Determination of Partition Coefficients of Metals in Natural Tropical Water     

Sonia Regina Giancoli Barreto  Wagner José Barreto  Elisangela Manjurma Deduch 《洁净——土壤、空气、水》2011,39(4):362-367

The values for the partition coefficient (K_d) were calculated for Ca, Mg, Cd, Cr, Cu, Fe, Mn, Pb, Ni, and Zn at 19 sites in the Capivara hydroelectric reservoir in Brazil. It was found that the relative values of K_d follow the order: Cr > Mn > Fe > Cu > Zn > Ni > Pb > Ca > Cd, differing from the values reported for K_d in aquatic systems in the northern hemisphere. A hierarchical cluster analysis and linear correlations showed that Cr is strongly associated with Fe and Cu, and that Cd is the only metal found in complexation with organic matter, explaining its higher solubility.  相似文献   

Temporal evolution of weathered cataclastic material in gravitational faults of the La Clapiere deep-seated landslide by mechanical approach     

Thomas Lebourg  Hernandez Mickael  Jomard Herv��  El Bedoui Bedoui Samyr  Bois Thomas  Zerathe Swann  Tric Emmanuel  Vidal Maurin Jr 《Landslides》2011,8(2):241-252

After a few years of research, the observation and the analysis of the deep-seated landslides suggest that these are mainly controlled by tectonic structures, which play a dominant role in the deformation of massif slopes. The La Clapière deep-seated landslide (Argentera Mercantour massif) is embedded in a deep-seated gravitational slope deformation affecting the entire slope, and characterized by specific landforms (trenches, scarps??). Onsite, the tangential displacement direction of the trenches and the scarps are controlled by the tectonic structures. The reactivation of the inherited fault in gravitational faults create a gouge material exposed to an additional mechanical and chemical weathering as well as an increased of leaching. The displacement of these reactivated faults gets increasingly important around the area of the La Clapière landslide and this since 3.6?ka BP. In this study, mechanical analysis and grain size distributions were performed and these data were analysed according to their proximity the La Clapiere landslide and times of initiation of the landslide by ¹⁰Be dating. Triaxial test results show that the effective cohesion decreases and the effective angle of internal friction increases from the unweathered area to the weathered area. The whole distribution of the grain size indicates that the further the shear zone is open or developed, the further the residual material loses its finest particles. This paper suggests that the mechanical evolution along the reactivated fault is influenced by the leaching processes. For the first time, we can extract from these data temporal behaviour of the two main mechanical parameters (cohesion and angle of internal friction) from the beginning of the La Clapiere landslide initiation (3.6 ka BP) to now.  相似文献   

GSD‐1G and MPI‐DING Reference Glasses for In Situ and Bulk Isotopic Determination     

Klaus Peter Jochum  Steven A. Wilson  Wafa Abouchami  Marghaleray Amini  Jérome Chmeleff  Anton Eisenhauer  Ernst Hegner  Linda M. Iaccheri  Bruno Kieffer  Joachim Krause  William F. McDonough  Regina Mertz‐Kraus  Ingrid Raczek  Roberta L. Rudnick  Denis Scholz  Grit Steinhoefel  Brigitte Stoll  Andreas Stracke  Sonia Tonarini  Dominique Weis  Ulrike Weis  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2011,35(2):193-226

This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.  相似文献   

Initialisation and predictability of the AMOC over the last 50 years in a climate model   总被引：1，自引：1，他引：0  

Didier Swingedouw  Juliette Mignot  Sonia Labetoulle  Eric Guilyardi  Gurvan Madec 《Climate Dynamics》2013,40(9-10):2381-2399

The mechanisms involved in Atlantic meridional overturning circulation (AMOC) decadal variability and predictability over the last 50 years are analysed in the IPSL–CM5A–LR model using historical and initialised simulations. The initialisation procedure only uses nudging towards sea surface temperature anomalies with a physically based restoring coefficient. When compared to two independent AMOC reconstructions, both the historical and nudged ensemble simulations exhibit skill at reproducing AMOC variations from 1977 onwards, and in particular two maxima occurring respectively around 1978 and 1997. We argue that one source of skill is related to the large Mount Agung volcanic eruption starting in 1963, which reset an internal 20-year variability cycle in the North Atlantic in the model. This cycle involves the East Greenland Current intensity, and advection of active tracers along the subpolar gyre, which leads to an AMOC maximum around 15 years after the Mount Agung eruption. The 1997 maximum occurs approximately 20 years after the former one. The nudged simulations better reproduce this second maximum than the historical simulations. This is due to the initialisation of a cooling of the convection sites in the 1980s under the effect of a persistent North Atlantic oscillation (NAO) positive phase, a feature not captured in the historical simulations. Hence we argue that the 20-year cycle excited by the 1963 Mount Agung eruption together with the NAO forcing both contributed to the 1990s AMOC maximum. These results support the existence of a 20-year cycle in the North Atlantic in the observations. Hindcasts following the CMIP5 protocol are launched from a nudged simulation every 5 years for the 1960–2005 period. They exhibit significant correlation skill score as compared to an independent reconstruction of the AMOC from 4-year lead-time average. This encouraging result is accompanied by increased correlation skills in reproducing the observed 2-m air temperature in the bordering regions of the North Atlantic as compared to non-initialized simulations. To a lesser extent, predicted precipitation tends to correlate with the nudged simulation in the tropical Atlantic. We argue that this skill is due to the initialisation and predictability of the AMOC in the present prediction system. The mechanisms evidenced here support the idea of volcanic eruptions as a pacemaker for internal variability of the AMOC. Together with the existence of a 20-year cycle in the North Atlantic they propose a novel and complementary explanation for the AMOC variations over the last 50 years.  相似文献   

Cosmological origin of the lowest metallicity halo stars     

Xavier Hernandez †  Andrea Ferrara 《Monthly notices of the Royal Astronomical Society》2001,324(2):484-490

We explore the predictions of the standard hierarchical clustering scenario of galaxy formation, regarding the numbers and metallicities of PopIII stars that are likely to be found within our Galaxy today. By PopIII we refer to stars formed at large redshift ( z >4), with low metallicities ([ Z /Z_⊙]<−2.5) and in small systems (total mass ≲ 2×10⁸ M_⊙) that are extremely sensitive to stellar feedback, and which through a prescribed merging history end up becoming part of the Milky Way today. An analytic, extended Press–Schechter formalism is used to obtain the mass functions of haloes which will host PopIII stars at a given redshift, and which will end up in Milky Way sized systems today. Each of these is modelled as a mini-galaxy, with a detailed treatment of the dark halo structure, angular momentum distribution, final gas temperature and disc instabilities, all of which determine the fraction of the baryons that are subject to star formation. The use of new primordial metallicity stellar evolutionary models allows us to trace the history of the stars formed, and give accurate estimates of their expected numbers today and their location in L /L_⊙ versus T /K Hertzsprung–Russell (HR) diagrams. A first comparison with observational data suggests that the initial mass function (IMF) of the first stars was increasingly high-mass weighted towards high redshifts, levelling off at z ≳9 at a characteristic stellar mass scale m _s=10–15 M_⊙.  相似文献   

Results from the Eso Large Program on Transneptunian Objects and Centaurs     

Boehnhardt  Hermann  Barucci  Antonella  Delsanti  Audrey  De Bergh  Catherine  Doressoundiram  Alain  Romon  Jennifer  Dotto  Elisabetta  Tozzi  Gianpaolo  Lazzarin  Monica  Fornasier  Sonia  Peixinho  Nuno  Hainaut  Olivier  Davies  John  Rousselot  Philippe  Barrera  Luis  Birkle  Kurt  Meech  Karen  Ortiz  JoseLuis  Sekiguchi  Tomohiko  Watanabe  Jun-ichi  Thomas  Nick  West  Richard 《Earth, Moon, and Planets》2003,92(1-4):145-156

BVRI photometry of 107 TNOs and Centaurs establishes the range of spectral gradients to be between –5 to 55%/100 nm (with one exception). A cluster of very red Cubewanos is firmly identified in orbits of low inclination and eccentricity beyond 40 AU from the Sun. Further correlations between surface colours and dynamical parameters (inclination and perihelion distance) are suggested for Cubewanos and scattered disk objects, but lack complete confidence for their reality. Plutinos and Centaurs do not show any clear correlation between surface colours and orbital parameters. We present in this paper 12 spectra obtained in the visible region and nine of them for which we obtained also near infrared spectra up to 2.4 microns. A few other objects have been observed, but the data are still under reduction and analysis. The principal reported results obtained are: (i) a wide range of visible slopes; (ii) evidence for surface variations on 2001 PT₁₃; and (iii) possible detection of few percent of water ice (1999 TC_36}, 2000 EB₁₇₃, 1999 DE₉, 2001 PT₁₃, 2000 QC₂₄₃, 1998 SG₃₅).  相似文献   

Systems of colliding bodies in a gravitational field: Impact velocity,inelasticity and sizes distributions     

Sonia Clairemidi 《Earth, Moon, and Planets》1987,38(3):237-248

We study numerically the dynamical evolution of a system of colliding bodies. Collisions are inelastic and the coefficient of rebound is a function of the impat velocity. Various functions are used. The system can reach an equilibrium state characterized by a finite thickness independently on the sense of variation of the functions. Within the frame of various distributions of the body sizes we observe a segregation rather than equipartition of the kinetic energy of random motions.  相似文献   

Comparison of absolute photoelectron fluxes measured on AE-C and AE-E with theoretical fluxes and predicted and measured N₂ 2PG 3371Å volume emission rates     

S.P. Hernandez  J.P. Doering  V.J. Abreu  G.A. Victor 《Planetary and Space Science》1983,31(2):221-233

As part of the continuing effort to improve the accuracy of the absolute measurements of the ambient photoelectron flux in the thermosphere from the Atmosphere Explorer Satellite Photoelectron Spectrometer experiments (PES), we present a detailed comparison of experimental photoelectron fluxes from AE-C and AE-E together with theoretical calculations of the ambient flux for the same geophysical conditions. As an additional check, the various experimental and theoretical fluxes are used to calculate the expected N₂ 2PG (0, 0) volume emission rate expected at 3371Å and these results are compared to AE-C Visible Airglow Experimental (VAE) experimental results. The comparisons clearly show that because of spacecraft shielding of the sensor on AE-C, the agreement with AE-E spectra for similar geophysical conditions ranges from good when shielding is minimal to poor for severe shielding cases. The calculated fluxes are lower by approx. a factor of 1.5–2.0 in absolute magnitude than the AE-E or unshielded AE-C fluxes. The N₂ 2PG volume emission rates calculated from the measured ambient electron fluxes overestimate the measured VAE volume emission rates by 20–30% while those calculated from the theoretical fluxes underestimate the measured emission rate by typically 30%. These data suggest therefore that the measured AE-E fluxes are 20–30% high.  相似文献   

Expansion dynamics of deciduous rubber plantations in Xishuangbanna,China during 2000–2010     

Weili Kou  Jinwei Dong  Alexander J. Hernandez  Yuanwei Qin  Geli Zhang 《地理信息系统科学与遥感》2018,55(6):905-925

Monoculture rubber plantations have been replacing tropical rain forests substantially in Southern China and Southeast Asia over the past several decades, which have affected human wellbeing and ecosystem services. However, to the best of our knowledge on the extent of rubber plantation expansion and their stand ages is limited. We tracked the spatiotemporal dynamics of deciduous rubber plantations in Xishuangbanna, the second largest natural rubber production region in China, from 2000 to 2010 using time-series data from the Phased Array type L-band Synthetic Aperture Radar (PALSAR), Landsat, and Moderate Resolution Imaging Spectroradiometer (MODIS). We found that rubber plantations have been expanding across a gradient from the low-elevation plains to the high elevation mountains. The areas of deciduous rubber plantations with stand ages ≤5, 6–10, and ≥11-year old were ~1.2 × 10⁵ ha, ~0.8 × 10⁵ ha, and ~2.9 × 10⁵ ha, respectively. Older rubber plantations were mainly located in low-elevation and species-rich regions (500–900 m) and younger rubber trees were distributed in areas of relative high-elevation with fragile ecosystems. Economic and market factors have driven the expansion of rubber plantations, which is not only a threat to biodiversity and environmental sustainability, but also a trigger for climatic disasters. This study illustrates that the integration of microwave, optical, and thermal data is an effective method for mapping deciduous rubber plantations in tropical mountainous regions and determining their stand ages. Our results demonstrate the spatiotemporal pattern of rubber expansions over the first decade of this century.  相似文献   

Mantle and crustal processes in the magmatism of the Campania region: inferences from mineralogy, geochemistry, and Sr–Nd–O isotopes of young hybrid volcanics of the Ischia island (South Italy)     

Massimo D’Antonio  Sonia Tonarini  Ilenia Arienzo  Lucia Civetta  Luigi Dallai  Roberto Moretti  Giovanni Orsi  Mariachiara Andria  Alberto Trecalli 《Contributions to Mineralogy and Petrology》2013,165(6):1173-1194

Ischia, one active volcano of the Phlegraean Volcanic District, prone to very high risk, is dominated by a caldera formed 55 ka BP, followed by resurgence of the collapsed area. Over the past 3 ka, the activity extruded evolved potassic magmas; only a few low-energy explosive events were fed by less evolved magmas. A geochemical and Sr–Nd–O isotope investigation has been performed on minerals and glass from products of three of such eruptions, Molara, Vateliero, and Cava Nocelle (<2.6 ka BP). Data document strong mineralogical, geochemical, and isotopic heterogeneities likely resulting from mingling/mixing processes among mafic and felsic magmas that already fed the Ischia volcanism in the past. Detailed study on the most mafic magma has permitted to investigate its origin. The mantle sector below Ischia underwent subduction processes that modified its pristine chemical, isotopic, and redox conditions by addition of ≤1 % of sediment fluids/melts. Similar processes occurred from Southeast to Northwest along the Apennine compressive margin, with addition of up to 2.5 % of sediment-derived material. This is shown by volcanics with poorly variable, typical δ¹⁸O mantle values, and ⁸⁷Sr/⁸⁶Sr progressively increasing toward typical continental crust values. Multiple partial melting of this modified mantle generated distinct primary magmas that occasionally assimilated continental crust, acquiring more ¹⁸O than ⁸⁷Sr. At Ischia, 7 % of Hercynian granodiorite assimilation produced isotopically distinct, K-basaltic to latitic magmas. A SW–NE regional tectonic structure gave these magmas coming from large depth the opportunity to mingle/mix with felsic magmas stagnating in shallower reservoirs, eventually triggering explosive eruptions.  相似文献