Hydrocarbons generated by hydropyrolysis of suspended marine particulate organic matter: Relationship to the oceanography of the Black Sea and the Rhodes Gyre     

Yeşim Çoban-Yildiz  Alec F. Gaines  Pat E. Keating  Gordon D. Love  Dennis McLoughlin  Colin E. Snape 《Organic Geochemistry》2009,40(2):270-282

The suspended particulate organic matter, SPOM, in the autumnal Black Sea has been characterised using catalytic hydropyrolysis (HyPy) of the total (bound plus free) lipid material. The technique, which generates maximum yields of volatile products from sediments, kerogens and phytoplankton, was followed using gas chromatography and gas chromatography/mass spectrometry. The generated alkanes were dominated by n-C₁₈, hypothesised to arise predominantly from unsaturated C₁₈ fatty acids. Steranes were generated from reductive conversion of free and bound sterols. The generation of branched alkanes and especially of hopanes provided formal evidence for the participation of bacteria in the mineralisation of the SPOM. Whereas similar distributions of n-alkanes were generated from SPOM sampled from different depths of the comparatively well-stirred Rhodes Gyre (eastern Mediterranean), mineralisation of the SPOM at each depth of the central Black Sea produced characteristic changes in the composition and concentration of the HyPy products. Depth profiles of the n-alkanes generated from SPOM in the region of the Rim Current were affected by the local hydrography. Polynuclear aromatic hydrocarbons (PAHs) of anthropogenic origin were present in the surface waters of the central Black Sea. Some methyl benzenes, thiophenes and pyrroles were also generated.  相似文献   

A New Statistical Perspective on Trophic Indexes for Shallow Lakes     

Köklü  Rabia  Alkış  Ayşenur 《Water Resources》2021,48(2):324-330

Water Resources - The aim of this study is to develop a new trophic level index using water quality parameters which are known to affect eutrophication but not in national and international...  相似文献   

Sediment transport at the network scale and its link to channel morphology in the braided Vjosa River system     

Simone Bizzi  Marco Tangi  Rafael J. P. Schmitt  John Pitlick  Hervé Piégay  Andrea Francesco Castelletti 《地球表面变化过程与地形》2021,46(14):2946-2962

In this article we apply the CASCADE network-scale sediment connectivity model to the Vjosa River in Albania. The Vjosa is one of the last unimpaired braided rivers in Europe and, at the same time, a data scarce environment, which limits our ability to model how this pristine river might respond to future human disturbance. To initialize the model, we use remotely sensed data and modeled hydrology from a regional model. We perform a reach-by-reach optimization of surface grain size distribution (GSD) and bedload transport capacity to ensure equilibrium conditions throughout the network. In order to account for the various sources of uncertainty in the calculation of transport capacity, we performed a global sensitivity analysis. The modeled GSD distributions generated by the sensitivity analysis generally match the six GSDs measured at different locations within the network. The modeled bedload sediment fluxes increase systematically downstream, and annual fluxes at the outlet of the Vjosa are well within an order of magnitude of fluxes derived from previous estimates of the annual suspended sediment load. We then use the modeled sediment fluxes as input to a set of theoretically derived functions that successfully discriminate between multi-thread and single-thread channel patterns. This finding provides additional validation of the model results by showing a clear connection between modeled sediment concentrations and observed river morphology. Finally, we observe that a reduction in sediment flux of about 50% (e.g., due to dams) would likely cause existing braided reaches to shift toward single thread morphology. The proposed method is widely applicable and opens a new avenue for application of network-scale sediment models that aid in the exploration of river stability to changes in water and sediment fluxes.  相似文献   

Warming the early earth—CO₂ reconsidered     

Philip von Paris  Heike Rauer  J. Lee Grenfell  Beate Patzer  Barbara Stracke  Franz Schreier 《Planetary and Space Science》2008,56(9):1244-1259

Despite a fainter Sun, the surface of the early Earth was mostly ice-free. Proposed solutions to this so-called “faint young Sun problem” have usually involved higher amounts of greenhouse gases than present in the modern-day atmosphere. However, geological evidence seemed to indicate that the atmospheric CO₂ concentrations during the Archaean and Proterozoic were far too low to keep the surface from freezing. With a radiative-convective model including new, updated thermal absorption coefficients, we found that the amount of CO₂ necessary to obtain 273 K at the surface is reduced up to an order of magnitude compared to previous studies. For the late Archaean and early Proterozoic period of the Earth, we calculate that CO₂ partial pressures of only about 2.9 mb are required to keep its surface from freezing which is compatible with the amount inferred from sediment studies. This conclusion was not significantly changed when we varied model parameters such as relative humidity or surface albedo, obtaining CO₂ partial pressures for the late Archaean between 1.5 and 5.5 mb. Thus, the contradiction between sediment data and model results disappears for the late Archaean and early proterozoic.  相似文献   

Top-down approach to design the relief system in a metropolitan city using UAV technology,part I: the first 48 h     

Vizvári  Béla  Golabi  Mahmoud  Nedjati  Arman  Gümüşbuğa  Ferhat  Izbirak  Gokhan 《Natural Hazards》2019,99(1):571-597

Natural Hazards - In this study, a relief system for a large metropolitan city exposed to serious earthquakes is designed and a top-down approach is applied. Afflicted people’s states and...  相似文献   

Precipitable water vapor (PWV) estimations from the site of the Eastern Anatolia Observatory<Superscript>∗</Superscript> (DAG), a new astronomical observatory in Turkey     

Sacit Özdemir  Cahit Yeşilyaprak  Bahadır Aktuğ  Derya Öztürk  Deniz Çoker  Recep Balbay 《Experimental Astronomy》2018,46(2):323-336

We present preliminary statistics on the precipitable water vapor (PWV) content over the Karakaya Hills in Erzurum city, where the largest optical and near-infrared astronomical telescope in Turkey will be operated. Since the observatory will observe in the near-infrared (NIR), it is intended to perform PWV measurements of the atmosphere above the site by using signal delays in Global Positioning System (GPS) communication. The analysis of the GPS data recorded on the summit for almost one year shows that the atmosphere over the site of the observatory, which has an altitude of 3170 m, has favorable conditions for NIR observations. From GPS measurements, we report that the site had an average PWV of 3.2 mm and a median PWV of 2.7 mm between October 6, 2016, and June 15, 2017. We also present the time dependency of the PWV content and the correlations between the amount of PWV and the other meteorological records gathered from radiosonde flights and ground-based measurements.  相似文献   

绝对重力仪激光器光纤对准调节方法概述     

任敏拴  商永杰  郑文科  康胜军  赵丕 《大地测量与地球动力学》2020,40(9):981-984

绝对重力仪激光器光纤由于应力变化、形状改变、震动或耦合器维护等原因破坏了输出激光的偏振态,使其在光纤内的传输变得非常不稳定,导致光纤输出激光的消光比值小于100,无法满足绝对重力观测条件。针对该问题,介绍了光纤对准调节的方法,通过设计消光比检测装置检验消光比值是否大于100。对#181和#250两台WEO100型He-Ne激光器的光纤进行对准调节实验,并通过消光比检测装置实测,两台激光器输出的光束消光比值满足绝对重力测量的条件,表明该对准调节方法科学有效。  相似文献   

LA COMPOSITION MINERALOGIQUE ET CHIMIQUE DES ROCHES ERUPTIVES ET PARTICULIEREMENT DES LAVES MESOZOIQUES ET PLUS RECENTES DE LA CHINE ORIENTALE Par A. Lacroix.     

Par A.Lacroix 《地质学报》1928,7(1):13-59

Au cours d'un voyage en Chine, effectue en decembre 1927, j'al eu I'honneur et le plaisir d'etre recu a Peking par la Societe geologique de Chine et d'etre ainsi le temoin de sa grande activite scientifique. Aussi, je tiens a lui offrir le resultat de l'etude mineralogique et chimique des roches que j'ai  相似文献   

Hydrochemical and isotopic properties of the Mahmutlu and Bağdatoğlu mineralized thermal springs, Kırşehir, Turkey     

N. Ünsal  M. Afşin 《Hydrogeology Journal》1999,7(6):540-545

The present study identifies the hydrochemical and isotopic properties of the Mahmutlu and Ba?dato?lu mineralized thermal springs in K?r?ehir province, a geothermal field in central Anatolia, Turkey. Based on these properties, a hydrogeological regime is proposed in order to explain the Mahmutlu–Ba?dato?lu geothermal system. The relation between the concentrations of the environmental stable isotopes deuterium and oxygen-18 in the water is similar to the relationship in global meteoric water, indicating that the water is of meteoric origin. Evaluation of the geochemical characteristics of the water reveals that these two thermal springs belong to the same hydrogeological system. The hydrogeological system comprises a fractured limestone member of the Çevirme Formation and the Kervansaray Formation as reservoir rocks, and the Delice?rmak Formation as an overlying aquitard. The waters of the Mahmutlu and Ba?dato?lu springs are mainly of the Na-Cl-SO4 type that originate from the Pohrenk evaporite. The thermal waters are undersaturated with respect to calcite, dolomite, halite, and gypsum. The δ 18O and δ 2H contents indicate a δ 18O shift in the Mahmutlu and Ba?dato?lu waters. The temperature range of the two reservoirs is estimated to be 98–158?°C, on the basis of Na+K+Ca and SiO2 geothermometers.  相似文献   

Assessment of a new solution for tracking pebbles in rivers based on active RFID          下载免费PDF全文

Mathieu Cassel  Thomas Dépret  Hervé Piégay 《地球表面变化过程与地形》2017,42(13):1938-1951

Low‐frequency passive integrated transponders (PIT tags), are commonly used for monitoring pebble mobility in gravel‐bed rivers. Although early studies reported high recovery rates for PIT tags used in small streams, recovery rates in larger systems remain low, substantially limiting the possibilities for their use in such rivers. These low recovery rates are potentially due to missed detections caused by tag signal collision, burial in the sediment layer deeper than the maximum detection range and insufficient (but still exhausting) field effort to cover the concerned areas. A potential solution for addressing these problems is to use active ultra‐high frequency (a‐UHF) transponders as these have a greater detection range and anti‐collision protocols. In order to assess the potential of such transponders for pebble tracking in rivers, we used 433.92 MHz COIN‐ID and COIN‐HC models (ELA Innovation Company, Montpellier, France). We completed several tests to (i) characterize transponder detection ranges in the water and in saturated sediment and (ii) develop field protocols for locating tags by combining global positioning systems (GPS) sites and transponder received signal strength indication (RSSI) levels. The results showed that (i) the maximum detection ranges are about 2.4 m in the water column and more than 2.6 m in a column of saturated gravelly‐sandy sediment, (ii) RSSI spatial interpolation can be used to determine transponder position with good accuracy (< 1 m), (iii) the desired minimal level of accuracy can be adjusted depending on in‐field effort and signal impulse interval, (iv) the RSSI maximal value observed cannot yet be used to determine transponder burial depth because of the multipath propagation of radio frequencies and the semi‐directional emission of the tag signal. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献