Geochemistry and mineralogy of a feldspathic lunar meteorite (regolith breccia), Northwest Africa 2200     

Hiroshi Nagaoka  Yuzuru Karouji  Tomoko Arai  Mitsuru Ebihara  Nobuyuki Hasebe 《Polar Science》2013,7(3-4):241-259

The lunar meteorite Northwest Africa (NWA) 2200 is a regolith breccia with a ferroan feldspathic bulk composition (Al₂O₃ = 30.1 wt.%; Mg^# = molar 100 × Mg/(Mg + Fe) = 59.2) and low Th content (0.42 μg/g). Lithologically, NWA 2200 is a diverse mixture of lithic and glassy clasts, mineral fragments, and impact glass spherules, all embedded in a dark glassy matrix. NWA 2200 contains some feldspathic brecciated rock components (ferroan anorthositic granulitic breccia, poikiloblastic granulitic breccia, and glassy melt breccia with an intersertal texture). The bulk compositions of these brecciated components indicate they are derived from ferroan troctolitic or noritic anorthosite lithologies (bulk Al₂O₃ = 26–30 wt.%; bulk FeO/MgO > 1.0). The bulk composition of NWA 2200 is more ferroan and feldspathic than the Apollo feldspathic regolith samples and feldspathic lunar regolith meteorites, and is also more depleted in incompatible elements (e.g., rare earth elements) than Apollo 16 feldspathic regolith samples. We conclude that NWA 2200 originated from a location different to the Apollo landing sites, and may have been sourced from the ferroan KREEP-poor highlands, “KREEP” materials are enriched in such elements as potassium (K), rare earth elements (REE), phosphorus (P).  相似文献   

Chemical characteristics of the Cretaceous-Tertiary boundary layer at Gubbio, Italy   总被引：2，自引：0，他引：2  

Mitsuru Ebihara  Tsutomu Miura 《Geochimica et cosmochimica acta》1996,60(24):5133-5144

Platinum metals (Pd, Ir, Pt) and Au were determined by radiochemical neutron activation analysis (RNAA) on Cretaceous-Tertiary (K---T) boundary samples collected at Gubbio, Italy. In addition, about thirty elements were determined by instrumental NAA (INAA) for both the Cretaceous and the Tertiary layer samples, as well as the boundary clay samples. Iridium and other Pt metals were observed to be similarly enriched, relative to CI-chondrite, in the boundary layers, i.e., they occur in chondritic ratios. On the other hand, correlations among the metals are not very good, suggesting that Pt metals were not incorporated into clay materials in a single phase, but rather, they behaved separately according to their own solution chemistries. In the Gubbio section, the chemical composition does not change so much across the K---T boundary layer, except for Ir (and possibly other Pt group elements) and is very similar to that of the “North American shale composite (NASC)”. Arsenic and Sb were observed not to be anomalously enriched in the Gubbio K---T boundary layers. This implies that their abundances cannot be a clue in elucidating an event which must have happened at the K---T boundary period. NASC-normalized REE abundance patterns for the boundary samples show characteristic features due to some REE precipitation out of seawater. REE abundances are not variable among the Cretaceous, the Tertiary, and the boundary samples, suggesting that conditions for precipitation and sedimentation were similar across the K---T boundary at Gubbio.  相似文献   

Lunar meteorite,Dhofar 1428: Feldspathic breccia containing KREEP and meteoritic components     

Yoshihiro Hidaka  Akira Yamaguchi  Mitsuru Ebihara 《Meteoritics & planetary science》2014,49(5):921-928

We have studied the feldspathic lunar meteorite Dhofar 1428 chemically and petrologically to better understand the evolution of the lunar surface. Dhofar 1428 is a feldspathic regolith breccia derived from the lunar highland. Bulk chemical and mineral compositions of Dhofar 1428 are similar to those of other feldspathic lunar meteorites. We found a few clasts of evolved lithologies, such as K‐rich plagioclases and quartz monzogabbro. Dhofar 1428 contains approximately 1 wt% of chondritic materials like CM chondrite on the basis of abundances of platinum group elements (Ru, Rh, Pd, Os, Ir, and Pt).  相似文献   

Suppression of resistive hose instability in a relativistic electron–positron flow     

Mitsuru Honda 《Monthly notices of the Royal Astronomical Society》2007,376(2):871-880

This paper presents the effects of electron–positron pair production on the linear growth of the resistive hose instability of a filamentary beam that could lead to snake-like distortion. For both the rectangular radial density profile and the diffuse profile reflecting the Bennett-type equilibrium for a self-collimating flow, the modified eigenvalue equations are derived from a Vlasov–Maxwell equation. While for the simple rectangular profile, current perturbation is localized at the sharp radial edge, for the realistic Bennett profile with an obscure edge, it is non-locally distributed over the entire beam, removing catastrophic wave–particle resonance. The pair production effects likely decrease the betatron frequency, and expand the beam radius to increase the resistive decay time of the perturbed current; these also lead to a reduction of the growth rate. It is shown that, for the Bennett profile case, the characteristic growth distance for a preferential mode can exceed the observational length-scale of astrophysical jets. This might provide the key to the problem of the stabilized transport of the astrophysical jets including extragalactic jets up to  Mpc (∼3 × 10²⁴ cm)  scales.  相似文献   

Petrology and geochemistry of a silicate clast from the Mount Padbury mesosiderite: Implications for metal‐silicate mixing events of mesosiderite     

Minako Tamaki  Akira Yamaguchi  Keiji Misawa  Mitsuru Ebihara  Hiroshi Takeda 《Meteoritics & planetary science》2006,41(12):1919-1928

Abstract— Petrological and bulk geochemical studies were performed on a large silicate clast from the Mount Padbury mesosiderite. The silicate clast is composed mainly of pyroxene and plagioclase with minor amounts of ilmenite, spinel, and other accessory minerals, and it shows subophitic texture. Pyroxenes in the clast are similar to those in type 5 eucrites and could have experienced prolonged thermal metamorphism after rapid crystallization from a near‐surface melt. Ilmenite and spinel vary chemically, indicating growth under disequilibrium conditions. The clast seems to have experienced an episode of rapid reheating and cooling, possibly as a result of metal‐silicate mixing. Abundances of siderophile elements are obviously higher than in eucrites, although the clast is also extremely depleted in highly siderophile elements. The fractionated pattern can be explained by injection of Fe‐FeS melts generated by partial melting of metallic portions during metal‐silicate mixing. The silicate clast had a complex petrogenesis that could have included: 1) rapid crystallization from magma in a lava flow or a shallow intrusion; 2) prolonged thermal metamorphism to equilibrate the mineral compositions of pyroxene and plagioclase after primary crystallization; 3) metal‐silicate mixing probably caused by the impact of solid metal bodies on the surface of the mesosiderite parent body; and 4) partial melting of metal and sulfide portions (and silicate in some cases) caused by the collisional heating, which produced Fe‐FeS melts with highly fractionated siderophile elements that were injected into silicate portions along cracks and fractures.  相似文献   

Feldspathic clasts in Yamato-86032: Remnants of the lunar crust with implications for its formation and impact history     

L. Nyquist  D. Bogard  A. Yamaguchi  C.-Y. Shih  Y. Karouji  M. Ebihara  Y. Reese  D. Garrison  G. McKay  H. Takeda 《Geochimica et cosmochimica acta》2006,70(24):5990-6015

Low concentrations of Th and Fe in the Yamato (Y)-86032 bulk meteorite support earlier suggestions that Y-86032 comes from a region of the moon far distant from the Procellarum KREEP Terrain (PKT), probably from the lunar farside. ³⁹Ar–⁴⁰Ar, Rb–Sr, Sm–Nd, and Sm-isotopic studies characterize the chronology of Y-86032 and its precursors in the mega regolith. One of the rock types present in a light gray breccia lithology is an anorthosite characterized by plagioclase with An 93, i.e., more sodic than lunar FANs, but with very low ⁸⁷Rb/⁸⁶Sr and ⁸⁷Sr/⁸⁶Sr similar to those of FANs. (FAN stands for Ferroan Anorthosite). This “An93 anorthosite” has Nd-isotopic systematics similar to those of nearside norites. A FAN-like “An97 anorthosite” is present in a second light-colored feldspathic breccia clast and has a more negative ε_Nd value consistent with residence in a LREE-enriched environment as would be provided by an early plagioclase flotation crust on the Lunar Magma Ocean (LMO). This result contrasts with generally positive values of ε_Nd for Apollo 16 FANs suggesting the possibility of assymetric development of the LMO. Other possible explanations for the dichotomy in ε_Nd values are advanced in the text. The Y-86032 protolith formed at least 4.43 ± 0.03 Ga ago as determined from a Sm–Nd isochron for mineral fragments from the breccia clast composed predominantly of An93 anorthosite and a second clast of more varied composition. We interpret the mineral fragments as being predominatly from a cogenetic rock suite. An ³⁹Ar–⁴⁰Ar age of 4.36–4.41 ± 0.035 Ga for a third clast composed predominantly of An97 anorthosite supports an old age for the protolith. Initial ¹⁴³Nd/¹⁴⁴Nd in that clast was −0.64 ± 0.13 ε-units below ¹⁴³Nd/¹⁴⁴Nd in reservoirs having chondritic Sm/Nd ratios, consistent with prior fractionation of mafic cumulates from the LMO. A maximum in the ³⁹Ar–⁴⁰Ar age spectrum of 4.23 ± 0.03 Ga for a second sample of the same feldspathic breccia clast probably reflects some diffusive ⁴⁰Ar loss. Lack of solar wind and lunar atmosphere implanted Ar in the light gray breccia clast allows determination of an ³⁹Ar/⁴⁰Ar age of 4.10 ± 0.02 Ga, which is interpreted as the time of initial brecciation of this litholgy. After correction for implanted lunar atmosphere ⁴⁰Ar, impact melt and dark regolith clasts give Ar ages of 3.8 ± 0.1 Ga implying melt formation and final breccia assembly 3.8 Ga ago. Some breccia lithologies were exposed to thermal neutron fluences of 2 × 10¹⁵ n/cm², only about 1% of the fluence experienced by some other lunar highlands meteorites. Other lithologies experienced neutron fluences of 1 × 10¹⁵ n/cm². Thus, Y-86032 spent most of the time following final brecciation deeply buried in the megaregolith. The neutron fluence data are consistent with cosmogenic ³⁸Ar_cos cosmic ray exposure ages of 10 Ma. Variations among differing lithologies in the amount of several regolith exposure indicators, including cosmogenic noble gas abundances, neutron capture induced variations in Sm isotopic abundances, and Ir contents, are consistent with a period of early (>3.8 Ga ago) lunar regolith exposure, subsequent deep burial at >5 m depth, and ejection from the moon 7–10 Ma ago.  相似文献   

Comparison of potentially toxic metals leaching from weathered rocks at a closed mine site between laboratory columns and field observation     

Omar R. Salinas Villafane  Toshifumi Igarashi  Mitsuru Kurosawa  Toshio Takase 《Applied Geochemistry》2012

Potentially toxic metals, such as Cu, Pb and Zn, are leached from weathered rocks at many closed mine sites due to the acidic environments and mineralogical modifications. The mobilized toxic metals may cause contamination of surrounding water bodies. In this study, both laboratory column experiments and field observations at a former mine located in the north of Japan were carried out to compare the leaching behavior of Cu, Pb and Zn. The thickness of the surface weathered rock was varied (10, 20 and 30 cm) for the columns experiments while porous cups for porewater sampling were set up at different depths (GL-15, -45, -70, and -95 cm) for the field observations. Deionized water was added once a week over 75 weeks to the columns to simulate rainfall while porewater was extracted by a vacuum pump in several sampling campaigns (over 18 months). Similar low pH and leaching behavior of potentially toxic metals were observed for column experiments and field observations. A moderate increase in concentration with depth was observed for Cu and Zn. However, no increase in concentration was observed for Pb. This suggests that the leaching of Cu and Zn is enhanced by the length of the flow pathway through the weathered rock layer while Pb concentration is restricted by the precipitation of insoluble Pb sulfate. Thus, the thickness of the weathered rock layer is an important parameter that should be taken into consideration to estimate the loads of some potentially toxic metals, which is important when designing remediation schemes.  相似文献   

Contributions of sandy lands and stony deserts to long-distance dust emission in China and Mongolia during 2000–2006   总被引：2，自引：0，他引：2  

Baolin Zhang  Atsushi Tsunekawa  Mitsuru Tsubo 《Global and Planetary Change》2008,60(3-4):487-504

More than 400 Moderate Resolution Imaging Spectroradiometer (MODIS) images of dust storm events were collected and analyzed, and individual events were tracked back to their origins. Dust tracks were determined from color composite images, brightness temperature difference (BTD) and the NOAA Hybrid Single-Particle Lagrangian Integrated Trajectory model. The results showed that five regions (sandy lands in central Inner Mongolia and the adjacent area of Mongolia; the Gobi Desert in Xinjiang and Gansu provinces, western Inner Mongolia, and the adjacent southwestern area of Mongolia; the Gobi Desert in southern Mongolia and the adjoining area of northern Inner Mongolia; sandy lands and deserts around the middle reaches of the Yellow River; and the area rimming the Taklimakan Desert) were the main contributors to long-lived mineral dusts in northern China and Mongolia. Of these dust production areas, sandy lands and stony deserts, rather than the sandy deserts of Inner Mongolia and Mongolia, were found to be the dominant dust sources, accounting for more than 75% of regional dust emission events. Dust events in the Taklimakan Desert were often local phenomena, although they could also be transported eastward if they were uplifted high enough to escape the enclosing topographic highs. Dust sources in northwestern China are mainly alluvial fans and dry lake and river beds. Success in identifying the sources and trajectories of Asian dust storms would guide future ground-based research and steppe degradation countermeasures and help reduce the uncertainties in modern modeling of Asian dust.  相似文献