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21.
The detection and characterisation of domains of intersecting fractures are important goals in several disciplines of current interest, including exploration and production of unconventional reservoirs, nuclear waste storage, CO2 sequestration, and groundwater hydrology, among others. The objective of this study is to propose a theoretical framework for quantifying the effects of fracture intersections on the frequency‐dependent elastic properties of fluid‐saturated porous and fractured rocks. Three characteristic frequency regimes for fluid pressure communication are identified. In the low‐frequency limit, fractures are in full pressure communication with the embedding porous matrix and with other fractures. Conversely, in the high‐frequency limit, fractures are hydraulically isolated from the matrix and from other fractures. At intermediate frequencies, fractures are hydraulically isolated from the matrix porosity but can be in hydraulic communication with each other, depending on whether fracture sets are intersecting. For each frequency regime, the effective stiffness coefficients are derived using the linear‐slip theory and anisotropic Gassmann equations. Explicit mathematical expressions for the two characteristic frequencies that separate the three frequency regimes are also determined. Theoretical predictions are then applied to two synthetic 2D samples, each containing two orthogonal fracture sets: one with and another without intersections. The resulting stiffness coefficients, Thomsen‐style anisotropy parameters, and the transition frequencies show good agreement with corresponding numerical simulations. The theoretical results are applicable not only to 2D but also to 3D fracture systems and are amenable to being employed in inversion schemes designed to characterise fracture systems.  相似文献   
22.
Quantifying the effects of pore-filling materials on elastic properties of porous rocks is of considerable interest in geophysical practice. For rocks saturated with fluids, the Gassmann equation is proved effective in estimating the exact change in seismic velocity or rock moduli upon the changes in properties of pore infill. For solid substance or viscoelastic materials, however, the Gassmann theory is not applicable as the rigidity of the pore fill (either elastic or viscoelastic) prevents pressure communication in the pore space, which is a key assumption of the Gassmann equation. In this paper, we explored the elastic properties of a sandstone sample saturated with fluid and solid substance under different confining pressures. This sandstone sample is saturated with octadecane, which is a hydrocarbon with a melting point of 28°C, making it convenient to use in the lab in both solid and fluid forms. Ultrasonically measured velocities of the dry rock exhibit strong pressure dependency, which is largely reduced for the filling of solid octadecane. Predictions by the Gassmann theory for the elastic moduli of the sandstone saturated with liquid octadecane are consistent with ultrasonic measurements, but underestimate the elastic moduli of the sandstone saturated with solid octadecane. Our analysis shows that the difference between the elastic moduli of the dry and solid-octadecane-saturated sandstone is controlled by the squirt flow between stiff, compliant, and the so-called intermediate pores (with an aspect ratio larger than that of compliant pore but much less than that of stiff pores). Therefore, we developed a triple porosity model to quantify the combined squirt flow effects of compliant and intermediate pores saturated with solid or viscoelastic infill. Full saturation of remaining stiff pores with solid or viscoelastic materials is then considered by the lower embedded bound theory. The proposed model gave a reasonable fit to the ultrasonic measurements of the elastic moduli of the sandstone saturated with liquid or solid octadecane. Comparison of the predictions by the new model to other solid substitution schemes implied that accounting for the combined effects of compliant and intermediate pores is necessary to explain the solid squirt effects.  相似文献   
23.
The Geochemical Atlas of Slovak Republic (49,036 km2) at a scale of 1 : 1,000,000 was compiled during 1991–1995 together with maps of associated geochemical and ecological features at a scale of 1 :200,000. Investigations were aimed at the evaluation of concentrations and distributions of Al, As, Ba, Be, Ca, Ce, Co, Cd, Cs, Cr, Cu, Fe, Ga, Hg, K, La, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Rb, Sb, Se, Sn, Sr, Th, U, V, W, Y, Zn, Zr in groundwater (16,359 samples), stream sediments (24,422 samples), rocks (3839 samples), soils (9892 samples from 4946 profiles; A and C horizons of each profile were sampled) and forest biomass (the foliage of the forest tree species from 3063 plots was sampled). In groundwater field measurements of temperature, pH, conductivity, dissolved O2, acidity, alkalinity were done. The evaluation was oriented to the natural radioactivity of the Slovak territory as follows: rocks (K, U, Th, Utot and dose rate, 15,573 reference spectrometric points), radon risk and water (Unat, 226Ra, 222Rn; 5271 samples). The main objective of the Geochemical Atlas was to construct single-component maps showing concentrations of chemical elements, compounds and measured parameters in the researched media of Slovakia at a scale of 1 : 1,000.000 and to create interactive databases of chemical composition and/or measured parameters of groundwater, biomass, rocks, soils, stream sediments and natural radioactivity, for the entire territory of the Slovak Republic. The single-component maps are not constructed in the part ‘Rocks’, where all the main rocks types of Slovakia are presented in the ‘Map of lithogeochemical rock types of Slovakia at a scale of 1: 500,000’. The edition of six atlases has been planned. In 1997 the first three atlases will appear (Groundwater, Biomass, Natural Radioactivity). Publishing of last three atlases (Rocks, Soils, Stream Sediments) is planned for 1998. Since the analytical works on stream sediments were finished during 1997, it was not possible to present here the results of that part of the Geochemical Atlas.  相似文献   
24.
Acquisition and registration of terrestrial 3D laser scans is a fundamental task in mapping and modeling of cities in three dimensions. To automate this task marker-free registration methods are required. Based on the existence of skyline features, this paper proposes a novel method. The skyline features are extracted from panoramic 3D scans and encoded as strings enabling the use of string matching for merging the scans. Initial results of the proposed method in the old city center of Bremen are pre-sented.  相似文献   
25.
Based on the ground survey of total-field magnetic data at 53 sites, which recorded a time-series over the interval 2003–2005, the core field + long wavelength lithospheric field over the middle-northern Croatia region was calculated. The area of the survey was 18900 km2, an average distance between the neighbouring sites being 12 km. The results were reduced to 2004.5 epoch. This “normal” total-field was estimated using the firstorder Taylor polynomial as a function of geographic coordinates, and the polynomial coefficients were calculated with three methods of adjustment: simple and weighted least squares fits and adjustment according to the most frequent value. The stability of the normal field was tested using the Monte Carlo-type test, by decreasing the input data set in each adjustment (up to 90%). All obtained field residuals (measured-“normal”) were mutually compared, as well as fit coefficients of the Taylor polynomials. The residual values indicate the presence of shorter-wavelength anomalies, specifically three major residual anomalies were found (−106 nT, 74 nT and 57 nT). The geostatistical analysis of the ground survey data and the normal field residuals (respectively), using the median absolute deviation method, was further conducted in order to evaluate the calculated anomalies. The geological situation around the anomalies derived by the median absolute deviation method, and around the normal field residual anomalies, is given. The correlation was found between higher value anomalies of the normal field residuals, and shallow volcanic rocks and oil field, respectively.  相似文献   
26.
Surface sediments (fraction <63 μm) from the source to the mouth of the Rječina, short (18.3 km) karst allogenic river in Croatia, which is an important source of drinking water, were studied to investigate their mineral (by XRD) and chemical (by ICP-MS) composition to check possible anthropogenic influence at the lower course due to paper industry and mills, and in the prodelta area from untreated municipal sewage and the large harbor of Rijeka town. In all analyzed sediment samples and in the sandstone source, rock quartz is a major mineral, while feldspar and mica group minerals are less abundant. Chlorite is a minor or trace mineral in all samples. Calcite and dolomite are abundant in the river prodelta, reflecting changes in bedrock lithology from flysch to carbonates. In river sediments, Fe is the most abundantly analyzed element, while Ca is the most abundant in prodelta sediments. Concentrations of Al, Mn, Ni, Cr, Co, La and Nd decrease downstream, while Mg, S, Na, B, Pb, Zn, As, Sn, U, Mo, Hg and Ag have relatively higher concentration in prodelta sediments. The results are compared with sediments of other rivers in the area: Raša, Rižana and Dragonja, as well as with those of the Rosandra Creek (Italy). Sediments in the Raša River showed similar behavior as those in the Rječina, as the highest concentration of metals was found in the restricted upper part of the estuary, characterized by rapid deposition of clay particles and terrestrial sedimentary organic matter. The comparison also showed that the most contaminated were the sediments from the Rižana, followed by those from the Rječina and Rosandra Creek, which had similar results. Among the studied elements, As was present in all sediment samples at concentrations >6 ppm that might have the lowest toxic effects. At the lower Rječina and in prodelta sediments, Pb was also present at slightly elevated concentrations (>31 ppm) that could cause such effects. Concentrations of Zn in the prodelta correspond to those occurring in moderately polluted sediments (90–200 ppm). In the prodelta sediments, Hg is slightly below toxicity threshold (1 ppm), while Ag is present at toxicity threshold (0.5 ppm) or close to it. Rječina River could act as a good illustrative example for behavior of toxic metals in allogenic karstic rivers, in which accumulation of anthropogenically introduced pollutants usually occurs in their estuaries, as a result of transport and deposition of fine particles.  相似文献   
27.
Analysis of E||X-polarized optical absorption spectra of natural olivines of various origin in the range of electronic spin-allowed dd-transitions of Fe2+ evidences that in some crystals, there is a weak ordering of Fe2+ as in M1, as in M2 structural sites. The samples of three different depth facies seem showing a vague tendency of lowering of k D -values from spinel-pyroxene (Sp-Px) through graphite-pyrope (G-Py) to diamond-pyrope (D-Py) facies, but the statistics are too poor (24 samples only) to be certain of it. Weak relations between Mg, Fe2+-distribution and iron content were found for the samples of Sp-Px- and G-Py-facies, while there is practically no one for those of the deepest D-Py facie.  相似文献   
28.
The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, a rare copper selenite chloride from volcanic fumaroles of the Great fissure Tolbachik eruption (Kamchatka peninsula, Russia), has been solved by direct methods and refined to R 1?=?0.044 on the basis of 2720 unique observed reflections. The mineral is orthorhombic, Pnma, a?=?17.769(7), b?=?6.448(3), c?=?10.522(4) Å, V?=?1205.6(8) Å3, Z?=?4. The The CuOmCln coordination polyhedra share edges to form tetramers that have 'additional' O1 and O2 atoms as centers. The O1Cu4 and O2Cu4 tetrahedra share common Cu atoms to form [O2Cu5]6+ sheets. The SeO3 groups and Cl atoms are adjacent to the [O2Cu5]6+ sheets to form complex layers parallel to (100). The Na+ cations are located in between the layers. A review of mixed-ligand CuOmCln coordination polyhedra in minerals and inorganic compounds is given. There are in total 26 stereochemically different mixed-ligand Cu-O-Cl coordinations.  相似文献   
29.
The surfaces of salt diapirs in the Zagros Mountains are mostly covered by surficial deposits, which significantly affect erosion rates, salt karst evolution, land use and the density of the vegetation cover. Eleven salt diapirs were selected for the study of surficial deposits in order to cover variability in the geology, morphology and climate in a majority of the diapirs in the Zagros Mountains and Persian Gulf Platform. The chemical and mineralogical compositions of 80 selected samples were studied mainly by X-ray powder diffraction and X-ray fluorescence. Changes in salinity along selected vertical profiles were studied together with the halite and gypsum distribution. The subaerial residuum formed from minerals and rock detritus released from the dissolved rock salt is by far the most abundant material on the diapirs. Fluvial sediments derived from this type of residuum are the second most common deposits found, while submarine residuum and marine sediments have only local importance. The mineralogical/chemical composition of surficial deposits varies amongst the three end members: evaporite minerals (gypsum/anhydrite and minor halite), carbonates (dolomite and calcite) and silicates-oxides (mainly quartz, phyllosilicates, and hematite). Based on infiltration tests on different types of surficial deposits, most of the rainwater will infiltrate, while overland flow predominates on rock salt exposures. Recharge concentration and thick accumulations of fine sediment support relatively rich vegetation cover in some places and even enable local agricultural activity. The source material, diapir relief, climatic conditions and vegetation cover were found to be the main factors affecting the development and erosion of surficial deposits. A difference was found in residuum type and landscape morphology between the relatively humid NW part of the studied area and the arid Persian Gulf coast: In the NW, the medium and thick residuum seems to be stable under current climatic conditions. Large sinkholes and blind valleys with sinking streams are common. On other diapirs, the original thick residuum is undergoing erosion and the new morphology is currently represented by salt exposures and badland-like landscapes or by fields of small sinkholes developed in the thin residuum. Models for evolution of the subaerial residuum and the diapir landscape/morphology are described in this paper. While the thick residuum with vegetation has very low erosion rates, the salt exposures and thin residuum are eroded rapidly. During wet periods (e.g. early Holocene), the diapirs rose and salt glaciers expanded as the influx of salt mass was much faster compared to erosion. After the onset of an arid climate, c. 6 ka BP, the rising of the some diapir surfaces decreased or even reversed due to acceleration of erosion thanks to vegetation degradation and changes in the residuum type and thickness.  相似文献   
30.
Benthic faunal assemblages were analysed from 47 stations in the central and southern parts of the Barents Sea, together with sedimentary and water column parameters, daily ice records and modelled integrated primary productivity. Sampling spanned areas influenced by Atlantic Water (AW) to those lying under Arctic Water (ArW), and included stations with mixed water masses. Ice cover suppressed water column productivity in the northern areas. Three main faunal groups were identified, based on similarity of numerical faunal composition. The northern and southern faunal groups were separated by the northernmost penetration of AW in the bottom water and the third group, the Hopen group, was influenced by modified bank water. Faunal abundances were significantly higher within the southern faunal group relative to the northern group, but the numbers of taxa present were similar. The particularly rich fauna of the Hopen group reflected sediment heterogeneity and tight pelagic–benthic coupling. These results suggest that a retreat and thinning of the ice cover in the Barents Sea likely will result in the northern parts of the Barents Sea becoming more Atlantic in character, with a higher productivity at the sea floor.  相似文献   
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