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71.
72.
基于旋转经验正交函数分解 (REOF) 方法探讨淮河流域1961—2010年夏季降水与厄尔尼诺/南方涛动 (ENSO)、北大西洋涛动 (NAO)、印度洋偶极子 (IOD)、太平洋年代际振荡 (PDO) 之间的关系,并进一步分析各气候因子不同位相单独以及联合对淮河流域夏季降水的影响。结果表明:淮河流域夏季降水与ENSO,PDO,NAO,IOD等气候因子具有较稳定的相关性,其中,PDO和IOD是影响淮河流域夏季降水的关键因子,且PDO与夏季降水呈显著负相关关系;各气候因子的冷暖位相单独及联合对淮河流域夏季降水的影响不同,PDO的冷期以及NAO,IOD冷位相使流域北部的夏季降水量呈显著增加趋势,PDO分别联合ENSO,NAO和IOD的冷、暖位相对流域北部地区和淮河上游地区的夏季降水影响显著。 相似文献
73.
为改善风云三号 (FY-3) 微波成像仪10.6 GHz通道空间分辨率,提出利用超分辨率图像重建算法进行图像重建。分析并指出FY-3微波成像仪10.6 GHz通道具有过采样特征,具备重建得到高于瞬时视场图像的潜力;基于超分辨率图像重建理论,根据FY-3气象卫星轨道、姿态,微波成像仪性能参数以及工作模式等物理约束,建立微波成像仪的超分辨率成像模型,并推导计算出超分辨率成像模型参数;采用POCS算法重建得到10.6 GHz通道的超分辨率图像,采用目视比较分析、图像统计分析对重建图像进行质量评价:重建图像像元平均梯度提高26.5%,功率谱分量和提高5.7%,重建图像具有更高的空间分辨率;台风亮温分析应用显示了从重建图像可发现更微小的景物细节目标。采用超分辨率图像重建算法对FY-3微波成像仪10.6 GHz通道进行重建处理,结果有效且正确,可为数据用户提供更多可用的遥感数据,对微波遥感数据应用具有提升作用。 相似文献
74.
利用新疆巴楚气象站1984—2013年逐日气象资料,运用线性回归、趋势系数、异常度、Mann-Kendall突变检验等方法,分析了巴楚县多时间尺度气温的变化特征对冬小麦生长发育和产量的影响。结果表明:近30 a巴楚县冬季、春季平均气温均呈上升趋势,其中春季平均气温上升趋势显著,并于1998年发生了增暖性突变;寒冷日和酷冷日数均呈减少趋势,其中寒冷日数在1996年发生了减少性突变;稳定通过0℃界限温度的初日表现为提前、终日表现为推迟,持续日数则相应表现为增加趋势;日最高气温≥30℃日数呈增加趋势;冬小麦生长季内前期气温偏低,后期气温偏高是影响小麦产量的主要气候因子,其中抽穗、开花期的平均气温与小麦产量显著相关。 相似文献
75.
76.
An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry
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Wen Zhang Liang Qi Zhaochu Hu Cunjiang Zheng Yongsheng Liu Haihong Chen Shan Gao Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(2):195-216
Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO3 results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF3 precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH4HF2 open vessel digestion and (c) NH4F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF3 and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH4HF2 or NH4F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO3, the white precipitates and the semi‐transparent gels present in the NH4HF2 and NH4F digestion methods could be efficiently dissolved by evaporation with HClO4. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time. 相似文献
77.
Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification
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Zhen Li Zhaochu Hu Detlef Günther Keqing Zong Yongsheng Liu Tao Luo Wen Zhang Shan Gao Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(4):477-491
Ilmenite (FeTiO3) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised 57Fe and 49Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm?2 and fs‐LA‐ICP‐MS. 相似文献
78.
79.
In organic-rich gas shales, clay minerals and organic matter (OM) have significant influences on the origin, preservation, and production of shale gas. Because of the substantial role of nanoscale pores in the generation, storage, and seepage of shale gas, we examined the effects of clay minerals and OM on nanoscale pore distribution characteristics in Lower Paleozoic shale gas reservoirs. Using the Niutitang and Longmaxi shales as examples, we determined the effects of clay minerals and OM on pores through sedimentation experiments. Field emission–scanning electron microscopy combined with low-pressure N2 adsorption of the samples before and after sedimentation showed significant differences in pore location and pore size distribution between the Niutitang and Longmaxi shales. Nanoscale pores mostly existed in OM in the Longmaxi shale and in clay minerals or OM–clay composites in the Niutitang shale. The distribution differences were attributed largely to variability in thermal evolution and tectonic development and might account for the difference in gas-bearing capacity between the Niutitang and Longmaxi reservoirs. In the nanoscale range, mesopores accounted for 61–76% of total nanoscale pore volume. Considerably developed nanoscale pores in OM were distributed in a broad size range in the Longmaxi shale, which led to good pore connectivity and gas production. Numerous narrow pores (i.e., pores?<?20 nm) in OM–clay composites were found in the Niutitang shale, and might account for this shale’s poor pore connectivity and low gas production efficiency. Enhancing the connectivity of the mesopores (especially pores?<?20 nm and those developed in OM–clay composites) might be the key to improving development of the Niutitang shale. The findings provide new insight into the formation and evolutionary mechanism of nanoscale pores developed in OM and clay minerals. 相似文献
80.
Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au (Sb) deposit and Au deposits at Zhaojialing, Wuxi, and Liaojia. In order to understand the mechanisms that led the formation of these Au deposits, we make detailed reviews on the geological characteristics of these Au deposits. Specifically, we present new LA-ICP-MS zircon U–Pb dating, along with elemental and Hf isotopic data from the Huashan Au (Sb) deposit. Our data suggests that the Huashan ore-related intrusions were emplaced during the Late Jurassic and Early Cretaceous periods (144–148 Ma). They are characterized by arc-magma features and high oxygen fugacity and are rich in inherited zircons. Zircon U–Pb ages and Lu–Hf isotopes from intrusions suggest that Proterozoic juvenile lithosphere is the main source of these intrusions. The regional geological history implies that lithosphere beneath southern Anhui was produced during a Proterozoic subduction and was fertilized with Au (Cu) in the process. Integrated with the results of previous studies, we inferred that Late Mesozoic intrusions formed by the remelting of the lithosphere could provide the metal endowment for the Au-rich deposits in southern Anhui. 相似文献