Fluctuation in proteinaceous labile organic matter verified with degradation rate constants of terrestrial biochemical indicators     

Junya Kudo  Kensei Kobayashi  Katsumi Marumo  Yoshinori Takano   《Organic Geochemistry》2006,37(12):1655

Biogenic amino acids, taken as representative of organic matter, were analyzed to determine the apparent degradation rate constant in boreal terrestrial sediment. Age determination using ¹⁴C dating gave two rate constants: the initial degradation rate constant for glycine (k_{GLY 1}), the simplest amino acid, was 1.5 × 10⁻³ yr⁻¹ (r = 0.97) until about 2200 yr BP. After the inflection point, the rate constant k_{GLY 2} was 9.1 × 10⁻⁵ yr⁻¹ (r = 0.73). The degradation of amino acids in the labile organic matter in the sediment was markedly affected by rapid processes. After the inflection point, the rate constant profiles for sub-surface amino acids were shown to have discontinuous relationships with sediment age. One pattern which emerged in the vertical distribution is that the biogenic amino acid degradation rate constant k was far greater in the labile organic matter phase than that in the refractory organic matter over the past 10,000 years.  相似文献   

Experimental and analytical studies on earthquake resisting behaviour of confined concrete block masonry structures     

Norio Hori  Norio Inoue  Dangol Purushotam  Tetsuya Nishida  Jun Kobayashi 《地震工程与结构动力学》2006,35(13):1699-1719

To improve the seismic performance of masonry structures, confined masonry that improves the seismic resistance of masonry structures by the confining effect of surrounding bond beams and tie columns is constructed. This study investigated the earthquake resisting behaviour of confined masonry structures that are being studied and constructed in China. The structural system consists of unreinforced block masonry walls with surrounding reinforced concrete bond beams and tie columns. The characteristics of the structure include: (1) damage to blocks is reduced and brittle failure is avoided by the comparatively lower strength of the joint mortar than that of the blocks, (2) the masonry walls and surrounding reinforced concrete bond beams and tie columns are securely jointed by the shear keys of the tie columns. In this study, wall specimens made of concrete blocks were tested under a cyclic lateral load and simulated by a rigid body spring model that models non‐linear behaviour by rigid bodies and boundary springs. The results of studies outline the resisting mechanism, indicating that a rigid body spring model is considered appropriate for analysing this type of structure. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

The 10 ka multiple vent pyroclastic eruption sequence at Tongariro Volcanic Centre, Taupo Volcanic Zone, New Zealand: Part 2. Petrological insights into magma storage and transport during regional extension     

Mitsuhiro Nakagawa  Ian A Nairn  Tetsuo Kobayashi   《Journal of Volcanology and Geothermal Research》1998,86(1-4)

The six eruption episodes of the 10 ka Pahoka–Mangamate (PM) sequence (see companion paper) occurred over a ?200–400-year period from a 15-km-long zone of multiple vents within the Tongariro Volcanic Centre (TgVC), located at the southern end of the Taupo Volcanic Zone (TVZ). Most TgVC eruptives are plagioclase-dominant pyroxene andesites and dacites, with strongly porphyritic textures indicating their derivation from magmas that ascended slowly and stagnated at shallow depths. In contrast, the PM pyroclastic eruptives show petrographic features (presence of phenocrystic and groundmass hornblende, and the coexistence of olivine and augite without plagioclase during crystallisation of phenocrysts and microphenocrysts) which suggest that their crystallisation occurred at depth. Depths exceeding 8 km are indicated for the dacitic magmas, and >20 km for the andesitic and basaltic andesitic magmas. Other petrographic features (aphyric nature, lack of reaction rims around hornblende, and the common occurrence of skeletal microphenocrystic to groundmass olivine in the andesites and basaltic andesites) suggest the PM magmas ascended rapidly immediately prior to their eruption, without any significant stagnation at shallow depths in the crust. The PM eruptives show three distinct linear trends in many oxide–oxide diagrams, suggesting geochemical division of the six episodes into three chronologically-sequential groups, early, middle and late. Disequilibrium features on a variety of scales (banded pumice, heterogeneous glassy matrix and presence of reversely zoned phenocrysts) suggest that each group contains the mixing products of two end-member magmas. Both of these end-member magmas are clearly different in each of the three groups, showing that the PM magma system was completely renewed at least three times during the eruption sequence. Minor compositional diversity within the eruptives of each group also allows the PM magmas to be distinguished in terms of their source vents. Because petrography suggests that the PM magmas did not stagnate at shallow levels during their ascent, the minor diversity in magmas from different vents indicates that magmas ascended from depth through separate conduits/dikes to erupt at different vents either simultaneously or sequentially. These unique modes of magma transport and eruption support the inferred simultaneous or sequential tapping of small separate magma bodies by regional rifting in the southern Taupo Volcanic Zone during the PM eruption sequence (see companion paper).  相似文献   

Outer slope faulting associated with the western Kuril and Japan trenches   总被引：5，自引：0，他引：5  

Kazuo Kobayashi  Masao Nakanishi  Kensaku Tamaki  & Yujiro Ogawa 《Geophysical Journal International》1998,134(2):356-372

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Determination of Chromium, Nickel, Copper and Zinc in Milligram Samples of Geological Materials Using Isotope Dilution High Resolution Inductively Coupled Plasma-Mass Spectrometry     

Akio Makishima  Katsura Kobayashi  Eizo Nakamura 《Geostandards and Geoanalytical Research》2002,26(1):41-51

A simple and accurate method for the determination of Cr, Ni, Cu and Zn at μg g^?1 levels in milligram‐sized bulk silicate materials is reported using isotope dilution high‐resolution inductively coupled plasma‐mass spectrometry (HR‐ICP‐MS) with a flow injection system. Silicate samples with Cr, Ni, Cu and Zn spikes were digested with HF‐HBr and Br₂, and subsequently decomposed at 518 K in a Teflon bomb. In this procedure, all sulfides and chromite, major hosts of these elements, were completely decomposed, thus allowing for isotope equilibration between the sample and spike. Magnesium and Al fluorides formed after the digestion of the sample were removed by centrifugation, and the supernatant was directly aspirated into a HR‐ICP‐MS at a mass resolution of 7500, where interfering oxide ions, ArO⁺, CaO⁺, TiO⁺, CrO⁺ and VO⁺, were separated from Cr⁺, Ni⁺, Cu⁺ and Zn⁺. No matrix effects were observed down to a dilution factor of 50. Detection limits for these elements in silicate samples were < 0.04 μg g^?1. The effectiveness of the technique was demonstrated by the analysis of 13 to 40 mg test portions of USGS and GSJ silicate reference materials with a major element composition ranging from andesite to peridotite, in addition to 8‐23 mg of the Smithsonian reference Allende. Both the reproducibility and the deviation from the reference value for most reference materials of various rock types were < 9%, and thus confirm that the method gives accurate analytical results for small sample sizes over a wide range of Cr, Ni, Cu and Zn contents. This method is, therefore, suitable for analysing small and/or precious bulk samples, such as meteorites, mantle peridotites and mineral separates, and for the characterisation of silicate and sulfide minerals for use as calibration samples in secondary ion mass spectrometry or laser ablation ICP‐MS.  相似文献   

Water-weakened lower crust and its role in the concentrated deformation in the Japanese Islands     

Yoshihisa Iio  Takeshi SagiyaYoji Kobayashi  Ichiro Shiozaki 《Earth and Planetary Science Letters》2002,203(1):245-253

The nature and origin of the concentrated deformation zone along the Japan Sea coast (NKTZ: Niigata-Kobe tectonic zone) was investigated by carefully analyzing the GPS data and qualitatively modeling the lower crust in NKTZ. It was concluded that this deformation zone is not a plate boundary between the Amurian plate (AMU) and the North America plate but is rather an internal deformation zone near the eastern margin of AMU. The data previously obtained on the conductivity anomalies in the lower crust and the ³He/⁴He ratios suggest that the concentrated deformation in NKTZ results from the lower crust in NKTZ being weakened by a high water content. The high water content is thought to result from the dehydration of subducting slabs. NKTZ has a higher water content in the lower crust than other regions do because there is no Philippine Sea plate (PHS) seismic slab beneath NKTZ. In other regions, it is estimated that the mantle wedge above the seismic Philippine Sea slab prevents the water dehydrated from the slab from rising to the lower crust, and that the lithosphere within PHS itself prevents the water dehydrated from the Pacific plate from rising up through it.  相似文献   

Policies and Practices for an Antiracist Geography at the Millennium     

Linda Peake  Audrey Kobayashi 《The Professional geographer》2002,54(1):50-61

As we enter the new millennium, geographers have a momentous opportunity to reflect upon the historical development of our discipline and the academic culture within which it thrives, with the aim of setting out an antiracist agenda. We advocate a fundamental refashioning of the discipline, not simply an extension of its research agenda; for racism, like gender, is not just another item in the lexicon of geographical subjects. The agenda includes, but is not limited to: clarifying relations between racism and law; racism and immigration policy; racism and poverty; and mobilizing racialized groups around policy issues. These items need to be addressed both through scholarship and through activism, as centering geographical practices in the streets rather than in the academy impels not only more effective social change, but also new theoretical understanding of geographies of engagement. Our agenda for antiracist geography also involves three aspects of institutional change: to build up on and extend traditional geographical scholarship; to change the basis of the discipline by extending the principles of antiracism throughout our institutional practices, particularly in the classroom; and to change the face of the discipline by increasing the participation and contributions of geographers of color.  相似文献   

Production of the Blood Pressure Lowing Peptides from Brown Alga （ Undaria pinnatifida ）     

Sato Minoru Oba Takashi Hosokawa Takao Yamaguchi Toshiyasu Nakano Toshiki Saito Tadao Muramoto Koji Kahara T akashi Funayama Katsura Kobayashi Akio Nakano Takahisa 《中国海洋大学学报(英文版)》2005,4(3):209-213

Brown alga （ Undaria pinnatifida） was treated with alginate lyase and hydrolyzed using 17 kinds of proteases and the inhibitory activity of the hydrolysates for the angiotensin-I-converting enzyme （ACE） was measured. Four hydrolysates with potent ACE-inhibitory activity were administered singly and orally to spontaneously hypertensive rats （SHRs）. The systolic blood pressure of SHRs decreases significantly after single oral administration of the brown alga hydrolysates by pro- tease S ＇ Amano＇ （from Bacillus stearothermophilus） at the concentration of 10 （mg protein） （kg body weight）^ - 1. In the 17 weeks of feeding experiment, 7-week-old SHRs were fed standard diet supplemented with the brown alga hydrolysates for 10 weeks. In SHRs fed 1.0 and 0.1% brown alga hydrolysates, elevating of systolic bloodpressure was significantly suppressed for 7 weeks. To elucidate the active components, the brown alga hydrolysates were fractionated by 1-butanol extraction and HPLC on a reverse-phase column. Seven kinds of ACE-inhibitory peptides were isolated and identified by amino acid composition analysis, sequence analysis, and LC-MS with the results Val-Tyr, Ile-Tyr, Ala-Trp, Phe-Tyr, Val-Trp, Ile-Trp, and Leu-Trp. Each peptide was determined to have an antihypertensive effect after a single oral administration in SHRs. The brown alga hydrolysates were also confirmed to decrease the blood pressure in humans.  相似文献   

A new method to calculate normal modes     

Naoki Kobayashi 《Geophysical Journal International》2007,168(1):315-331

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INVERSION OF STRIKE-SLIP MOVEMENTS ALONG THE YARLUNG ZANGBO SUTURE ZONE, TIBET     

Kobayashi Kenta  Matsuoka Atsushi  Yang Qun  Nagahashi Toru  Takei Masahiko  Zeng Qinggao  Wang Yujin 《地学前缘》2000,(Z1)

INVERSION OF STRIKE-SLIP MOVEMENTS ALONG THE YARLUNG ZANGBO SUTURE ZONE, TIBET  相似文献