Dissolution–precipitation processes governing the carbonation and silicification of the serpentinite sole of the New Caledonia ophiolite     

Marc?UlrichEmail author  Manuel?Mu?oz  Stéphane?Guillot  Michel?Cathelineau  Christian?Picard  Benoit?Quesnel  Philippe?Boulvais  Clément?Couteau 《Contributions to Mineralogy and Petrology》2014,167(1):952

The weathering of mantle peridotite tectonically exposed to the atmosphere leads commonly to natural carbonation processes. Extensive cryptocrystalline magnesite veins and stock-work are widespread in the serpentinite sole of the New Caledonia ophiolite. Silica is systematically associated with magnesite. It is commonly admitted that Mg and Si are released during the laterization of overlying peridotites. Thus, the occurrence of these veins is generally attributed to a per descensum mechanism that involves the infiltration of meteoric waters enriched in dissolved atmospheric CO₂. In this study, we investigate serpentinite carbonation processes, and related silicification, based on a detailed petrographic and crystal chemical study of serpentinites. The relationships between serpentine and alteration products are described using an original method for the analysis of micro-X-ray fluorescence images performed at the centimeter scale. Our investigations highlight a carbonation mechanism, together with precipitation of amorphous silica and sepiolite, based on a dissolution–precipitation process. In contrast with the per descensum Mg/Si-enrichment model that is mainly concentrated in rock fractures, dissolution–precipitation process is much more pervasive. Thus, although the texture of rocks remains relatively preserved, this process extends more widely into the rock and may represent a major part of total carbonation of the ophiolite.  相似文献   

The Greenland ice sheet and greenhouse warming     

Philippe Huybrechts  Anne Letreguilly  Niels Reeh 《Global and Planetary Change》1991,3(4)

Increased melting on glaciers and ice sheets and rising sea level are often mentioned as important aspects of the anticipated greenhouse warming of the earth's atmosphere. This paper deals with the sensitivity of Greenland's ice mass budget and presents a tentative projection of the Greenland component of future sea level rise for the next few hundred years. To do this, the ‘Villach II temperature scenario’ is prescribed,output from a comprehensive mass balance model is used to drive a high-resolution 3-D thermomechanic model of the ice sheet.The mass balance model consists of two parts: the accumulation part is based on presently observed values and is forced by changes in mean anr tempeerature. The ablation model is based on the degree-day method and accounts for daily and annual temperature cycle, a different degree-day factor for ice and snow melting and superimposed ice formation. Under present-day climatic conditions, the following total mass balance results (in ice equivalent per years): 599.3 × 10⁹ m³ of accumulation, 281.7 × 10⁹m³ of runoff assuming a balanced budget, 317.6 × 10⁹m³ of iceberg calving. A 1K uniform warming is then calculated to increase the runoff by 119.5 × 10⁹ m³. Since accumulation also increases by 32 × 10⁹ m³, this leads to reduction of the total mass balance by 887.5 × 10⁹ m³ of ice, corresponding to a sea level rise of 0.22 mm/yr. For temperature increase larger than 2.7 K, runoff, exceeds accumulation, and if ice sheet dynamics were to remain unchanged, this would add an extra amount of 0.8 mmyr to the worl's oceans.Imposing the Villach II scenario (warming up to 4.23 K) and accumulating mass balance changes forward in time (static response) would then result in a global sea level rise of 7.1 cm by 2100 AD, but this figure may go up to as much as 40 cm per century in case the warming is doubled. In a subsequent dynamic model involving the ice flow, the ice sheet is found to produce a counteracting effect by dynamically producing steeper slopes at the margin, thereby reducing the area over which runoff can take place. This effect is particularly apparent in the northeastern part of the ice sheet, and is also more pronounced for the smaller temperature perturbations. Nevertheless, all these experiments certainly highlight the vulnerability of the Greenland ice sheet with respect to a climatic warming.  相似文献   

A mass‐balance approach to estimate in‐stream processes in a large river     

Samuel Teissier  Sabine Sauvage  Philippe Vervier  Frédéric Garabétian  José‐Miguel Sánchez‐Pérez 《水文研究》2008,22(3):420-428

A mass‐balance approach was used to estimate in‐stream processes related to inorganic nitrogen species (NH₄⁺, NO₂^? and NO₃^?) in a large river characterized by highly variable hydrological conditions, the Garonne River (south‐west France). Studies were conducted in two consecutive reaches of 30 km located downstream of the Toulouse agglomeration (population 760 000, seventh order), impacted by modification of discharge regime and high nitrogen concentrations. The mass‐balance was calculated by two methods: the first is based on a variable residence time (VRT) simulated by a one‐dimensional (1‐D) hydraulic model; the second is a based on a calculation using constant residence time (CRT) evaluated according to hydrographic peaks. In the context of the study, removal of dissolved inorganic nitrogen (DIN) for a reach of 30 km is underestimated by 11% with the CRT method. In sub‐reaches, the discrepancy between the two methods led to a 50% overestimation of DIN removal in the upper reach (13 km) and a 43% underestimation in the lower reach (17 km) using the CRT method. The study highlights the importance of residence time determination when using modelling approaches in the assessment of whole stream processes in short‐duration mass‐balance for a large river under variable hydrological conditions. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Influence of a hedge surrounding bottomland on seasonal soil‐water movement     

Virginie Caubel  Catherine Grimaldi  Philippe Merot  Michel Grimaldi 《水文研究》2003,17(9):1811-1821

The influence of a hedge surrounding bottomland on soil‐water movement along the hillslope was studied on a plot scale for 28 months. The study was based on the comparison of two transects, one with a hedge, the other without, using mainly a dense grid of tensiometers. The influence of the bottomland hedge was located in the area where tree roots were developed, several metres upslope from the hedge, and could be observed both in the saturated and non‐saturated zone, from May to December. The hedge induced a high rate of soil drying, because of the high evaporative capacity of the trees. We evaluated that water uptake by the hedge during the growing season was at least 100 mm higher than without a hedge. This increased drying rate led to a delayed rewetting of the soils upslope from the hedge in autumn, of about 1 month compared with the situation without a hedge. Several consequences of this delayed rewetting are expected: a delay in the return of subsurface transfer from the hillslope to the riparian zone, a buffering effect of hedges on floods, already observed at the catchment scale, and an increased residence time of pollutants. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Estimating Long-Term Solar Irradiance Variability: A New Approach     

Vigouroux  Anne  Pap  Judit M.  Delache  Philippe 《Solar physics》1997,176(1):1-21

The detection of solar irradiance variations (both bolometric and at various wavelengths) by satellite-based experiments during the last one-and-a-half decades stimulated modeling efforts to help identify their causes and to provide estimates of irradiance data for those time intervals when no satellite observations exist. In this paper we present estimates of the long-term irradiance changes developed with Fourier and wavelet transforms. The month-to-month irradiance variations, after removing the solar cycle related long-term changes, are studied with the cross-correlation technique. Results of the analysis reveal a significant phase shift at 3 months between the full-disk magnetic field strength and total solar and UV irradiance, with irradiance leading the magnetic field variability. In addition to this time delay between the changes in solar irradiance and the magnetic field, a 10-month phase shift has been found between the UV flux at 280 nm and total solar irradiance corrected for sunspot darkening. The existence of these phase shifts suggests the possibility of a coupling between the physical processes taking place below, in, and above the photosphere.  相似文献   

Nearby Protoclusters as Laboratories for Understanding Star Formation on Galactic Scales     

Philippe André 《Astrophysics and Space Science》2002,281(1-2):51-66

Detailed studies of nearby cluster-forming molecular clouds can help us understand the physical processes by which most stars form in galaxies. I review recent advances made on this subject. Submillimeter observations of nearby protoclusters suggest that stars are generally built from finite, detached reservoirs of mass inside molecular cloud cores, and point to a cloud fragmentation origin for the IMF. Much progress in this field will come from future large submillimeter instruments such as Herschel and ALMA. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   

Prediction-Focused Subsurface Modeling: Investigating the Need for Accuracy in Flow-Based Inverse Modeling   总被引：1，自引：1，他引：0  

Céline Scheidt  Philippe Renard  Jef Caers 《Mathematical Geosciences》2015,47(2):173-191

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Laura Sigg: Investigating the Speciation,Bioavailability and Ecotoxicology of Trace Metals in Natural Waters     

Bernhard Wehrli  Philippe Behra 《Aquatic Geochemistry》2015,21(2-4):59-64

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Benchmarks for multicomponent reactive transport across a cement/clay interface     

Nicolas C. M. Marty  Olivier Bildstein  Philippe Blanc  Francis Claret  Benoit Cochepin  Eric C. Gaucher  Diederik Jacques  Jean-Eric Lartigue  Sanheng Liu  K. Ulrich Mayer  Johannes C. L. Meeussen  Isabelle Munier  Ingmar Pointeau  Danyang Su  Carl I. Steefel 《Computational Geosciences》2015,19(3):635-653

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Highly gravity-driven flow of a NAPL in water-saturated porous media using the discontinuous Galerkin finite-element method with a generalised Godunov scheme     

Lauriane Schneider  Raphaël di Chiara Roupert  Gerhard Schäfer  Philippe Helluy 《Computational Geosciences》2015,19(4):855-876

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