Thoughts on ‘MgSO4 ion association in seawater’ by Fisher,Gieskes and Hsu     

Ricardo M. Pytkowicz 《Marine Chemistry》1983,13(1):73-74

The correct values of the association constants of MgSO₄ and the adequacy of using the Debye—Hückel equation are considered.  相似文献   

Characterisation of Soot Emitted by Domestic Heating,Aircraft and Cars Using Diesel or Biodiesel   总被引：1，自引：0，他引：1  

Anne?Smekens  Ricardo?Henrique?Moreton?Godoi  Patrick?Berghmans  René?Van?GriekenEmail author 《Journal of Atmospheric Chemistry》2005,52(1):45-62

The characterisation of aggregates, like soot, firstly requires the determination of the size distribution of the primary particles. The primary particle size of combustion generated aggregates depends upon the combustion environment and the formation conditions, such as temperature, pressure and fuel-to-air ratio, among others. Since the combustion characteristics are different in the different types of burners, the characterisation of primary particles may offer the possibility to distinguish soot from different sources. In this paper, we present the signature of the primary particles and the aggregates of soot emitted by cars using diesel or biodiesel, by domestic heating, and by aircraft exhausts, which can be considered as the major sources as derived from measurements on transmission electron micrographs. The size distributions of all aggregates types with different aerodynamic diameter were log-normal and quasi-monodisperse. The size distribution of the primary particles for soot emitted by different sources showed minor differences. However, a comparison between the diameter of the primary particles and those obtained using a standard method for carbon black revealed discrepancies. The median diameter of the primary particles was combined with the median number of primary particles in an aggregate to calculate the relative particle surface area available for adsorption. In a similar way, the relative specific surface area was determined. The surface area was measured using the Brunauer-Emmett-Teller (B.E.T.) nitrogen adsorption method and the relative surface area available for adsorption was calculated.  相似文献   

Embryotoxicity of the antifouling biocide zinc pyrithione to sea urchin (Paracentrotus lividus) and mussel (Mytilus edulis)     

Bellas J  Granmo K  Beiras R 《Marine pollution bulletin》2005,50(11):1382-1385

The effects of the new antifouling compound zinc pyrithione (Zpt) on the embryonic development of sea urchin (Paracentrotus lividus) and mussel (Mytilus edulis) were investigated in laboratory toxicity tests. The median effective concentrations (EC50) were 7.7 nM for sea urchin embryos and 8 nM for mussel embryos. Toxic effects of Zpt on the larval growth of the sea urchin were detected at 0.5 nM. Predicted environmental concentrations of Zpt in pleasure craft harbours are higher than the predicted no effect concentrations for sea urchin and mussel embryos, indicating that Zpt may pose a threat to those species from exposure in the field.  相似文献   

Water quality and presence of pesticides in a tropical coastal wetland in southern Mexico   总被引：6，自引：0，他引：6  

Hernández-Romero AH  Tovilla-Hernández C  Malo EA  Bello-Mendoza R 《Marine pollution bulletin》2004,48(11-12):1130-1141

The water quality of the Pozuelos-Murillo lagoon system in southern Mexico was evaluated during three periods between March and October 2002, with particular emphasis on the detection of organochlorine and organophosphorous pesticide residues in water and sediments. Physicochemical and microbiological parameters of water were also measured and integrated in a water quality index (WQI). Multivariate analysis was used to regionalise the lagoon system as a function of the behaviour of all measured parameters. Solid phase micro-extraction followed by gas chromatography (SPME-GC) was used for pesticide analysis. The concentration of phosphorous was found to be higher than that of nitrogenous compounds. This, besides a deficiency in dissolved oxygen and a high organic matter concentration (as COD), reflects eutrophication processes in some areas of the system. Measured levels of faecal coliforms and oils and greases were above the limits established by Mexican law and comparable to the concentrations reported for other highly polluted systems in Mexico. Residues of DDD (2.0 microg L(-1)) in water and DDE (247 ng g(-1)) and endosulfan I (814 ng g(-1)) sediments were detected by SPME-GC. The spatial distribution of these contaminants implies major potential risks because the most polluted sites were found to be those with the highest fishing activity. Although in general the WQI is on acceptable levels (65-80%), some contamination problems are evident.  相似文献   

Aquarium species: deadly invaders     

Calado R  Chapman PM 《Marine pollution bulletin》2006,52(6):599-601

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Biomarkers of exposure and effect in the Brazilian flounder Paralichthys orbignyanus (Teleostei: Paralichthyidae) from the Patos Lagoon estuary (Southern Brazil)     

Amado LL  Robaldo RB  Geracitano L  Monserrat JM  Bianchini A 《Marine pollution bulletin》2006,52(2):207-213

Biomarkers of exposure (liver metallothionein-like proteins content and catalase and glutathione S-transferase activities) and effect (liver lipoperoxidation and blood cell DNA damage) of contaminants were analyzed in the Brazilian flounder Paralichthys orbignyanus from the Patos Lagoon estuary (Southern Brazil). Flounders were collected for a year in two sites: "Coroa do Boi" (polluted site) and "Saco do Justino" (non-polluted site). Results indicated that micronucleated cells frequency was the best biomarker to distinguish flounders from the two sites. Taken together, data from DNA damage analyses (micronucleus test and comet assay) indicated that flounders from the non-polluted site efficiently repaired the DNA breaks, contrary to those from the polluted site, which probably had their DNA repair system inhibited or exhausted. Furthermore, data from enzyme activities (catalase and GST) and lipid peroxidation indicated that flounders from the polluted site were under oxidative stress in summer and autumn.  相似文献   

An exotic Cretaceous kimberlite linked to metasomatized lithospheric mantle beneath the southwestern margin of the Francisco Craton,Brazil     

Luísa D.V.Carvalho  Tiago Jalowitzki  Ricardo Scholz  Guilherme O.Gonalves  Marcelo Peres Rocha  Rogério Silvestre Pereir  Cristiano Lana  Marco Paulo de Castro  Gláucia Queiroga  Reinhardt A.Fuck 《地学前缘(英文版)》2022,(1):182-203

We present major and trace element compositions of mineral concentrates comprising garnet xenocrysts,ilmenite,phlogopite,spinel,zircon,and uncommon minerals (ti...  相似文献   

Witnessing the impact of the 1783–1784 Laki eruption in the Southern Hemisphere     

Ricardo M. Trigo  J. M. Vaquero  R. B. Stothers 《Climatic change》2010,99(3-4):535-546

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Spatial and temporal changes in dry-snow line altitude on the Antarctic Peninsula     

Jorge Arigony-Neto  Helmut Saurer  Jefferson C. Simões  Frank Rau  Ricardo Jaña  Steffen Vogt  Hermann Gossmann 《Climatic change》2009,94(1-2):19-33

Drastic changes were detected in glacial systems of the Antarctic Peninsula in the last decades. The observed phenomena comprise the disintegration of ice shelves, acceleration and thinning of glaciers, and retreat of glacier fronts. However, due to the lack of consistent systematic observations in particular of the higher parts of the glacial systems, it is difficult to predict further responses of the Antarctic Peninsula glaciers to climatic change. The present paper analyses spatial and temporal variations of changes in the dry-snow line altitude on the Antarctic Peninsula as extracted from a time series (1992–2005) of ERS-1/2 SAR and Envisat ASAR data. Upward changes in dry-snow line altitude were observed in general, and are attributed to extreme high-temperature events impacting the central plateaus of the Antarctic Peninsula and the increasing duration of warming periods. A mean decrease in dry-snow line altitude was detected on the west side of the peninsula and is identified as a response to recorded increase in precipitation and accumulation. These results validate the capability of SAR data for deriving superficial parameters of glaciers to be used as indicators of climatic changes in high-latitude regions where operational restrictions limit conventional meteorological observations.  相似文献   

Extreme rainfalls in SE South America   总被引：1，自引：0，他引：1  

Mariano Re  Vicente Ricardo Barros 《Climatic change》2009,96(1-2):119-136

Heavy rainfall trends in a region of south-eastern South America during 1959–2002 were discussed using daily data of 52 meteorological stations of Argentina, Brazil and Uruguay. Changes in intensity and frequency were both studied with different statistical tests and approaches to check the significance of trends of single and regional aggregated rainfall series. There were predominant positive trends in the annual maximum rainfalls, as well as a remarkable increment in the frequency of heavy rainfalls over thresholds ranging from 50 to 150 mm. However, significant positive trends were not shown in the series of annual maximums and shown only in 15% to 30% of the series of frequencies over thresholds. This lack of significance is due to the high variability of heavy rainfalls in space and time, which makes difficult their capture by single rain gauges. Thus, when the assessment of the heavy rainfall indicators of intensity and frequency were conducted at the regional and sub-regional level, it showed significant trends, both in intensity and frequency over thresholds, with a clearer signal in central and eastern Argentina between 30° and 40° S.  相似文献