Secondary‐volatiles linked metallic iron in eucrites: The dual‐origin metals of Camel Donga          下载免费PDF全文

Paul H. Warren  Junko Isa  Mitsuru Ebihara  Akira Yamaguchi  Bastian Baecker 《Meteoritics & planetary science》2017,52(4):737-761

The unique occurrence of abundant (~1 vol%) near‐pure‐Fe metal in the Camel Donga eucrite is more complicated than previously believed. In addition to that component of groundmass metal, scattered within the meteorite are discrete nodules of much higher kamacite abundance. We have studied the petrology and composition of two of these nodules in the form of samples we call CD2 and CD3. The nodules are ovoids 11 (CD2) to 15 (CD3) mm across, with metal, or inferred preweathering metal, abundances of 12–17 vol% (CD2 is unfortunately quite weathered). The CD3 nodule also includes at its center a 5 mm ovoid clumping (6 vol%) of F‐apatite. Both nodules are fine‐grained, so the high Fe metal and apatite contents are clearly not flukes of inadequate sampling. The metals within the nodules are distinctly Ni‐rich (0.3–0.6 wt%) compared to the pure‐Fe (Ni generally 0.01 wt%) groundmass metals. Bulk analyses of three pieces of the CD2 nodule show that trace siderophile elements Ir, Os, and Co are commensurately enriched; Au is enriched to a lesser degree. The siderophile evidence shows the nodules did not form by in situ reduction of pyroxene FeO. Moreover, the nodules do not show features such as silica‐phase enrichment or pyroxene with reduced FeO (as constrained by FeO/MgO and especially FeO/MnO) predicted by the in situ reduction model. The oxide minerals, even in groundmass samples well away from the nodules, also show little evidence of reduction. Although the nodule boundaries are generally sharp, groundmass‐metal Ni content is anti‐correlated with distance from the CD3 nodule. We infer that the nodules represent materials that originated within impactors into the Camel Donga portion of the eucrite crust, but probably were profoundly altered during later metamorphism/metasomatism. Origin of the pure‐Fe groundmass metal remains enigmatic. In situ reduction probably played an important role, and association in the same meteorite of the Fe‐nodules is probably significant. But the fluid during alteration was probably not (as previously modeled) purely S and O, of simple heat‐driven internal derivation. We conjecture a two‐stage metasomatism, as fluids passed through Camel Donga after impact heating of volatile‐rich chondritic masses (survivors of gentle accretionary impacts) within the nearby crust. First, reduction to form troilite may have been triggered by fluids rich in S₂ and CO (derived from the protonodules?), and then in a distinct later stage, fluids were (comparatively) H₂O‐rich, and thus reacted with troilite to form pure‐Fe metal along with H₂S and SO₂. The early eucrite crust was in places a dynamic fluid‐bearing environment that hosted complex chemical processes, including some that engendered significant diversity among metal+sulfide alterations.  相似文献   

An anomalous eucrite,Dhofar 007, and a possible genetic relationship with mesosiderites     

Akira Yamaguchi  Takehiko Setoyanagi  Mitsuru Ebihara 《Meteoritics & planetary science》2006,41(6):863-874

Abstract— We studied the texture, mineralogy, and bulk chemical composition of Dhofar 007, a basaltic achondrite. Dhofar 007 is a polymict breccia that is mostly composed of coarse‐grained granular (CG) clasts with a minor amount of xenolithic components, such as a fragment of Mg‐rich pyroxene. The coarse‐grained, relict gabbroic texture, mineral chemistry, and bulk chemical data of the coarse‐grained clast indicate that the CG clasts were originally a cumulate rock crystallized in a crust of the parent body. However, in contrast to monomict eucrites, the siderophile elements are highly enriched and could have been introduced by impact events. Dhofar 007 appears to have experienced a two‐stage postcrystallization thermal history: rapid cooling at high temperatures and slow cooling at lower temperatures. The presence of pigeonite with closely spaced, fine augite lamellae suggests that this rock was cooled rapidly from higher temperatures (>0.5 °C/yr at ˜1000 °C) than typical cumulate eucrites. However, the presence of the cloudy zone in taenite and the Ni profile across the kamacite‐taenite boundaries indicates that the cooling rate was very slow at lower temperatures (˜1–10 °C/Myr at <600–700 °C). The slow cooling rate is comparable to those in mesosiderites and pallasites. The two‐stage thermal history and the relative abundance of siderophile elements similar to those for metallic portions in mesosiderites suggest that Dhofar 007 is a large inclusion of mesosiderite. However, we cannot rule out a possibility that Dhofar 007 is an anomalous eucrite.  相似文献   

Changes in fish community in seagrass beds in Mangoku-ura Bay from 2009 to 2014, the period before and after the tsunami following the 2011 off the Pacific coast of Tohoku earthquake     

Jun Shoji  Mitsuru Morimoto 《Journal of Oceanography》2016,72(1):91-98

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Analysis of change of red tide species in Yodo River estuary by the numerical ecosystem model     

Hayashi M  Yanagi T 《Marine pollution bulletin》2008,57(1-5):103-107

Occurrence number of red tides in Osaka Bay in Japan is more than 20 cases every year. Diatom red tide was dominant in Osaka Bay, but the non-diatom red tide was dominant in early 1990s. Therefore, the material cycling in Yodo River estuary in Osaka Bay during August from 1991 to 2000 was analyzed by using the numerical ecosystem model and field observation data to clarify the reasons of change in red tide species. Year-to-year variation in calculated concentration ratio of diatom to non-diatom corresponds to the variation in observed ratio of red tide days of diatom to non-diatom. Limiting nutrient of primary production is phosphate over the period. Diatom dominated from 1991 to 1993, but it was difficult for non-diatom to grow due to the limitation by physical condition. Non-diatom was able to grow because of good physical and nutrient conditions from 1994 to 1996. And diatom dominated again under the good physical condition, and phosphorus supply was not enough for non-diatom to grow from 1998 to 2000. Phosphate concentration in the lower layer of Yodo River estuary was important to the variation in red tide species in the upper layer of Yodo River estuary.  相似文献   

Transformation of arsenic compounds in modern intertidal sediments of Iriomote Island, Japan   总被引：1，自引：0，他引：1  

Harue Masuda  Yoshito Yamatani  Mitsuru Okai   《Journal of Geochemical Exploration》2005,87(2):587-81

The arsenic accumulation process in intertidal sediments of Iriomote Island, Japan, is analyzed as a naturally balanced arsenic-fixation system. Major and minor element chemistry is analyzed by X-ray fluorescence photometry, mineralogy is investigated by X-ray diffractometry, and four arsenic compounds are characterized by hydrogen-generated atomic absorption photometry. It is found that arsenic is accumulated by iron hydroxides/oxides precipitated following the decomposition of humic acids in the shallower sediment, and is subsequently incorporated into iron sulfide minerals at depth. The arsenic is immobile during incorporation into arsenic-bearing phases, suggesting that arsenic is unlikely to be released into the porewater under natural conditions in early diagenesis. The formation and decomposition of arsenic-bearing organic compounds appear to be associated with the formation and decomposition of arsenic in oxyhydroxides/oxides, suggesting that microbial activity may play an important role in controlling the behavior of arsenic and arsenic-bearing phases in the sediment column.  相似文献   

Are C1 chondrites chemically fractionated? a trace element study     

Mitsuru Ebihara  Rainer Wolf  Edward Anders 《Geochimica et cosmochimica acta》1982,46(10):1849-1861

Six C1 chondrite samples and a C2 xenolith from the Plainview H5 chondrite were analyzed by radiochemical neutron activation for the elements Ag, Au, Bi, Br, Cd, Ce, Cs, Eu, Ge, In, Ir, Lu, Nd, Ni, Os, Pd, Pt, Rb, Re, Sb, Se, Sn, Tb, Te, Tl, Yb, and Zn. The data were combined with 9 earlier analyses from this laboratory and examined for evidence of chemical fractionation in C1 chondrites.A number of elements (Br, Rb, Cs, Au, Re, Os, Ni, Pd, Sb, Bi, In, Te) show small but correlated variations. Those of the first 8 probably reflect hydrothermal alteration in the meteorite parent body, whereas those of Sb, Bi, In, and Te may at least in part involve nebular processes. Br and Au show systematic abundance differences from meteorite to meteorite, which suggests hydrothermal transport on a kilometer scale. The remaining elements vary from sample to sample, suggesting transport on a centimeter scale.There is no conclusive evidence for nebular fractionation affecting C1 's. Though C1 chondrites have lower $\text{Zr}\text{Hf}$ and $\text{Ir}\text{Re}$ ratios than do other chondrite classes, these ratios vary in other classes, suggesting that those classes rather than C1's are fractionated. Three fractionation-prone REE—Ce, Eu, and Yb have essentially the same relative abundances in C1's and all other chondrite classes, and hence apparently are not fractionated in C1's. We did not confirm the large Tb and Yb variations in C1's reported by other workers.We present revised mean C1 abundances for 35 elements, based on the new data and a critical selection of literature data. Changes are generally less than 10%, except for Br, Rb, Ag, Sb, Te, Au, and the REE.The Plainview C2 xenolith has normal trace element abundances, except for 3 elements falling appreciably above the C2 range: Rb, Cs, and Bi. Hydrothermal alteration may be the reason for all 3, though nebular fractionation remains a possibility for Bi.  相似文献   

两个相连湖泊的微生态系统——云南高原湖泊中浅水的星云湖和深水的抚仙湖研究   总被引：4，自引：0，他引：4  

大久保贤治  熊谷道夫  坂本充  宋学良  张子雄 《云南地理环境研究》2002,14(2):10-19

抚仙湖是中国云南省的一个深水湖，连接着富营养化的浅水湖－－星云湖，星云湖排放含绿藻的水进入抚仙湖。两湖位于省会昆明附近，由于地方文化、集约化农业、以及旅游业的发展，两湖已经富营养化。因为湖泊体积容量的级别差异，深水湖的富营养化几乎没被注意，抚仙湖秋季下层滞水带缺氧已经关注了20年，似乎下层滞水带是深水湖富营养化的指标或趋势。抚仙湖看起来目前情况尚好，可以说寡营养，然而，外界负荷是潜在的，且是以稳定的加速度进行的。在此对浅水湖富营养化的原因进行了讨论，包括在其它云南湖泊观察到富营养化的过程，再者，对两个连相湖的藻和蓝藻碎片的大小构成进行比照。为了与深水的抚仙湖状况进行比较，简略介绍了一个日本的深湖及其径流系统。其中，涡流和它的微生态系统，在两者中相关性很好。对于以涡流生态系统的见解判断微生态系统的深水湖富营养化问题将给予概括。  相似文献   

Effect of subsurface water level on gully headcut retreat in tropical highlands of Ethiopia     

Mesenbet Yibeltal  Atsushi Tsunekawa  Nigussie Haregeweyn  Enyew Adgo  Derege Tsegaye Meshesha  Tsugiyuki Masunaga  Mitsuru Tsubo  Paolo Billi  Kindiye Ebabu  Mulatu Liyew Berihun 《地球表面变化过程与地形》2021,46(6):1209-1222

Gully erosion is a major cause of soil loss and severe land degradation in sub-humid Ethiopia. The objective of this study was to investigate the role and the effect of subsurface water level change on gully headcut retreat, gully formation and expansion in high rainfall tropical regions in the Ethiopian highlands. During the rainy seasons of 2017–2019, the expansion rate of 16 fixed gullies was measured and subsurface water levels were measured by piezometers installed near gully heads. During the study period, headcut retreats ranged from 0.70 to 2.35 m, with a mean value of 1.49 ± 0.56 m year⁻¹, and average depth of the surface water level varied between 1.12 and 2.82 m, with a mean value of 2.62 m. Gully cross-section areas ranged from 2.90 to 20.90 m², with an average of 9.31 ± 4.80 m². Volumetric retreat of gully headcuts ranged from 4.49 to 40.55 m³ and averaged 13.34 ± 9.10 m³. Soil loss from individual gullies ranged from 5.79 to 52.31 t year⁻¹ and averaged 17.21 ± 11.74 t year⁻¹. The headcut retreat rate and sediment yield were closely related over the three study seasons. Elevated subsurface water levels facilitated the slumping of gully banks and heads, causing high sediment yield. When the soil was saturated, bank collapse and headcut retreat were favoured by the combination of elevated subsurface water and high rainfall. This study indicates that area exclosures are effective in controlling subsurface water level, thus reducing gully headcut retreat and associated soil loss.  相似文献   

Chemical characteristics of the lherzolitic shergottite Yamato 000097: magmatism on Mars inferred from the chemical compositions of shergottites   总被引：1，自引：1，他引：0  

Naoki Shirai  Mitsuru Ebihara 《Polar Science》2009,3(2):117-133

As a part of a consortium study, we analyzed the Martian meteorite Yamato (Y) 000097 by prompt gamma-ray analysis, instrumental neutron activation analysis, and instrumental photon activation analysis. For comparison, we also analyzed Allan Hills (ALH) 77005 using the same methods. The data confirm that Y000097 belongs to lherzolitic shergottites in terms of chemical composition. Although there exist slight differences in elemental abundances among lherzolitic shergottites due to differences in the modal abundances of constituent minerals, they have essentially the same chemical compositions, suggesting they are genetically related and experienced similar formation histories.Zr/Hf ratios obtained for Y000097 and ALH 77005 are subchondritic, consistent with values reported for other lherzolitic shergottites and olivine-phyric shergottites. Such fractionation can be explained by invoking clinopyroxene, ilmenite, or majorite in the petrogenesis of the shergottites' source material. CI-normalized Hf/Sm ratios obtained for Y000097 and ALH 77005 are 1.52 and 1.37, respectively, consistent with superchondritic Hf/Sm ratios reported for shergottites. Based on experimentally derived partition coefficients, majorite is the best candidate mineral for the fractionation of Hf and Sm in shergottites.  相似文献   

Evaluating spatial and temporal variations of rainfall erosivity,case of Central Rift Valley of Ethiopia   总被引：1，自引：0，他引：1  

Derege Tsegaye Meshesha  Atsushi Tsunekawa  Mitsuru Tsubo  Nigussie Haregeweyn  Enyew Adgo 《Theoretical and Applied Climatology》2015,119(3-4):515-522

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