these differences. Layering provides pre‐existing planes of weakness that facilitate crater collapse, thus explaining the overall shallower depths of mare craters and the onset of crater collapse (i.e., the transition from simple to complex crater morphology) at smaller diameters as compared to highland craters. This suggests that layering and its interplay with target strength and porosity may play a more significant role than previously considered.  相似文献   
38.
The Juan de Fuca Eddy is a seasonal, counter-clockwise gyre off the mouth of the Strait of Juan de Fuca between Washington, USA and British Columbia, Canada that may provide favorable feeding habitat for juvenile coho salmon (Oncorhynchus kisutch) during their early marine existence. In late September 2002, physical and biological sampling was conducted along two transects of the eddy region. Surface rope trawling was conducted to capture juvenile salmon and other nekton, along with bongo and neuston net tows to examine potential mesozooplanktonic salmon prey. Presence of the Juan de Fuca Eddy was confirmed with vertical water profiles. In addition, nutrient and chlorophyll a concentrations collected from 3-m depth were within the range observed in previous studies within the eddy region. In the mesozooplankton community, euphausiids, chaetognaths, and decapod megalopae were common. In the diet of juvenile coho salmon, euphausiids and decapod megalopae were dominant by percent number, and larval and juvenile fish were dominant by percent weight. Feeding intensity (percent body weight) based on stomach contents was variable, but not significantly different among stations. To compare the Juan de Fuca Eddy region with an upwelling area, we sampled along a transect off La Push (LP), Washington, USA which is south of the eddy. The eddy region was found to be less productive than the LP transect. Nutrients were lower, chlorophyll a concentrations were higher, and zooplankton abundance was generally higher along the LP transect than in the eddy region. In addition, more juvenile coho salmon were captured from the LP transect than the eddy region. Prey items in stomachs of salmon from the LP transect were heterogeneous compared to those from the eddy region. Feeding intensity along the LP transect was slightly lower and more variable than in the eddy region, and differences in feeding intensity among LP stations were significant. In addition, feeding intensities among stations nested within regions were significantly different.  相似文献   
39.
In order for methane to be economically produced from the seafloor, prediction and detection of massive hydrate deposits will be necessary. In many cases, hydrate samples recovered from seafloor sediments appear as veins or nodules, suggesting that there are strong geologic controls on where hydrate is likely to accumulate. Experiments have been conducted examining massive hydrate accumulation from methane gas bubbles within natural and synthetic sediments in a large volume pressure vessel through temperature and pressure data, as well as visual observations. Observations of hydrate growth suggest that accumulation of gas bubbles within void spaces and at sediment interfaces likely results in the formation of massive hydrate deposits. Methane hydrate was first observed as a thin film forming at the gas/water interface of methane bubbles trapped within sediment void spaces. As bubbles accumulated, massive hydrate growth occurred. These experiments suggest that in systems containing free methane gas, bubble pathways and accumulation points likely control the location and habit of massive hydrate deposits.  相似文献   
40.
Migration decisions are complex and are linked to multiple vulnerabilities, including changing ecological conditions precipitated by climate change. As ecological thresholds are met, community-wide migrations will become more common. These community-wide migrations are more likely to occur to already vulnerable populations, and may levy high social costs. In order to prevent the negative outcomes associated with forced migration and diaspora, policy intervention is likely. Our research examines the case study of Shishmaref, Alaska, where relocation as an adaptation strategy to changing ecological conditions is the only sustainable option. We find that the colonial history in Shishmaref is explicitly linked to contemporary exposure to hazards and increased vulnerability. We further assess obstacles to a State sponsored relocation. These obstacles include disaster response protocol that does not adequately accommodate climate change scenarios. Relocation planning is further complicated by feelings of mis- and under-representation of local voices in political arenas. This case demonstrates the interrelatedness between historically constructed vulnerability and obstacles to adaptation planning. We also offer unique insight into the details of relocation planning as an adaptation strategy among one of the first community-wide migrations associated with climate change.  相似文献   
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