Trace-element composition and zoning in clinopyroxene- and amphibole-group minerals: Implications for element partitioning and evolution of carbonatites     

Ekaterina P. Reguir  Anton R. Chakhmouradian  Laura Pisiak  Norman M. Halden  Panseok Yang  Cheng Xu  Jindřich Kynický  Chris G. Couëslan 《Lithos》2012

The present work is a first comprehensive study of the trace-element composition and zoning in clinopyroxene- and amphibole-group minerals from carbonatites, incorporating samples from 14 localities worldwide (Afrikanda, Aley, Alnö, Blue River, Eden Lake, Huayangchuan, Murun, Oka, Ozernaya Varaka, Ozernyi, Paint Lake, Pinghe, Prairie Lake, Turiy Mys). The new electron-microprobe data presented here significantly extend the known compositional range of clinopyroxenes and amphiboles from carbonatites. These data confirm that calcic and sodic clinopyroxenes from carbonatites are not separated by a compositional gap, instead forming an arcuate trend from nearly pure diopside through intermediate aegirine–augite compositions confined to a limited range of CaFeSi₂O₆ contents (15–45 mol%) to aegirine with < 25 mol% of CaMgSi₂O₆ and a negligible proportion of CaFeSi₂O₆. A large set of LA-ICPMS data shows that the clinopyroxenes of different composition are characterized by relatively low levels of Cr, Co and Ni (≤ 40 ppm) and manifold variations in the concentration of trivalent lithophile and some incompatible elements (1–150 ppm Sc, 26–6870 ppm V, 5–550 ppm Sr, 90–2360 ppm Zr, and nil to 150 ppm REE), recorded in some cases within a single crystal. The relative contribution of clinopyroxenes to the whole-rock Rb, Nb, Ta, Th and U budget is negligible. The major-element compositional range of amphiboles spans from alkali- and Al-poor members (tremolite) to Na–Al-rich Mg- or, less commonly, Fe-dominant members (magnesiohastingsite, hastingsite and pargasite), to calcic–sodic, sodic and potassic–sodic compositions intermediate between magnesio-ferrikatophorite, richterite, magnesioriebeckite, ferri-nyböite and (potassic-)magnesio-arfvedsonite. In comparison with the clinopyroxenes, the amphiboles contain similar levels of tetravalent high-field-strength elements (Ti, Zr and Hf) and compatible transition elements (Cr, Co and Ni), but are capable of incorporating much higher concentrations of Sc and incompatible elements (up to 500 ppm Sc, 43 ppm Rb, 1470 ppm Sr, 1230 ppm Ba, 80 ppm Pb, 1070 ppm REE, 140 ppm Y, and 180 ppm Nb). In some carbonatites, amphiboles contribute as much as 25% of the Zr + Hf, 15% of the Sr and 35% of the Rb + Ba whole-rock budget. Both clinopyroxenes and amphiboles may also host a significant share (~ 10%) of the bulk heavy-REE content. Our trace-element data show that the partitioning of REE between clinopyroxene (and, in some samples, amphibole) and the melt is clearly bimodal and requires a revision of the existing models assuming single-site REE partitioning. Clinopyroxenes and amphiboles from carbonatites exhibit a diversity of zoning patterns that cannot be explained exclusively on the basis of crystal chemistry and relative compatibility of different trace-element in these minerals. Paragenetic analysis indicates that in most cases, the observed zoning patterns develop in response to removal of selected trace elements by phases co-precipitating with clinopyroxene and amphibole (especially magnetite, fluorapatite, phlogopite and pyrochlore). With the exception of magnesiohastingsite–richterite sample from Afrikanda, the invariability of trace-element ratios in the majority of zoned clinopyroxene and amphibole crystals implies that fluids are not involved in the development of zoning in these minerals. The implications of the new trace-element data for mineral exploration targeting REE, Nb and other types of carbonatite-hosted rare-metal mineralization are discussed.  相似文献   

Cytochrome P4501A biomarker indication of the timeline of chronic exposure of Barrow's goldeneyes to residual Exxon Valdez oil     

Esler D  Ballachey BE  Trust KA  Iverson SA  Reed JA  Miles AK  Henderson JD  Woodin BR  Stegeman JJ  McAdie M  Mulcahy DM  Wilson BW 《Marine pollution bulletin》2011,62(3):609-614

We examined hepatic EROD activity, as an indicator of CYP1A induction, in Barrow’s goldeneyes captured in areas oiled during the 1989 Exxon Valdez spill and those from nearby unoiled areas. We found that average EROD activity differed between areas during 2005, although the magnitude of the difference was reduced relative to a previous study from 1996/1997, and we found that areas did not differ by 2009. Similarly, we found that the proportion of individuals captured from oiled areas with elevated EROD activity (?2 times unoiled average) declined from 41% in winter 1996/1997 to 10% in 2005 and 15% in 2009. This work adds to a body of literature describing the timelines over which vertebrates were exposed to residual Exxon Valdez oil and indicates that, for Barrow’s goldeneyes in Prince William Sound, exposure persisted for many years with evidence of substantially reduced exposure by 2 decades after the spill.  相似文献   

Granitic magmatism,basement ages,and provenance indicators in the Malay Peninsula: Insights from detrital zircon U–Pb and Hf-isotope data     

Inga Sevastjanova  Benjamin Clements  Robert Hall  Elena A. Belousova  William L. Griffin  Norman Pearson 《Gondwana Research》2011,19(4):1024-1039

The Malay Peninsula lies on two continental blocks, Sibumasu and East Malaya, which are intruded by granitoids in two provinces: the Main Range and Eastern. Previous models propose that Permian–Triassic granitoids are subduction-related and syn-to post-collisional. We present 752 U–Pb analyses that were carried out on zircons from river sands in the Malay Peninsula; of these, 243 grains were selected for Hf-isotope analyses. Our data suggest a more complex Sibumasu–East Malaya collision history. ¹⁷⁶Hf/¹⁷⁷Hf_i ratios reveal that Permian–Triassic zircons were sourced from three magmatic suites: (a) Permian crustally-derived granitoids, (b) Early-Middle Triassic granitoids with mixed mantle–crust sources, and (c) Late Triassic crustally-derived granitoids. This suggests three Permian–Triassic episodes of magmatism in the Malay Peninsula, two of which occurred in the Eastern Province. Although the exact timing of the Sibumasu–East Malaya collision remains unresolved, current data suggest that it occurred before the Late Triassic, probably in Late Permian–Early Triassic. Our data also indicate that Sibumasu and East Malaya basements are chronologically heterogeneous, but predominantly of Proterozoic age. Some basement may be Neoarchaean but there is no evidence for basement older than 2.8 Ga. Finally, we show that Hf-isotope signatures of Triassic zircons can be used as provenance indicators.  相似文献   

Uranium and Thorium Concentration and Isotopic Composition in Five Glass (BHVO‐2G,BCR‐2G,NKT‐1G,T1‐G,ATHO‐G) and Two Powder (BHVO‐2, BCR‐2) Reference Materials     

Kathryn A. Matthews  Michael T. Murrell  Steven J. Goldstein  Andrew J. Nunn  Deborah E. Norman 《Geostandards and Geoanalytical Research》2011,35(2):227-234

Here we report uranium and thorium isotopic ratios and elemental concentrations measured in solid reference materials from the USGS (BHVO‐2G, BCR‐2G, NKT‐1G), as well as those from the MPI‐DING series (T1‐G, ATHO‐G). Specifically created for microanalysis, these naturally‐sourced glasses were fused from rock powders. They cover a range of compositions, elemental concentrations and expected isotopic ratios. The U‐Th isotopic ratios of two powdered source materials (BCR‐2, BHVO‐2) were also characterised. These new measurements via multi‐collector thermal ionisation mass spectrometry and multi‐collector inductively coupled plasma‐mass spectrometry can now be used to assess the relative performance of techniques and facilitate comparison of U‐Th data amongst laboratories in the geoscience community for in situ and bulk analyses.  相似文献   

A Comparative Study of Five Reference Materials and the Lombard Meteorite for the Determination of the Platinum‐Group Elements and Gold by LA‐ICP‐MS     

Sarah Gilbert  Leonid Danyushevsky  Philip Robinson  Cora Wohlgemuth‐Ueberwasser  Norman Pearson  Dany Savard  Marc Norman  Jacob Hanley 《Geostandards and Geoanalytical Research》2013,37(1):51-64

A range of independently characterised reference materials (RMs) for LA‐ICP‐MS, used for the determination of the platinum‐group elements (PGE) and Au in a sulfide matrix, were analysed and compared: 8b, PGE‐A, NiS‐3, Po727‐T1, Po724‐T and the Lombard meteorite. The newly developed RM NiS‐3 was used as the RM for the calibration of all LA‐ICP‐MS analyses and the measured concentrations of the other RMs compared against their published concentrations. This data were also used to assess the consistency of concentrations calibrated against the different RMs. It was found that Po727‐T1 and 8b produced results that were comparable, within uncertainty, for all elements. Po727‐T1 also produced consistent results with NiS‐3 for all elements. All other RMs showed differences for some elements, especially Ru in Po724‐T, and Os, Ir and Au in PGE‐A. The homogeneity of the PGE and Au in each RM was assessed, by comparing the precision of multiple LA‐ICP‐MS spot analyses with the average uncertainty of the signal. Po724‐T, Po727‐T1 and the Lombard meteorite were found to be homogeneous for all elements, but 8b, PGE‐A and NiS‐3 were heterogeneous for some elements. This is the first direct comparison between a range of independently characterised PGE and Au LA‐ICP‐MS RMs.  相似文献   

Elevation adjustments of paired natural levees during flooding of the Saskatchewan River     

Norman D. Smith  Marta Pérez‐Arlucea  Douglas A. Edmonds  Rudy L. Slingerland 《地球表面变化过程与地形》2009,34(8):1060-1068

Natural levees control the exchange of water between an alluvial channel and its floodplain, but little is known about the spatial distribution and evolution of levee heights. The summer 2005 flood of the Saskatchewan River (Cumberland Marshes, east‐central Saskatchewan) inundated large areas of floodplain for up to seven weeks, forming prominent new deposits on natural levees along main‐stem channels. Measurements of flood‐deposit thickness and crest heights of 61 levee pairs show that the thickest deposits occur on the lower pre‐flood levee in 80% of the sites, though no clear relationship exists between deposit thickness and magnitude of height difference. Only 16% of the pairs displayed thicker deposits on the higher levee, half of which occurred at sites where relatively clear floodbasin waters re‐entered turbid channels during general flooding. Difference in crest elevation (ΔE) between paired levees is approximately log‐normally distributed, both before and after the flood, though with different mean values. Supplemental observations from tank experiments indicate that during near‐bankfull flows, temporally and spatially variable deposition and erosion occur on levees due to backwater effects associated with nearby channel bars and irregular rises of the channel bed forced by channel extension. During floods, preferential deposition in lows tends to even out crest heights. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Truncation of the distribution of ground-motion residuals   总被引：4，自引：3，他引：1  

Fleur O. Strasser  Julian J. Bommer  Norman A. Abrahamson 《Journal of Seismology》2008,12(1):79-105

Recent studies to assess very long-term seismic hazard in the USA and in Europe have highlighted the importance of the upper tail of the ground-motion distribution at the very low annual frequencies of exceedance required by these projects. In particular, the use of an unbounded lognormal distribution to represent the aleatory variability of ground motions leads to very high and potentially unphysical estimates of the expected level of shaking. Current practice in seismic hazard analysis consists of truncating the ground-motion distribution at a fixed number (ε _max) of standard deviations (σ). However, there is a general lack of consensus regarding the truncation level to adopt. This paper investigates whether a physical basis for choosing ε _max can be found, by examining records with large positive residuals from the dataset used to derive one of the ground-motion models of the Next Generation Attenuation (NGA) project. In particular, interpretations of the selected records in terms of causative physical mechanisms are reviewed. This leads to the conclusion that even in well-documented cases, it is not possible to establish a robust correlation between specific physical mechanisms and large values of the residuals, and thus obtain direct physical constraints on ε _max. Alternative approaches based on absolute levels of ground motion and numerical simulations are discussed. However, the choice of ε _max is likely to remain a matter of judgment for the foreseeable future, in view of the large epistemic uncertainties associated with these alternatives. Additional issues arise from the coupling between ε _max and σ, which causes the truncation level in terms of absolute ground motion to be dependent on the predictive equation used. Furthermore, the absolute truncation level implied by ε _max will also be affected if σ is reduced significantly. These factors contribute to rendering a truncation scheme based on a single ε _max value impractical.  相似文献   

On topographic coupling of surface and internal tides     

Peter G. Baines  John W. Miles 《Deep Sea Research Part I: Oceanographic Research Papers》2000,47(12):124

The problem of the generation of internal tides through the interaction of surface tides with oceanic bottom topography is re-examined, taking into account the horizontal components of the Earth's rotation. It is shown that previous models that have omitted these terms may be readily extended to include them, and changes in the magnitude and character of the barotropic to baroclinic conversion are estimated. For semi-diurnal tides the energy conversion is increased, but only by about 2%. However, the character of the waves differs at high latitudes, where the phase and location of the wave energy may change by as much as 14%. Accordingly, inclusion of these terms is recommended in future studies with these models.  相似文献   

On viscoelastic eddy viscosity for flow over a wavy surface     

John Miles 《Boundary-Layer Meteorology》1996,79(1-2):177-179

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An Analytic Model For A Mantle Plume Fed By A Boundary Layer     

Norman H. Sleep 《Geophysical Journal International》1987,90(1):119-128

Summary. An approximate analytical solution for flow in a mantle plume of constant radius, viscosity, and density contrast is obtained in cylindrical coordinates. the differential equations for vertical velocity of the mantle surrounding the plume and for topography are homologous to the equation for flexure of an elastic plate. Although the model is too simple to be fully applicable to the Earth, one can conclude that the vertical velocity in the mantle changes significantly away from plumes, that the viscosity of the plume is important for controlling flow rate, and that the long-wavelength geoid anomalies are sensitive to the viscosity of the surrounding mantle. the first induced upwelling away from a plume is quite weak and unlikely to control the spacing of plumes.  相似文献