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63.
Yu Higuchi Yutaka Yanagimoto Kazuyoshi Hoshi Sadao Unou Fumio Akiba Kunishige Tonoike Keita Koda 《Island Arc》2007,16(3):374-393
Abstract To clarify the regional distribution and characteristics of the sedimentary deposits in the northern part of the Philippine Sea, multichannel seismic reflection surveys of 26 864 km in total length were performed. The seismic reflection data were interpreted and correlated with available Deep Sea Drilling Project/Ocean Drilling Program (DSDP/ODP) data and a general stratigraphic framework of the area was established. The sedimentary deposits in this area were divided into five layers; Units I, II, III, IV and V in ascending order. Their approximate geological ages are the Early Eocene, Middle to Late Eocene, Oligocene, Miocene and Pliocene‐Pleistocene, respectively. Seismic records were classified into three seismic facies, Facies A, B and C, on the basis of their characteristics. They were judged to represent pelagic and hemipelagic sediments of non‐volcanic origin, fine pyroclastic sediments and coarse pyroclastic or volcanic sediments, respectively, by comparing them with lithological data in the DSDP/ODP holes. From the thickness and facies distributions of these sediments, a sedimentary history in the area was reconstructed as follows. The oldest sediments in the study area, Unit I, interfinger with some parts of the Daito Ridge (acoustic basement) in the Minami Daito Basin. The geological age of the unit is estimated by microfossils in the sediment and supports the idea that this part of the Daito Ridge is composed of the Early Eocene oceanic basalt. Later, a fair amount of sediments were deposited in the Minami Daito Basin in the Middle to Late Eocene age. A large volume of volcanic materials was supplied from the Paleo‐Kyushu‐Palau Ridge in the Kita Daito Basin in the Eocene and Oligocene ages. The eastern part of the Shikoku and Parece Vela basins is characterized by volcanic sediments supplied from the Nishi Shichito and West Mariana Ridges in the Miocene age. However, pelagic and hemipelagic sediments prevail in the northern part of the Shikoku Basin in the Miocene or later. In short, the area of principal sedimentation has generally shifted from west to east through geological time, reflecting the evolution of the island arc systems with the same trend in the northern Philippine Sea. 相似文献
64.
Rebecca A. French Niven Monsegue Mitsuhiro Murayama Michael F. Hochella Jr. 《Physics and Chemistry of Minerals》2014,41(4):237-246
The phase transformation of schwertmannite, an iron oxyhydroxide sulfate nanomineral synthesized at room temperature and at 75 °C using H2O2 to drive the precipitation of schwertmannite from ferrous sulfate (Regenspurg et al. in Geochim Cosmochim Acta 68:1185–1197, 2004), was studied using high-resolution transmission electron microscopy. The results of this study suggest that schwertmannite synthesized using this method should not be described as a single phase with a repeating unit cell, but as a polyphasic nanomineral with crystalline areas spanning less than a few nanometers in diameter, within a characteristic ‘pin-cushion’-like amorphous matrix. The difference in synthesis temperature affected the density of the needles on the schwertmannite surface. The needles on the higher-temperature schwertmannite displayed a dendritic morphology, whereas the needles on the room-temperature schwertmannite were more closely packed. Visible lattice fringes in the schwertmannite samples are consistent with the powder X-ray diffraction (XRD) pattern taken on the bulk schwertmannite and also matched d-spacings for goethite, indicating a close structural relationship between schwertmannite and goethite. The incomplete transformation from schwertmannite to goethite over 24 h at 75 °C was tracked using XRD and TEM. TEM images suggest that the sample collected after 24 h consists of aggregates of goethite nanocrystals. Comparing the synthetic schwertmannite in this study to a study on schwertmannite produced at 85 °C, which used ferric sulfate, reveals that synthesis conditions can result in significant differences in needle crystal structure. The bulk powder XRD patterns for the schwertmannite produced using these two samples were indistinguishable from one another. Future studies using synthetic schwertmannite should account for these differences when determining schwertmannite’s structure, reactivity, and capacity to take up elements like arsenic. The schwertmannite synthesized by the Regenspurg et al. method produces a mineral that is consistent with the structure and morphology of natural schwertmannite observed in our previous study using XRD and TEM, making this an ideal synthetic method for laboratory-based mineralogical and geochemical studies that intend to be environmentally relevant. 相似文献