Melting of iron–silicon alloy up to the core–mantle boundary pressure: implications to the thermal structure of the Earth’s core     

Hidetoshi Asanuma  Eiji Ohtani  Takeshi Sakai  Hidenori Terasaki  Seiji Kamada  Tadashi Kondo  Takumi Kikegawa 《Physics and Chemistry of Minerals》2010,37(6):353-359

The melting temperature of Fe–18 wt% Si alloy was determined up to 119 GPa based on a change of laser heating efficiency and the texture of the recovered samples in the laser-heated diamond anvil cell experiments. We have also investigated the subsolidus phase relations of Fe–18 wt% Si alloy by the in-situ X-ray diffraction method and confirmed that the bcc phase is stable at least up to 57 GPa and high temperature. The melting curve of the alloy was fitted by the Simon’s equation, P(GPa)/a = (T _m(K)/T ₀) ^c , with parameters, T ₀ = 1,473 K, a = 3.5 ± 1.1 GPa, and c = 4.5 ± 0.4. The melting temperature of bcc Fe–18 wt% Si alloy is comparable with that of pure iron in the pressure range of this work. The melting temperature of Fe–18 wt% Si alloy is estimated to be 3,300–3,500 K at 135 GPa, and 4,000–4,200 K at around 330 GPa, which may provide the lower bound of the temperatures at the core–mantle boundary and the inner core–outer core boundary if the light element in the core is silicon.  相似文献   

Free oscillations of a laterally heterogenous and anelastic earth   总被引：1，自引：0，他引：1  

Seiji Tsuboi 《Pure and Applied Geophysics》1995,145(3-4):445-457

We calculate normal modes of the laterally heterogeneous and anelastic earth model by using the variational method to include the coupling of the modes due to the asphericity of the earth. If the aspherical anelasticity correlates with the heterogeneity of elastic velocity structure, the quality factorQ of the split singlets has a correlation with the eigenfrequency. This can cause a center frequency shift of the spectral peak with time. We perform a synthetic experiment to examine whether the magnitude of the shift can become an observable for the realistic lateral heterogeneity model of anelasticity. The result of the experiment reveals that the shift of the center frequency is consistent with the initial estimate for the fundamental spheroidal modes used in the experiment. We then examine the actual seismograms of the June 9, 1994, Bolivian earthquake to determine if this shift of center frequency can be observed. Although the amount of the center frequency shift of each multiplet is large, there is no consistent shift of the center frequency that is predicted in the synthetic experiment.  相似文献   

Behavior of polycyclic aromatic hydrocarbons at impact shock: Its implication for survival of organic materials delivered to the early Earth     

Koichi Mimura  Seiji Toyama 《Geochimica et cosmochimica acta》2005,69(1):201-209

Polycyclic aromatic hydrocarbons (PAHs) with a hydrous or an unhydrous mineral matrix were impacted and analyzed, to study the behavior of PAHs against shock. Results of the shock experiments suggested that volatiles discharged from the hydrous mineral did not influence the behavior of PAHs against shock. The shocked samples contained unreacted starting PAHs, soot-like materials insoluble in dichloromethane, and secondarily formed PAHs with molecular weights ranging from 128 to 404. Approximately 95% of starting PAHs decomposed at ∼30 GPa and the dominant product was the soot-like materials. Formation mechanisms of the shock products were explained by reaction processes under static high pressure-temperature conditions (e.g., carbonization, radical addition reaction, ring cross linking, and methylation).We applied these results to estimate the survival degree of organic matter delivered by carbonaceous asteroids against their impact pressures at the accretion stage of early Earth. If we use a simplified homogeneous accretion model without atmosphere to represent the stage, the radius of Earth causing 30 GPa, the pressure at which PAHs almost decompose, was calculated as 2270 km (4.0 km s⁻¹ of impact velocity) for the impact of carbonaceous asteroids. In the case of impactors striking not land but oceans on the early Earth, the impact velocity for the decomposition of PAHs was estimated to be 6.0 km s⁻¹. These impact velocities should have been commonly realized on the early Earth, due to the airburst and the aerobreak of impactors in the dense atmosphere. The early Earth should have been a favorable environment for obtaining and maintaining a large quantity of prebiotic organic materials leading to life.  相似文献   

Quaternary tectonic rotation in central Japan: Paleomagnetism of the Eboshidake volcanic rocks     

Yasuto  Itoh  Toshiyasu  Miyazaki  Seiji  Nishizaki 《Island Arc》2007,16(3):457-464

Abstract   Neotectonic crustal deformation in central Japan near a triple-junction of plates is investigated on the basis of paleomagnetic data. The progressive thermal demagnetization test isolated characteristic remanent magnetization from 18 sites of the early Quaternary Eboshidake volcanic rocks erupted around the termination of active strike-slip faults. The site-mean directions show considerably large scatter in declinations, and easterly deflection in average (D_m = −161.7°). On the basis of inclination statistics, measured inclinations (I_m = −48.9°, δI = 6.6°) are concordant with an expected value from latitude of the study area. Because the sampling was planned to cover a wide stratigraphic range and eliminate the effect of geomagnetic secular variation, an easterly deflection is attributed to clockwise rotation around vertical axis. Together with previous paleomagnetic data, the present study indicates that clockwise-rotated areas in central Japan are aligned on a northeast–southwest recent shear zone delineated through geodetic survey. Deflection and scatter of paleomagnetic declinations of the Eboshidake volcanic rocks are much greater than those extrapolated from a recent strain rate, and might be explained by complicated motion anticipated at fault terminations and/or enhanced crustal rotation under elevated temperatures around a Quaternary volcanic province.  相似文献   

The Relation Between Large-Scale Coronal Propagating Fronts and Type II Radio Bursts     

Nariaki V. Nitta  Wei Liu  Nat Gopalswamy  Seiji Yashiro 《Solar physics》2014,289(12):4589-4606

Large-scale, wave-like disturbances in extreme-ultraviolet (EUV) and type II radio bursts are often associated with coronal mass ejections (CMEs). Both phenomena may signify shock waves driven by CMEs. Taking EUV full-disk images at an unprecedented cadence, the Atmospheric Imaging Assembly (AIA) onboard the Solar Dynamics Observatory has observed the so-called EIT waves or large-scale coronal propagating fronts (LCPFs) from their early evolution, which coincides with the period when most metric type II bursts occur. This article discusses the relation of LCPFs as captured by AIA with metric type II bursts. We show examples of type II bursts without a clear LCPF and fast LCPFs without a type II burst. Part of the disconnect between the two phenomena may be due to the difficulty in identifying them objectively. Furthermore, it is possible that the individual LCPFs and type II bursts may reflect different physical processes and external factors. In particular, the type II bursts that start at low frequencies and high altitudes tend to accompany an extended arc-shaped feature, which probably represents the 3D structure of the CME and the shock wave around it, and not just its near-surface track, which has usually been identified with EIT waves. This feature expands and propagates toward and beyond the limb. These events may be characterized by stretching of field lines in the radial direction and may be distinct from other LCPFs, which may be explained in terms of sudden lateral expansion of the coronal volume. Neither LCPFs nor type II bursts by themselves serve as necessary conditions for coronal shock waves, but these phenomena may provide useful information on the early evolution of the shock waves in 3D when both are clearly identified in eruptive events.  相似文献   

On the Equivalence of Two Methods For Computing Partial Derivatives of Seismic Waveforms     

Robert J. Geller  Tatsuhiko Hara  Seiji Tsuboi 《Geophysical Journal International》1990,100(1):153-156

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Ca‐Al‐Fe‐rich inclusion in the Vigarano CV3 chondrite     

Seiji MARUYAMA  Naotaka TOMIOKA 《Meteoritics & planetary science》2011,46(5):690-700

Abstract– An anomalous Ca‐Al‐Fe‐rich spherical inclusion (CAFI) was found in the Vigarano CV3 chondrite. The CAFI has an igneous texture and contains large amounts of almost pure and coarse‐grained hercynite grains (approximately 56 vol%) as well as refractory phases such as grossite and perovskite. However, melilite and Mg‐spinel, which are common in ordinary Ca‐Al‐rich inclusions, are very rare (<1 vol%). Another unique characteristic of the CAFI is the presence in its core of dmitryivanovite (CaAl₂O₄), which was formed by shock metamorphism of a low‐pressure form of CaAl₂O₄ that was originally crystallized from a molten droplet. The fine‐grained hercynite and unidentified aluminous phase in the rim of the CAFI may have been produced from grossite during aqueous alteration in the Vigarano parent body.  相似文献   

Sound velocity measurements in dhcp-FeH up to 70 GPa with inelastic X-ray scattering: Implications for the composition of the Earth's core     

Yuki Shibazaki  Eiji Ohtani  Hiroshi Fukui  Takeshi Sakai  Seiji Kamada  Daisuke Ishikawa  Satoshi Tsutsui  Alfred Q.R. Baron  Naoya Nishitani  Naohisa Hirao  Kenichi Takemura 《Earth and Planetary Science Letters》2012

We have determined the density evolution of the sound velocity of dhcp-FeH_x (x ≈ 1) up to 70 GPa at room temperature, by inelastic X-ray scattering and by X-ray diffraction. We find that the variation of V_P with density is different for the ferromagnetic and nonmagnetic dhcp-FeH_x, and that only nonmagnetic dhcp-FeH_x follows Birch's law. Combining our results with Birch's law for iron and assuming an ideal two-component mixing model, we obtain an upper bound of the hydrogen content in the Earth's inner core, 0.23(6) wt.% H, corresponding to FeH_0.13(3). The iron alloy with 0.23(6) wt.% H can satisfy the density, and compressional and shear sound velocities of the PREM inner core, assuming that there are no other light elements in the inner core.  相似文献   

Uncertainty Estimate of Surface Irradiances Computed with MODIS-, CALIPSO-, and CloudSat-Derived Cloud and Aerosol Properties   总被引：1，自引：0，他引：1  

Seiji Kato  Norman G. Loeb  David A. Rutan  Fred G. Rose  Sunny Sun-Mack  Walter F. Miller  Yan Chen 《Surveys in Geophysics》2012,33(3-4):395-412

Differences of modeled surface upward and downward longwave and shortwave irradiances are calculated using modeled irradiance computed with active sensor-derived and passive sensor-derived cloud and aerosol properties. The irradiance differences are calculated for various temporal and spatial scales, monthly gridded, monthly zonal, monthly global, and annual global. Using the irradiance differences, the uncertainty of surface irradiances is estimated. The uncertainty (1σ) of the annual global surface downward longwave and shortwave is, respectively, 7?W?m^?2 (out of 345?W?m^?2) and 4?W?m^?2 (out of 192?W?m^?2), after known bias errors are removed. Similarly, the uncertainty of the annual global surface upward longwave and shortwave is, respectively, 3?W?m^?2 (out of 398?W?m^?2) and 3?W?m^?2 (out of 23?W?m^?2). The uncertainty is for modeled irradiances computed using cloud properties derived from imagers on a sun-synchronous orbit that covers the globe every day (e.g., moderate-resolution imaging spectrometer) or modeled irradiances computed for nadir view only active sensors on a sun-synchronous orbit such as Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation and CloudSat. If we assume that longwave and shortwave uncertainties are independent of each other, but up- and downward components are correlated with each other, the uncertainty in global annual mean net surface irradiance is 12?W?m^?2. One-sigma uncertainty bounds of the satellite-based net surface irradiance are 106?W?m^?2 and 130?W?m^?2.  相似文献   

Elemental and isotopic abundances of lithium in chondrule constituents in the Allende meteorite     

Seiji Maruyama  Masaki Watanabe  Tak Kunihiro  Eizo Nakamura 《Geochimica et cosmochimica acta》2009,73(3):778-793

Elemental and isotopic abundances of lithium in chondrule constituents in the Allende CV3 meteorite were determined using secondary ion mass spectrometry. Olivines and mesostasis dominated by a feldspathic phase are depleted in Li ( and , respectively). In contrast, low-Ca pyroxenes and mesostasis dominated by a Na-rich phase are enriched in Li ( and , respectively) and the interchondrule matrix is generally enriched in Li ( on average). The Li isotopic abundance of olivine ranges from to 21. The spatial distributions of elemental and isotopic abundances of Li in olivines within individual chondrules exhibit no systematic pattern. This suggests that the distribution of Li in olivine was not disturbed during aqueous alteration or thermal metamorphism on the Allende meteorite parent body. Although mesostasis is the last crystallizing phase from a chondrule melt and is expected to be enriched in Li, in the Allende meteorite it is generally depleted in Li. We suggest that during aqueous alteration on the CV asteroid, Li in mesostasis was leached out by aqueous fluids. The Li-enriched Na-rich mesostasis was probably produced later by infiltration of Na-rich fluids. It seems likely that aqueous fluids sequestered alkali elements from the Allende-chondrite region in the CV parent asteroid, although significant amounts of Li are preserved in ferrous olivine in the interchondrule matrix.  相似文献