Competitive Sorption of Antimony with Zinc,Nickel, and Aluminum in a Seaweed Based Fixed‐bed Sorption Column     

Adil Bakir  Peter McLoughlin  Syed A. M. Tofail  Eddy Fitzgerald 《洁净——土壤、空气、水》2009,37(9):712-719

The removal of heavy metals such as Ni(II), Zn(II), Al(III), and Sb(III) from aqueous metal solutions was investigated using novel, cost effective, seaweed derived sorbents. Studies with a laboratory scale fixed‐bed sorption column, using a seaweed waste material (referred to as waste Ascophyllum product (WAP)) from the processing of Ascophyllum nodosum as biosorbent, demonstrated high removal efficiencies (RE) for a variety of heavy metals including Ni(II), Zn(II) and Al(III), with 90, 90 and 74% RE achieved from initial 10 mg/L metal solutions, respectively. The presence of Sb(III) in multi component metal solutions suppressed the removal of Ni(II), Zn(II) and Al(III), reducing the RE to 28, 17 and 24%, respectively. The use of Polysiphonia lanosa as a biosorbent showed a 67% RE for Sb(III), both alone and in combination with other metals. Potentiometric and conductometric titrations, X‐ray photoelectron and mid‐infrared spectroscopic analysis demonstrated that carboxyl, alcohol, sulfonate and ether groups were heavily involved in Sb(III) binding by P. lanosa. Only carboxyl and sulfonate groups were involved in Sb(III) binding by WAP. Furthermore, a greater amount of weak acidic groups (mainly carboxylic functions) were involved in Sb(III) binding by P. lanosa, compared to WAP which involved a greater concentration of strong acidic groups (mainly sulfonates).  相似文献   

A comprehensive study on the surface chemistry of particulate matter collected from Jeddah,Saudi Arabia     

Asim Jilani  Syed Zajif Hussain  Mohd Hafiz Dzarfan Othman  Usama Zulfiqar  Muhammad Bilal Shakoor  Imran Ullah Khan  Javed Iqbal  Attieh A. Al-Ghamdi  Ahmed Alshahrie 《Journal of Atmospheric Chemistry》2018,75(3):271-283

In this work, the X-ray Photoelectron Spectroscopy (XPS) technique is utilized to analyze the surface chemical composition of particulate matter (PM) which was collected from various locations at Jeddah, Saudi Arabia. The main elements found on the surface of PM are carbon (C), oxygen (O) and silicon (Si) with combined percentage of 89.4–94.9 while traces of nitrogen (N), calcium (Ca), aluminum (Al), sodium (Na), chlorine (Cl), manganese (Mg), and sulfur (S) were also present. The analyzed XPS chemical state of C, O and Si was further used to determine their bonding with other elements occurring over the surface of PM. Carbon was found in the form of carbides (18.86%), fluorides (2.39%) and carbonates (78.75%); oxygen was observed as oxides (21.05%) and hydroxides (73.42%) of other metals; and silicon was detected as silicones (12.16%), nitrides (82.53%) and silicates (5.25%). The particle size of a PM is also of great concern for health issues, and thus has been investigated by the Field Emission Scanning Electron Microscope (FESEM). The Energy Dispersive X-ray Spectroscopy (EDS) was employed for cross verification of detected elements by XPS.  相似文献   

Integrated geo-microbial and trace metal anomalies for detection of hydrocarbon microseepage in Ahmedabad block of Cambay basin,India     

M. A. Rasheed  P. L. Srinivasa Rao  Annapurna Boruah  Syed Zaheer Hasan  Bougi Mohamoud Mohamed Seddik  Disha Pandey  T. Harinarayana 《Journal of the Geological Society of India》2016,88(4):433-439

The aim of the present work is to define the geo-microbial signatures along with trace metals, and to investigate whether the geo-microbial anomalies have correlation with trace metal anomalies in Ahmedabad block of Cambay basin. The surface geochemical techniques are based on seepage of light hydrocarbon gases from the oil and gas pools to the shallow surface and can bring up near-surface oxidation reduction zones that favor the development of a diverse array of chemical and mineralogical changes. The paper reports the role of hydrocarbon microseepage in surface alterations of trace metal concentrations and hydrocarbon oxidizing bacteria and its interrelationship. For the purpose a total of 90 soil samples are collected in grid pattern of 2 x 2 km interval. The paper reports the chemical alterations associated with trace metals in soils that are related to hydrocarbon microseepages above some of the major oil and gas fields of this petroliferous region. The concentrations of V (0 to149 ppm), Cr (2 to 192 ppm), Cu (4 to 171 ppm), Se (98 to 440 ppm), Zn (56 to 1215 ppm) are obtained. It is observed that the concentrations of trace elements are tremendously increased when they are compared with their normal concentrations in soils. In this study the hydrocarbon oxidizing bacterial counts ranged between 1.0 x 10³ and 1.59 x 10⁶ cfu/g of soil sample respectively. The attempt has made for the first time, which revealed good correlation as both these anomalies are found as apical in relation. Integrated studies between trace elements and hydrocarbon oxidizing bacterial anomalies showed positive correlation with existing oil and gas wells in the study area.  相似文献   

Elimination of Interferences in the Determination of Palladium,Platinum and Rhodium Mass Fractions in Moss Samples using ICP‐MS/MS          下载免费PDF全文

Terhi Suoranta  Syed N. H. Bokhari  Thomas Meisel  Matti Niemelä  Paavo Perämäki 《Geostandards and Geoanalytical Research》2016,40(4):559-569

Moss samples (Pleurozium schreberi) exposed to traffic‐related emission of Pd, Pt and Rh were analysed in this study. Successful elimination of interferences was achieved in the determination of Pd, Pt and Rh mass fractions in these samples using inductively coupled plasma‐tandem mass spectrometry (ICP‐MS/MS). Based on the results, a reliable determination of Pd, Pt and Rh mass fractions in microwave‐digested moss samples was obtained using ammonia (10% NH₃ in He) in the collision/reaction cell when ¹⁰³Rh was measured either on‐mass (103→103) or with mass‐shift (103→171) and mass‐shifts for ¹⁰⁸Pd (108→159) and ¹⁹⁵Pt (195→229) were used. The ICP‐MS/MS procedure was validated using BCR‐723 (road dust) as a reference material. In addition, a good agreement between the ICP‐MS/MS results and the results obtained with cloud point extraction and quadrupole ICP‐MS was observed for the moss samples.  相似文献   

Petrophysical parameters and modelling of the Eocene reservoirs in the Qadirpur area,Central Indus Basin,Pakistan: implications from well log analysis     

Miraj Khan  Mohammad Arif  Nowrad Ali  Mohammad Yaseen  Ammar Ahmed  Syed Mamoon Siyar 《Arabian Journal of Geosciences》2016,9(5):425

The Eocene rock units of the Qadirpur field, Central Indus Basin (Pakistan), are investigated petrophysically for their detailed reservoir characterization. The different petrophysical parameters determined include the following: true resistivity, shale volume, total porosity, effective porosity, density and neutron porosity, water and hydrocarbon saturation, bulk volume of water, lithology, gas effect, P-wave velocity, movable hydrocarbon index and irreducible water saturation and integrated with different cross-plots. The Eocene reservoirs are excellent with high effective porosity (2–32 %) and hydrocarbon saturation (10–93 %). Among these, the Sui Upper Limestone is an overall a poor reservoir; however, it has some hydrocarbon-rich intervals with high effective porosity and better net pay. All the net pay zones identified show low and variable shale volume (5–30 %). The secondary porosity has added to the total and effective porosities in these reservoirs. The main contributors to the porosity are the chalky, intercrystalline and vuggy/fracture types. The thickness of the reservoirs zones ranges from 4.5 to 62 m. These reservoirs are gas-producing carbonates with almost irreducible water saturation (0.002–0.01) and are likely to produce water-free hydrocarbons. The lower values of moveable hydrocarbon index (0.07–0.9) show that the hydrocarbons are moveable spontaneously to the well bore. The proposed correlation model shows that the reservoirs have an inclined geometry and are a part of an anticlinal trap.  相似文献   

Determination of summer monsoon onset and its related large-scale circulation characteristics over Pakistan   总被引：1，自引：1，他引：0  

M. Latif  F. S. Syed 《Theoretical and Applied Climatology》2016,125(3-4):509-520

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Lunar concrete: Prospects and challenges     

Anwar Khitab  Waqas Anwar  Imran Mehmood  Syed Minhaj Saleem Kazmi  Muhammad Junaid Munir 《Astronomy Reports》2016,60(2):306-312

The possibility of using concrete as a construction material at the Moon surface is considered. Dissimilarities between the Earth and the Moon and their possible effects on concrete are also emphasized. Availability of constituent materials for concrete at lunar surface is addressed. An emphasis is given to two types of materials, namely, hydraulic concrete and sulfur concrete. Hydraulic concrete necessitates the use of water and sulfur concrete makes use of molten sulfur in lieu of cement and water.  相似文献   

Seasonal variation in the trawl codend selectivity of picarel (Spicare smaris)     

Ozbilgin  Huseyin; Tosunoglu  Zafer; Tokac  Adnan; Metin  Gulnur 《ICES Journal of Marine Science》2007,64(8):1569-1572

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Lithologic mapping of a forested montane terrain from Landsat 5 TM image     

Taufique H. Mahmood  Khaled Hasan  Syed Humayun Akhter 《国际地球制图》2019,34(7):750-768

Thick forest cover and poor infrastructures are the major hindrances for detailed lithologic mapping in an inaccessible montane landscape. To overcome these limitations, we utilize a Landsat 5 TM image to map lithology using vegetation and drainage pattern as an indicator of underlying rock types in a heavily forested region of the Chittagong Hill Tracts area located in southeastern Bangladesh. We use supervised and unsupervised classifiers for a vegetation-based approach while on-screen digitization is used for drainage patterns-based mapping. Field observations were used for mapping lithology and evaluating accuracy. Overall, our results agree well with the current geologic map and improve it by providing a more spatially detailed distribution of the sandstone and shale. The performances of all approaches are good at the inner and outer flanks of anticlines located in the study area while the drainage pattern mapping performs best at the mid-flank area.  相似文献   

Propagation of Coronal Mass Ejections Observed During the Rising Phase of Solar Cycle 24     

M. Syed Ibrahim  P. K. Manoharan  A. Shanmugaraju 《Solar physics》2017,292(9):133

In this study, we investigate the interplanetary consequences and travel time details of 58 coronal mass ejections (CMEs) in the Sun–Earth distance. The CMEs considered are halo and partial halo events of width \({>}\,120\)°. These CMEs occurred during 2009?–?2013, in the ascending phase of the Solar Cycle 24. Moreover, they are Earth-directed events that originated close to the centre of the solar disk (within about \(\pm30\)° from the Sun’s centre) and propagated approximately along the Sun–Earth line. For each CME, the onset time and the initial speed have been estimated from the white-light images observed by the LASCO coronagraphs onboard the SOHO space mission. These CMEs cover an initial speed range of \({\sim}\,260\,\mbox{--}\,2700~\mbox{km}\,\mbox{s}^{-1}\). For these CMEs, the associated interplanetary shocks (IP shocks) and interplanetary CMEs (ICMEs) at the near-Earth environment have been identified from in-situ solar wind measurements available at the OMNI data base. Most of these events have been associated with moderate to intense IP shocks. However, these events have caused only weak to moderate geomagnetic storms in the Earth’s magnetosphere. The relationship of the travel time with the initial speed of the CME has been compared with the observations made in the previous Cycle 23, during 1996?–?2004. In the present study, for a given initial speed of the CME, the travel time and the speed at 1 AU suggest that the CME was most likely not much affected by the drag caused by the slow-speed dominated heliosphere. Additionally, the weak geomagnetic storms and moderate IP shocks associated with the current set of Earth-directed CMEs indicate magnetically weak CME events of Cycle 24. The magnetic energy that is available to propagate CME and cause geomagnetic storm could be significantly low.  相似文献