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Crystal chemistry of merrillite from Martian meteorites: Mineralogical recorders of magmatic processes and planetary differentiation 下载免费PDF全文
C. K. Shearer P. V. Burger J. J. Papike F. M. McCubbin A. S. Bell 《Meteoritics & planetary science》2015,50(4):649-673
Merrillite is a ubiquitous accessory phase in a variety of Martian meteorite lithologies. The Martian merrillites exhibit a positive correlation between Mg# and Na and a negative correlation between Mg# and both Mn and vacancies in the octahedral Na‐site. Their REE patterns are varied and range from LREE‐depleted to LREE‐enriched. The dominant cation substitutions in the Martian merrillites are Fe2+VI Mg‐site?Mg2+VI Mg‐site and Ca2+VI Na‐site + □VI Na‐site?2Na+VI Na‐site. The REE substitution into the 8‐fold coordinated Ca‐site is accommodated by the coupled substitution CaVIII Ca‐site + (Na)VI Na‐site ?(Y3+ + REE3+)VIII Ca‐site + □VI Na‐site. The REE substitution is significantly more prevalent in lunar merrillite and can be used as a “fingerprint” to distinguish lunar from Martian meteorites. The substitution of OH? (whitlockite) and/or F? (bobdownsite) for O2? on one of the phosphate tetrahedrons appears to be rather insignificant. The correlations among Na, Mg#, Mn, and Na‐site vacancies are linked to the premerrillite crystallization history of the melt and the crystal chemical behavior of the Mg‐ and Na‐sites. The former reflects the sequence and extent of plagioclase and pyroxene crystallization. The differences in REE pattern shapes among the merrillites reflect source regions for the Martian basalts and the shapes are not greatly perturbed by the crystallization history. The occurrence of merrillite does not imply low‐volatile component in the Martian magmas. However, the low whitlockite and bobdownsite contents suggest that these samples were not altered by hydrothermal fluids and therefore not reset owing to aqueous fluid interactions. Consequently, the young ages of the shergottites are probably true igneous crystallization ages. 相似文献
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C. Houser † G. Masters M. Flanagan P. Shearer 《Geophysical Journal International》2008,174(1):178-194
Global mapping of 410 and 660 km discontinuity topography and transition zone thickness has proven to be a powerful tool for constraining mantle chemistry, dynamics and mineralogy. Numerous seismic and mineral physics studies suggest that the 410 km discontinuity results from the phase change of olivine to wadsleyite and the 660 km discontinuity results from the phase change of ringwoodite to perovskite and magnesiowustite. Underside reflections of the 410 and 660 km discontinuities arrive as precursors to SS . With the recent development of a semi-automated method of determining SS arrivals, we have more than tripled the Flanagan and Shearer (1998a) data set of handpicked SS waveforms. We are able to increase resolution by stacking waveforms in 5° rather than 10° radius bins as well as increasing data coverage significantly in the southern hemisphere. The resulting SS-S410S and SS-S660S times are heavily influenced by upper-mantle velocity structure. We perform a joint inversion for discontinuity topography and velocity heterogeneity as well as performing a simple velocity correction to the precursor differential times and find little difference between the two methods. The 660 km discontinuity topography and transition zone thickness are correlated with velocities in the transition zone whereas the 410 km discontinuity topography is not. In addition, the 410 km discontinuity topography is not correlated with the 660 km discontinuity topography, rather anticorrelated, as expected due to the opposite signs of the Clapeyron slopes of their respective phase changes. These results suggest that, whereas the topography of 660 km discontinuity could be dominated by thermal effects, the topography of the 410 km discontinuity is likely dominated by compositional effects. In addition, unlike previous studies which find less topography on the 410 km discontinuity than on the 660 km discontinuity, our 410 and 660 km topography have similar amplitudes. 相似文献
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Exploring the Moon's surface for remnants of the lunar mantle 1. Dunite xenoliths in mare basalts. A crustal or mantle origin? 下载免费PDF全文
Charles K. Shearer Paul V. Burger Aaron S. Bell Yunbin Guan Clive R. Neal 《Meteoritics & planetary science》2015,50(8):1449-1467
Remotely sensed observations from recent missions (e.g., GRAIL, Kaguya, Chandrayaan‐1) have been interpreted as indicating that the deep crust and upper mantle are close to or at the lunar surface in many large impact basins (e.g., Crisium, Apollo, Moscoviense). If this is correct, the capability of either impact or volcanic processes to transport mantle lithologies to the lunar surface should be enhanced in these regions. Somewhat problematic to these observations and interpretations is that examples of mantle lithologies in the lunar sample collection (Apollo Program, Luna Program, lunar meteorites) are at best ambiguous. Dunite xenoliths in high‐Ti mare basalt 74275 are one of these ambiguous examples. In this high‐Ti mare basalt, olivine occurs in three generations: olivine associated with dunite xenoliths, olivine megacrysts, and olivine microphenocrysts. The dunite xenoliths are anhedral in shape and are generally greater than 800 μm in diameter. The interior of the xenoliths are fairly homogeneous with regard to many divalent cations. For example, the Mg# (Mg/Mg + Fe × 100) ranges from 82 to 83 in their interiors and decreases from 82 to 68 over the 10–30 μm wide outer rim. Titanium and phosphorus X‐ray maps of the xenolith illustrate that these slow diffusing elements preserve primary cumulate zoning textures. These textures indicate that the xenoliths consist of many individual olivine grains approximately 150–200 μm in diameter with low Ti, Al, and P cores. These highly incompatible elements are enriched in the outer Fe‐rich rims of the xenoliths and slightly enriched in the rims of the individual olivine grains. Highly compatible elements in olivine such as Ni exhibit a decrease in the rim surrounding the xenolith, an increase in the incompatible element depleted cores of the individual olivine grains, and a slight decrease in the “interior rims” of the individual olivine grains. Inferred melt composition, liquid lines of descent, and zoning profiles enable the reconstruction of the petrogenesis of the dunite xenoliths. Preservation of primary magmatic zoning (Ti, P, Al) and lack of textures similar to high‐pressure mineral assemblages exhibited by the Mg‐suite (Shearer et al. 2015) indicate that these xenoliths do not represent deep crustal or shallow mantle lithologies. Further, they are chemically and mineralogically distinct from Mg‐suite dunites identified from the Apollo 17 site. More likely, they represent olivine cumulates that crystallized from a low‐Ti mare basalt at intermediate to shallow crustal levels. The parent basalt to the dunite xenolith lithology was more primitive than low‐Ti basalts thus far returned from the Moon. Furthermore, this parental magma and its more evolved daughter magmas are not represented in the basalt sample suite returned from the Taurus‐Littrow Valley by the Apollo 17 mission. The dunite xenolith records several episodes of crystallization and re‐equilibration. During the last episode of re‐equilibration, the dunite cumulate was sampled by the 74275 high‐Ti basalt and transported over a period of 30–70 days to the lunar surface. 相似文献
18.
Edward S. Grew Nikolai N. Pertsev Stanislav Vrána Martin G. Yates Charles K. Shearer Michael Wiedenbeck 《Contributions to Mineralogy and Petrology》1998,131(1):22-38
Kornerupine, (□,Fe,Mg)(Mg,Fe,Al)9(Si,Al,B)5 (O,OH,F)22, has been reported with talc in rocks from six localities worldwide, but only at Chilapila Hill in the Lufilian Arc, Zambia
do textural relationships imply that kornerupine (Krn) equilibrated with talc (Tlc) during a prograde metamorphic event at
T≈ 640 °C, P≈ 13 kbar; a prograde Krn + Tlc assemblage has also been reported from Mautia Hill, Tanzania (P ≤ 13 kbar). In order to estimate possible constraints on the stability range for the kornerupine + talc paragenesis in nature,
we constructed a P-T diagram in the model system MgO-Al2O3-SiO2-H2O (MASH) for seven phases quartz (Qtz), B-free kornerupine sensu stricto, anthophyllite (Ath), chlorite (Chl), cordierite
(Crd), kyanite (Ky), and talc. The minimum pressure for Krn + Tlc + Ky stability in MASH is close to that for Ky + Tlc stability,
i.e., 6–8 kbar, at T≤ 780 °C. However, in the natural system, B2O3 and Na2O are major constituents in Krn and orthoamphibole (Oam), respectively, and dravitic tourmaline (Tur) is widespread. The critical
assemblage alternative to Krn + Tlc in nature is Tur + Oam. The upper pressure limit of Tur + Ath is determined by the upper
pressure for anthophyllite: 7.7–10.5 kbar at 682–794 °C in the MgO-SiO2-H2O system (Chernosky et al. 1985, Am Mineral 70:223–236), and is undoubtedly higher in the presence of Na2O, CaO, and Al2O3. At three of the six localities, talc is a retrograde phase; nonetheless, it possibly equilibrated with kornerupine on the
retrograde path or during a later metamorphic event at P-T conditions appropriate for Ky + Tlc. At the sixth locality (Mulvoj, southwestern Pamir Mountains, Tajikistan), Krn is found
in the same thin section as talc and kyanite and all three minerals formed during a prograde metamorphic event at T≥ 650 °C, P near 7 kbar. However, Krn is restricted to a lens 4 to 6 mm thick of phlogopite + anthophyllite + Tur and it does not touch
either talc or kyanite. A reaction relating the Mulvoj and Chilapila Hill (Krn + Tlc + Ky + Qtz + Tur) parageneses is calculated
from compositions in the Mulvoj rock to be 0.40Tur + 2.55Ath + 1.33H2O + 0.27F = Krn + 2.16Tlc + 0.36B2O3 + 0.02Rutile + 0.19Na2O + 0.17CaO. Given the difference in metamorphic pressures estimated for Mulvoj and Chilapila Hill, Krn + Tlc is inferred
to be favored by increasing pressure as well as by low Na2O and CaO contents. Some FeO, F, Fe2O3, and BeO are present in measurable amounts in at least one of the phases in the Mulvoj and Chilapila Hill whiteschists (e.g.,
Krn contains 0.24–0.67 wt% BeO), but the effect of these constituents is subordinate to that of Na2O, CaO and B2O3. The Krn + Tlc could be a more important assemblage in B-bearing whiteschists than has been reported to date, particularly
at pressures where orthoamphibole is no longer stable.
Received: 21 April 1997 / Accepted: 13 October 1997 相似文献
19.
广东清远早、晚稻稻田甲烷排放的观测研究 总被引:1,自引:0,他引:1
分析了2003、2004年广东省清远市郊区早、晚稻稻田甲烷(CH4)的排放通量,结果表明:广东清远早、晚稻稻田CH4排放通量的几何平均值2003年为4,38mg·m^-2·h^-1和6.09mg·m^-2·h^-1;2004年为5.17mg·m^-2·h^-1和8.3mg·m^-2·h^-1,土壤有机质含量是造成2003和2004年CH4排放差异的原因之一。水稻品种的不同,CH4排放通量也有所不同,实验表明,水稻品种“七丝尖”的排放通量比品种“金优99”高1.08mg·m^-2·h^-1,产量却只有64%。此外,与相关的测量结果进行初步比较。 相似文献
20.
A system is described which makes best use of the high quantum efficiency and high count rate capability of avalanche photodiodes
for high time resolution observations of optical pulsars. The use of three APDs allows simultaneous photometry of the target
and a reference star, and the monitoring of the sky background. By minimising the optical components in the light path the
optical efficiency of the system is maximised. The TRIFFID (Shearer, A., Stappers, B., O'Connor, P., Golden, A., Strom, R.,
Redfern, M., Ryan, O.: Science 301, 493–495 (2003)) and OPTIMA (Straubmeier, C., Kanbach, G., Schrey, F.: Exp. Astron. 11, 157–170 (2001)) have shown that fibre-fed APD arrays can produce excellent results. This, new, system was used on the 6m
BTA in November 2003 – results on the Crab pulsar are presented. 相似文献