Spontaneous strain at the structural phase transition in NaNO3     

Richard J. Reeder  Simon A. T. Redfern  Ekhard Salje 《Physics and Chemistry of Minerals》1988,15(6):605-611

The temperature dependence of the hexagonal c unit cell parameter of high-purity NaNO₃ shows an anomaly at 553 K corresponding to the orientational ordering transition. The a unit cell parameter is barely influenced by the transition. The single component spontaneous strain for this zone boundary instability is large (55×10^–3 at 295 K), and couples quadratically with the order parameter. The critical exponent is found to have the value 0.22 ± 0.01, which differs from that expected in the classical case. Below ca 450 K, crossover to tricritical behaviour is observed (=1/4). The temperature evolution of the macroscopic order parameter as revealed by the temperature dependence of the spontaneous strain follows a tricritical behaviour between 70 K and 450 K. At temperatures below 70 K order parameter saturation is observed. Combined with recent data from specific heat measurements, the critical exponents suggest that the three-dimensional, three-states Potts model may describe the transition.Precursor spontaneous strain above T _c is consistent with local ordering and may result from fluctuations associated with an antiordered NO₃ group pair configuration.  相似文献   

Oxygen isotope geochemistry of the Mesozoic volcanics of the Etendeka Formation,Namibia     

Chris Harris  H. Stuart Smith  Simon C. Milner  Anthony J. Erlank  Andrew R. Duncan  Julian S. Marsh  Nicholas P. Ikin 《Contributions to Mineralogy and Petrology》1989,102(4):454-461

The Etendeka Formation volcanics consist of a bimodal association of basalts and quartz latites. Forty three new whole rock oxygen isotope analyses are reported for all the major magma types. All the rocks except a minor suite of dolerites have higher ¹⁸O values than normal mantle. The basic rocks (average of 29=8.8) have significantly different ¹⁸O to the acid rocks (average of 10=14.4) These data are apparently consistent with previously published petrogenetic models, which propose that the basalts were affected by crustal contamination and that the quartz latites are crustally derived. However, mineral oxygen data show that there is significant oxygen isotopic disequilibrium between phenocryst and whole rock, the latter being significantly higher in most cases. One of the basic magma types (the Tafelberg basalts) shows mutual positive correlations between ¹⁸O, SiO₂ and _Sr. If these correlations are due to crustal contamination, then as much as 45% contamination is required by material having a ¹⁸O value of 15 which is the maximum observed value in the Damaran basement rocks. In the absence of pyroxene phenocryst ¹⁸O data for the high _Sr Tafelberg basalts (they are aphyric), it is not possible to confirm that contamination has taken place. An alternative explanation is that the correlation between _Sr and SiO₂ resulted from assimilation coupled with fractional crystallization (AFC) (before emplacement). Post-eruption alteration resulted in a correlation between SiO₂ ¹⁸O because the material with the most Si-O bonds was able to concentrate ¹⁸O more effectively. The limited mineral data for the quartz latites suggests that there is some source heterogeneity. A pyroxene ¹⁸O value of 10% for a southern Etendeka quartz latite is consistent with a crustal source.  相似文献   

A model of channel response in disturbed alluvial channels   总被引：2，自引：0，他引：2  

Andrew Simon 《地球表面变化过程与地形》1989,14(1):11-26

Dredging and straightening of alluvial channels between 1959 and 1978 in West Tennessee caused a series of morphologic changes along modified reaches and tributary streams. Degradation occurred for 10 to 15 years at sites upstream of the area of maximum disturbance and lowered bed-levels by as much as 6·1 m. Following degradation, reaches upstream of the area of maximum disturbance experienced a secondary aggradation phase in response to excessive incision and gradient reduction. Aggradation downstream of the area of maximum disturbance reached 0·12 m per year with the greatest rates occurring near the stream mouths. The adjustment of channel geometry and phases of channel evolution are characterized by six process-oriented stages of morphologic development—premodified, constructed, degradation, threshold, aggradation, and restabilization. Down-cutting and toe removal during the degradation stage causes bank failure by mass wasting when the critical height and angle of the bank material is exceeded (threshold stage). Channel widening continues through the aggradation stage as the ‘slough line’ develops as an initial site of lower-bank stability. The bank profile develops three dynamic elements (1) vertical face (70° to 90°), (2) upper bank (25° to 50°), and (3) slough line (20° to 25°). Alternate channel bars form during the restabilization stage and represent incipient meandering of the channel.  相似文献   

Hydraulic borehole characterization through the application of moment methods to fluid conductivity logs     

Simon Lw  Van Kelley  Stratis Vomvoris 《Journal of Applied Geophysics》1994,31(1-4)

In any type of groundwater transport problem (contaminant solutes, heat, etc.), knowledge of the location and properties of pathways of increased hydraulic conductivity is essential. However, answering such questions in strongly heterogeneous media, such as fractured rock, can be very difficult and budget-intensive with standard geophysical or hydrogeological field investigations. We present a new testing concept and analysis procedure based on a time sequence of wellbore electric conductivity logs, which provides the exact location and the outflow parameters (transmissivity, formation fluid conductivity) of flowing features (fractures, faults, layers) intercepted by the borehole.Previously the quantitative analysis of this time sequence of electrical conductivity logs was based on a code, called BORE, used to simulate borehole fluid conductivity profiles given these parameters. The present report describes a new direct (not iterative) method for analyzing a short time series of electric conductivity logs which is based on moment quantities of the individual outflow peaks, and applies it to synthetic as well as to field data. The results of the method are promising and are discussed in terms of the method's advantages and limitations. In particular it is shown that the method is capable of reproducing hydraulic properties derived from packer tests well within a factor of three, which is below the range of what is recognized as the accuracy of packer tests themselves. Furthermore the new method is much quicker than the previously used iterative fitting procedure and is even capable of handling transient fracture outflow conditions.  相似文献   

Chernobyl radiocaesium in upland watershed-lake systems,Galloway, south west Scotland     

Simon M. Hutchinson 《Journal of Paleolimnology》1994,10(3):169-180

Levels of Chernobyl radiocaesium found in the upland region of Galloway, south west Scotland were relatively high e.g. catchment mean¹³⁴Cs inventories ranged from 5.72±2.64 kBq m² to 8.72±1.46 kBq m². The nuclear weapons test¹³⁷Cs content of soils and peats was significantly augmented. Accurate assessment of spatial variations and temporal changes in the levels of contamination, however, are inhibited by its marked, short-range heterogeneity. No significant change in mean catchment inventories was detected over a twelve month period. Lake sediment inventories, however, were consistently enhanced from initially lower levels of contamination than their catchments' surfaces. Pre Chernobyl catchment and lake sediment¹³⁷Cs inventories, however, show no such contrast. Both are substantially lower than rainfall based predictions. These observations of the relative levels of Chernobyl and pre-existing radiocaesium in watersheds and their waterbodies have important implications for both the assessment of the catchment and lake residence times of particle-associated contaminants and the use of lake sediment records as monitors of such pollutants.  相似文献   

Commentary on “The Entrepreneurial City: Fabricating Urban Development in Syracuse,New York”     

Rutherford H. Platt 《The Professional geographer》1994,46(2):250-252

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Serpentinization and infiltration metasomatism in the Trinity peridotite,Klamath province,northern California: implications for subduction zones     

Simon M. Peacock 《Contributions to Mineralogy and Petrology》1987,95(1):55-70

The Trinity peridotite was emplaced over metabasalts and metasedimentary rocks of the central metamorphic belt along the Devonian Trinity thrust zone. Three metamorphic events can be recognized in the Trinity peridotite: (1) antigorite (D= –63 to –65%.) formation related to regional underthrusting of the central metamorphic belt; (2) contact metamorphism associated with Mesozoic dioritic plutons; and (3) late-stage formation of lizardite ± brucite and chrysotile (D= –127 to –175%.) due to infiltration of meteoric waters. Abundant relict phases indicate incomplete reactions and strongly suggest that the availability of H₂O was a controlling factor during serpentinization.Antigorite (event 1) formed as a result of infiltration into the Trinity peridotite of mixed H₂O-CO₂ fluids derived from the underlying central metamorphic belt. Foliation defined by magnetite veins and shear zones within antigorite serpentinites are subparallel to the Trinity thrust. The assemblage Fo + Atg + Chl + Mag ± Tr ± Carb reflects partial hydration of peridotite at 425–570° C. Talc-rich serpentinite formed along the thrust as a result of the infiltration of silica-bearing fluids. Metasomatic mass-balance calculations based on silica solubilities and the extent of antigorite serpentinization suggest that 80–175 volumes of fluid have passed through a given volume of original peridotite at the Trinity thrust.The Trinity thrust probably represents a Devonian subduction zone. Thermodynamic calculations suggest that hydration reactions account for 30–35% of the total heat released by the cooling Trinity peridotite. By analogy, similar hydration reactions are to be expected in the overlying mantle wedge of a subduction zone which act to retard cooling of the hanging wall, just as dehydration reactions delay heating of the downgoing slab. Metasomatic zones formed in peridotite at the Trinity thrust may reflect similar metasomatic processes to those proposed to occur in the mantle wedge above a subducting slab.  相似文献   

Man-induced gradient adjustment of the South Fork Forked Deer River,west Tennessee     

Andrew Simon  Clarence H. Robbins 《Environmental Geology》1987,9(2):109-118

Channel modifications from 1968 to 1969 on the South Fork Forked Deer River in western Tennessee have caused upstream degradation, downstream aggradation, and bank failures along the altered channels, adjacent reaches, and tributaries. The result of these adjustments is a general decrease in gradient as the channel attempts to absorb the imposed increase in energy conditions created by channelization. Headward degradation at a rate of approximately 2.57 km/yr on the South Fork Forked Deer River caused from 1.52 m to about 3.14 m of incision over a 13.5 km reach from 1969 to 1981. As a consequence of substantially increased sediment supply, approximately 2.13 m of aggradation was induced downstream of this reach during the same period. This accumulation represents a 60% recovery of bed level at the downstream site since the completion of channel work in 1969. Gradient adjustment with time is described by exponential decay functions. The length of time required for adjustment to some new quasi-equilibrium condition is computed by these decay functions and is about 20 years from the completion of channel work. Adjusted slopes are less than predisturbed values, probably because straightened channels dissipate less energy by friction, allowing more energy for sediment transport. An equivalent sediment load, therefore, can be transported at a considerably gentler slope. The predisturbed slope exceeds the adjusted slope by an order of magnitude on the downstream reach of the South Fork Forked Deer River.  相似文献   

Sunsets, twilights and evening skies: Eden and Marjorie Meinel. Cambridge University Press, Cambridge, 1983, x + 163 pp. £17.50, US$ 29.95, hardcover     

C.M.R. Platt 《Dynamics of Atmospheres and Oceans》1985,9(3):315-316

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Structural history of high-pressure metamorphic rocks in the southern vanoise massif,french alps,and their relation to alpine tectonic events     

T.P Platt  G.S Lister 《Journal of Structural Geology》1985,7(1):19-35

A nappe of amphibolite-facies metamorphic rocks of pre-Permian age in the southern Vanoise massif (the Arpont schist) has been affected by an Alpine HP/LT metamorphism. The first mesoscopically recognizable deformation (D₁) post-dated the high-pressure peak (jadeitic pyroxene + quartz, glaucophane + ?lawsonite), and was associated with glaucophane + epidote. D₁ produced a flat-lying schistosity and a NW-trending glaucophane lineation, and was probably associated with nappe displacement involving NW-directed subhorizontal shear. D₂ formed small-scale folds and a foliation associated with chlorite + albite. The changing parageneses during the period pre-D₁ to D₁ to D₂ suggest decreasing pressure, so that the deformation appears to have been related to the uplift history, rather than to the process of tectonic burial. D₂ was followed by a static metamorphism (green biotite + chlorite + albite), possibly of Lepontine age. SE-directed backthrusting and folding (D₃), and later differential uplift along steep faults, took place under low-grade conditions.  相似文献